JPS6112955B2 - - Google Patents
Info
- Publication number
- JPS6112955B2 JPS6112955B2 JP51042227A JP4222776A JPS6112955B2 JP S6112955 B2 JPS6112955 B2 JP S6112955B2 JP 51042227 A JP51042227 A JP 51042227A JP 4222776 A JP4222776 A JP 4222776A JP S6112955 B2 JPS6112955 B2 JP S6112955B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- water
- ink
- powder
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000000843 powder Substances 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 8
- 238000004513 sizing Methods 0.000 claims description 8
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 8
- 235000019441 ethanol Nutrition 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000005018 casein Substances 0.000 description 5
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 5
- 235000021240 caseins Nutrition 0.000 description 5
- 239000003292 glue Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000779 smoke Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000011928 denatured alcohol Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000004302 potassium sorbate Substances 0.000 description 2
- 235000010241 potassium sorbate Nutrition 0.000 description 2
- 229940069338 potassium sorbate Drugs 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 244000038022 Chenopodium capitatum Species 0.000 description 1
- 235000004391 Chenopodium capitatum Nutrition 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 229940116229 borneol Drugs 0.000 description 1
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- -1 polyoxyethylene nonyl phenyl ether Polymers 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
【発明の詳細な説明】
従来市販の墨は固形状あるいは液状であつて、
前者は使用前にすずりを用いてすり液状とせねば
ならない面倒さがあり、後者は容器を必要とし包
装費が高価になる等の欠点があつた。これらの欠
点を改良し墨を粉末化しようと試みられたことも
あるが、飛散して周囲を汚し、かつ水をはじいて
きわめて溶けにくく使いにくかつた。本発明は墨
をきわめて水に溶けやすい顆粒状とし、保存・携
行・使用に簡便でしかも量産可能かつ簡易包装可
能で安価に供給できる特徴がある。[Detailed Description of the Invention] Traditionally commercially available ink is either solid or liquid,
The former has the trouble of having to make it into a slurry before use, while the latter requires a container and is expensive to package. Attempts have been made to improve upon these shortcomings by turning ink into powder, but it scatters, staining the surrounding area, and repels water, making it extremely difficult to dissolve and difficult to use. The present invention has the characteristics that ink is made into granules that are extremely soluble in water, and that it is easy to store, carry, and use, can be mass-produced, can be easily packaged, and can be supplied at low cost.
本発明に用いる水溶性糊剤としてはニカワ、ゼ
ラチン、カゼイン、アラビアゴム、デキストリン
のような動植物性糊剤やカルボキシメチルセルロ
ーズ、ポリビニールアルコールのような合成糊剤
が使用できる。中でもニカワ、カゼインは古来よ
り使用される墨の粘り、のびやにじみ具合等に等
しい効果を与えるので望ましく、ニカワ又はカゼ
インを糊剤として単独で使用するかあるいはこれ
らを主成分とし他の糊剤を補助的に用いることが
望ましい。顔料としては油煙、松煙、カーボン・
ブラツクまたは黒色水性分散顔料等が用いられる
が、ナタネ油を燃焼させて得た油煙が最上質であ
る。必要に応じて糊剤・顔料に湿潤剤としてグリ
セリン、エチレングリコール、ジエチレングリコ
ール、プロピレングリコール等の多価アルコール
を顔料分散剤としてポリオキシエチレンノニルフ
エニルエーテルやポリオキシエチレンソルビタン
モノステアレート等の非イオン活性剤を防腐剤と
してジヒドロ酢酸ソーダ、安息香酸ソーダ、ソル
ビン酸カリ等を芳香剤としてボルネオール等を添
加してもよい。そして粉末化した墨を造粒する湿
潤剤としてはメチルアルコール、エチルアルコー
ル、プロピルアルコール等の低級の親水性アルコ
ールが用いられる。これらのアルコールは１〜10
％（好ましくは２〜５％）の水分を含有する必要
がある。この理由については後述する。 As the water-soluble sizing agent used in the present invention, animal and vegetable sizing agents such as glue, gelatin, casein, gum arabic, and dextrin, and synthetic sizing agents such as carboxymethyl cellulose and polyvinyl alcohol can be used. Among them, glue and casein are desirable because they have the same effect on the stickiness, spreadability, and bleeding of ink that has been used since ancient times. Glue or casein can be used alone as a sizing agent, or these can be used as the main ingredients and other sizing agents can be used. It is desirable to use it as a supplement. Pigments include oil smoke, pine smoke, carbon,
Black or black aqueous dispersion pigments are used, but the best quality is oil smoke obtained by burning rapeseed oil. If necessary, use polyhydric alcohols such as glycerin, ethylene glycol, diethylene glycol, and propylene glycol as wetting agents for thickening agents and pigments, and nonionic substances such as polyoxyethylene nonyl phenyl ether and polyoxyethylene sorbitan monostearate as pigment dispersants. The activator may be used as a preservative, and sodium dihydroacetate, sodium benzoate, potassium sorbate, etc. may be used as an aromatic agent, and borneol or the like may be added. As a wetting agent for granulating the powdered ink, lower hydrophilic alcohols such as methyl alcohol, ethyl alcohol, and propyl alcohol are used. These alcohols are 1-10
% (preferably 2 to 5%). The reason for this will be explained later.
これらの成分より本発明顆粒状の墨を製造する
には３〜10重量部（以下単に部と記す）（好まし
くは５〜８部）の糊剤０〜10部（好ましくは５〜
８部）の湿潤剤０〜1.5部（好ましくは0.2〜１
部）の界面活性剤０〜１部の防腐剤成分の総量が
100部となる量の水を加熱撹拌により混合溶解さ
せる。この溶液に２−30部（好ましくは５−22
部）の顔料を加え高速撹拌機により分離させて墨
汁とする。あるいは顔料の種類によつては少量の
水により濃厚溶液をつくり、３本ロールミル等で
練つたあと水の残りを加えて撹拌し墨汁とする。
この墨汁を30℃〜50℃の加温常態で３〜７Kg/cm2
の空気圧力で80〜120℃の熱風中に噴霧し、ある
いは加熱回転円板に当てて急速乾燥させ粉末とす
る。この場合の乾燥速度は10〜50/hr.である。
この際乾燥装置中を減圧状態とすることにより、
熱風の温度を低めることができるとともに乾燥能
率を高めることも可能である。このようにして得
た粉末状の墨500部に対し10〜25部（好ましくは
15〜20部）の微量の水分を含む低級アルコールを
噴霧器を用いて吹付ける。アルコールは粉末状の
墨を半潤性として造粒しやすくするが、このとき
水分は糊剤の表面を１部溶かし粉末粒子間に凝集
力を与えるが水分が多いと粉末が凝固しすぎてで
きた顆粒状墨の水溶性が悪くなり、水分が少いと
粉末が凝固せず顆粒となりがたい。又粉末中に若
干の水分が残るので、その水分の量に応じアルコ
ールに添加する水の量は適宜減少させる。又変性
アルコールを用いると既に適量の水分を含んでい
るので水分を加えることなくそのままで使用でき
る。 To produce the granular ink of the present invention from these components, 3 to 10 parts by weight (hereinafter simply referred to as parts) (preferably 5 to 8 parts) of a sizing agent (preferably 5 to 10 parts) are added.
8 parts) of wetting agent 0-1.5 parts (preferably 0.2-1
part) of surfactant 0 to 1 part) The total amount of preservative components is
Mix and dissolve 100 parts of water by heating and stirring. 2-30 parts (preferably 5-22 parts) of this solution
Add the pigment from part) and separate it using a high-speed stirrer to make India ink. Alternatively, depending on the type of pigment, make a concentrated solution with a small amount of water, knead it with a three-roll mill, etc., then add the rest of the water and stir to make India ink.
This India ink is heated at 30℃ to 50℃ to produce 3 to 7Kg/ cm2.
It is sprayed into hot air at a temperature of 80 to 120 degrees Celsius or exposed to a heating rotating disk for rapid drying to form a powder. The drying rate in this case is 10-50/hr.
At this time, by reducing the pressure inside the drying equipment,
It is also possible to lower the temperature of hot air and increase drying efficiency. 10 to 25 parts (preferably
Spray lower alcohol containing a trace amount of water (15 to 20 parts) using a sprayer. Alcohol makes powdered ink semi-moisturable and makes it easier to granulate.At this time, water partially dissolves the surface of the sizing agent and provides cohesive force between the powder particles, but if there is too much water, the powder will coagulate too much, resulting in granulation. The water solubility of the granular ink becomes poor, and if the water content is low, the powder will not coagulate and will be difficult to form into granules. Also, since some water remains in the powder, the amount of water added to the alcohol is appropriately reduced depending on the amount of water. Furthermore, when denatured alcohol is used, it already contains an appropriate amount of water, so it can be used as is without adding water.
次に実施例をあげて本発明をさらに詳しく説明
する。 Next, the present invention will be explained in more detail with reference to Examples.
実施例 １
膠 5.0部
グリセリン 7.0部
ノニポール160 0.5部
−第一工業製薬(株)製界面活性剤−ジヒドロ酢酸ソ
ーダ 0.3部
水 75.2部
を高速撹拌機に投入し60℃で１時間加熱撹拌し完
全に溶解させる。溶解後
ナタネ油油煙 12.0部
を加え40℃で１時間更に撹拌を続け均一な墨汁と
する。この墨汁を加温状態40℃で５Kg/cm2の空気
圧力で100℃の熱風中に噴霧し急速乾燥させ粉末
とする。Example 1 Glue 5.0 parts Glycerin 7.0 parts Nonipol 160 0.5 parts - Daiichi Kogyo Seiyaku Co., Ltd. Surfactant - Sodium dihydroacetate 0.3 parts Water 75.2 parts were put into a high-speed stirrer and heated and stirred at 60°C for 1 hour to complete. Dissolve in. After dissolving, add 12.0 parts of rapeseed oil smoke and continue stirring at 40℃ for 1 hour to make a uniform ink. This India ink is heated at 40°C and sprayed into hot air at 100°C with an air pressure of 5 kg/cm 2 and rapidly dried to form a powder.
かくして得た粉末状の墨100部に３％の水を含
むエチルアルコール15部を噴霧器を用いて吹つ
け、充分撹拌した後、造粒機（例えば不二パウダ
ル株式会社製EXD−60型）にて直径0.8mmの多数
の孔を有する金属板を通して押出すと重力により
適当な長さ（１mm）で切断され顆粒状に成形され
る。次に熱風乾燥器中で約60℃で２時間加熱乾燥
して顆粒状の墨を得た。 15 parts of ethyl alcohol containing 3% water was sprayed onto 100 parts of the powdered ink thus obtained using a sprayer, and after thorough stirring, the mixture was placed in a granulator (for example, EXD-60 model manufactured by Fuji Paudal Co., Ltd.). The mixture is then extruded through a metal plate with many holes of 0.8 mm in diameter, cut into appropriate lengths (1 mm) by gravity, and formed into granules. Next, the mixture was dried by heating at about 60° C. for 2 hours in a hot air dryer to obtain granular ink.
実施例 ２
カゼイン 5.0部
トリエタノールアミン（カゼインの可溶化剤）
1.5部
エチレングリコール 5.0部
エマゾール3130 0.3部
−花王石鹸(株)製界面活性剤−安息香酸ソーダ
1.0部
水 17.2部
を実施例１に準じて濃厚な溶液を調製し、
カーボンブラツク 10.0部
を加え３本ロールで充分混練し
水 60.0部
を加えて墨汁とした後、実施例１に準じて粉末と
し、かくして得た粉末100部に変性アルコールを
加え造粒して顆粒状の墨を得た。Example 2 Casein 5.0 parts Triethanolamine (casein solubilizer)
1.5 parts ethylene glycol 5.0 parts Emazol 3130 0.3 parts - Surfactant manufactured by Kao Soap Co., Ltd. - Sodium benzoate
Prepare a concentrated solution of 1.0 parts and 17.2 parts of water according to Example 1, add 10.0 parts of carbon black, thoroughly knead with three rolls, add 60.0 parts of water to make Indian ink, and prepare a powder according to Example 1. Then, denatured alcohol was added to 100 parts of the powder thus obtained and granulated to obtain granular ink.
実施例 ３
ニカワ 6.0部
デキストリン 2.0部
プロピレングリコール 5.0部
ソルビン酸カリ 0.5部
ブラツクPRコラニール−ヘキスト社製分散顔料
（内水分11部） 20.0部
水 66.5部
を実施例１に準じて粉末とし、かくして得た粉末
100部に変性アルコール18部を加え、実施例１に
準じて造粒して顆粒状の墨を得た。Example 3 Glue 6.0 parts Dextrin 2.0 parts Propylene glycol 5.0 parts Potassium sorbate 0.5 parts Black PR Colanil-Hoechst dispersed pigment (inner moisture 11 parts) 20.0 parts Water 66.5 parts were made into powder according to Example 1, and thus obtained. powder
18 parts of denatured alcohol was added to 100 parts and granulated according to Example 1 to obtain granular ink.
Claims (1)
乾燥して粉末状とし、微量の水分を含む低級アル
コールを噴霧した後造粒処理する顆粒状墨の製造
法。1. A method for producing granular ink in which an aqueous sizing solution and a pigment are kneaded, sprayed and rapidly dried to form a powder, and a lower alcohol containing a trace amount of water is sprayed, followed by granulation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4222776A JPS52126318A (en) | 1976-04-13 | 1976-04-13 | Method of manufacturing granular ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4222776A JPS52126318A (en) | 1976-04-13 | 1976-04-13 | Method of manufacturing granular ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS52126318A JPS52126318A (en) | 1977-10-24 |
| JPS6112955B2 true JPS6112955B2 (en) | 1986-04-10 |
Family
ID=12630138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4222776A Granted JPS52126318A (en) | 1976-04-13 | 1976-04-13 | Method of manufacturing granular ink |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS52126318A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000281955A (en) * | 1999-04-01 | 2000-10-10 | Kuretake Seishiyoudou:Kk | Material, such as sumi, used for calligraphy or painting and production thereof |
-
1976
- 1976-04-13 JP JP4222776A patent/JPS52126318A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS52126318A (en) | 1977-10-24 |
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