JPS5964543A - Carbon umber glass composition for electromelting furnace - Google Patents
Carbon umber glass composition for electromelting furnaceInfo
- Publication number
- JPS5964543A JPS5964543A JP17424182A JP17424182A JPS5964543A JP S5964543 A JPS5964543 A JP S5964543A JP 17424182 A JP17424182 A JP 17424182A JP 17424182 A JP17424182 A JP 17424182A JP S5964543 A JPS5964543 A JP S5964543A
- Authority
- JP
- Japan
- Prior art keywords
- glass
- carbon
- glass composition
- umber
- furnace
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 14
- 239000000203 mixture Substances 0.000 title claims abstract description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title abstract 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract 2
- 150000001340 alkali metals Chemical group 0.000 claims abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract 2
- 150000001342 alkaline earth metals Chemical group 0.000 claims abstract 2
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- MQWCQFCZUNBTCM-UHFFFAOYSA-N 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfanyl-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(SC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O MQWCQFCZUNBTCM-UHFFFAOYSA-N 0.000 claims 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 239000012535 impurity Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000005187 foaming Methods 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、コールドトップ方式電融炉で、カーボンアン
バーガラスを製造する組成に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a composition for producing carbon amber glass in a cold top type electric melting furnace.
コールドトップ方式電融炉とは、その溶融槽において、
その上面に均等に原料を投入し、表面を常に冷たい原料
バッチで覆いｌグら、下部でガラスを溶融する方式であ
る。A cold-top electric melting furnace has a melting tank that
In this method, raw materials are poured evenly onto the top surface, the surface is always covered with a cold batch of raw materials, and the glass is melted at the bottom.
従来、コールドトップ方式の電融炉では、カーボンアン
バーガラスは、酸化還元反応のために起る発泡または噴
火現象のために、コールトド１．プを形成するために必
要なバッチ層を継続して維持することができず、カーボ
ンアンバーガラスを製造することはで＠なかった。Conventionally, in cold-top type electric melting furnaces, carbon amber glass has a cold 1. It was not possible to continuously maintain the batch layer necessary to form the carbon amber glass.
本発明の組成は、高温域では実用カーボンアンバーガラ
スとはｙ同じ粘度特性を持ち、作業温度域における粘度
は、カーボンアンバー着色ＩＣよる温度勾配と、ガラス
自身の粘性勾配により粘性は増加するので、表面のガラ
ス層は急激に硬化し、前述のような発泡捷たは噴火現象
を防＋Ｌでき、安定した上部のバッチ層を確実に継続し
て維持できるよう改良てれた組成で、コールトド、プ方
式電融炉でカーボンアンバーガラスを製造することを可
能にしたことである。The composition of the present invention has the same viscosity characteristics as practical carbon amber glass in the high temperature range, and the viscosity in the working temperature range increases due to the temperature gradient caused by the carbon amber coloring IC and the viscosity gradient of the glass itself. The glass layer on the surface hardens rapidly, preventing foaming and eruption as described above, and has an improved composition that ensures the continuous maintenance of a stable upper batch layer. This made it possible to produce carbon amber glass in an electric melting furnace.
本発明の第２の効果は、燃焼炉では原ネ１投入ロ捷たは
溶融槽で、１日当り数回溶融ガラスを採取して、色調見
本などと比較してカーボン量を増減して色調調整しなけ
ればならず、大変手数を要している。一方この方式にお
いては、ガラスの溶融がバッチ層の下部で行われ雰囲気
の影響を受けないためカーボンアンバーガラスの色調調
整は、添加するカーボン量を増減する操作のみで極めて
単純化てれる。The second effect of the present invention is that the molten glass is sampled several times a day in the combustion furnace by adding raw energy or in the melting tank, and the color tone is adjusted by increasing or decreasing the amount of carbon compared to the color sample. It has to be done and it takes a lot of effort. On the other hand, in this method, the glass is melted at the bottom of the batch layer and is not affected by the atmosphere, so the color tone adjustment of the carbon amber glass can be extremely simplified by simply increasing or decreasing the amount of carbon added.
本発明の第３の効果ｔま、原料単価の安い石灰を多量に
使用し、一方単価の高いソーダ灰を減することが可能と
なり、原料原価を低減できることになり、その工業的価
値は極めて犬である。The third effect of the present invention is that it is possible to use a large amount of lime, which is cheap as a raw material, while reducing the amount of soda ash, which is expensive. It is.
引用文献 ガラス工学ハンドブック 昭和５０会９−３０２８０−References Glass Engineering Handbook 1975 Society 9-30280-
Claims (1)
ールドトップ方式電融炉にて製造する場合に、ＣａＯ成
分を多量に使用することを特徴とする下表に示す範囲（
重ｉ′％で表わしである）のガラス組成。 成 分 ５ｉ０２ ＋ Ａｔ２０３ ＋ Ｆｅ２Ｏ３６０〜８０
ＣａＯ６〜１４ ＲＯ、Ｏ〜８ Ｒ２０１０〜１７ ８０３０〜α２ 上記５ｉ０２ ＋ Ａｔ２０３ ＋ Ｆｅ２Ｏ３１ｃ与
えた％は、その配合物と共にガラスの中に不純物として
少量含有でれる任意のＴｉＯ２、ＭｎＯ２ｔたはこの化
合物群のうちの他のいくつかを含むものとする。またＲ
ＯＶｉアルカリ土金属（８）の酸化物を、Ｒ２０はアル
カリ金属幅）の酸化物を、それぞれ示すものとする。[Claims] When carbon amber glass containing sulfide and carbon is produced in a cold-top electric melting furnace, the range shown in the table below is characterized by using a large amount of CaO component (
glass composition (expressed in weight i'%). Component 5i02 + At203 + Fe2O360~80
CaO6~14 RO, O~8 R2010~17 8030~α2 5i02 + At203 + Fe2O31c The percentage given above is for any TiO2, MnO2t or this group of compounds that may be contained in a small amount as an impurity in the glass together with its formulation. This shall include some of the others. Also R
OVi represents an oxide of an alkaline earth metal (8), and R20 represents an oxide of an alkali metal (8).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17424182A JPS5964543A (en) | 1982-10-04 | 1982-10-04 | Carbon umber glass composition for electromelting furnace |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17424182A JPS5964543A (en) | 1982-10-04 | 1982-10-04 | Carbon umber glass composition for electromelting furnace |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5964543A true JPS5964543A (en) | 1984-04-12 |
Family
ID=15975177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17424182A Pending JPS5964543A (en) | 1982-10-04 | 1982-10-04 | Carbon umber glass composition for electromelting furnace |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5964543A (en) |
-
1982
- 1982-10-04 JP JP17424182A patent/JPS5964543A/en active Pending
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