JPS6062006A - Electric field moderating sheet - Google Patents
Electric field moderating sheetInfo
- Publication number
- JPS6062006A JPS6062006A JP17041883A JP17041883A JPS6062006A JP S6062006 A JPS6062006 A JP S6062006A JP 17041883 A JP17041883 A JP 17041883A JP 17041883 A JP17041883 A JP 17041883A JP S6062006 A JPS6062006 A JP S6062006A
- Authority
- JP
- Japan
- Prior art keywords
- electric field
- sheet
- iminium
- fibrous material
- tonq
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000005684 electric field Effects 0.000 title claims description 12
- 150000001768 cations Chemical class 0.000 claims description 10
- 239000002657 fibrous material Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 239000006229 carbon black Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000116 mitigating effect Effects 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000004020 conductor Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000012212 insulator Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- JXPDNDHCMMOJPC-UHFFFAOYSA-N 2-hydroxybutanedinitrile Chemical compound N#CC(O)CC#N JXPDNDHCMMOJPC-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- DCZFGQYXRKMVFG-UHFFFAOYSA-N cyclohexane-1,4-dione Chemical compound O=C1CCC(=O)CC1 DCZFGQYXRKMVFG-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- MQCJIZHQXNUAQQ-UHFFFAOYSA-N 1,3-dithiolan-2-imine Chemical compound N=C1SCCS1 MQCJIZHQXNUAQQ-UHFFFAOYSA-N 0.000 description 1
- OOWWSVCXJZJIBE-UHFFFAOYSA-N 1,3-dithiolan-2-ylidene(dimethyl)azanium Chemical compound C[N+](C)=C1SCCS1 OOWWSVCXJZJIBE-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- HCGZJHQCNPSKBA-UHFFFAOYSA-N N=S1SCCC1 Chemical compound N=S1SCCC1 HCGZJHQCNPSKBA-UHFFFAOYSA-N 0.000 description 1
- ZCJMOCGWFVBHIP-UHFFFAOYSA-N Nc1cc(N)[s+]s1 Chemical compound Nc1cc(N)[s+]s1 ZCJMOCGWFVBHIP-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical group [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- INZYYBKSEHSTCV-UHFFFAOYSA-N dithiol-1-ium Chemical compound C1=CS[S+]=C1 INZYYBKSEHSTCV-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- -1 polyethylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Non-Insulated Conductors (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（イ）産業上の利用分野
この発明は、電界緩和用シートに関する。さらに詳しく
は、半：！！′７＋電性電荷移動錯体を繊維状物に吸着
又は付着し、て誘電率の大きい半導電性の電界緩和用シ
ートを得ることに関する。DETAILED DESCRIPTION OF THE INVENTION (a) Field of Industrial Application This invention relates to a sheet for mitigating an electric field. For more details, see Han:! ! The present invention relates to obtaining a semiconductive electric field relaxation sheet with a high dielectric constant by adsorbing or adhering a '7+ electric charge transfer complex to a fibrous material.
（ロ）従来技術
従来、電線、ケーブル、トランス、モーター、発ｒＬ機
などにおいて高電圧がかかる場合、急激な電界傾斜に起
因する絶縁破壊などが生じやすく、その急激な電界傾斜
を緩和するために、全屈、カーボンなどの電導体とプラ
スチックス、マイカ、ガラス、繊維、セラミックスなど
の絶縁体との間に電界緩和用プラスチックスをシート状
又はフィルム状として介在させている。通常、ｍ導体と
絶縁体の中間の半導体領域で誘電率の太きいものが望ま
しい。(b) Prior Art Conventionally, when high voltage is applied to electric wires, cables, transformers, motors, generators, etc., dielectric breakdown due to a sudden electric field gradient tends to occur, and in order to alleviate the sudden electric field gradient, Plastics for mitigating the electric field is interposed in the form of a sheet or film between a conductor such as , full bending, or carbon and an insulator such as plastics, mica, glass, fiber, or ceramics. Usually, a semiconductor region between an m-conductor and an insulator with a large dielectric constant is desirable.
従来から用いられている電界緩和材はいずれもカーボン
ブラックを用いたもので、例えば繊維にカーボンブラッ
クを含浸させた布や、プラスチックス中にカーボンブラ
ックを均一に分散させたシート、フィルムがある。しか
し前者の場合、カーボンブラックの含浸不良がおこりや
すく水分を吸収しやすい等の欠点が有り、後者において
は、有機高分子中へ電気抵抗を下げるため多量（通常１
０〜４０重」１の無機物であるカーボンブラックが混合
されているため機械的強度が不足するという欠点が有っ
た。All conventional electric field mitigation materials use carbon black, such as cloth made of fibers impregnated with carbon black, and sheets and films made of plastic with carbon black uniformly dispersed therein. However, in the former case, there are disadvantages such as poor impregnation of carbon black and easy absorption of water, while in the latter case, a large amount (usually 1
Since carbon black, which is an inorganic substance weighing 0 to 40% by weight, is mixed, there was a drawback that mechanical strength was insufficient.
？慢 発明の目的
この発明は、電界緩和用に好適な誘電率の大きい半導性
のシートを得るこ之を目的とする。? OBJECT OF THE INVENTION The object of the present invention is to obtain a semiconducting sheet with a high dielectric constant suitable for electric field relaxation.
に）発明の４ｉ１〜成
この発明は、７，７．８．８−テトラシアノキノジメタ
ンと、イミニウムカチオン、イミニウムダイカチオン及
びジチオリウムカチオンから選ばれるカチオンとの半導
電性電荷移動錯体を繊維状物に吸着又は付着してなる電
界緩和用シートを提供するものである。4i1 to 4i1 of the invention This invention provides a semiconductive charge transfer complex of 7,7.8.8-tetracyanoquinodimethane and a cation selected from iminium cations, iminium dications and dithiolium cations. The object of the present invention is to provide an electric field relaxation sheet made by adsorbing or adhering to a fibrous material.
この発明にお【する繊維状物としては、セルロース、ア
セテート、麻、綿、ポリエチレンテレフタレート、ナイ
ロン、ビニロン等の天然又は合成のモノフィラメントあ
るいはこれを紡糸したもの、網状物、ガーゼ、織物等が
ある。The fibrous materials used in the present invention include natural or synthetic monofilaments such as cellulose, acetate, hemp, cotton, polyethylene terephthalate, nylon, and vinylon, or spun products thereof, nets, gauze, and woven fabrics.
この発明に用いる繊維状物に吸着又は付着させる半導電
性電荷移動錯体は、７．７．８．８−テトラシアノキノ
ジメタン（以下ＴＯＱと略記〕とイミニウムカチオン、
イミニウムダイカチオン又はジチオリウムカチオンから
なる錯体である。The semiconductive charge transfer complex to be adsorbed or attached to the fibrous material used in this invention includes 7.7.8.8-tetracyanoquinodimethane (hereinafter abbreviated as TOQ) and an iminium cation.
It is a complex consisting of iminium dication or dithiolium cation.
この発明に用いるＴＧＮＱ、はＪ、Ａ、Ｏ，Ｓ−、Ｍｏ
ｌ、１３４゜３３７０〜３３７４頁（１９６２年）に記
載のよう薔こ１．４−シクロヘキサンジオンとマロンニ
トリルの縮合生成物から製造できまたＴＧＮＱ塩は昭和
５５年日本化学会春季年会講演要旨４Ｕ特２に記載の方
法で製造できる。TGNQ used in this invention is J, A, O, S-, Mo
TGNQ salt can be produced from the condensation product of 1,4-cyclohexanedione and malonitrile as described in J. I., 134°, pp. 3370-3374 (1962), and TGNQ salt can be produced from the condensation product of 1,4-cyclohexanedione and malonitrile as described in 1982 Chemical Society of Japan Spring Annual Meeting Lecture Abstracts 4U. It can be produced by the method described in Special Feature 2.
この発明のイミニウムカチオンＴＯＮＱ塩は、一般式（
Ｉ）
（式中ｍは１又は２、ｎは２又は３、Ｘ及びＹはイオウ
原子又はセレン原子、Ｒ工及びＲ２は７ ルー＋ル又は
フェニル基である）
上記に属する化合物としては例えばＮ、Ｎ−ジメチル−
１，３−ジチオラン−２−イミニウムＴＯＮＱが含まれ
る。The iminium cation TONQ salt of this invention has the general formula (
I) (In the formula, m is 1 or 2, n is 2 or 3, X and Y are a sulfur atom or a selenium atom, and R and R2 are a 7 molecule or a phenyl group) Examples of compounds belonging to the above include N , N-dimethyl-
Includes 1,3-dithiolane-2-iminium TONQ.
イミニウムダイカチオンＴＯＮＱ、塩は一般式〔のＲＲ
（［
（式中ｌは２又は３、ｍは２．３又番ま４、ｎ Ｉｔ
２又は６、Ｒは水素原子又はメチル基である２上記にＩ
ｔハする化合物としては例え番ｆＮ、ｒ−ジメチルーＮ
、Ｎ’−エチレン（ジチオラン−２−イミニウム） Ｔ
ＯＮＱが含まれる。The iminium dication TONQ, salt has the general formula RR ([ (where l is 2 or 3, m is 2.3 or 4, n It
2 or 6, R is a hydrogen atom or a methyl group 2 The above I
Examples of compounds that do this include fN, r-dimethyl-N
, N'-ethylene (dithiolan-2-iminium) T
Contains ONQ.
又は一般式（Ｉ［り
で示され、上記に４する化合物として番ま例え＋ｆλｉ
ｋ＋＋−ビス（１３−ジチオラン−２−イリデン）ピペ
ラジン−１，４−ジイウムＴＯＮＱが含まれる。Or as a compound represented by the general formula
Includes k++-bis(13-dithiolane-2-ylidene)piperazine-1,4-dium TONQ.
ジチオリウムカチオンＴＯＮＱ塩は一般式（２）（式中
ｍは１．２．３又は７、ｎ＝１．２又Ｃよ４、Ｒは水素
原子、フェニル基又はアミノ基、Ｒ２＜１水素原子、エ
チル基、フェニル基又（まベンジル基で′あるン
上記に属する化合物としては例えば３，５−ジアミノ−
１，２−ジチオリウムＴＯＨＱが含ま第１る。The dithiolium cation TONQ salt has the general formula (2) (where m is 1.2.3 or 7, n = 1.2 or C is 4, R is a hydrogen atom, a phenyl group or an amino group, and R2<1 hydrogen atom) , ethyl group, phenyl group or benzyl group. Examples of compounds belonging to the above groups include 3,5-diamino-
The first contains 1,2-dithiolium TOHQ.
上記半導電性電荷移動錯体を各種溶媒に所定の％濃度（
通常０．１〜３０％濃度］で分散させたり溶解させた後
、これらの分散又は（谷１ｑ１！液蚤こ１）；１に己赫
（維状物を十分に浸漬させたり、あるｔ’？まｇｒｌＥ
己５上１孜又は溶；介液を繊維状物に噴跳器で均一に吠
きイ１ ＋ｊ、次いで十分に乾繰することにより、この
発Ｉ！ｌｉの電界緩和用シートか得られる。The above semiconducting charge transfer complex was added to various solvents at a predetermined % concentration (
After dispersing or dissolving them at a concentration of 0.1 to 30% (usually 0.1 to 30%), the fibrous material is fully immersed in the dispersion or (1 q 1! liquid filtration 1); ?magrlE
Sprinkle the liquid evenly on the fibrous material with a sprayer, and then dry thoroughly to remove the liquid. A sheet for mitigating the electric field of li is obtained.
このようにして得られた繊維状物は、その繊維を構成す
る各単紬維の内部及び／又は表面に前記ＴＯＮＱ錯体分
子が吸着もしくは付着してなるものであり繊Ｗ、ｉＩ−
全体としてＴＯＮ（９錯体を均一に吸着もしくは付着し
てなるもので゛ある。The fibrous material thus obtained has the TONQ complex molecules adsorbed or attached to the inside and/or surface of each single fiber constituting the fiber, and is composed of fibers W, iI-
As a whole, it is made up of TON (9 complexes) uniformly adsorbed or attached.
以下、この発明の実施例を示して詳説するが１、この発
明はこれに限定されることはない。Hereinafter, the present invention will be described in detail with reference to examples (1), but the present invention is not limited thereto.
（１９実施例
実施例１
ジメチルボルムアミドにＮ、Ｎ−ジメチル−１，３−ジ
チオラン−２−イミニウムＴＯＩＱ、複雑塩を溶解し所
定の（農産として、これにナイロン繊維を浸漬後、乾燥
させ吸着させた。このようにして得られたシートの導Ｔ
Ｕ率および誘電率を第１図に示す。(19 Examples Example 1 N,N-dimethyl-1,3-dithiolan-2-iminium TOIQ, complex salt was dissolved in dimethylborumamide and a prescribed amount (as an agricultural product, nylon fibers were immersed in it, dried and adsorbed. The conductivity of the sheet thus obtained was
The U constant and dielectric constant are shown in FIG.
（図中の洛号は、上記Ｉ’ＯＮＱ塩の濃度を示すもので
、（１）は０．１、（２）は０．５、（３）は１．０
、 ＋４１は５．０、（５）は１０ 、＋６１は３０％
であり、（７）はジメチルホルムアミドにＮ、Ｎ’−ジ
メチル−Ｎ、Ｎ’−エチレン（ジチオラン−２−イミニ
ウムノＴＯＨＱ複雑塩を溶解し１０％の濃度としたもの
、（８）はジメチルポルムアミドに３．５−ジアミノ−
１，２−ジチオリウムＴＯＮＱ複雑塩を溶解し１０ ％
の４度としたものである。ノ
ｓｉ図から明らかなように、比抵抗は電導体と絶縁体の
中間の半導体飴域（１０１２〜１ｏ５Ωｃｍ ）であり
誘電率εも１５〜１００と大きく、７１１界緩和用シー
トとして非常に優れていることがわかる。(The Raku numbers in the figure indicate the concentrations of the above I'ONQ salts; (1) is 0.1, (2) is 0.5, and (3) is 1.0.
, +41 is 5.0, (5) is 10, +61 is 30%
(7) is N,N'-dimethyl-N,N'-ethylene (dithiolane-2-iminium-TOHQ complex salt dissolved in dimethylformamide to a concentration of 10%), and (8) is dimethylformamide. 3,5-diamino-
1,2-dithiolium TONQ complex salt dissolved at 10%
This is the 4th degree. As is clear from the SI diagram, the specific resistance is in the semiconductor range between that of a conductor and an insulator (1012 to 105 Ωcm), and the dielectric constant ε is also large at 15 to 100, making it an excellent sheet for 711 field relaxation. I know that there is.
（へ）発明の効果
以上のよう１こ、この発明における電界緩和用シートは
、特に繊維状物が溶剤で膨利した場合に商い効果が得ら
れる。(f) Effects of the Invention As described above, the electric field relaxation sheet of the present invention provides a commercial effect, particularly when the fibrous material is swollen with a solvent.
このようにして得たｉｎ ４１６状物は、従来のカーボ
ンブラックを用いたものに比して、機械的強度の低下や
含ヴ不良等の問題点が解消されたものであり、そのまま
シート状でも使用できるし、さらには高分子中に練り込
んで使用することができ、＋４−１界復和を必要とする
各種成形品等として好適である。The in-416-like material obtained in this way has problems such as decreased mechanical strength and poor inclusion compared to those using conventional carbon black, and can be used as is in the form of a sheet. It can be used, or even kneaded into polymers, and is suitable for various molded products that require +4-1 field restoration.
第１図は実施例１によって作成したシートの導？：Ｉ、
率および誘電率を示すグラフである。
第１図
１０５０１■ ２艶
誘電率（６０Ｈｚ）Figure 1 shows the diagram of the sheet prepared according to Example 1. :I,
2 is a graph showing the coefficient and dielectric constant. Fig. 1 10501■ 2 gloss dielectric constant (60Hz)
Claims (1)
イミニウムカチオン、イミニウムダイカチオン及びジチ
オリウムカチオンから選ばれるカチオンとの半導電性電
荷移動錯体を繊維状物に吸着又は付着してなる電界緩和
用シート。1, 7,7,8.8-tetracyanoquinodimethane,
An electric field relaxation sheet comprising a semiconductive charge transfer complex with a cation selected from iminium cations, iminium dications, and dithiolium cations adsorbed or attached to a fibrous material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17041883A JPS6062006A (en) | 1983-09-14 | 1983-09-14 | Electric field moderating sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17041883A JPS6062006A (en) | 1983-09-14 | 1983-09-14 | Electric field moderating sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6062006A true JPS6062006A (en) | 1985-04-10 |
Family
ID=15904554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17041883A Pending JPS6062006A (en) | 1983-09-14 | 1983-09-14 | Electric field moderating sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6062006A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0359799A (en) * | 1989-07-28 | 1991-03-14 | Hochiki Corp | Fire sensor |
-
1983
- 1983-09-14 JP JP17041883A patent/JPS6062006A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0359799A (en) * | 1989-07-28 | 1991-03-14 | Hochiki Corp | Fire sensor |
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