JPS6043568A - Floor material having anti-scorch property - Google Patents
Floor material having anti-scorch propertyInfo
- Publication number
- JPS6043568A JPS6043568A JP15163883A JP15163883A JPS6043568A JP S6043568 A JPS6043568 A JP S6043568A JP 15163883 A JP15163883 A JP 15163883A JP 15163883 A JP15163883 A JP 15163883A JP S6043568 A JPS6043568 A JP S6043568A
- Authority
- JP
- Japan
- Prior art keywords
- heat
- resistant
- layer
- flooring material
- flooring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims description 15
- 229920005989 resin Polymers 0.000 claims description 20
- 239000011347 resin Substances 0.000 claims description 20
- 239000010410 layer Substances 0.000 claims description 17
- 238000009408 flooring Methods 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 5
- 239000002344 surface layer Substances 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 4
- 235000019504 cigarettes Nutrition 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000011342 resin composition Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- GZBSIABKXVPBFY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GZBSIABKXVPBFY-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 125000000174 L-prolyl group Chemical group [H]N1C([H])([H])C([H])([H])C([H])([H])[C@@]1([H])C(*)=O 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical class C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920006015 heat resistant resin Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920002601 oligoester Polymers 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
Landscapes
- Floor Finish (AREA)
- Laminated Bodies (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明はたばこの火等に対し耐熱性乞有する床材に関す
る１、
一般に合成樹脂床材は、バッキングペース上に、色彩、
図柄、模様等を組入れたｐｖｃ 等の樹脂層を積層形成
したものであるため、使用温度はほぼ１００・〜２００
℃と低温であり、たばこの火等により偶発的に加熱され
ると、分解しあるいは燃焼して焦げ跡を残す。したがっ
て、たとえ微小部分の加熱においても著しく美観欠損ね
ろ結果となり、場合によっては広い面積部分ヲ率り替え
る必要が生じて、経済的に著しい不利益を被ることとな
る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a flooring material that is heat resistant against cigarette burns, etc. 1. Generally, synthetic resin flooring materials have color,
Since it is made of laminated resin layers such as PVC that incorporate designs and patterns, the operating temperature is approximately 100-200℃.
℃, and if it is accidentally heated by a cigarette, it decomposes or burns, leaving scorch marks. Therefore, heating even a minute portion will result in a significant loss of aesthetics, and in some cases, it will be necessary to replace a large area, resulting in a significant economic disadvantage.
この様な使用面での不都合をなくすため、種々の提案が
なされている。特開昭５３−１４１３６３号には紫外線
架橋可能なオリゴエステルアクリレートχ含む塩ビペー
ストヲ部分的に硬化させ、未硬化部分に塩ビチップ乞付
着させ、更に前記塩ビペーストヲ塗り重ねた耐久性床敷
シートが記載されている。しかしながら、この様な構成
では耐久性、耐熱性共にｔ分ではなく、しかも塩ビチッ
プを部分的に付着させることにより模様な形成するのみ
では、広範な色柄、模様を選択採用することはできない
。Various proposals have been made to eliminate such inconveniences in use. JP-A-53-141363 discloses a durable bedding sheet in which a vinyl chloride paste containing an oligoester acrylate χ which can be cross-linked by ultraviolet rays is partially cured, a vinyl chloride chip is attached to the uncured part, and the vinyl chloride paste is coated again. is listed. However, with such a structure, both durability and heat resistance are not up to T minutes, and furthermore, it is not possible to select and adopt a wide range of colors and patterns simply by forming patterns by partially attaching PVC chips.
また、特開昭５７−２０５６６３号には、熱伝導性を付
与するための金属層乞設けて微小部分の加熱を分散する
ことができる構造の床材が記載されている。しかしなが
ら、この床材の表層部分はポリエステ〃、ポリカーボネ
ート、テフロン等の耐熱樹脂層が設けられてはいろもの
の、耐熱性、耐熱性に関しては十分とは言い１ｏｔａい
。Further, Japanese Patent Application Laid-open No. 57-205663 describes a flooring material having a structure in which a metal layer is provided to impart thermal conductivity so that heating of minute portions can be dispersed. However, although the surface layer of this flooring material is provided with a heat-resistant resin layer made of polyester, polycarbonate, Teflon, etc., its heat resistance is still far from sufficient.
本発明の目的は、床材本来の美観を損なうことなしに、
たばこの火等に対し優れた耐熱性を発揮丁にとのできる
床材乞提供することにある。The purpose of the present invention is to
To provide a flooring material that exhibits excellent heat resistance against cigarette burns and the like.
即ち、本発明の耐熱性を有する床材は、表層部分に耐熱
無機物質を充填した透明樹脂層を設けてなることを特徴
とするものである。That is, the heat-resistant flooring material of the present invention is characterized in that the surface layer is provided with a transparent resin layer filled with a heat-resistant inorganic substance.
本発明で使用する耐熱無機物質は、人工あるいは天然の
ガラス質あるいは結晶質の物質であり、形状は特に制限
されず、粉状、繊維状、球形、矩形、無定形等の何れで
もよい。＠脂中に充填した状態で光を透過し得、基本的
には無色の物質であることが好ましい。具体的には、例
えばガラスピーズ、ガラス繊維、シラスバルーン等の珪
酸塩ガラス、石英砂、雲母、ガラス繊維織布、不織布等
が挙げられる。The heat-resistant inorganic substance used in the present invention is an artificial or natural glassy or crystalline substance, and its shape is not particularly limited, and may be powdery, fibrous, spherical, rectangular, amorphous, or the like. It is preferably a substance that can transmit light when filled in a fat and is basically colorless. Specifically, examples include glass beads, glass fibers, silicate glasses such as glass balloons, quartz sand, mica, glass fiber woven fabrics, nonwoven fabrics, and the like.
本発明で使用する透明樹脂は、オレフィン、スチレン、
アクリル酸及びメタクリル酸のエステル、塩化ビニル、
酢酸ビニル、ビニルアルコール停のホモポリマー及びコ
ポリ寸−等であることができるが、好ましくは、紫外線
架橋型樹脂を含有する液状樹脂組成物の硬化物であるこ
とが好ましい。この紫外線架橋型の樹脂どしては、オリ
ゴエチレングリコールソアクリラート。The transparent resin used in the present invention includes olefin, styrene,
Esters of acrylic acid and methacrylic acid, vinyl chloride,
It may be a homopolymer or a copolymer of vinyl acetate or vinyl alcohol, but it is preferably a cured product of a liquid resin composition containing an ultraviolet crosslinkable resin. This UV cross-linked resin is oligoethylene glycol soacrylate.
メチレンビスアクリルアミド、ペンタニジトリトールア
クＩＪラード、ゾベノタエＩＪ ）リトールペンタアク
リレート、エチレングリコールシアクリレート、トリメ
チロールプロ／やントリアクリレート、テトラメチロー
ルメタンテトラアクリレート等のビニル結＠−ヲ有する
多官北上ツマ−、オリゴマー及び単官能性七ツマ−を組
合せ。Methylenebisacrylamide, pentaniditritol acrylate, zobenotae IJ) Polyfunctional Kitakami Tsuma with vinyl linkage such as ritol pentaacrylate, ethylene glycol cyacrylate, trimethylol pro/and triacrylate, tetramethylolmethane tetraacrylate, etc. -, a combination of oligomers and monofunctional septamers.
更にエポキシ樹脂、ポリ９レタン、Ｉリピニルアルコー
ル、、１５１Ｊアクリルエステシーアルコール変性ポリ
アミド等のポリマー、ベンゾイン系、キノン類、アゾ化
合物等の増感剤、し１゛ツクス系等の開始剤を適宜配合
したものであることができる。この様な配合の組成物に
可塑剤、安定剤等の添加剤及びＤＯＰ、ＤＢＰ 等の溶
剤？加えてダル化し、あるいはエマルジョン化して液状
樹脂組成物とし、あるいはこの液状物に東に前記の透明
樹脂成分を加えて液状樹脂組成物とすることかでざる。Furthermore, polymers such as epoxy resin, poly-9-rethane, I-lipinyl alcohol, 151J acrylic aesthetic alcohol-modified polyamide, sensitizers such as benzoin series, quinones, azo compounds, and initiators such as 1x series are added as appropriate. It can be a blended product. Are additives such as plasticizers and stabilizers, and solvents such as DOP and DBP added to such a composition? In addition, it can be mulled or emulsified to obtain a liquid resin composition, or the above-mentioned transparent resin component can be added to this liquid to form a liquid resin composition.
また、市販のＵＶ塗料等をそのまま用いることもできる
。この組成物′＆：塗布′し、硬化させるには、公知の
方法ン用いろことがでキ、塗布はパーコーター、スボン
ソロールコーター、硬化は紫外線照射及び加熱イ適宜選
択して行なうことができる。Moreover, commercially available UV paints and the like can also be used as they are. This composition can be applied and cured using a known method, and the application can be carried out using a percoater or a sponsolol coater, and the curing can be carried out by ultraviolet irradiation or heating, appropriately selected.
前記耐熱無機物質の透明樹脂層への配合量は、樹脂分１
００重縫邪知対して、５０〜５００重景部、更には１ｏ
ｏ〜２００重量部であることが好ましい。また、透明樹
脂層の表面は、樹脂分により平たんに仕上げてもよいし
、耐熱無機物質の量を多く喋るかあるいは形状を太き（
することにより凹凸にイ±″上げてノンスリップ性を付
与してもよい。The amount of the heat-resistant inorganic substance added to the transparent resin layer is 1 resin content.
Against 00 Jyuu Jachi, 50 to 500 Jukeibu, and even 1o
The amount is preferably 0 to 200 parts by weight. In addition, the surface of the transparent resin layer may be finished flat depending on the resin content, or may be finished with a large amount of heat-resistant inorganic material or thickened (
By doing so, the unevenness may be increased to provide non-slip properties.
本発明の床材は、従来公知の４１“ダ成の床材の表／ｉ
！部分に前記透明樹脂層を設けたものであることができ
る。最も１ｊ１１便な惜成としては、例えば、図面に示
した如く、アスベスト紙、アスベストフェルト、布、不
織布、ガラスクロス、パ□ガラス繊維織布、塩ビシート
、寒冷紗等のバッキングペース１に塩ビシート、塩ビ着
色層、あるいは特開昭５１−８７５６４号、同５１−８
７５６３ 号に記載されている如く、適宜の彩色を施し
た熱可塑性樹脂のチップ、ベレット等を適宜の色彩、図
柄等でスフ・リーン印刷したチップ模様層など、所望の
色彩、図柄、模様等を配した樹脂層２を固着し、更に樹
脂層２上に前記耐熱無機物質６を充填した透明樹脂層４
を設けたものが挙げられる。この様に、表層部分に透明
樹脂層を設けることにより、床材本来の美観はそのまま
保つことができろ。The flooring material of the present invention is similar to the conventionally known 41" flooring material.
! The transparent resin layer may be provided on a portion thereof. For example, as shown in the drawing, asbestos paper, asbestos felt, cloth, non-woven fabric, glass cloth, glass fiber woven fabric, PVC sheet, cheesecloth, etc. are used as backing paste 1, and PVC sheet, PVC colored layer or JP-A No. 51-87564, No. 51-8
As described in No. 7563, a desired color, design, pattern, etc. can be applied, such as a chip pattern layer in which thermoplastic resin chips, pellets, etc., which have been appropriately colored, are printed with thin strips in appropriate colors, designs, etc. A transparent resin layer 4 is fixed to the resin layer 2 and is further filled with the heat-resistant inorganic substance 6 on the resin layer 2.
Examples include those with In this way, by providing a transparent resin layer on the surface layer, the original beauty of the flooring material can be maintained.
実施例
市販のビニール床材（商品名ハーベスト並びにグレイト
ン、富双合成株式会社製）′の表面に市販のＵＶ塗料（
商品名紫外線硬化、塗料・積比ビーム、大日精化社製）
１００重量部に対し、ガラスピーズ（５０μ前後）１０
．０重量部ならびに２００重量部の割合の配合物を塗布
し、紫外線照射炉により硬化させて、”ａ開平たん及び
凹凸状の２種の床材を得た（透明樹脂層の厚みは１００
μ前後どした）。Example A commercially available UV paint (
Product name: UV curing, paint/volume ratio beam, manufactured by Dainichiseika Co., Ltd.)
10 parts of glass beads (around 50μ) per 100 parts by weight
．． The formulations were applied in proportions of 0 parts by weight and 200 parts by weight, and cured in an ultraviolet irradiation oven to obtain two types of flooring materials, flat and uneven (the thickness of the transparent resin layer was 100 parts by weight).
).
これらの床材はビニル床材本来の美観を損なっておらず
、また、たばこの火を長時間当接しておいても床材表面
に焦げ跡が残るといった事故は起らなかった１゜These flooring materials have not lost the original beauty of vinyl flooring, and there have been no incidents of burnt marks remaining on the surface of the flooring material even when exposed to a cigarette for a long time.
図面は、本発明の床材の構成例を示した断面図である。 ４・・・透明樹脂層 The drawing is a sectional view showing an example of the structure of the flooring material of the present invention. 4...Transparent resin layer
Claims (1)
？設けてなること火特徴とする耐熱性な石する床材。 （２）透明樹１指層は、紫外線架橋型樹脂を含有する液
状樹脂ト［Ｉ酸物を塗設したものである特許請求の範囲
第ｉｌ＋項記載の耐熱性を有する床材。[Claims] ([) A transparent resin layer whose surface layer is filled with a heat-resistant inorganic substance? The flooring is made of heat-resistant stone, which is characterized by its fire resistance. (2) The heat-resistant flooring material according to claim 1+, wherein the first layer of transparent wood is coated with a liquid resin containing an ultraviolet cross-linked resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15163883A JPS6043568A (en) | 1983-08-22 | 1983-08-22 | Floor material having anti-scorch property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15163883A JPS6043568A (en) | 1983-08-22 | 1983-08-22 | Floor material having anti-scorch property |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6043568A true JPS6043568A (en) | 1985-03-08 |
Family
ID=15522923
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15163883A Pending JPS6043568A (en) | 1983-08-22 | 1983-08-22 | Floor material having anti-scorch property |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6043568A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60141943A (en) * | 1983-12-29 | 1985-07-27 | タキロン株式会社 | Floor material |
| JPH01138047U (en) * | 1988-03-14 | 1989-09-21 | ||
| JPH02132265A (en) * | 1988-11-11 | 1990-05-21 | Tajima Inc | Heat resisting floor material |
| JPH02123539U (en) * | 1989-03-20 | 1990-10-11 | ||
| JPH03129062A (en) * | 1989-10-14 | 1991-06-03 | Matsushita Electric Works Ltd | Slip preventing floor member and manufacturing method therefor |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55138557A (en) * | 1979-04-15 | 1980-10-29 | Matsushita Electric Works Ltd | Synthetic resin floor material |
| JPS5622869A (en) * | 1979-07-31 | 1981-03-04 | Dainippon Printing Co Ltd | Floor tile and its manufacture |
| JPS5721661A (en) * | 1980-07-16 | 1982-02-04 | Noda Plywood Mfg Co Ltd | Richly solid looking painted flooring and manufacture thereof |
| JPS5721667A (en) * | 1980-07-11 | 1982-02-04 | Sumitomo Metal Ind | Installation of multi-layer concrete construction |
| JPS57143058A (en) * | 1981-02-24 | 1982-09-04 | Armstrong World Ind Inc | Non-skid plastic floor cover product and production thereof |
-
1983
- 1983-08-22 JP JP15163883A patent/JPS6043568A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55138557A (en) * | 1979-04-15 | 1980-10-29 | Matsushita Electric Works Ltd | Synthetic resin floor material |
| JPS5622869A (en) * | 1979-07-31 | 1981-03-04 | Dainippon Printing Co Ltd | Floor tile and its manufacture |
| JPS5721667A (en) * | 1980-07-11 | 1982-02-04 | Sumitomo Metal Ind | Installation of multi-layer concrete construction |
| JPS5721661A (en) * | 1980-07-16 | 1982-02-04 | Noda Plywood Mfg Co Ltd | Richly solid looking painted flooring and manufacture thereof |
| JPS57143058A (en) * | 1981-02-24 | 1982-09-04 | Armstrong World Ind Inc | Non-skid plastic floor cover product and production thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60141943A (en) * | 1983-12-29 | 1985-07-27 | タキロン株式会社 | Floor material |
| JPH01138047U (en) * | 1988-03-14 | 1989-09-21 | ||
| JPH02132265A (en) * | 1988-11-11 | 1990-05-21 | Tajima Inc | Heat resisting floor material |
| JPH02123539U (en) * | 1989-03-20 | 1990-10-11 | ||
| JPH03129062A (en) * | 1989-10-14 | 1991-06-03 | Matsushita Electric Works Ltd | Slip preventing floor member and manufacturing method therefor |
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