JPS6081312A - Polyester monofilament for fishery - Google Patents
Polyester monofilament for fisheryInfo
- Publication number
- JPS6081312A JPS6081312A JP58185168A JP18516883A JPS6081312A JP S6081312 A JPS6081312 A JP S6081312A JP 58185168 A JP58185168 A JP 58185168A JP 18516883 A JP18516883 A JP 18516883A JP S6081312 A JPS6081312 A JP S6081312A
- Authority
- JP
- Japan
- Prior art keywords
- polyester
- monofilament
- polysiloxane
- fishing
- master pellet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 19
- -1 polysiloxane Polymers 0.000 claims abstract description 16
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 14
- 239000002344 surface layer Substances 0.000 claims description 4
- 239000008188 pellet Substances 0.000 abstract description 8
- 238000009987 spinning Methods 0.000 abstract description 7
- 239000000306 component Substances 0.000 abstract description 5
- 239000008358 core component Substances 0.000 abstract description 3
- 239000002657 fibrous material Substances 0.000 abstract description 3
- 125000000217 alkyl group Chemical group 0.000 abstract description 2
- 125000003118 aryl group Chemical group 0.000 abstract description 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 9
- 239000002131 composite material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000195493 Cryptophyta Species 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 235000015170 shellfish Nutrition 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/80—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
- Y02A40/81—Aquaculture, e.g. of fish
Landscapes
- Farming Of Fish And Shellfish (AREA)
- Artificial Filaments (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は海洋生物１４着防止能をｌｉづる漁業用ポリニ
スデルモノフィラメントに関づるものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a polynisder monofilament for fishing use that has the ability to prevent marine organisms from landing on it.
さらに詳しくは、藻類や貝類などの海洋生物が付着しに
（い漁業用ポリエステルモノフィラメンｉ〜に閉覆るも
のである。More specifically, marine organisms such as algae and shellfish are attached to the polyester monofilament for fishing use.
従来、漁網、ロープ、生りＮおよび漁礁などの海洋で使
用する繊ｌｉｔ資材や構造体への海洋生物の付着が問題
と４賞っている。とくに遠洋漁業から近海漁業へ、また
捕獲漁業から裁培漁業へとΦ点を置き換える必要のある
現在、養殖漁業用繊維の重要性が一段と強まっており、
これらの１１維への海いる。Conventionally, the adhesion of marine organisms to fiber materials and structures used in the ocean, such as fishing nets, ropes, fishing nets, and fishing reefs, has been considered a problem. Especially now that there is a need to change the Φ point from deep-sea fishing to near-sea fishing, and from capture fishing to cultivation fishing, the importance of fibers for aquaculture is increasing.
These 11 fibers are connected to each other.
この課題については、既に幾多の１ｕｌｌ究がなされ、
各種の薬剤や対応策が開発されている。ところが実情は
Ｃｕ、ｌ−１ｃ１．８口、△Ｓなとの金属化合物、Ｃ１
系、Ｓ系などの非金属化合物などが有効とされており、
人体に対りる無害性や耐久性の点で十分なものとはいえ
ない。すなわら、これらの化合物はその有毒性のゆえに
海洋、／ｌ物ｆＮＪ１防止能を右づるのであり、尚洋汚
染の原因となり、奇形魚の発生をもまねくといった好ま
しからざる結果を！１Ｕている。Many 1ull studies have already been carried out on this subject,
Various drugs and countermeasures have been developed. However, the actual situation is that a metal compound of Cu, l-1c1.8, △S, C1
Non-metallic compounds such as S-based and S-based are considered to be effective.
It cannot be said to be sufficient in terms of harmlessness to the human body and durability. In other words, due to their toxicity, these compounds have a negative effect on their ability to prevent NJ1 in the ocean, causing pollution in the ocean, and leading to the occurrence of deformed fish. There are 1U.
本発明者らはこれらの状況をふまえて毒性がなく、かつ
づぐれた海洋生物付着防止能を有する漁業用繊Ｎ素祠を
１［）るべく、鋭意検問を■ねた結果、ポリシロキサン
を含有４るポリニスデルモノフィラメントが上記目的に
合致りることを見出し、本発明に到達した。In view of these circumstances, the inventors of the present invention conducted extensive research in order to find a non-toxic fishing fabric with excellent ability to prevent the attachment of marine organisms.As a result, they found that polysiloxane It has been discovered that the polynisder monofilament containing 4 meets the above object, and the present invention has been achieved.
すなわら本発明は海洋買初、とくに漁業用としてポリニ
スデルモノフィラメントを用いるに際し、−１”／７−
ｔ”ｒ璧ゝノ）〜σ）実昭ｎ＃、ｌＬｒ／Ｊさた（メー
＃’＋＋１ｊＩＩ５ノロキサンを含有せしめることによ
り尚洋生物のイ」肴を防止づることを特徴とするもので
ある。In other words, when using polynisder monofilament for marine purchasing, especially for fishing, the present invention provides a
It is characterized by containing noroxane, which prevents the appearance of saccharine of sea creatures.
ポリシロキサンを少なくとも表層部に含イ」してなる本
弁明の漁業用ポリエステルモノフィラメントを得る方法
としでは、次の三通りの方法が挙げられる。The following three methods can be used to obtain the fishing polyester monofilament of the present invention which contains polysiloxane at least in its surface layer.
第一の方法は予じめポリシロキサンをポリエステルに混
練した高ＩＩ６のマスターベレン１〜を作製しておき、
このマスターペレットとポリエステルとを所定の比率で
混合しブレンド紡糸づる方法である。この方法によると
、任意の濃度のポリシロ主１ノンがポリコースデルモノ
フィラメント全体にわたってｆｉぼ均一に分散したもの
が得られる。The first method is to prepare a high II6 master berene 1~ by kneading polysiloxane with polyester in advance,
This method involves mixing these master pellets and polyester in a predetermined ratio and spinning a blend. According to this method, it is possible to obtain polysilone monofilament having an arbitrary concentration dispersed almost uniformly throughout the polycoder monofilament.
第二の方法は第一の方法と同様に高ＩＩ！Ｉのボリシｌ
］キサンを含有りるポリエステルマスターペレットある
いはこれに所定比率でポリエステルを混合したしのを鞘
成分とし、ポリエステルを芯成分としｌζ複合糸を作製
づる方法である。この方法によると任意の濃度のポリシ
ロキリンを有し、かつ任意の厚さを有する表層部を設け
ることができる。The second method is the same as the first method! The name of I
] In this method, a polyester master pellet containing xane or a polyester mixed therein at a predetermined ratio is used as a sheath component, and polyester is used as a core component to produce a lζ composite yarn. According to this method, it is possible to provide a surface layer having an arbitrary concentration of polysiloquiline and an arbitrary thickness.
第三の方法は予め紡糸、延伸して作製したポリエステル
Ｕノフィラメントの表面にポリシロキサンを含有りるポ
リエステルを溶ｒＡｌ＋コーｊイングする方法である。The third method is to coat polyester containing polysiloxane on the surface of polyester U nofilament prepared by spinning and drawing in advance.
本発明で使用ηるポリシロキサンは次式＜Ｒ１，Ｒ２，
はアルキル基、シクロアルキル基、アリール基）の化学
＋ｆ４造をイｊづるしのが好適である。具体的には、１
ヘーレシリコーン（株）製Ｓ ＋−＋２００などのポリ
ジメヂルボリシロキリンやＳ ｌ−１５１０などのポリ
マ１ニルメヂルシロキリンなどが挙げられる。The polysiloxane used in the present invention has the following formula <R1, R2,
It is preferable to represent the chemical +f4 structure of an alkyl group, cycloalkyl group, or aryl group. Specifically, 1
Examples include polydimethylbolysiloquiline such as S+-+200 manufactured by Heerle Silicone Co., Ltd. and polymeric dimethylsiloquiline such as S1-1510.
また本発明で用いるポリエステルとはボリノフルキレン
テレフタレートまたはそのへΦ合体であり、具体的には
ポリエチレンデレフタレ−１〜、ポリゾヂレンデレノタ
レ−１−ａ３よびそれらのＪｔ［合体などが挙げられる
。In addition, the polyester used in the present invention is borinofulkylene terephthalate or its Φ combination, and specifically, polyethylene derephthalate-1 to polyzoylene derenotare-1-a3 and their Jt [combined, etc.] can be mentioned.
ポリシロキサンの添加間は、ボリシロキ４ノンを含有づ
るポリエステルの層に対し、０．３−３重量％が適当で
ある。０．３重間％より少い場合は海洋生物イ」着防止
能が不十分であり、高濃度になるにつれ性能が良くなる
が、３重け％を越えると糸の物性低下Ｊ３よび製糸性の
点で好ましくない。During the addition of polysiloxane, 0.3-3% by weight, based on the layer of polyester containing polysiloxane, is suitable. If the concentration is less than 0.3% by weight, the ability to prevent marine organisms from sticking is insufficient, and as the concentration increases, the performance improves, but if it exceeds 3% by weight, the physical properties of the yarn will deteriorate and the yarn spinning property will deteriorate. Unfavorable in this respect.
ただし、表面に溶融コーティングする場合に限り１０重
量％までのｍＩａのものが使用できる。However, a mIa of up to 10% by weight can be used only when melt coating the surface.
ポリシロキサンを含有した表層を設けることにより、海
洋生物イ」着防止能がイ」与される理由についＣは定か
ではないが、ポリシロキサンの特性である撥水性ど臼１
型性が寄与しているものと推察される。Although it is not clear why providing a surface layer containing polysiloxane provides the ability to prevent marine organisms from adhering to it, it is clear that the water-repellent properties of polysiloxane
It is surmised that type characteristics contribute to this.
しかして本発明の漁業用ポリエステルＬノフイラメン１
へは藻類や貝類などの海洋生物付着防止能がづぐれてａ
３つ、漁網、ロープ、生り簡などの海洋で使用覆る繊維
素材として石川である。Therefore, the polyester L-nofilamen for fishing of the present invention 1
The ability to prevent the adhesion of marine organisms such as algae and shellfish is poor.
The third is Ishikawa, which is used as a textile material used in the ocean, such as fishing nets, ropes, and cloth.
以下に実施例により本発明をさらに詳細に説明する。The present invention will be explained in more detail with reference to Examples below.
実施例１
因右ｔｌｉｌｎＯ−７のポリエチレンテレフタレート（
Ｂ ）に２ Ｅ） ”Ｃニａ３りる粘度３０，０００ボ
イスのポリジメチルシロ主１ノンを１５蛋吊％添加し、
二軸の１クストルーダーを用いて溶１１押出しを（ｊな
い、カッティングしてマスターペレツ１−（Ａ）を１９
１こ。Example 1 Polyethylene terephthalate of tlilnO-7 (
B) to 2E) 15% of polydimethylsilone with a viscosity of 30,000 voices was added,
Extrude the melt 11 using a twin-screw 1-crust truder (not cut) and make the master pellets 1-(A) 19
1 piece.
ポリ」ブレンｊレフタレ−１−（１３）とマスターベレ
ン１へ（△）を乾燥後、重量化で（Ｂ ） ／ （Δ）
−９８、６／ １ 、４．９８ ／ ２．９０／１０．
８０／２０．６７／３３の割合で混合し、ポリジメヂル
シロキ４ノンに８度に換鋒し−Ｕ０．２１．０．３．１
，５．３．０，４．９５重量％の混合ペレッ１〜を１ｇ
だ。After drying Poly'BlenjLeftale-1-(13) and Masterbelen1 (△), it was weighed (B) / (Δ)
-98, 6/1, 4.98/2.90/10.
Mixed in the ratio of 80/20.67/33 and converted to polydimedylsiloquinone 8 times - U0.21.0.3.1
, 5.3.0, 4.95% by weight mixed pellets 1~1g
is.
これらの混合ポリマＪ３よひマスターペレツ１−を混合
しないポリ上チレンテレフタレ−１−のみをスクリュー
径６５ ｍｍのエクストルーダを用い、２９０°Ｃの紡
糸温度で溶融紡糸した。 紡出後、水冷・固化し、引き
続き５イ８に延伸ジノ（糸直径２．７ｍｍのモノフィラ
メン１−を得た。（Ｂ）／（△） ＝ （５７／ ３３
の混合ポリマについては、延伸時の糸切れが多く、生産
性が不良であった。Only polyethylene terephthalate 1-, which was not mixed with these mixed polymer J3 master pellets 1-, was melt-spun at a spinning temperature of 290°C using an extruder with a screw diameter of 65 mm. After spinning, it was water-cooled and solidified, and then stretched to 5-8 to obtain monofilament 1- with a thread diameter of 2.7 mm. (B)/(△) = (57/33
Regarding the mixed polymer, there were many thread breakages during stretching, resulting in poor productivity.
ｊｑられた０水へ（の七ノフィラメン１へを用いて目金
！５０（財）の亀甲状絹を編網した。それぞれの網から
２１１１ｘ４ｍの大きさのものを切りとり、長崎県島原
半島の小浜沖の海中に設置した。網の４ｍ長の辺を−１
−上方向にし、網の上部が水ｆｆ３１Ｎとなる位胃に垂
直に設置した。A net of 50 pieces of tortoise-like silk was knitted using the seven filamen 1 of 0 water that had been placed in the water.A piece of 2111 x 4 m in size was cut from each net and sent to Kohama, Shimabara Peninsula, Nagasaki Prefecture. It was set up in the sea off the coast.The 4m long side of the net was -1
- The net was placed vertically on the stomach so that the upper part of the net was water ff31N.
２月から８月までの６ケ月間向中に設置した後の網の重
量とＩｆｄ中に沈める前の網の重Ｒとの差を、７ｆσ中
に沈める前の重量て除してｔｌｊｊ汀生物のイＮＪ首率
（％）を紳出覆ると、表１の如くてあっ／ｊ 。The difference between the weight of the net after it has been placed in the ocean for 6 months from February to August and the weight R of the net before being submerged in Ifd is divided by the weight before being submerged in 7fσ to determine the net biological value. If we change the NJ head rate (%) in Table 1, we get a/j.
東１
ポリジメヂルシロ 海（羊牛物イ４
：１−′ｌＪン１ｌ１５度（％） 着率（％）０ ５４
０
０．２１ ３８６
０．３０ Ｇ７
１、！ｉ０ ２３
３．００ １２
４．９５ １４
表１から明らか４１ように、ポリシト１−１リンの含イ
１により、海洋生物イ」着Ｍが著しく減少Ｊる。East 1 Polyjimajiru Shiro Sea (Sheep and Cattle) 4: 1-'lJ'n 1l 15 degrees (%) Arrival rate (%) 0 54
0 0.21 386 0.30 G7 1,! i0 23 3.00 12 4.95 14 As is clear from Table 1, the inclusion of polycyto-1-1 phosphorus significantly reduces the amount of marine organisms.
実施例２
実施例１に記載したポリジメブルシａ ：ｌザレンｎ１
哀０．２１．０．３．１．５．３，０．４．９５重量％
の混合ベレン１〜を鞘成分とし、ポリ上ヂレンデレノタ
レ−１・（Ｂ）を芯成分とした複合糸を製造しｌこ。Example 2 Polydimebursia a:lzalen n1 described in Example 1
0.21.0.3.1.5.3, 0.4.95% by weight
A composite yarn was produced using Mixed Berene 1~ as a sheath component and polyurethane polyamide 1 (B) as a core component.
芯／鞘複合比を８０ ／ ２０どしで、紡糸温度２９０
°Ｃ″Ｃ′溶融紡出した後、糸ｉｉ’ｊ径２．５ｍｍの
Ｌノフィラメントを得た。The core/sheath composite ratio is 80/20, and the spinning temperature is 290.
After melt spinning at °C''C', L-nofilaments with a diameter of 2.5 mm were obtained.
実施例１と同様にポリシメブルシ【二１キリン濶１臭４
．９５重量％のものを鞘成分に用いたものについては、
延伸時の糸切れが目）“１つた。Polyshimebrushi [21 Kirinto 1 odor 4] was prepared in the same manner as in Example 1.
．． For those using 95% by weight as the sheath component,
There was one thread breakage during stretching.
１！１られたモノノィラメントを用い（実施例１ど同様
の海祥生物（−１乞デストを杓４「っ／ｊ結果を表１に
承り。1!Using the monofilament obtained in Example 1, the results are shown in Table 1.The results are shown in Table 1.
衣」し
鞘成分のポリジメヂル 尚洋イ１物イ」シロキリ−ン濶
１哀（％） ４率く％ン０ ４９０
０．２１ ４１０
０．３０ ４５
１、Ｆｉｏ ３８
３．００ ２０
４．９５ １６Polydimetyl, the sheath component of the sheath.
Claims (1)
漁業用ポリエステルモノフィラメン１〜。A polyester monofilament for fishing use 1 containing polysiloxane at least in the surface layer of the yarn.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58185168A JPS6081312A (en) | 1983-10-05 | 1983-10-05 | Polyester monofilament for fishery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58185168A JPS6081312A (en) | 1983-10-05 | 1983-10-05 | Polyester monofilament for fishery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6081312A true JPS6081312A (en) | 1985-05-09 |
Family
ID=16166018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58185168A Pending JPS6081312A (en) | 1983-10-05 | 1983-10-05 | Polyester monofilament for fishery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6081312A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995001471A1 (en) * | 1993-07-02 | 1995-01-12 | Rhone-Poulenc Viscosuisse S.A. | Process for producing soil-repellent and abrasion-resistant monofilaments and their use |
| WO1995004847A1 (en) * | 1993-08-06 | 1995-02-16 | Rhone-Poulenc Viscosuisse S.A. | Monofilaments with improved weavability and use of the fabrics produced therewith |
-
1983
- 1983-10-05 JP JP58185168A patent/JPS6081312A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995001471A1 (en) * | 1993-07-02 | 1995-01-12 | Rhone-Poulenc Viscosuisse S.A. | Process for producing soil-repellent and abrasion-resistant monofilaments and their use |
| WO1995004847A1 (en) * | 1993-08-06 | 1995-02-16 | Rhone-Poulenc Viscosuisse S.A. | Monofilaments with improved weavability and use of the fabrics produced therewith |
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