JPS5996665A - Electrolyte for lithium battery - Google Patents
Electrolyte for lithium batteryInfo
- Publication number
- JPS5996665A JPS5996665A JP57206572A JP20657282A JPS5996665A JP S5996665 A JPS5996665 A JP S5996665A JP 57206572 A JP57206572 A JP 57206572A JP 20657282 A JP20657282 A JP 20657282A JP S5996665 A JPS5996665 A JP S5996665A
- Authority
- JP
- Japan
- Prior art keywords
- lithium
- jethoxyethane
- lithium battery
- solvent
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Primary Cells (AREA)
- Secondary Cells (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
丸明の許創な１ｉ５１．Ｌ！Ｊ：１
本発明は、リチウム′電池にハ」いる電、イ故に閥する
ものである。[Detailed description of the invention] Marumei's original 1i51. L! J:1 The present invention focuses on the electricity contained in lithium batteries.
リチウノ・を負懐ン占ゴ必負として井」いる゛屯ｌ也Ｖ
ま、小盈ｅ市エネルギ密区紮ｍする゛電池として研究さ
れているが、その二次化が大きな四屯点となっている。I'm looking forward to seeing Richiuno as a must-see.
Well, it is being researched as a battery that can be used in the energy-dense area of Xiaoying City, but its secondary use is a major problem.
二次化が可能な正協活物質として、Ｖ２０Ｂ、Ｖｅ Ｏ
□！号の余病酸化物、Ｔｉ５ｚ、ＶＳ＊等の屑状化合物
が、Ｌｉとの間でトポケミカルな反応をする化８吻とし
て知られており 、机ｈｆでチタン、ジルコニウム、ハ
ンニウム、ニオビウム、タンタル、バナジウムの硫化物
、セレン化物、テルル化物を用いた′電池（米国瞥計第
４，０８９，０５２号明細刊参照）等が開示されている
。As a Seikyo active material that can be secondaryized, V20B, Ve O
□! Scrap compounds such as No. oxide, Ti5z, and VS* are known as chemical compounds that undergo topochemical reactions with Li. A battery using vanadium sulfide, selenide, or telluride (see specification of U.S. Beammeter No. 4,089,052) has been disclosed.
しかしながら、このような二次電池用正恰活物負の研究
に比して、Ｌｉ焼の光放電有性に１０・」する研究は光
分と（ｌよいえず、Ｌｉ二次電池失視のためには、元放
′−効半及びサイクル寿都専の冗放′屯特性の艮灯な屯
厚ト液の探査が皿太な間也となっている。Ｌｉ ４メの
光放屯効幕を同上させる試みとしてｒｌ Ｌ ｉ Ｃｔ
Ｏ４／プロピレンカーボネイトにニトロメタンＡ ５０
２＝の′ＩＩＪ８カ１１ ＝ｔＪを力ｌえる試み（Ｅｌ
ｅｃｔｒ。However, compared to such positive and negative research on active materials for secondary batteries, research that investigates the photodischarge properties of Li-fired materials has been found to be 10% of the time. In order to achieve this, the exploration of the light emission characteristics of the original radiation effect and the cycle Jutsu-sen is a major step.The light radiation effect of Li 4 rl L i Ct as an attempt to make the curtain ditto
O4/propylene carbonate with nitromethane A 50
2 = 'IIJ8 Ka11 = Attempt to strengthen tJ (El
ectr.
ｃｈｉｍｉｃａ、Ａｃｔａ、ｖｏｌ、２２． 第７５Ｊ
ｉｔ＝８３声（１９７７） ：］寺が行なわｌしている
が必すしも光分とｒｉｂえす、ざらにイザ・註の倹れた
リチウムニ仄喝池刀：ｌ亀ｎ十ン牧が求められている。chimica, Acta, vol, 22. 75th J
it = 83 voices (1977): ] The temple is doing it, but it is also necessary to rib it with light, and it is a waste of lithium, and it is a sword, and it is called for. ing.
本究明は０、このような現状に亦みなされたものであ（
）、その目的は畳重率が局くかつＬｉ幌の充放′電荷性
の優れたリチウム−次及び二次′屯？巴用非水屯屏孜を
仇供することにある。This research has been neglected due to the current situation (
), its purpose is to produce lithium secondary and secondary lithium ions with a localized folding ratio and excellent charging and discharging properties. The purpose is to avenge Tomoe's non-suishitun-bingei.
したがって、本丸甲」によるリチウ１ａｌｌｋ用非水′
区屏ン吹はリチウムｊ益を；Ｍ ４’、：’、、浴媒に
溶剛、させた非水屯耐牧においで、前ａ［シ非水′畦麻
敢の有機ン谷媒として１．２−ジェトキシエタンと、前
に＋：１．２−ジェトキシエタンより高話藏率の非プロ
トンｔ？ｉ＋、住γ谷媒との混合溶媒を・用いた俗を籍
飲とするものである。Therefore, the non-water '
Gu Ping blowing lithium J benefit; 1.2-jethoxyethane and before +: aproton t with a higher conversion rate than 1.2-jethoxyethane? It is commonly used as a mixed solvent with i+ and Sumiya medium.
本究明によれは、萌似浴媒として、１．２−ジによシ々
ｔ′−牟が動く、かつＬｉ襖の充放も翁憔の優秀なリチ
ウム二次屯他用非水゛砒屏１ｗを逼り（することができ
る。According to the present study, as a similar bath medium, 1.2-di and t'-particles move more and more, and the charging of Li sliding doors is also possible with the excellent lithium secondary tank and other non-aqueous baths. It is possible to read 1w of folding pages.
不発閃を史に卸しく説明する。Explaining the misfires in history.
リチウム二次電池は、リチウムるｊｔ急γ占１ｆ寅とし
、Ｌｉ イオンに刈し、゛電気化学的に重性で、かつＬ
ｉ イオンと可逆的な′喝気化字反応を行なう吻買を
正べη活吻買とし、リチウム墳全肩°６す溶媒に溶解さ
せ７迦非水゛Ｆ４Ｊ、汚トイ′ｋを用いたものであるか
、このリチウムニ（７ＣＩ４．ｉｌＪ川の／ｒｊ′１・
７２浴ハとして、本究明においては、１．２−ジェトキ
シエタンと、１祇ｒｊｔ歳の畳重率を同上させるだめに
は、Ｌｉから浴ａ・々への≠
や府媒禾中のＬｉ鴻がｐ珪１゛触し易く、かつＬｉ
イオンの７シ動（住が入きい争が心安であると２）えら
れる。１，２−ジェトキシエタンはＬｉへの／Ｘ応性が
低い午がゾロられているが、その誘′颯皐は低く（５，
Ｃ２５’Ｃ）年δ玉ではその特注は必ずしも゛光分では
ない。この独な安水を、１，２−ジェトキシエタンと１
．２−ジトキエタンよシ尚妨屯牟の非プロトン憾註浴奴
との混合溶媒を用いた岨屏液ン１に用する十によシ胸た
づ一争が勘侍される。Lithium secondary batteries are made of lithium, which has a high concentration of 1f, and is made into Li ions, which are electrochemically heavy and
1. A reversible chemical reaction with ions that undergoes a reversible vaporization reaction is used as an active chemical, which is dissolved in a solvent containing lithium ions and used in a non-aqueous solution. Is this lithium ni (7CI4.ilJ river/rj′1・
As for 72 baths, in this investigation, in order to make the convolution rate of 1,2-jetoxyethane and 1 yrjt the same as above, it is necessary to change the ratio from Li to baths a and ≠ and the Li hong in the middle of the government. Easy to touch and Li
Aeon's 7-movement (2) is said to be a safe place to live and fight. Although 1,2-jethoxyethane has low /X reactivity to Li, its attraction is low (5,
C25'C) In the year δ ball, the custom order is not necessarily ゛light minute. This unique ammonium water is mixed with 1,2-jethoxyethane and 1
．． 2- Ditokiethane and the aprotic aprotons used in the liquid mixture using mixed solvents are considered to be a serious problem.
本９６鴫による祇ｈｆ撤のＭ↑μ市銖は０り運のように
、１．２−ジェトキシエタンと、ｌ、２−ジェトキシエ
タンより市誘−率の非プロトン性極性溶媒との混合溶媒
であるが、これらに、溶解される溶ηは従来この４□□
□０屯亀に用いられる浴質を目出に用いることができる
。たとえば、ＬｉＣ１Ｃｈ ＋ＬｉＢＦ、。As expected, M↑μ is a mixed solvent of 1,2-jethoxyethane and an aprotic polar solvent with a lower dielectric constant than l,2-jethoxyethane. However, the molten η dissolved in these is conventionally 4□□
□The bath quality used for 0tunkame can be used for mede. For example, LiC1Ch +LiBF.
ＬｉＡｓＦａ 、ＬｉＰＦｇ、ＬｉＡｔＣ４＋寺の魚１
候坂及びＣＦ”ｓ ＳＯｍ Ｌｉｔ ＣＦｓ ＣＯＯＬ
ｉ 等の有板塩を用いることができる。LiAsFa, LiPFg, LiAtC4 + temple fish 1
Kourizaka and CF”s SOm Lit CFs COOL
A plate salt such as i can be used.
これらの溶％は前記壱伝溶婬に、好ましくは０．５〜２
．５ 溶庁［される。溶解する溶″員が０，５Ｎ未渦
であると、充放Ｉｖ、萄性が着しく低下し、２．５Ｎを
超えると面質は溶層しないからである。The melting percentage of these is preferably 0.5 to 2
．． 5. To be dissolved. This is because if the melt member to be dissolved is 0.5N without vortex, the charging/discharging Iv and the viscosity will be severely reduced, and if it exceeds 2.5N, the surface quality will not become a molten layer.
１．２−ジエトキシエタ／と混合する１、２−ジェトキ
シエタンよシ尚誘電半の非プロトン４＠３性陪媒は、従
来この極の′電池に用いられる尚誘亀率浴媒を目出に井
」いる事ができる。たとえは、）゛ロピレンカーボイ・
イト、ｒ−５？’テロラクトン、ジメチルスルホキシド
、スルホラン、Ｎ、Ｎ−ジメチルホルムアミド、Ｎ、Ｎ
−ジメチルアセトアミド寺の中から遇ばれたｌ種以上の
溶媒を用いる事ができる。1,2-diethoxyethane is mixed with 1,2-diethoxyethane, which is a semi-dielectric aprotic 4@3 carrier medium. ” You can be there. The analogy is)
Ito, r-5? 'Telolactone, dimethyl sulfoxide, sulfolane, N,N-dimethylformamide, N,N
- Dimethylacetamide It is possible to use more than one solvent selected from the group.
１．２−ジェトキシエタン及び１．２−ジェトキシエタ
ンより尚妨屯半の非プロトン側性省媒の混合比は、１．
ｆましくは１：９〜９：１１ 岐も好ましくば５ ：
５ 戸１４畝でめる。１：９以下の九・ｄ比でるると＼
１ｆ−４Ｊイｉをで昆合した息味が７カ、くなシ、単独
糸の充放曳・；１ｆ−１＋（ｔこガつさ、充放′醸特性
が悠化するからである。The mixing ratio of 1.2-jetoxyethane and the aproton-saving medium that is less than 1.2-jetoxyethane is 1.
Preferably 1:9 to 9:11 and preferably 5:
5. House with 14 ridges. If you get a 9.d ratio of 1:9 or less,
1f-4Ji is combined with 7 colors, kunashi, and single thread's charge and release. .
以下、本究明の火、殉汐りを説明する。Below, I will explain the fire of this investigation and my martyrdom.
美加１・し１１１
ｙｔ獣をイ′Ｉ−用蜆、λ４句・吃（ｆｃ Ｌ ｉ
を参ｊ１（て也・１其としてＬｉを用いた屯（民金肘１
み、Ｐｔ４史上にＬｉ を析出させることにより、Ｌｉ
ｒｌ！ｉｌ＜の尤放兎崎注を副廻した。Mika 1 111
Refer to j1 (Teya, 1).
By precipitating Li in Pt4 history, Li
rl! I made a copy of il <'s Yuho Tozaki Note.
電層７ｅ−Ｖこは、ＩＮＬｉＢＦａを１．２−ジェトキ
シエタン（以下、ＤＥＯＥと１も記する）とプロピレン
刀−ボネイト（以下、ＰＣとＵ杓記する）のｌ＝１体４
頁比１比台７＋Ｊ訊Ｋｔ谷消６せたものを用いた。The electric layer 7e-V is formed by forming INLiBFa into l=1 body of 1,2-jetoxyethane (hereinafter also referred to as DEOE) and propylene carbonate (hereinafter referred to as PC) 4
I used a page ratio of 1, 7 + J, Kt, and 6.
この祇屏数の尋電年ｉｄ４．７ＸＩ０１Ω−１ｍ−１で
あり、Ｉ ＮＬ ｉＢＦ’４ ／Ｐ Ｃ単独糸の寺厄半
及びｌＮＬｉ１ｌＦ、／ＤＥＯｍ早独ホの７＃、４ 半
でりる３、６刈Ｏ−８Ω−’ ！−”及び゛１．２刈０
−８Ω−７”よＩ）Ｇ］かツタ。This number of folding numbers is id 4.7 , 6 cut O-8Ω-'! -” and “1.2 moi 0
-8Ω-7” yoI)G] or ivy.
測矩は、まず５ｍＡ／ｆｆｌ の定′亀訛で１分ｉ’ｉ
、４ｊ、 Ｐｔ幌上にＬｉを析出させ光電した浚、５ｍ
Ａ／ｃｄの麓ＫｍＣでｐｔ＋ｘ上に析出したＬｉ＋ イ
オンとして放−するサイクル試飲をイ：ｒなった。充放
電動￥は、ｐｔ物の電位変化よシ釆め、Ｐｔ惨上に析出
したＬｉをＬｉ＋ イオンとして放電させるのに太した
′喝気燻とＰｔ（ｓｊ＜上にＬｉを析出させるだめｘＪ
Ａした也気賞との比から詩、出した。First, measure the rectangle at 5 mA/ffl for 1 minute.
, 4j, photoelectrically deposited Li on a Pt canopy, 5 m long.
A cycle sample was conducted to release Li+ ions precipitated on pt+x at KmC at the foot of A/CD. The charging/discharging electric current is determined by considering the potential change of the Pt material, and using a thick swell to discharge the Li deposited on the Pt surface as Li+ ions and Pt (sj
I submitted a poem based on the comparison with the Yaki Award which I received an A.
８１図は、充放岨幼キとサイクル数の図１・床を示す図
であシ、図中のａは上配磁脚准を用い）ｃ場合であり、
ｂ及びＣは、ぞれぞれ、１ＮＬｉＢＦｎ／ＰＣ及びｌＮ
ＬｉＢＦ４／ＤＥＯ玖 単６ズ糸の′曳Ｈｔ故を用いた
徊合の充放眠符件２参考クリとして示した０第１図から
千」るように、牢ｊ虫糸（ｂ、ｃ）に比べて人混金糸（
ａ）は明らかに、充放亀符゛匡は１ら上している〇実施
例
一屏畝として、２ ＮＬ ｉ ＣＬＯａケＰＣとＤＥＯ
Ｅの体積７昆会比１：９の混合電媒に添附さぜたものを
用いた以タトは、笑施丙１と１−＝Ｊ休にして、Ｌｉの
単独糸の２ｈ屯卓である４、３Ｘ１０−’Ω−１ｄ１及
び３ 、３ Ｘ １０−８Ｏ−”ｔｉｎ−” よシ商か
った。第２図は充放′屯／／ＪＪ牟とサイクルはの１力
恍を示す凶であり、図中の（ａ）は本発明の２ ＮＬ
ｉ ＣｔＯ＜ ／Ｐ Ｃ／ＤＥＯＥ （体４Ａ混合比ｌ
：９）金奄屏散として用いた嶺会であシ、図中の（ｂ）
及び（Ｃ）は参考ｔ・１」として、各々、ＩＮＬｉＣｔ
０４／ＰＣ及びＩ ＮＬ ｉＣＬｏｔ ／ＤＥＯＥ率犯
溶媒糸゛岨肘θを用いたへ□１台のＬｉ似の光放電イジ
注を示したものである。第２凶から判る様に、単斜；ｈ
（ｂ 。Figure 81 is a diagram showing Figure 1 and the floor of the charging and discharging force and the number of cycles.
b and C are 1NLiBFn/PC and 1N, respectively
LiBF4/DEO 绖 As shown in Figure 1, the prison thread (b, c) is shown as a reference. Compared to the human mixed thread (
Obviously, a) is higher than 1. As an example, 2 NL i CLOa ke PC and DEO
This is a 2h tunshu of a single thread of Li with a volume of 7 of E added to a mixed electric medium with a ratio of 1:9, with 1 and 1-=J. 4,3X10-'Ω-1d1 and 3,3X10-8O-"tin-" worked well. Figure 2 shows the power of charge and release//JJ and the cycle, and (a) in the figure is the 2NL of the present invention.
i CtO< /P C/DEOE (body 4A mixing ratio l
:9) Ashi Minekai used as a kinjuban, (b) in the figure
and (C) are reference t・1'', respectively, INLiCt
04/PC and INL iCLot/DEOE A Li-like photodischarge model using a solvent thread θ is shown. As you can see from the second sin, monoclinic; h
(b.
Ｃ）に比べて、？■、′一台ホ（ａ）は明らかに光取、
。！ｉ守性は１ｉｊｊ上している。Compared to C)? ■、'Ichitaiho (a) is clearly Mitsutori,
. ! i-observance has increased by 1ijj.
夫ｙｉＳｌ クリ３
砥騨欣として、２ＮＬｉＣｔＯ４をｐｃとＤＥＯＥの体
積混合比１：１の混せ俗妹に電解させたものを用いた以
外は、実施ルす１と同様にしてＬｉの充放亀将牡ｆｃ曲
ｊ別した。Li charging and discharging mechanism was carried out in the same manner as in Example 1, except that 2N LiCtO4 was mixed with PC and DEOE at a volumetric mixing ratio of 1:1 and electrolyzed as the tod. Masao fc song j is different.
この′−ｐｐ＋奴の婢喝牢は７．５Ｘ１０−”Ω−１副
−１であシ、２ ＮＬ ｉ Ｃｔｅａ ／Ｐ Ｃ単独系
及び２ＮＬｉ ＣＬＯ４／ＤＥＯＥ ４３５Ｊ＝Ｏｍ
ｍ４＝でｈる４、３ｘｌＯ−” Ω−”ｃｒｎ′″１及
び３１１．・３Ｘ１０．−”Ω−１百−１第３図は、光
放電効率とサイクル飲の閃称全示す図であシ、図中の（
ａ）は本発明の２ Ｎ Ｌ ｉ ＣｔＯａ ／ＰＣ／Ｄ
ＥＯＥ （＋４Ｎ混合比１：ｌ）を電ｍ液として用い
たく合であシ、図中の（ｂ）及び（ｃ）は、参考例とし
て各々、Ｉ ＮＬ Ｉ Ｃｔｒｉ ／Ｐ Ｃ及びＩ Ｎ
Ｌ ｉ Ｃｌ−０＜／ＤＥＯＥ単独溶媒系奄）寸手液を
用いた場合のＬｉ極の充放′−特性を示したものである
。This '-pp+ guy's blackmail prison is 7.5X10-''Ω-1 sub-1, 2NLi Ctea /PC single system and 2NLi CLO4/DEOE 435J=Om
m4 = h4, 3xlO-"Ω-"crn'"1 and 311.・3 (in the figure)
a) is 2 N L i CtOa /PC/D of the present invention
When EOE (+4N mixing ratio 1:l) is used as the electrolytic liquid, (b) and (c) in the figure are reference examples, respectively.
This figure shows the charging and discharging characteristics of the Li electrode when a liquid containing LiCl-0</DEOE as a single solvent was used.
第３図から判る様に、単独系（ｂ、ｃ）に比べて混合糸
（ａ）は明らかに光放電％社は向上している。As can be seen from FIG. 3, the photodischarge percentage of the mixed yarn (a) is clearly improved compared to the single yarns (b, c).
以上の説明から明らかなように本発明によればリチウム
塩を有戦溶媒に電解させた非水寛ルト液においてＭ桜電
媒として１．２−ジェトキシエタンと１，２−ジェトキ
シエタンよ＃）尚誘電率の電媒との混合６媒を用いる事
によシ、寺奄半も尚く、かつＬｉ極の光放電特注が優れ
たリテウムニ次篭池用非水篭片ｒ液を提・洪する弗がで
きる。As is clear from the above explanation, according to the present invention, 1,2-jethoxyethane and 1,2-jethoxyethane are used as the M electrolyte in a non-hydrolyte solution in which lithium salt is electrolyzed in a hot solvent. By using a mixed 6 medium with an electric medium of a certain ratio, Terasa is able to provide a non-aqueous liquid for use in lithium nitride ponds, which is also excellent in Li-pole photodischarge customization. I can do it.
第１図〜８３図は本発明によ、る亀Ｐｌ“敵孕７１−１
いた棚台のＬｉ １■の充放屯効Ａｇと“リーイクル麻
の関・１糸を示す図である。
出願人イい人 目４ 宮 正 李第１図
ブイクル数
第２図
ブイク沙数Figures 1 to 83 show Rutore Pl "Enemy Pregnancy 71-1" according to the present invention.
This is a diagram showing the charge and discharge effect Ag of Li 1■ on the shelf stand and the 1st line of "Liikuru hemp".
Claims (1)
ト’Ａ反において前記治恒溶媒として、１１２−ジェト
キシエタンと、ＨＩＪＭｅ Ｉ ！ ２−ジェトキシエ
タンよシ向誘電率の非プロトン性物性溶奴の１棟以上の
混合溶媒を用いた孕を神体とするリチウム電池用゛ら解
散。In the lithium battery "Kamelt'A" in which a lithium salt is dissolved in a treatment bath medium, 112-jethoxyethane and HIJMe I! are used as the treatment solvent. 2-Jetoxyethane is an aprotic physical property with a dielectric constant in the diagonal direction.It is used for lithium batteries using a mixed solvent of one or more molten metals.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57206572A JPS5996665A (en) | 1982-11-25 | 1982-11-25 | Electrolyte for lithium battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57206572A JPS5996665A (en) | 1982-11-25 | 1982-11-25 | Electrolyte for lithium battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5996665A true JPS5996665A (en) | 1984-06-04 |
| JPH0351068B2 JPH0351068B2 (en) | 1991-08-05 |
Family
ID=16525618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57206572A Granted JPS5996665A (en) | 1982-11-25 | 1982-11-25 | Electrolyte for lithium battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5996665A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63105478A (en) * | 1986-10-20 | 1988-05-10 | Sanyo Electric Co Ltd | Secondary battery |
| JPS6414877A (en) * | 1987-07-08 | 1989-01-19 | Fuji Electrochemical Co Ltd | Nonaqueous electrolyte battery |
| JPS6414879A (en) * | 1987-07-08 | 1989-01-19 | Fuji Electrochemical Co Ltd | Nonaqueous electrolyte battery |
| JPH01200562A (en) * | 1988-02-05 | 1989-08-11 | Fuji Elelctrochem Co Ltd | non-aqueous electrolyte battery |
| JPH01200563A (en) * | 1988-02-05 | 1989-08-11 | Fuji Elelctrochem Co Ltd | Nonaqueous electrolyte cell |
| WO2006049027A1 (en) * | 2004-11-04 | 2006-05-11 | Matsushita Electric Industrial Co., Ltd. | Secondary battery with terminal for surface mounting |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7784147B2 (en) | 2003-09-05 | 2010-08-31 | Brunswick Bowling & Billiards Corporation | Bowling lane conditioning machine |
| RU2370324C2 (en) | 2003-09-05 | 2009-10-20 | Брансвик Боулинг Энд Биллиардс Корпорэйшн | Device and method of bowling trek maintenance using precise feed injectors |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5416623A (en) * | 1971-02-03 | 1979-02-07 | Du Pont | Highhenergyydensity battery |
| JPS5864768A (en) * | 1981-10-14 | 1983-04-18 | Sanyo Electric Co Ltd | non-aqueous electrolyte battery |
-
1982
- 1982-11-25 JP JP57206572A patent/JPS5996665A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5416623A (en) * | 1971-02-03 | 1979-02-07 | Du Pont | Highhenergyydensity battery |
| JPS5864768A (en) * | 1981-10-14 | 1983-04-18 | Sanyo Electric Co Ltd | non-aqueous electrolyte battery |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63105478A (en) * | 1986-10-20 | 1988-05-10 | Sanyo Electric Co Ltd | Secondary battery |
| JPS6414877A (en) * | 1987-07-08 | 1989-01-19 | Fuji Electrochemical Co Ltd | Nonaqueous electrolyte battery |
| JPS6414879A (en) * | 1987-07-08 | 1989-01-19 | Fuji Electrochemical Co Ltd | Nonaqueous electrolyte battery |
| JPH01200562A (en) * | 1988-02-05 | 1989-08-11 | Fuji Elelctrochem Co Ltd | non-aqueous electrolyte battery |
| JPH01200563A (en) * | 1988-02-05 | 1989-08-11 | Fuji Elelctrochem Co Ltd | Nonaqueous electrolyte cell |
| WO2006049027A1 (en) * | 2004-11-04 | 2006-05-11 | Matsushita Electric Industrial Co., Ltd. | Secondary battery with terminal for surface mounting |
| JPWO2006049027A1 (en) * | 2004-11-04 | 2008-05-29 | 松下電器産業株式会社 | Secondary battery with surface mount terminals |
| US7622226B2 (en) | 2004-11-04 | 2009-11-24 | Panasonic Corporation | Secondary battery having a terminal for surface mounting |
| JP5022035B2 (en) * | 2004-11-04 | 2012-09-12 | パナソニック株式会社 | Secondary battery with surface mount terminals |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0351068B2 (en) | 1991-08-05 |
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