JPS608202A - Repellent against acarids and repelling - Google Patents
Repellent against acarids and repellingInfo
- Publication number
- JPS608202A JPS608202A JP58116589A JP11658983A JPS608202A JP S608202 A JPS608202 A JP S608202A JP 58116589 A JP58116589 A JP 58116589A JP 11658983 A JP11658983 A JP 11658983A JP S608202 A JPS608202 A JP S608202A
- Authority
- JP
- Japan
- Prior art keywords
- active ingredient
- mites
- para
- acid ester
- ester compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
本発明はダニ類、特に家屋内に発生して害を及ぼすコナ
ダニ類やチリダニ類を主とした屋内性のグー INの忌
避剤及び忌避方法に関するものであり、さらに詳しくは
塩素化メタキシレノール及び/又はパラオキシ安息香酸
エステル化合物を有効成分とする忌避剤及びこれを対象
物(ダニが発生、或いは繁殖しないようにするべきもの
)に散布、添加、塗布、含浸等の処理をすることにより
、それらにダニfAがつかないようにするダニ類の忌避
法に関するものである9屋内性のダ−Sは、近年、シW
fft造が気密性を増したこと、さらに暖房設置が昔
及したことにより、冬期にもある程度の増殖が可能とな
った結果、これらによる°被害が著しく増加した。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a repellent and a method for repelling mites, especially indoor mites and house dust mites that are harmful when they occur inside houses. is a repellent containing chlorinated metaxylenol and/or paraoxybenzoic acid ester compound as an active ingredient, and treatments such as spraying, adding, coating, impregnating, etc. with it on objects (objects to be prevented from generating or breeding mites). This relates to a method of repelling mites that prevents mites from attaching to them.
Due to the increased airtightness of fft structures and the introduction of heating systems in the past, it became possible for them to proliferate to a certain extent even in the winter, resulting in a significant increase in damage caused by these.
その他に最近は大掃除をしなくなったこと、寝具を充分
に日光に当てることが少なくなったことなども被害が増
−加した原因と考えられている。Other factors that are thought to be contributing factors to the increase in damage include people not doing much cleaning these days and not exposing their bedding to enough sunlight.
それらのうちで、ケナガーナダニは鉄筋コンクリート住
宅などで入居者の入るまでに長い間閉め切っておかれる
ことにより、また入居後も梅雨時などには室内が高湿度
iこ保たれるため。Among them, woolly mites are caused by reinforced concrete houses that are kept closed for a long time before the occupants move in, and also because the indoor humidity remains high even after the tenant moves in, such as during the rainy season.
畳の中で大丘に増殖したものが這い出して来て入居者に
不快な害を与えた。Things that had grown in the tatami mats were crawling out and causing unpleasant harm to the residents.
また、コナダニの補食者であるツメダニM4b増加し、
それが人を刺すことをこよる害も多発した。。In addition, the number of tick M4b, which is a prey of the white mite, increased.
It also caused a lot of harm because it stung people. .
一方チリダ=類は一般的に学校や家庭の室内塵の中に最
も多く見られ、大部分を構成することも多い、また2そ
の被害はアレルギー症などの原因となると云われ、その
防除のため殺虫剤を保持させた紙やw&維製品が知られ
ている。On the other hand, Chillidae are generally found most often in the indoor dust of schools and homes, and often make up the majority of the dust. Paper and textile products containing insecticides are known.
忌避剤の利用が安全でかつ経済的な方法であり、これま
で知られている昆虫やダニ類の忌避剤としてはN、B1
−ジエチルトルアミド、2,5,4゜5−ビス(デルタ
−ブチレン)テトフハイドロ7A/7ラール、ジ−ノル
マp−プロピル4’/シンコメロネ−)、!/−ノルマ
ルーブチルサクシネート、2とドロキシエチルオクチル
サルファイド、ピリミジン誘導体、フタ/l’riJl
エステル類ピペリジン誘導体、キサントゲン酸誘導体、
アゼピン誘導体、ピベ】りン誘導体、七ルフォリン1傅
導体、ピロリジン銹導体、キノン類二価ア/l/:l−
ル、グリーー〃エーテ/l/石、あるいは。The use of repellents is a safe and economical method, and the known repellents for insects and mites include N and B1.
-diethyltoluamide, 2,5,4°5-bis(delta-butylene)tetofhydro7A/7ral, di-norma p-propyl4'/cincomemelone),! /-Normal-butyl succinate, 2 and droxyethyl octylsulfide, pyrimidine derivative, lid/l'riJl
Ester piperidine derivatives, xanthate derivatives,
Azepine derivatives, Pibe] Phosphorus derivatives, Heptaruforin 1 conductor, Pyrrolidine conductor, Quinones divalent a/l/:l-
le, gree〃ete/l/stone, or.
オクタクロルジプロピルニー5′μ、ビベロニルブトキ
サイド、N−(2−エチルヘキ$/A/)−ビンクロへ
1ター5−工ン−2,5ジカルボキシイミド、N−(2
−エチルヘキシル)−1−4ソプロピA/−4−メチル
ビシクロ[2,2,2]]オクトー5−二ン2.3−シ
カ〃ボ午Vイミが拳げられるが、屋内性のダ=Mについ
ては効力的に満足なものが得られていない現状である。octachlordipropyl 5'μ, biveronyl butoxide, N-(2-ethylhexylhex$/A/)-binchlor, 5-en-2,5 dicarboximide, N-(2
-ethylhexyl)-1-4sopropyl A/-4-methylbicyclo[2,2,2]]octo-5-2-2,3-cycabo porcelain is fisted, but indoor da=M Currently, we have not been able to obtain anything that satisfies the effectiveness of this.
本発明者に前記の如な突管に鑑み、鋭意研究の結果、塩
素化メタキシレノール及び/又は。In view of the above-mentioned tubes, the inventors of the present invention conducted extensive research and found that chlorinated meta-xylenol and/or.
パフオキシ安息香酸エステル化合物がダニ類の忌避に対
して極めて有効であることを見い出し本発明を完成した
ものである。The inventors have completed the present invention by discovering that puffoxybenzoic acid ester compounds are extremely effective in repelling mites.
すなわち本発明は塩素化メタキシレノール及び/又はパ
フオキシ安息香酸エステル化合物を有効成分とするダニ
類の忌避剤、および該忌避剤をダニ類の被害から防護し
ようとする対象物に塗布、散布または含有させることを
特徴とするダニ類の忌避方法を提供するものである。That is, the present invention provides a mite repellent containing a chlorinated metaxylenol and/or a puff oxybenzoic acid ester compound as an active ingredient, and a method for applying, spraying, or containing the repellent on an object to be protected from damage by mites. The present invention provides a method for repelling mites characterized by the following.
本発明の有効成分の1つであるパフオキシ安息香酸エス
テル化合物としてはパツオキV5R−息香酸メチ〃、パ
ツオキV安息香酸エチル、パフオキシ安息香酸ブチ〃、
パフオキシ安息香酸プロピ〃、パフオキシ安息香酸ネジ
ル等が拳げられる。Puffoxybenzoic acid ester compounds, which are one of the active ingredients of the present invention, include Patsuoki V5R-methyzoate, Patsuoki V ethyl benzoate, puffoxybenzoic acid butylate,
Puffed propylene benzoate, puffed oxybenzoate, etc. are used.
本発明方法な英雄するにはグーの発生、棲息しやすい対
象物またはその周辺物に該有効成分そのままか、あるい
はキジロール等の溶剤に溶解するか乳剤化する停、in
4常の方法で製剤化して塗布、i*布または含有させれ
ばよい。対象物または周辺物としては畳、カーペット等
の敷物家屋の床材、抑入れ、飼料・穀物袋、ソファ−等
の家具を挙げることができる。また該有効成分を含有さ
せる會こはamや樹脂中に含ませるのみならず糊液JP
塗料中にあらかじめ含有させてmいてもよい6その含有
角は加工方法によって昌なるが、0.05f/n1以上
含ませることが望ましい、また他の忌避剤と本発明の方
法をvt用することもできることはいうまでもない。The method of the present invention is effective against the generation of goo, by applying the active ingredient to the object or its surroundings, which is likely to inhabit, or by dissolving or emulsifying the active ingredient in a solvent such as Kijirol.
4. It may be formulated by a conventional method and applied, applied to cloth, or contained. Examples of the object or surrounding objects include rugs such as tatami mats and carpets, flooring materials for houses, cages, feed/grain bags, and furniture such as sofas. In addition, the active ingredient can be contained not only in am or resin, but also in paste JP.
It may be included in the paint in advance. 6 Its content angle varies depending on the processing method, but it is desirable to include it at 0.05 f/n1 or more, and the method of the present invention can be used with other repellents. Needless to say, you can also do it.
木腎明の忌避剤および忌避方法によれば前記のような公
知の忌避剤による方法に比べて非常に1響5い忌避効果
を示し、さらに効力の持続性。According to the repellent and repellent method of Akira Kinki, the repellent effect is far superior to that of the methods using known repellents as mentioned above, and the effect is more durable.
経済性、安全性、非興剤抵FC性などの点で有利である
。It is advantageous in terms of economy, safety, FC resistance, etc.
以下実施例に“C本発明を説明する。The present invention will be explained in the following examples.
実施例1
列用飼料のクフ7ト袋の外紙にパラクロロメタキシレノ
ールのキジロール溶液をパフクロロメタキシレノールα
5v〜の割合で塗布したもの3個を無処理袋2個を対照
とし、ケナガロナダニの多い倉庫へ放置した。1力月後
各袋について5ケ所カbら5X5cm切片を切り出して
顕微鏡下でダニ数を数え平均値をめた。その結果第1表
に示すように1本発明の処理をしたtAにはダニの付着
はほとんどなかった。Example 1 Puff chloromethaxylenol α to the outer paper of a 7-ton bag of feed for rows.
Three bags coated at a rate of 5v~ were left in a warehouse where there were a lot of woolly mites, with two untreated bags as a control. After one month, 5 x 5 cm sections were cut from 5 locations on each bag, and the number of mites was counted under a microscope and the average value was calculated. As a result, as shown in Table 1, almost no mites were attached to the tA treated according to the present invention.
wS1表
実施例2
8Bフテツクスに本発明の有効成分を混合したものを用
い、ポリプロピレフ1次基布にアクリ/l/ 内p’a
ヲタフテイングしたものをジュートへ次八布に接着し
カーペットを?l!造した。対照として昆虫やダニ類の
忌避物質として知られたものを同(°f5に処理した。wS1 Table Example 2 Using 8B footwear mixed with the active ingredient of the present invention, a polypropylene primary base fabric was coated with acrylic/l/inner p'a.
Glue the wotufting to jute and then glue it to eight fabrics to make a carpet? l! Built. As a control, a substance known to repel insects and mites was treated at the same temperature (°f5).
各々5×5d片に切りとリケナガコナダ二を放置し50
X20X10cIlの容器中に5枚体宛配置し24時間
後に付着状況を消窄した。その結果、第2表tこ示すよ
うに本発明の忌避剤を用いたものはダニ類の付着がほと
んどなかった。Cut each piece into 5 x 5 d pieces and leave Rike-naga-konada-2 for 50
Five pieces were placed in a 20 x 10 cIl container, and the adhesion was quenched after 24 hours. As a result, as shown in Table 2, there was almost no adhesion of mites to the products using the repellent of the present invention.
畳床の表面に本発明の有効成分であるパフクロロメタキ
シレノールと対照とし°CのN、N−ジエチルトリアミ
ドのキンロール溶液を有効成分量27/dの割合で散布
したものに畳表をつけ。The surface of the tatami floor was sprayed with puffed chloromethaxylenol, which is the active ingredient of the present invention, and a Kinrol solution of N,N-diethyltriamide at °C as a control at a ratio of 27/d of the active ingredient, and then the tatami surface was attached.
無処理の畳とそれぞれ2枚つつ鉄筋、コンクy−ト造り
のアパートの6畳の間を二敷き込み、水をはった容器を
畳上に置いて部屋を閉め切った。They laid two untreated tatami mats and two reinforcing steel concrete tatami mats in the 6 tatami room of their apartment building, placed two containers of water on top of the tatami mats, and closed off the room.
5力月後、5カ月後に観察のため畳の上に水をはったシ
ャーレ6ケづつを置き、24時間後。After 5 months and 5 months, six petri dishes each filled with water were placed on a tatami mat for observation, and 24 hours later.
水面に浮んだダニ数を顕微鏡下で数えた。The number of mites floating on the water surface was counted under a microscope.
その結果、第5表に示すように1本発明の処理を施した
畳の上においたシャーレ中のダニの数は他のものに比べ
著しく少なかった。As a result, as shown in Table 5, the number of mites in the Petri dish placed on the tatami mat treated with the present invention was significantly lower than in the other dishes.
’n 5 s シャーレ中のダニ数(5ケ平均)英雄例
4
パフオキシ安息香酸ブチルのエチルアルコ−/l/溶液
をクロス帖りのソファ−の表面に有効成分:IN 19
/dの割合で散布し、無処理品とともに居間に置いて使
用した。'n 5s Number of mites in a petri dish (average of 5 mites) Example 4 Apply a solution of butyl puffoxybenzoate in ethyl alcohol to the surface of a cloth sofa Active ingredient: IN 19
It was sprayed at a rate of /d and placed in the living room along with untreated products.
6力月後に吸引式の電気掃除器をかけ、集まったチリを
飽和食塩水に入れて攪拌し、ダニをグーリから公序させ
て吸引、濾過し、濾紙上に集めてト!′I微鏡下で数え
た。そのl?を果、第4表に示すように1本発明の処理
を施したソファ−にはダニの付着が掩めて少なかった。After 6 months, use a suction vacuum cleaner, add the collected dust to saturated saline, stir, remove the dust mites from the gourds, suction, filter, collect on filter paper, and do it! 'I Counted under a microscope. That l? As a result, as shown in Table 4, the sofa treated according to the present invention had significantly fewer mites attached to it.
第 3 表 特許用門人 神東塗料株式会社Table 3 Patent student Shinto Paint Co., Ltd.
Claims (1)
安息香酸エステル化合物を有効成分とするダニ類の忌避
剤。 2、塩素化メタキシレ/−ル及び/又はパフオキシ安息
香酸エステル化合物を有効成分とするダニ類の忌避剤を
ダニ類の?I!!害から防護しようとする:tJ象物に
塗布、散布または含有させることを特徴とするダニ類の
忌避方法。 5、 対象物が畳、カーペット等の敷物、家屋の床材、
押入れ、飼料・穀物袋、ソファ−等の家具である特許請
求の範囲第2項記載のダニ?J゛1の忌避方法。[Scope of Claims] 1. A mite repellent containing jfl dilated metaxylenol and/or a puffoxybenzoic acid ester compound as an active ingredient. 2. Is it possible to use a mite repellent containing chlorinated metaxylene and/or puffoxybenzoic acid ester compound as an active ingredient against mites? I! ! To protect from harm: tJ A method for repelling mites characterized by applying, spraying, or containing it on an object. 5. The object is rugs such as tatami mats, carpets, flooring of houses,
The mites described in claim 2 that are furniture such as closets, feed/grain bags, and sofas? How to avoid J゛1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58116589A JPS608202A (en) | 1983-06-27 | 1983-06-27 | Repellent against acarids and repelling |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58116589A JPS608202A (en) | 1983-06-27 | 1983-06-27 | Repellent against acarids and repelling |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS608202A true JPS608202A (en) | 1985-01-17 |
Family
ID=14690876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58116589A Pending JPS608202A (en) | 1983-06-27 | 1983-06-27 | Repellent against acarids and repelling |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS608202A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61202802A (en) * | 1985-03-06 | 1986-09-08 | 日本セメント株式会社 | Manufacture of instantaneous mold-release concrete block |
| JPS623903A (en) * | 1985-06-29 | 1987-01-09 | 富士特殊コンクリ−ト工業株式会社 | Manufacture of concrete product |
| JPS6233107A (en) * | 1985-08-06 | 1987-02-13 | Earth Chem Corp Ltd | Mite controlling agent |
| JPS6283107A (en) * | 1985-10-08 | 1987-04-16 | 三谷セキサン株式会社 | Manufacture of concrete block with seat |
| JPS62246886A (en) * | 1986-04-18 | 1987-10-28 | ナショナル住宅産業株式会社 | Glazed inorganic substrate |
| JPH02204005A (en) * | 1989-02-03 | 1990-08-14 | Chiyoda Tech & Ind Co Ltd | Method for forming concrete product with facing |
| JPH0649985A (en) * | 1992-07-10 | 1994-02-22 | Matsuoka Concrete Kogyo Kk | Surface decoration of concrete product |
| JPH072585A (en) * | 1993-05-21 | 1995-01-06 | Fuji Tokushu Concrete Kogyo Kk | Surface-decorated concrete product made of porous aggregate |
| JPH07195335A (en) * | 1993-08-30 | 1995-08-01 | Fuji Tokushu Concrete Kogyo Kk | Surface decorative concrete block |
| JP2019069934A (en) * | 2017-10-05 | 2019-05-09 | 上野製薬株式会社 | Pest repellent |
-
1983
- 1983-06-27 JP JP58116589A patent/JPS608202A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61202802A (en) * | 1985-03-06 | 1986-09-08 | 日本セメント株式会社 | Manufacture of instantaneous mold-release concrete block |
| JPS623903A (en) * | 1985-06-29 | 1987-01-09 | 富士特殊コンクリ−ト工業株式会社 | Manufacture of concrete product |
| JPS6233107A (en) * | 1985-08-06 | 1987-02-13 | Earth Chem Corp Ltd | Mite controlling agent |
| JPS6283107A (en) * | 1985-10-08 | 1987-04-16 | 三谷セキサン株式会社 | Manufacture of concrete block with seat |
| JPS62246886A (en) * | 1986-04-18 | 1987-10-28 | ナショナル住宅産業株式会社 | Glazed inorganic substrate |
| JPH02204005A (en) * | 1989-02-03 | 1990-08-14 | Chiyoda Tech & Ind Co Ltd | Method for forming concrete product with facing |
| JPH0649985A (en) * | 1992-07-10 | 1994-02-22 | Matsuoka Concrete Kogyo Kk | Surface decoration of concrete product |
| JPH072585A (en) * | 1993-05-21 | 1995-01-06 | Fuji Tokushu Concrete Kogyo Kk | Surface-decorated concrete product made of porous aggregate |
| JPH07195335A (en) * | 1993-08-30 | 1995-08-01 | Fuji Tokushu Concrete Kogyo Kk | Surface decorative concrete block |
| JP2019069934A (en) * | 2017-10-05 | 2019-05-09 | 上野製薬株式会社 | Pest repellent |
| JP2023016854A (en) * | 2017-10-05 | 2023-02-02 | 上野製薬株式会社 | pest repellent |
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