JPS5945352A - Novel flame-retardant resin composition - Google Patents
Novel flame-retardant resin compositionInfo
- Publication number
- JPS5945352A JPS5945352A JP15704782A JP15704782A JPS5945352A JP S5945352 A JPS5945352 A JP S5945352A JP 15704782 A JP15704782 A JP 15704782A JP 15704782 A JP15704782 A JP 15704782A JP S5945352 A JPS5945352 A JP S5945352A
- Authority
- JP
- Japan
- Prior art keywords
- melem
- melon
- resin composition
- retardant resin
- polyamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 7
- 239000011342 resin composition Substances 0.000 title claims description 3
- 239000004952 Polyamide Substances 0.000 claims abstract description 5
- 229920002647 polyamide Polymers 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 3
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 abstract description 17
- 229920000877 Melamine resin Polymers 0.000 abstract description 8
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract description 8
- 229920005989 resin Polymers 0.000 abstract description 7
- 239000011347 resin Substances 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- 244000241257 Cucumis melo Species 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 238000001354 calcination Methods 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 241000219112 Cucumis Species 0.000 description 17
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 17
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 17
- 239000002253 acid Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 229920006122 polyamide resin Polymers 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- -1 isophthalic acid Chemical class 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241000951471 Citrus junos Species 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- CJYXCQLOZNIMFP-UHFFFAOYSA-N azocan-2-one Chemical compound O=C1CCCCCCN1 CJYXCQLOZNIMFP-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000004455 differential thermal analysis Methods 0.000 description 1
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- XUWHAWMETYGRKB-UHFFFAOYSA-N piperidin-2-one Chemical compound O=C1CCCCN1 XUWHAWMETYGRKB-UHFFFAOYSA-N 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- KLNPWTHGTVSSEU-UHFFFAOYSA-N undecane-1,11-diamine Chemical compound NCCCCCCCCCCCN KLNPWTHGTVSSEU-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
本発明はポリアミドに対し７．メレム、メロンを１棟−
ｊたＶｉ２柚以上配合して成る新規な難燃性樹脂組成物
に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention provides 7. Melem, one melon -
The present invention relates to a novel flame-retardant resin composition containing at least 2 yuzu and Vi2.
近年、火災時の安全性の見地から合成Ｉｆ ｊｌ？＜に
対する難燃性の要求は益々高１っており、各種の合成樹
脂に対して数多くの離燃化剤が提案されている。In recent years, synthetic If jl? The demand for flame retardancy is becoming higher and higher, and a large number of flame retarding agents have been proposed for various synthetic resins.
本発明者はポリアミドに対する難燃化剤について、鋭意
研死した結果、メラミンを高温で焼成することによって
得られる式（１）で示さｎるメレム、メロンの１株また
は２種以上配合してなる組成物は合成樹脂の難燃化に対
して大きく寄与することを見出し２本発明に至ったもの
である。As a result of extensive research into flame retardants for polyamides, the present inventors have found that they contain one or more strains of melem and melon represented by the formula (1) obtained by firing melamine at high temperatures. It was discovered that the composition greatly contributes to flame retardation of synthetic resins, leading to the present invention.
式（１）の構造を有するメレムの製造については。Regarding the production of melem having the structure of formula (1).
メラばンを４００〜５００℃で数時間焼成することによ
り得る仁とができ、メロンの製造については撞木らの文
献（工業化学雑誌６６．８０４ページ（１９６３）
） に記載されているが。The melon kernels are obtained by baking melon at 400-500°C for several hours, and the production of melon is described in the literature by Maki et al.
).
メラミンｆ：５００〜５５０℃で脱アンモニアが認めら
ｎ−１ｔくなるまで焼成することにより、容易に得るこ
とができる。Melamine f: Can be easily obtained by firing at 500 to 550°C until no deammonia is observed and n-1t is reached.
示差熱分析に上ると分解１品度ｒまメレムは５００Ｖ以
上、メロンは６０ ［］ ’Ｃ以上であり、いずｆＬも
有機化合物としては極めて高い熱安定性金石している。Differential thermal analysis shows that the decomposition level of melem is over 500 V, and that of melon is over 60[]'C, indicating that IzufL has extremely high thermal stability as an organic compound.
また、メレム、メロンの窒素含有量はいずれも６０％以
上と尚く不燃性化合物である。Furthermore, both melem and melon have a nitrogen content of 60% or more, and are nonflammable compounds.
近年寸すまず市機能性樹脂の開発は盛んであり、 １１
１１１熱性につい−（もより１′、−ｆ＋ （晶に而・
１性をもつことが要求さ才ｔ、それに応じて成型加工Ｙ
黒度もより高温ＩＩＩ Ｋシフトしている。In recent years, the development of functional resins has been active, and 11
111 About fever -(more than 1', -f+ (crystal)
It is required to have one property, and the molding process is done accordingly.
The blackness has also shifted to higher temperatures.
ある棟の有機系難燃化剤については、高温の成型加工温
度、又商渦ふん囲気Ｆにおいて分解を起すものがあり、
！色の発生や製品物性の低下などをもたらすことがある
ため、おのずから便用湯度に制限かも反らさ１−る。Some of the organic flame retardants in one building decompose at high molding temperatures and in the commercial vortex surrounding air F.
! Since it may cause color generation and deterioration of product properties, there may be a natural limit to the hot water temperature for toilet use.
一方、 本発明によるメレム、メロンについては有機系
でありながら極めて高温まで安定であり高温のふん囲気
化、筒編の成型加工Ｔ都度でも一切分解を起さない。On the other hand, although melem and melon according to the present invention are organic, they are stable up to extremely high temperatures and do not decompose at all even during high-temperature gasification and tube knitting processing.
すぐ扛た難燃性伺与効来とともに高温安定性に優ｎるこ
とか本発明のメレム、メロンの大きな特徴である。The melem and melon of the present invention are characterized by their excellent flame retardant properties and excellent high temperature stability.
本発明において使用されるポリアミド樹脂としては、ε
−カグロラクタム、アミノカプロン酸、エナントラクタ
ム、７−アミツヘゾタン酸。The polyamide resin used in the present invention includes ε
-caglolactam, aminocaproic acid, enantholactam, 7-amitzhezotanic acid.
１１−アミノウンデカン酸、９−アミノノプン酸。11-aminoundecanoic acid, 9-aminopenoic acid.
α−ピロリドン、α−ピペリドンなどの重合体。Polymers such as α-pyrrolidone and α-piperidone.
ヘキサ−メチレンジアミン、ノナメチレンジアミン、ウ
ンデカメチレンジアミン、ドデカメチレンジアミン、メ
タキシリレンジアミンなどのジアミンとテレフタル酸、
イソフタル酸、−γジピン酸、セバシン酸、ドデカンニ
塩基酸、ゲルタール酸などのジカルボン酸と重縮合せし
めて得られる重合体重たはこ扛らの共重合体１例えはナ
イロン４．６．７．８．１１．１２．６＋６．６・９，
６゜１０．６．１１，６・１２，６’［’、６／６・６
．６／１２゜などがあげらｎる。 これらのポリアミ
ド和↑脂は、２種以上併用してもよいし、その他の樹Ｂ
ＦＩ例えばポリエステル、ポリオレフィン、ＡＢＳ。Diamines such as hexamethylene diamine, nonamethylene diamine, undecamethylene diamine, dodecamethylene diamine, metaxylylene diamine and terephthalic acid,
A copolymer of polymers obtained by polycondensation with dicarboxylic acids such as isophthalic acid, -gamma dipic acid, sebacic acid, dodecane dibasic acid, and geltaric acid.An example is nylon 4.6.7.8 .11.12.6+6.6・9,
6゜10.6.11,6・12,6'[',6/6・6
．． Examples include 6/12°. Two or more of these polyamide ↑ resins may be used in combination, or other resins B
FI such as polyester, polyolefin, ABS.
Ａｓ々どを含有していてもよい。It may also contain As.
ポリアミド樹脂に難燃性を付与させる方法については、
これまでメラミン、シアヌレート。For information on how to impart flame retardancy to polyamide resin,
Until now, melamine and cyanurate.
メラミン・シアヌレート、メラム等ヲチΣ刀０する方法
が提案されている。しかし、一般にポリアミド樹脂の成
形加工温度に、２５０℃前後と高いために、これらの添
加物は何れも一部列華あるいは熱分解を起したり、金型
にくもりを生じやすいなど９作業性及び成形上に難点が
あった。Methods such as melamine cyanurate and melam have been proposed. However, since the molding temperature of polyamide resin is generally high, around 250°C, these additives may cause some oxidation or thermal decomposition, and may cause cloudiness in the mold. There was a problem with molding.
ところが、ポリアミド樹脂にメレム、メロンを配合する
ことにより、難燃性を付与させる方法についてはメレム
、メロン自体が４００℃以上という高温で焼成すること
により得られる物質である為に極めて耐熱性が高く、前
記した成形加工温度においては、全く変化が起らない。However, as for the method of imparting flame retardancy by blending melem and melon into polyamide resin, melem and melon themselves have extremely high heat resistance as they are obtained by baking at high temperatures of over 400℃. , no change occurs at the above-mentioned molding temperature.
寸た。金型のくもりも非常（め生じにくい。Dimensions. The mold is also very cloudy (hard to cause cloudiness).
これらの点が本発明において大きな特徴である。These points are major features of the present invention.
メレム、メロンの配合量について説明すると樹脂に対し
０．５〜６０重量％、好ましくｒ１５〜２０重鳳％であ
り、メレム、メロンを単独あるいは併用してもよい。ま
た場合によっては、他の難燃化剤であるメラミン、シア
ヌール酸、メラミン、シアヌレート、メラムなど公知の
化合物と併用してもよい。 配合量がこれより少ないと
難燃化効果に乏しく、これより多いと難燃化効果はあっ
ても、脆化する等の欠点がでてくることにより２本来の
性質がそこなわれるので好ましくない。 本難燃化剤の
使用に際しては通常の飽加剤である滑剤、染料、顔料や
ガラス繊維、炭素繊維等の充填剤が添加さ扛ても差しつ
かえない。The blending amount of melem and melon is 0.5 to 60% by weight, preferably 15 to 20% by weight, based on the resin, and melem and melon may be used alone or in combination. In some cases, it may be used in combination with other flame retardants such as melamine, cyanuric acid, melamine, cyanurate, melam, and other known compounds. If the amount is less than this, the flame retardant effect will be poor, and if it is more than this, even if there is a flame retardant effect, disadvantages such as embrittlement will occur and the two original properties will be impaired, so it is not preferable. . When using this flame retardant, ordinary saturants such as lubricants, dyes, pigments, and fillers such as glass fibers and carbon fibers may be added.
次に、実施例に即して発明を更に詳しく説明する。Next, the invention will be explained in more detail based on examples.
実施例１，２，３，４．５
ナイロン６．６（無化成レオナー６，６１５０Ｏ８）を
粉砕後、予め２５０℃、１５時間乾燥したメレム、メロ
ン（粒径５〜１０μ）を表１に示す割合で添加混合し、
更に８０℃で１０時間乾燥し、射出成形により試験片を
作製した。Examples 1, 2, 3, 4.5 Melem and melon (particle size 5 to 10μ), which were pre-dried at 250°C for 15 hours after pulverizing nylon 6.6 (non-chemically formed Leonor 6,6150O8), are shown in Table 1. Add and mix in proportion,
It was further dried at 80° C. for 10 hours, and a test piece was prepared by injection molding.
なお、引張強度はＡＳＴＭ−Ｄ−６３８，アイゾッド衝
撃強度はΔＲ’ｒ Ｍ −Ｄ〜２５６（ノツチ付）に準
じ、燃焼時間ｆｉＡＳＴＭ−Ｄ−６３５（−ｄｌ−イア
ｆ ） ＶＣ準じて測定した。The tensile strength was measured according to ASTM-D-638, the Izod impact strength was measured according to ΔR'r M -D~256 (notched), and the burning time was measured according to ASTM-D-635 (-dl-ear f ) VC.
また、ブリードアウト試験は試験片ケ８０℃。In addition, the bleed-out test was performed on a test piece at 80°C.
９０％Ｒ８で１週間放置し２表面のブリードアウトの上
熱を観察した。捷た比較例ｖｊメレム。The sample was left at 90% R8 for one week, and bleed-out and heat were observed on the two surfaces. Comparative example vj melem.
メロンの代りにメラミンをハＩいた例である。This is an example of using melamine instead of melon.
結果は表１に一括掲載した。The results are listed in Table 1.
表１より明らかなごとく、メレム、メロン添加により燃
焼時間は２部添加においても極めて効果があり、熱変形
温ＩＷも向上ｌ−た。As is clear from Table 1, the addition of melem and melon was extremely effective in reducing the combustion time even when 2 parts were added, and the heat distortion temperature IW was also improved.
この傾向はナイロン−６，６以外のポリアミド樹脂につ
いても同様であった。また、同一樹脂の射出成形時にお
いて金型のくもりは認められなかった。This tendency was the same for polyamide resins other than nylon-6,6. Furthermore, no clouding of the mold was observed during injection molding of the same resin.
寸た。燃焼時間はメロン象加囁ば２ ｗｔ％でもブラン
ク（参考例１）と比較して太ｌＪな低下を示し、熱変形
温度も向上した。また、同一樹脂の射出成形時において
金型のくもりは認められなかった。Dimensions. The combustion time showed a large decrease in lJ compared to the blank (Reference Example 1) even when the melon was added at 2 wt%, and the heat distortion temperature also improved. Furthermore, no clouding of the mold was observed during injection molding of the same resin.
特許出願人 日産化学工業株式会社Patent applicant: Nissan Chemical Industries, Ltd.
Claims (1)
に１種又は２種以上含有することを特徴とする新規な難
燃性樹脂組成物。(1) A novel flame-retardant resin composition characterized by containing one or more compounds having the structure of the following formula (1) in a polyamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15704782A JPS5945352A (en) | 1982-09-09 | 1982-09-09 | Novel flame-retardant resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15704782A JPS5945352A (en) | 1982-09-09 | 1982-09-09 | Novel flame-retardant resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5945352A true JPS5945352A (en) | 1984-03-14 |
| JPS6149342B2 JPS6149342B2 (en) | 1986-10-29 |
Family
ID=15641030
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15704782A Granted JPS5945352A (en) | 1982-09-09 | 1982-09-09 | Novel flame-retardant resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5945352A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3722118A1 (en) * | 1987-07-03 | 1989-01-12 | Brueggemann L Kg | SELF-EXTINGUISHING THERMOPLASTIC MASS FROM POLYCONDENSATION PRODUCTS |
| NL1011631C2 (en) * | 1999-03-22 | 2000-09-27 | Dsm Nv | Flame-retardant composition and method for its preparation. |
| WO2000056840A1 (en) * | 1999-03-22 | 2000-09-28 | Dsm N.V. | Flame-retarding composition and process for the preparation thereof |
| NL1013105C2 (en) * | 1999-09-21 | 2001-03-22 | Dsm Nv | Flame-retardant mixture. |
| JP2001172282A (en) * | 1999-12-14 | 2001-06-26 | Nissan Chem Ind Ltd | Method for producing melem |
-
1982
- 1982-09-09 JP JP15704782A patent/JPS5945352A/en active Granted
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3722118A1 (en) * | 1987-07-03 | 1989-01-12 | Brueggemann L Kg | SELF-EXTINGUISHING THERMOPLASTIC MASS FROM POLYCONDENSATION PRODUCTS |
| DE3722118C2 (en) * | 1987-07-03 | 1992-01-02 | L. Brueggemann Kg, 7100 Heilbronn, De | |
| NL1011631C2 (en) * | 1999-03-22 | 2000-09-27 | Dsm Nv | Flame-retardant composition and method for its preparation. |
| WO2000056840A1 (en) * | 1999-03-22 | 2000-09-28 | Dsm N.V. | Flame-retarding composition and process for the preparation thereof |
| US6646030B2 (en) | 1999-03-22 | 2003-11-11 | Ciba Specialty Chemicals Corporation | Flame-retarding composition and process for the preparation thereof |
| AU768261B2 (en) * | 1999-03-22 | 2003-12-04 | Ciba Specialty Chemicals Holding Inc. | Flame-retarding composition and process for the preparation thereof |
| NL1013105C2 (en) * | 1999-09-21 | 2001-03-22 | Dsm Nv | Flame-retardant mixture. |
| WO2001021698A1 (en) * | 1999-09-21 | 2001-03-29 | Dsm N.V. | Flame-retardant mixture |
| US6630526B2 (en) | 1999-09-21 | 2003-10-07 | Ciba Specialty Chemicals Corporation | Flame-retardant mixture |
| KR100697913B1 (en) | 1999-09-21 | 2007-03-20 | 시바 스페셜티 케미칼스 홀딩 인크. | Flame retardant mixture |
| JP2001172282A (en) * | 1999-12-14 | 2001-06-26 | Nissan Chem Ind Ltd | Method for producing melem |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6149342B2 (en) | 1986-10-29 |
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