JPS61192792A - 担持型硫化鉄コロイド触媒を用いた石炭の水添液化方法 - Google Patents

担持型硫化鉄コロイド触媒を用いた石炭の水添液化方法

Info

Publication number: JPS61192792A
Authority: JP; Japan
Prior art keywords: iron; coal; iron sulfide; catalyst; sulfide
Prior art date: 1985-02-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP60032819A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0112799B2 (fr

Inventor

Yukimichi Nakao

幸道中尾

Kyoji Kaeriyama

帰山　享二

Masao Suda

須田　昌男

Takanobu Shiosaki

汐崎　孝信

Shinnosuke Ikumi

井汲　真之佑

Mikio Ueda

幹夫上田

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsui Engineering and Shipbuilding Co Ltd

National Institute of Advanced Industrial Science and Technology AIST

Original Assignee

Agency of Industrial Science and Technology

Mitsui Engineering and Shipbuilding Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-02-22

Filing date

1985-02-22

Publication date

1986-08-27

1985-02-22 Application filed by Agency of Industrial Science and Technology, Mitsui Engineering and Shipbuilding Co Ltd filed Critical Agency of Industrial Science and Technology

1985-02-22 Priority to JP60032819A priority Critical patent/JPS61192792A/ja

1986-08-27 Publication of JPS61192792A publication Critical patent/JPS61192792A/ja

1989-03-02 Publication of JPH0112799B2 publication Critical patent/JPH0112799B2/ja

Status Granted legal-status Critical Current

Links

MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 title claims abstract description 51
239000003054 catalyst Substances 0.000 title claims abstract description 41
239000003245 coal Substances 0.000 title claims abstract description 41
239000000084 colloidal system Substances 0.000 title claims abstract description 22
238000005984 hydrogenation reaction Methods 0.000 title abstract description 12
150000002484 inorganic compounds Chemical class 0.000 claims abstract description 18
229910010272 inorganic material Inorganic materials 0.000 claims abstract description 18
238000000034 method Methods 0.000 claims description 17
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 40
229910052742 iron Inorganic materials 0.000 abstract description 19
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
229910000019 calcium carbonate Inorganic materials 0.000 abstract description 5
229910052979 sodium sulfide Inorganic materials 0.000 abstract description 5
239000001257 hydrogen Substances 0.000 abstract description 4
229910052739 hydrogen Inorganic materials 0.000 abstract description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 3
229910000358 iron sulfate Inorganic materials 0.000 abstract description 3
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 abstract description 3
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract description 2
235000010216 calcium carbonate Nutrition 0.000 abstract description 2
239000000017 hydrogel Substances 0.000 abstract 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 abstract 1
-1 Na2S Chemical class 0.000 abstract 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
229910052783 alkali metal Inorganic materials 0.000 abstract 1
150000001340 alkali metals Chemical class 0.000 abstract 1
VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 abstract 1
150000002500 ions Chemical class 0.000 abstract 1
238000006243 chemical reaction Methods 0.000 description 17
239000003921 oil Substances 0.000 description 11
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
150000002505 iron Chemical class 0.000 description 6
239000011593 sulfur Substances 0.000 description 6
229910052717 sulfur Inorganic materials 0.000 description 6
238000001914 filtration Methods 0.000 description 5
239000007788 liquid Substances 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
239000004094 surface-active agent Substances 0.000 description 5
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 4
238000001035 drying Methods 0.000 description 4
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 4
239000000243 solution Substances 0.000 description 4
150000003464 sulfur compounds Chemical class 0.000 description 4
229910052977 alkali metal sulfide Inorganic materials 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
239000002002 slurry Substances 0.000 description 3
238000001179 sorption measurement Methods 0.000 description 3
238000003756 stirring Methods 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
235000012254 magnesium hydroxide Nutrition 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000006228 supernatant Substances 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003250 coal slurry Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
235000012245 magnesium oxide Nutrition 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
239000000203 mixture Substances 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 1
239000012256 powdered iron Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000010457 zeolite Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Landscapes

Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

JP60032819A 1985-02-22 1985-02-22 担持型硫化鉄コロイド触媒を用いた石炭の水添液化方法 Granted JPS61192792A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP60032819A JPS61192792A (ja)	1985-02-22	1985-02-22	担持型硫化鉄コロイド触媒を用いた石炭の水添液化方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP60032819A JPS61192792A (ja)	1985-02-22	1985-02-22	担持型硫化鉄コロイド触媒を用いた石炭の水添液化方法

Publications (2)

Publication Number	Publication Date
JPS61192792A true JPS61192792A (ja)	1986-08-27
JPH0112799B2 JPH0112799B2 (fr)	1989-03-02

Family

ID=12369437

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP60032819A Granted JPS61192792A (ja)	1985-02-22	1985-02-22	担持型硫化鉄コロイド触媒を用いた石炭の水添液化方法

Country Status (1)

Country	Link
JP (1)	JPS61192792A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN108201893A (zh) *	2016-12-20	2018-06-26	北京大学深圳研究生院	FeSx薄膜、肼撑苯基化合物及沉积方法和制备方法
CN111408335A (zh) *	2019-01-04	2020-07-14	华南农业大学	一种改性吸水珠纳米复合材料及其制备方法与应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS58109588A (ja) *	1981-12-24	1983-06-29	Agency Of Ind Science & Technol	硫化鉄コロイドを触媒とする石炭の直接液化方法

1985
- 1985-02-22 JP JP60032819A patent/JPS61192792A/ja active Granted

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS58109588A (ja) *	1981-12-24	1983-06-29	Agency Of Ind Science & Technol	硫化鉄コロイドを触媒とする石炭の直接液化方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN108201893A (zh) *	2016-12-20	2018-06-26	北京大学深圳研究生院	FeSx薄膜、肼撑苯基化合物及沉积方法和制备方法
CN108201893B (zh) *	2016-12-20	2020-10-09	北京大学深圳研究生院	FeSx薄膜、肼撑苯基化合物及沉积方法和制备方法
CN111408335A (zh) *	2019-01-04	2020-07-14	华南农业大学	一种改性吸水珠纳米复合材料及其制备方法与应用

Also Published As

Publication number	Publication date
JPH0112799B2 (fr)	1989-03-02

Legal Events

Date	Code	Title	Description
2005-02-22	EXPY	Cancellation because of completion of term

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