JPS60231420A - コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法 - Google Patents

コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法

Info

Publication number: JPS60231420A
Authority: JP; Japan
Prior art keywords: cobalt; nickel; extraction; extractant; branched alkyl
Prior art date: 1983-12-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP24781883A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0448733B2 (fr

Inventor

Akihiro Fujimoto

藤本　明広

Isamu Miura

勇三浦

Tadanori Matsumura

松村　忠典

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Daihachi Chemical Industry Co Ltd

Original Assignee

Daihachi Chemical Industry Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-12-28

Filing date

1983-12-28

Publication date

1985-11-18

1983-12-28 Application filed by Daihachi Chemical Industry Co Ltd filed Critical Daihachi Chemical Industry Co Ltd

1983-12-28 Priority to JP24781883A priority Critical patent/JPS60231420A/ja

1985-11-18 Publication of JPS60231420A publication Critical patent/JPS60231420A/ja

1992-08-07 Publication of JPH0448733B2 publication Critical patent/JPH0448733B2/ja

Status Granted legal-status Critical Current

Links

229910052759 nickel Inorganic materials 0.000 title claims abstract description 69
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 132
229910017052 cobalt Inorganic materials 0.000 title claims description 111
239000010941 cobalt Substances 0.000 title claims description 111
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims description 111
239000007864 aqueous solution Substances 0.000 title claims description 29
238000000926 separation method Methods 0.000 title description 21
125000000217 alkyl group Chemical group 0.000 claims abstract description 38
239000002904 solvent Substances 0.000 claims abstract description 11
238000002156 mixing Methods 0.000 claims abstract description 5
238000000605 extraction Methods 0.000 claims description 86
238000000034 method Methods 0.000 claims description 32
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 20
239000011575 calcium Substances 0.000 claims description 20
229910052791 calcium Inorganic materials 0.000 claims description 20
239000002253 acid Substances 0.000 claims description 19
-1 1-methylheptyl group Chemical group 0.000 claims description 18
150000002148 esters Chemical class 0.000 claims description 16
239000000243 solution Substances 0.000 claims description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
125000004432 carbon atom Chemical group C* 0.000 claims description 7
125000001424 substituent group Chemical group 0.000 claims 3
125000005600 alkyl phosphonate group Chemical group 0.000 abstract 3
239000003153 chemical reaction reagent Substances 0.000 abstract 2
XUQLZJVBTGOVPT-UHFFFAOYSA-N octan-2-ylphosphonic acid Chemical compound CCCCCCC(C)P(O)(O)=O XUQLZJVBTGOVPT-UHFFFAOYSA-N 0.000 abstract 1
239000012074 organic phase Substances 0.000 description 41
239000008346 aqueous phase Substances 0.000 description 30
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
229910052751 metal Inorganic materials 0.000 description 10
239000002184 metal Substances 0.000 description 10
239000007788 liquid Substances 0.000 description 9
239000000284 extract Substances 0.000 description 8
150000007522 mineralic acids Chemical class 0.000 description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
229910052799 carbon Inorganic materials 0.000 description 7
239000003960 organic solvent Substances 0.000 description 7
238000000638 solvent extraction Methods 0.000 description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 6
230000000052 comparative effect Effects 0.000 description 6
230000000694 effects Effects 0.000 description 6
150000002739 metals Chemical class 0.000 description 6
238000005406 washing Methods 0.000 description 6
238000004140 cleaning Methods 0.000 description 5
229910001429 cobalt ion Inorganic materials 0.000 description 5
229910021645 metal ion Inorganic materials 0.000 description 5
239000002994 raw material Substances 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
ZGDWHDKHJKZZIQ-UHFFFAOYSA-N cobalt nickel Chemical compound [Co].[Ni].[Ni].[Ni] ZGDWHDKHJKZZIQ-UHFFFAOYSA-N 0.000 description 4
239000003350 kerosene Substances 0.000 description 4
238000011084 recovery Methods 0.000 description 4
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
239000003513 alkali Substances 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
229910001453 nickel ion Inorganic materials 0.000 description 3
229910017604 nitric acid Inorganic materials 0.000 description 3
239000012071 phase Substances 0.000 description 3
238000005191 phase separation Methods 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
ZDFBXXSHBTVQMB-UHFFFAOYSA-N 2-ethylhexoxy(2-ethylhexyl)phosphinic acid Chemical compound CCCCC(CC)COP(O)(=O)CC(CC)CCCC ZDFBXXSHBTVQMB-UHFFFAOYSA-N 0.000 description 2
CRLAISPERADHHT-UHFFFAOYSA-N 2-ethylhexyl(octan-2-yloxy)phosphinic acid Chemical compound CCCCCCC(C)OP(O)(=O)CC(CC)CCCC CRLAISPERADHHT-UHFFFAOYSA-N 0.000 description 2
239000004808 2-ethylhexylester Substances 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
OGJLPLDTKZHLLH-UHFFFAOYSA-N [Ca].[Co] Chemical compound [Ca].[Co] OGJLPLDTKZHLLH-UHFFFAOYSA-N 0.000 description 2
150000001868 cobalt Chemical class 0.000 description 2
235000013399 edible fruits Nutrition 0.000 description 2
239000003792 electrolyte Substances 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
150000002815 nickel Chemical class 0.000 description 2
125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 description 1
PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 1
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
GXCLVBGFBYZDAG-UHFFFAOYSA-N N-[2-(1H-indol-3-yl)ethyl]-N-methylprop-2-en-1-amine Chemical compound CN(CCC1=CNC2=C1C=CC=C2)CC=C GXCLVBGFBYZDAG-UHFFFAOYSA-N 0.000 description 1
238000003723 Smelting Methods 0.000 description 1
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910001413 alkali metal ion Inorganic materials 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
210000003323 beak Anatomy 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
229910000361 cobalt sulfate Inorganic materials 0.000 description 1
229940044175 cobalt sulfate Drugs 0.000 description 1
KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000002440 industrial waste Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000000622 liquid--liquid extraction Methods 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
DOLZKNFSRCEOFV-UHFFFAOYSA-L nickel(2+);oxalate Chemical class [Ni+2].[O-]C(=O)C([O-])=O DOLZKNFSRCEOFV-UHFFFAOYSA-L 0.000 description 1
229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
150000002903 organophosphorus compounds Chemical class 0.000 description 1
125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000002407 reforming Methods 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
239000002893 slag Substances 0.000 description 1
235000011121 sodium hydroxide Nutrition 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1

Landscapes

Inorganic Compounds Of Heavy Metals (AREA)
Manufacture And Refinement Of Metals (AREA)

JP24781883A 1983-12-28 1983-12-28 コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法 Granted JPS60231420A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP24781883A JPS60231420A (ja)	1983-12-28	1983-12-28	コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP24781883A JPS60231420A (ja)	1983-12-28	1983-12-28	コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法

Publications (2)

Publication Number	Publication Date
JPS60231420A true JPS60231420A (ja)	1985-11-18
JPH0448733B2 JPH0448733B2 (fr)	1992-08-07

Family

ID=17169114

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP24781883A Granted JPS60231420A (ja)	1983-12-28	1983-12-28	コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法

Country Status (1)

Country	Link
JP (1)	JPS60231420A (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5470553A (en) *	1993-12-07	1995-11-28	Industrial Technology Research Institute	Method for separating cobalt, nickel, and aluminum ions in sulfuric acid aqueous solutions and the extractant compositions used therein
JP2008527164A (ja) *	2004-12-30	2008-07-24	ビーエイチピー・ビリトン・エスエスエム・テクノロジー・ピーティーワイ・リミテッド	樹脂溶出液流からニッケル及びコバルトを回収する方法
JP2012153546A (ja) *	2011-01-24	2012-08-16	Sumitomo Metal Mining Co Ltd	硫酸コバルトの製造方法
WO2013099551A1 (fr) *	2011-12-26	2013-07-04	住友金属鉱山株式会社	Procédé de fabrication de sulfate de cobalt
JP2015145820A (ja) *	2014-02-03	2015-08-13	住友金属鉱山株式会社	脂溶性リン化合物の定量方法
JP2017008407A (ja) *	2015-06-22	2017-01-12	住友金属鉱山株式会社	カルシウムの分離方法
WO2018043703A1 (fr) *	2016-09-05	2018-03-08	住友金属鉱山株式会社	Procédé de production de solutions contenant du nickel ou du cobalt
WO2022224499A1 (fr) *	2021-04-22	2022-10-27	住友金属鉱山株式会社	Procédé de production de sulfate de cobalt
JP2023004393A (ja) *	2021-06-25	2023-01-17	住友金属鉱山株式会社	硫酸コバルトの製造方法

1983
- 1983-12-28 JP JP24781883A patent/JPS60231420A/ja active Granted

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5470553A (en) *	1993-12-07	1995-11-28	Industrial Technology Research Institute	Method for separating cobalt, nickel, and aluminum ions in sulfuric acid aqueous solutions and the extractant compositions used therein
JP2008527164A (ja) *	2004-12-30	2008-07-24	ビーエイチピー・ビリトン・エスエスエム・テクノロジー・ピーティーワイ・リミテッド	樹脂溶出液流からニッケル及びコバルトを回収する方法
JP2012153546A (ja) *	2011-01-24	2012-08-16	Sumitomo Metal Mining Co Ltd	硫酸コバルトの製造方法
WO2013099551A1 (fr) *	2011-12-26	2013-07-04	住友金属鉱山株式会社	Procédé de fabrication de sulfate de cobalt
US9428820B2 (en)	2011-12-26	2016-08-30	Sumitomo Metal Mining Co., Ltd.	Method for producing cobalt sulfate
JP2015145820A (ja) *	2014-02-03	2015-08-13	住友金属鉱山株式会社	脂溶性リン化合物の定量方法
JP2017008407A (ja) *	2015-06-22	2017-01-12	住友金属鉱山株式会社	カルシウムの分離方法
WO2018043703A1 (fr) *	2016-09-05	2018-03-08	住友金属鉱山株式会社	Procédé de production de solutions contenant du nickel ou du cobalt
JP2018039682A (ja) *	2016-09-05	2018-03-15	住友金属鉱山株式会社	ニッケル、コバルトを含有する溶液の製造方法
RU2726618C1 (ru) *	2016-09-05	2020-07-15	Сумитомо Метал Майнинг Ко., Лтд.	Способ получения растворов, содержащих никель или кобальт
WO2022224499A1 (fr) *	2021-04-22	2022-10-27	住友金属鉱山株式会社	Procédé de production de sulfate de cobalt
JP2022167760A (ja) *	2021-04-22	2022-11-04	住友金属鉱山株式会社	硫酸コバルトの製造方法
JP2023004393A (ja) *	2021-06-25	2023-01-17	住友金属鉱山株式会社	硫酸コバルトの製造方法

Also Published As

Publication number	Publication date
JPH0448733B2 (fr)	1992-08-07

Publication	Publication Date	Title
USRE32694E (en)	1988-06-14	Separation of cobalt and nickel by solvent extraction
US3399055A (en)	1968-08-27	Separation of cobalt by liquid extraction from acid solutions
JPS60231420A (ja)	1985-11-18	コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法
JPH0445570B2 (fr)	1992-07-27
JP3369855B2 (ja)	2003-01-20	高純度ニッケル水溶液の製造方法
JP2017165995A (ja)	2017-09-21	スカンジウム精製方法
JPH0210764B2 (fr)	1990-03-09
US4915919A (en)	1990-04-10	Recovery of germanium from aqueous solutions by solvent extraction
JP4259165B2 (ja)	2009-04-30	コバルトとカルシウムを含む硫酸ニッケル水溶液の精製方法
WO2016209178A1 (fr)	2016-12-29	Récupération de scandium et de dérivés de celui-ci à partir d'une solution de lixiviation chargée avec des métaux obtenus en conséquence de la lixiviation de minerais latéritiques comprenant du nickel, du cobalt et du scandium, et des sources secondaires comprenant du scandium
US20240327233A1 (en)	2024-10-03	Process for producing high purity aluminium materials
JP2025536829A (ja)	2025-11-07	マンガンの抽出の方法
JPS61170528A (ja)	1986-08-01	コバルトの剥離回収方法
CA1083830A (fr)	1980-08-19	Traitement des residus de zinc par echange ionique
JPS6139386B2 (fr)	1986-09-03
JP2636940B2 (ja)	1997-08-06	水溶液からの鉄イオンの抽出方法および抽出溶媒からの鉄イオンの逆抽出方法
JPH0377859B2 (fr)	1991-12-11
JPH0432712B2 (fr)	1992-06-01
JPS621570B2 (fr)	1987-01-14
GB2034290A (en)	1980-06-04	Separation of Cobalt from Nickel by Solvent Extraction
JPS6114133A (ja)	1986-01-22	アルミニウム電解発生ダストからガリウムを回収する方法
OA21426A (en)	2024-06-05	Process for producing high purity aluminium materials.
JPS6158531B2 (fr)	1986-12-12
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