JPS61107980A - Resin treatment of wooden material - Google Patents

Resin treatment of wooden material

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Publication number
JPS61107980A
JPS61107980A JP22836984A JP22836984A JPS61107980A JP S61107980 A JPS61107980 A JP S61107980A JP 22836984 A JP22836984 A JP 22836984A JP 22836984 A JP22836984 A JP 22836984A JP S61107980 A JPS61107980 A JP S61107980A
Authority
JP
Japan
Prior art keywords
epoxy resin
resin
liquid epoxy
wood
wooden material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP22836984A
Other languages
Japanese (ja)
Other versions
JPS6214351B2 (en
Inventor
Hisayoshi Osumi
大隅 久芳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Gakki Co Ltd
Original Assignee
Nippon Gakki Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Gakki Co Ltd filed Critical Nippon Gakki Co Ltd
Priority to JP22836984A priority Critical patent/JPS61107980A/en
Publication of JPS61107980A publication Critical patent/JPS61107980A/en
Publication of JPS6214351B2 publication Critical patent/JPS6214351B2/ja
Granted legal-status Critical Current

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Abstract

PURPOSE:To attain to simplify manufacturing work, by coating the surface of a wooden material with a solid epoxy resin and a liquid epoxy resin and subsequently applying heat treatment to the coated one. CONSTITUTION:A liquid epoxy resin layer 2 is applied to the surface of a wooden material 1 in a basis wt. of about 20-200g/m<2>. Next, a powdery epoxy resin is scattered to the liquid epoxy resin layer 4 in a basis wt. of about 100-300g/m<2> to form a powdery epoxy resin layer 3 Subsequently, the wooden material 1, which was provided with the liquid epoxy resin layer 2 and the powdery epoxy resin layer 3, is held between two release films 4, 4 and subjected to hot pressing treatment by hot presses 5, 5 and said release films 4, 4 are released to obtain a resin treated wooden material 6.

Description

【発明の詳細な説明】[Detailed description of the invention]

〔産業上の利用分野〕 この発明は、木質材の樹脂処理法に係り、木質材表面に
固体エポキシ@脂と液体エポキシ樹脂とを組み合?て適
用し、熱圧処理することにより、木質材の表面に平滑で
均一な樹脂膜を形成するとともに木質材内部にも樹脂を
浸透さt固化せしめて木質材を強化するようにするもの
である。 〔従来の技術〕 従来の木質材の樹脂処理法としては、木質材を減圧加圧
処理で不飽々μポリエステル樹脂などの樹脂を含浸させ
、熱圧硬化ぜしめるWPC法や、不繊布や紙などに樹脂
を含浸させ、乾燥さぜたのち、木質材上に被覆し、熱圧
硬化させるオーバーレイ紙法や、不織布や紙などに粉体
のエポキシ樹脂等を融着?しめ、これを木質材とともに
熱圧硬化させる粉体at Iihフィルム法などが知ら
れている。 〔発明が解決しようとする問題点〕 しかしながら、これらの樹脂処理法には次のような問題
点があり、その解決か望まれていた。まずWPO法では
、減圧加圧処理で樹脂を含浸させるようにしているので
、工程が複雑で設備も大がかりとなり、製造コストが嵩
み、また得られた処理木質材の表面には樹脂膜が形成さ
れず、別に上塗りが必要である。 また、オーバレイ紙法や粉体樹脂フィルム法では、樹脂
の流れが悪く、導管の大きな木質材では、「浮き」や「
白化」現象が生じて使用できない。 不織布や紙を使用するのでこれが樹脂膜に残存し、樹脂
層の透明感が劣り、膜厚が大きくなるので(100μm
以上)、屈曲性が悪い。 〔問題点を解決するための手段〕 そこで、この発明では、固体エポキシ樹脂と液体エポキ
シ樹脂とを組み合せ、木質材表面に塗布や散布等の手段
によって適用し、ついでこれを熱圧処理することにより
、上記問題点を解決するようにした。 以下、図面を参照しつつ工程を追っ
[Industrial Application Field] This invention relates to a resin treatment method for wood materials, in which a solid epoxy @ fat and a liquid epoxy resin are combined on the surface of the wood material. By applying the resin to the surface of the wood and subjecting it to heat and pressure treatment, a smooth and uniform resin film is formed on the surface of the wood, and the resin also penetrates into the wood and hardens to strengthen the wood. . [Conventional technology] Conventional resin treatment methods for wood materials include the WPC method, in which wood materials are impregnated with a resin such as unsaturated μ polyester resin by vacuum and pressure treatment, and hardened under heat and pressure; The overlay paper method involves impregnating a resin with resin, drying it, coating it on a wood material, and curing it under heat. Or, do you use the overlay paper method, in which a resin is impregnated with resin, dried, and then coated on a wood material and cured under heat? Or is there a method of fusing powdered epoxy resin, etc., to nonwoven fabric or paper? A powder at IIh film method is known, in which the powder is compressed and cured by heat and pressure together with a wood material. [Problems to be Solved by the Invention] However, these resin treatment methods have the following problems, and a solution to these problems has been desired. First, in the WPO method, resin is impregnated by pressure reduction and pressure treatment, so the process is complicated and the equipment is large-scale, increasing manufacturing costs, and a resin film is formed on the surface of the resulting treated wood. No, a separate top coat is required. In addition, with the overlay paper method and powder resin film method, the flow of the resin is poor, and when using wood materials with large conduits, "floating" or "
Cannot be used due to "whitening" phenomenon. Since non-woven fabric or paper is used, this remains in the resin film, reducing the transparency of the resin layer and increasing the film thickness (100 μm).
above), the flexibility is poor. [Means for solving the problem] Therefore, in this invention, a solid epoxy resin and a liquid epoxy resin are combined, applied to the surface of a wooden material by means such as coating or spraying, and then subjected to heat and pressure treatment. , to solve the above problems. Below, follow the process while referring to the drawings.

【詳細に説明する。 第1図ないし第4図は、この発明のwR脂処理法の一例
を示すもので、図中符号lは、突板、化粧単板などで代
表される板状の木質材である。 この木質材10表面には、第】図に示すように、まず液
体エポキシ檎脂層2が設けられる。この液体エポキシ樹
脂層2は、液体エポキシ樹脂をロールコータなどの塗布
手段によって、坪量20〜200Jil/m程度に塗布
することによって得られる。ここで使用される液体エポ
キシ樹脂としては、常温(20〜25℃)で液状を呈す
るエポキシ樹脂に、所定の意地の硬化剤を添加した液状
のものが使用され、例えばビス7−1−ノールム型エポ
キシ樹脂ではエポキシ当量が225程度以下のものがこ
れに該当する。その他、ノボ2ツク型エポキシ樹脂、グ
リシジルエステ/L/型エポキシ樹脂、臭素化エポキシ
樹脂等で常温で液状を呈するものも使用できる。 次に、この液体エポキシ樹脂層2上に、第2図に示すよ
うに粉体エポキシ樹脂#3を設ける。この粉体エポキシ
樹脂層3は、常温で固体のエポキシ*11*に所定の公
比の硬化剤を添加し、たものを粒径50〜150μTr
L程度に粉砕してなる粉末状のエポキシ樹脂を、静電塗
装、散布などの手段によって坪gioo−300,p/
ぜ程度に散布することによって得られる。ここで用いら
れる固体エポキシ樹脂とは、常温(20〜25℃)で固
体状であるエポキシ樹脂であって、例えばとスフエノー
ルA型エポキシ樹脂ではエポキシ当量225程度以上、
通常450以上のものが該当し、その他ノボラック型エ
ポキシ樹脂、グリシジルエステル型エポキシ樹脂、臭素
化エポキシ樹脂などで常温で固体のものが使用できる。 また、粉末状のエポキシ樹脂には、必要に応じて炭酸カ
ルシク°ムなどの体質顔料、着色材、消泡剤を加えても
よい。 ついで、第3図に示すように、液体エポキシ樹脂層2お
よび粉体エポキシ樹脂M3が設けられた木質材1を、2
枚の離型用フィルム4.4で挿み、ホットプレス5.5
などによって熱圧処理する。 Jllli!型用フィルム4には、耐熱性、非粘着性の
厚み15〜50μm程度のフッ素樹脂フィルムが好適で
ある。熱圧処理条件は、液体エポキシ樹脂層2および粉
体エポキシ樹脂NI3を構成する液体エポキシ樹脂およ
び固体エポキシ樹脂の種類、木質材10表面等によつ【
適宜法められるが、通常は温度130〜150℃、時間
7〜20分、圧力は合板等の積層に適用される程度の圧
のまたはそれ以下の圧力とされる。 こり熱圧処理によって、液体エポキシ樹脂は、その粘度
が急激に低下して高流動化し、木質材中に浸透してゆく
、これと同時に木質材l中に仁っている水分、空気等が
気泡として高流動化状態の液状エポキシ樹脂中を外方に
移動し、外部に散逸する。また、同体エポキシ樹脂も諮
融するが、七のだ融粘度は大きいので、木質材1表面の
導管部などの凹部に流入するとともに表面に滞まり、表
面に洩る液体エポキシ樹脂と混合するう加熱が巡行する
と、両方のエポキシ樹脂が架橋しはじめ、固化する。 ついで、第4図に示すように、11!型用フイルム4.
4を剥離すれば、目的とする樹脂処理木質材6が得られ
る。かくして得られた樹脂処理木質材6は、その内部が
エポキシ樹脂で固められ強化されるとともに表面の専管
部もエポキシ樹脂で埋められ、表面には樹脂膜7が形成
されている。なお、離型用フィルム4に艷泊しフィルム
を用いれば、a(Jjill膜7は@tpxシ仕上げと
なり、虎有りフイルムを用いれば艶有り仕上げとなる。 〔作用〕 このような樹脂処理法によれば、エポキシ便脂の含浸と
硬化とが熱圧処理で同時に行えることになるので、工程
数が少なくなり、作業の簡略化が図れ、設備もわずかで
よい、また、エポキシ樹脂全体としての流れ(70−)
が良(、深(、大きな導管部などの凹部にも十分樹脂が
流れ込み、木質材lの表面には硬化エポキシ樹脂よりな
る平滑な樹脂膜7か形成され、上塗り塗装を不要とする
こともできる。さらに、不織布や紙などの樹脂担体を使
用しないので樹脂膜7は透明感の良好な塗膜となり、か
つ膜厚をその分薄くすることができるので、屈曲性の良
い樹脂処理材6を得ることも、できる。 また、粉体エポキシ樹脂と液体エポキシ樹脂とを組み合
ぜているので、粉体エポキシ樹脂のみでは、木質材lに
対する密着性がないので作業時に流動してしまい、取扱
いが面倒でるるなとの問題や、液体エポキシ側脂のみで
は熱圧処理時、すぐに流動化して外部に流出してしまう
などの問題がない。 〔他の具体例〕 第5図は、この発明の樹脂処理法の他の例を示すもので
ある。この例の処理法では、粉体エポキシ樹脂と液体エ
ポキシ樹脂とを予め所定の量比で混合したペースト状の
一合物を、ロールコーメ、ドクターブレードなどの手段
によって木質材1表面に塗布して混合エポキシ樹脂層8
を設け、ついで離氾用フィルム4.4で挾んで熱圧処理
するようにしている。この処理法では、エポキシ樹脂の
塗布工程が一回で済み、作業能率が向上する。 〔実施例1〕 木質材として、厚み0.2 amのアメリカンフォール
ナツト化粧突板を不織布で晟打ちしたものを用意した。 この突板の表面に、液体エポキシ樹11ti層トシて、
エピコート828(エポキシ当k190、液状、油化シ
ェル製)100重蓋部に硬化剤2−エチ、nt −4−
メチル−イミダゾ−/L/3重量部を1合したものを1
00#/m塗布した。ついで、この上に、粉体エポキシ
樹脂層として、エピコート1004(エポキシ当[90
0,固体状、油化シェル[)100重蓋部に硬化剤2−
エチル−4−メチル−イミダゾ−/I/3重量部を配合
し、ボールミルで100メツシユパスまで粉砕した粉体
エポキシ樹脂を200.!9/ゴ敗化した。厚さ25μ
mのポリフッ化ビニ−/l/フィルムの1llIi型用
フイ〃ムで挿み、ホットプレスにて130℃、lO分熱
圧処浬した。 得られた樹脂処理突板は、樹脂強化され、かつ表面には
約100μmの厚さの透明感、平滑性の良好なml+m
pIAが形成され、美麗な仕上りのアメリカンウオール
ナツト化粧材でめった。 〔実施例2〕 木質材として、厚み0.2 y<rttのアメリカンフ
ォールナツト化粧突板を不織化で泉打ちしたものを用意
した。この突板の六回に、混合エポキシ樹脂層トシテ、
xピコ−ト828 100iiij部に2−一エチルー
4−メチルーイミダゾール3重製部を配合して100メ
ツシユパスに粉砕したものを加えて混合、攪拌したペー
スト状混合物を300I/TrXに塗布した。これを実
施例1と同様にして熱圧処理し、樹り処理突板を得た。 得られた樹脂処理アメリカンフォールナツト突板は同様
に大鹿な仕上りであった。 〔発明の効果〕 以上説明したように、この発明の本質材のifn脂処脂
性理法木質材の表面を固体エポキシ樹脂および液体エポ
キシ樹脂で彼恨し、これを熱圧処理するものであるので
、エポキシI(脂の含浸と硬化とが熱圧処理で一挙に行
えることになり、製造作業の簡略化が計れ、製造設備も
簡単なもので済む。 また、エポキシ樹脂全体としての流動性が大きく、導管
部などの凹部にも充分樹脂が流れ込み、表面には上塗り
塗膜に代る平滑で均一な樹脂膜が形成され、そのまま化
粧材として製品とすることもできる。
[Explain in detail. 1 to 4 show an example of the wR fat treatment method of the present invention, and the reference numeral 1 in the figures represents a plate-shaped wood material such as a veneer or a decorative veneer. On the surface of this wood material 10, first, a liquid epoxy resin layer 2 is provided, as shown in FIG. This liquid epoxy resin layer 2 is obtained by applying liquid epoxy resin to a basis weight of about 20 to 200 Jil/m using a coating means such as a roll coater. The liquid epoxy resin used here is a liquid epoxy resin that is liquid at room temperature (20 to 25°C) and a predetermined curing agent added thereto, such as the Bis7-1-norm type. This applies to epoxy resins that have an epoxy equivalent of about 225 or less. In addition, epoxy resins that are liquid at room temperature, such as Novo2-type epoxy resin, glycidyl ester/L/type epoxy resin, and brominated epoxy resin, can also be used. Next, powder epoxy resin #3 is provided on this liquid epoxy resin layer 2 as shown in FIG. This powder epoxy resin layer 3 is made by adding a curing agent in a predetermined common ratio to epoxy *11* that is solid at room temperature, and then forming a mixture with a particle size of 50 to 150 μTr.
Powdered epoxy resin that has been crushed to about L size is applied by means such as electrostatic coating or spraying.
It can be obtained by dispersing it in small amounts. The solid epoxy resin used here is an epoxy resin that is solid at room temperature (20 to 25°C), and for example, Suphenol A type epoxy resin has an epoxy equivalent of about 225 or more,
Generally, those having a molecular weight of 450 or higher are applicable, and other types of novolac type epoxy resin, glycidyl ester type epoxy resin, brominated epoxy resin, etc. that are solid at room temperature can be used. Further, an extender pigment such as calcium carbonate, a coloring agent, and an antifoaming agent may be added to the powdered epoxy resin as necessary. Next, as shown in FIG. 3, the wooden material 1 provided with the liquid epoxy resin layer 2 and the powder epoxy resin M3 is
Insert with a sheet of release film 4.4, hot press 5.5
Heat and pressure treatment is performed. Jlli! As the mold film 4, a heat-resistant, non-adhesive fluororesin film having a thickness of about 15 to 50 μm is suitable. [
The temperature is usually 130 to 150°C, the time is 7 to 20 minutes, and the pressure is the same or lower than that applied to laminated sheets of plywood, etc., although the conditions may be determined as appropriate. Due to the heat and pressure treatment, the liquid epoxy resin rapidly reduces its viscosity, becomes highly fluid, and penetrates into the wood.At the same time, the moisture, air, etc. in the wood become bubbles. The liquid epoxy resin moves outward through the highly fluidized liquid epoxy resin and dissipates to the outside. In addition, the homogeneous epoxy resin also melts, but since it has a high melt viscosity, it flows into concavities such as conduits on the surface of the wood material 1 and stays on the surface, where it mixes with the liquid epoxy resin leaking onto the surface. As the heating cycle continues, both epoxy resins begin to crosslink and solidify. Then, as shown in Figure 4, 11! Film for mold 4.
By peeling 4, the desired resin-treated wood material 6 can be obtained. The interior of the thus obtained resin-treated wood material 6 is hardened and strengthened with epoxy resin, and the exclusive portion on the surface is also filled with epoxy resin, and a resin film 7 is formed on the surface. Note that if a film is used as the release film 4, the a(Jjill film 7 will have a @tpx finish, and if a film with a tabular pattern is used, a glossy finish will be obtained. According to the epoxy resin impregnation and curing can be done simultaneously by heat and pressure treatment, the number of steps is reduced, the work is simplified, and only a small amount of equipment is required, and the overall flow of epoxy resin is improved. (70-)
The resin flows sufficiently into concave areas such as large conduits, and a smooth resin film 7 made of hardened epoxy resin is formed on the surface of the wooden material, making it possible to eliminate the need for a top coat. Furthermore, since a resin carrier such as nonwoven fabric or paper is not used, the resin film 7 becomes a coating film with good transparency, and the film thickness can be made correspondingly thinner, so that a resin treated material 6 with good flexibility is obtained. In addition, since powder epoxy resin and liquid epoxy resin are combined, powder epoxy resin alone does not have the adhesion to the wood material, so it flows during work, making handling difficult. There is no problem with the liquid epoxy side fat, and there are no problems such as the liquid epoxy side fat immediately becoming fluidized and flowing out during heat and pressure treatment. [Other Specific Examples] This shows another example of the resin treatment method. In this treatment method, a paste-like mixture of powdered epoxy resin and liquid epoxy resin in a predetermined ratio is mixed with a roll comb or a doctor blade. A mixed epoxy resin layer 8 is applied to the surface of the wood material 1 by means such as
, and then sandwiched between flood-relief films 4.4 and subjected to heat-pressure treatment. This treatment method requires only one epoxy resin application step, improving work efficiency. [Example 1] As a wood material, a 0.2 am thick American fall nut decorative veneer was beaten with a non-woven fabric. On the surface of this veneer, apply an 11ti layer of liquid epoxy resin.
Epikote 828 (epoxy K190, liquid, made by Yuka Shell) 100 hardening agent 2-ethyl, nt-4- in the lid part
1 mixture of methyl-imidazo-/L/3 parts by weight
00 #/m was applied. Then, on top of this, Epikote 1004 (epoxy resin [90
0, solid, oily shell [) 100 hardening agent in the lid part 2-
A powdered epoxy resin containing 3 parts by weight of ethyl-4-methyl-imidazo-/I/1 and pulverized in a ball mill to a mesh pass of 200. ! 9/ Go was defeated. Thickness 25μ
It was inserted with a 1llIi type film of polyfluorinated vinyl/l/m film and subjected to hot pressure treatment at 130° C. for 10 minutes using a hot press. The obtained resin-treated veneer is resin-reinforced and has a transparent surface with a thickness of about 100 μm and a smooth surface with good ml+m
PIA is formed and finished with American walnut decorative material with a beautiful finish. [Example 2] As a wood material, an American fall nut decorative veneer with a thickness of 0.2 y<rtt was prepared by sprinkling it into a non-woven state. Six times on this veneer, add a layer of mixed epoxy resin,
Three parts of 2-1 ethyl-4-methyl-imidazole were blended with 100 parts of Picote 828, pulverized to 100 mesh passes, mixed and stirred, and a paste-like mixture was applied to 300I/TrX. This was subjected to heat and pressure treatment in the same manner as in Example 1 to obtain a wood-treated veneer. The resulting resin-treated American fall nut veneer had a similar finish. [Effects of the Invention] As explained above, the surface of the essential material of the present invention is treated with a solid epoxy resin and a liquid epoxy resin, and then subjected to heat and pressure treatment. Epoxy I (impregnating with fat and curing can be done all at once by heat-pressure treatment, simplifying manufacturing work and requiring simple manufacturing equipment. In addition, the epoxy resin as a whole has high fluidity, The resin flows sufficiently into concave portions such as conduit portions, and a smooth and uniform resin film is formed on the surface in place of a top coat, and can be used as a product as a decorative material.

【図面の簡単な説明】[Brief explanation of drawings]

第1図ないし第4図は、この発明の樹脂処理法の一例を
工程順に示す説明図、 第5図は、この発明の樹脂処理法の他の例を示す説明図
でおる。 1・・・木質材、2・・・液体エポキシ樹脂層、3・・
・粉体エポキシ樹脂層、5・・・ホットプレス、6・・
・樹脂処理木質材。
1 to 4 are explanatory diagrams showing an example of the resin treatment method of the present invention in the order of steps, and FIG. 5 is an explanatory diagram showing another example of the resin treatment method of the present invention. 1... Wood material, 2... Liquid epoxy resin layer, 3...
・Powder epoxy resin layer, 5...hot press, 6...
・Resin treated wood material.

Claims (3)

【特許請求の範囲】[Claims] (1)木質材の表面を固体エポキシ樹脂および液体エポ
キシ樹脂で被覆し、ついでこれを熱圧処理することを特
徴とする木質材の樹脂処理法。
(1) A method for treating wood with resin, which comprises coating the surface of the wood with a solid epoxy resin and a liquid epoxy resin, and then subjecting it to heat and pressure treatment.
(2)木質材の表面に液体エポキシ樹脂を塗布し、さら
にこの上に固体エポキシ樹脂を置き、ついでこれを熱圧
処理することを特徴とする特許請求の範囲第1項記載の
木質材の樹脂処理法。
(2) A resin for wood material according to claim 1, characterized in that a liquid epoxy resin is applied to the surface of the wood material, a solid epoxy resin is further placed on top of the liquid epoxy resin, and then this is subjected to heat and pressure treatment. Processing method.
(3)木質材の表面に液体エポキシ樹脂と固体エポキシ
樹脂との混合物を塗布し、ついでこれを熱圧処理するこ
とを特徴とする特許請求の範囲第1項記載の木質材の樹
脂処理法。
(3) A method for treating a wood material with resin according to claim 1, which comprises applying a mixture of a liquid epoxy resin and a solid epoxy resin to the surface of the wood material, and then subjecting the mixture to heat and pressure treatment.
JP22836984A 1984-10-30 1984-10-30 Resin treatment of wooden material Granted JPS61107980A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22836984A JPS61107980A (en) 1984-10-30 1984-10-30 Resin treatment of wooden material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22836984A JPS61107980A (en) 1984-10-30 1984-10-30 Resin treatment of wooden material

Publications (2)

Publication Number Publication Date
JPS61107980A true JPS61107980A (en) 1986-05-26
JPS6214351B2 JPS6214351B2 (en) 1987-04-01

Family

ID=16875381

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22836984A Granted JPS61107980A (en) 1984-10-30 1984-10-30 Resin treatment of wooden material

Country Status (1)

Country Link
JP (1) JPS61107980A (en)

Also Published As

Publication number Publication date
JPS6214351B2 (en) 1987-04-01

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