JPS61233607A - Production of clear delustering agent for manicure enamel - Google Patents
Production of clear delustering agent for manicure enamelInfo
- Publication number
- JPS61233607A JPS61233607A JP7331685A JP7331685A JPS61233607A JP S61233607 A JPS61233607 A JP S61233607A JP 7331685 A JP7331685 A JP 7331685A JP 7331685 A JP7331685 A JP 7331685A JP S61233607 A JPS61233607 A JP S61233607A
- Authority
- JP
- Japan
- Prior art keywords
- substance
- weight
- nail polish
- polymethyl methacrylate
- propylene carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 210000003298 dental enamel Anatomy 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000000126 substance Substances 0.000 claims abstract description 22
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 9
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 9
- 125000000129 anionic group Chemical group 0.000 claims abstract description 6
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- XKTYXVDYIKIYJP-UHFFFAOYSA-N 3h-dioxole Chemical compound C1OOC=C1 XKTYXVDYIKIYJP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004908 Emulsion polymer Substances 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 8
- 239000000839 emulsion Substances 0.000 abstract description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000010186 staining Methods 0.000 abstract description 2
- 230000003796 beauty Effects 0.000 abstract 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- -1 jetanolamine Chemical compound 0.000 description 4
- 235000019645 odor Nutrition 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 3
- 230000009965 odorless effect Effects 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- UKRMTDMNPNQXHN-UHFFFAOYSA-N 4-methyl-1,3-dioxolan-2-one Chemical compound CC1COC(=O)O1.CC1COC(=O)O1 UKRMTDMNPNQXHN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012213 gelatinous substance Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は主として女性が美容上、爪に塗布したマニキュ
アエナメルを落とすために用いる透明除光剤に関するも
ので、無色透明にゲル化し、無臭且つ引火性がなく、而
も美的感に優れて取扱いが安全な除光剤が得られるよう
にしたことを目的とする。[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a transparent nail polish remover used mainly by women to remove nail polish enamel applied to their nails for cosmetic purposes. To provide a nail polish remover that is not flammable, has an excellent aesthetic feel, and is safe to handle.
一般に女性が爪に塗布したマニキュアエナメルは、毎日
又は長くても数日毎の短期間にこれを落として再度塗り
直しするのが普通である。Generally, the nail polish enamel applied to the nails by women is removed and reapplied every day or at most every few days for a short period of time.
そしてそのマニキュアエナメルを落とすための除光する
物質として従来は、液体又はクリーム状の製品が普及し
ている。Conventionally, liquid or cream-like products have been widely used as light-removing substances for removing nail polish enamel.
前者即ち液体除光物製品の成分は例えば、アセトンＣＨ
３ＣＯＣＨ２６８，０重量％、酢酸ブチルＣ１ｌ□ｃｏ
ｏｃ１１□ＣＨ２ＣＨ２Ｃｌ＋３ ５．０１量％、酢酸
エチルＣ１ｈＣＯＯＣＩＩ□ＣＩ３ ２０．０重量％、
ヒマシ油２．０重量％、プロピレングリコール５．０重
量％の各組成物を単に混合して成るものである。The ingredients of the former liquid nail polish remover product are, for example, acetone CH
3COCH268.0% by weight, butyl acetate C1l□co
oc11□CH2CH2Cl+3 5.01% by weight, ethyl acetate C1hCOOCII□CI3 20.0% by weight,
The composition is simply mixed with 2.0% by weight of castor oil and 5.0% by weight of propylene glycol.
また後者即ちクリーム状除光物製品の成分例は、有機ベ
ントナイト（ヘントナイトを四級アミントリアルチルヘ
ンシルアンモニウム塩で処理したもの）既存化物質Ｎｏ
、２６９４．８’、０重量％、ミネラルスピリット８２
〜９２重量％、アセトン３．０〜１０重星％の組成物か
ら成り、前記の有機ヘントナイトをミネラルスピリット
に増粘させ、このケル化したものにアセトンを加えて均
一にし、これを除光剤とするものである。In addition, examples of the ingredients of the latter cream-like nail polish remover product include organic bentonite (hentonite treated with quaternary amine real tylphensylammonium salt) and existing substance No.
, 2694.8', 0% by weight, Mineral Spirit 82
It consists of a composition of ~92% by weight and 3.0-10% acetone, the above-mentioned organic hetonite is thickened with mineral spirit, acetone is added to the kelized product to make it homogeneous, and this is used as a nail polish remover. That is.
ところが前記除光動物のうち前者は、その組成物を単に
混合してなるものであるから、臭いが強く且つアセトン
の引火無月５℃、発火点５００’Ｃ。However, since the former of the above-mentioned deodorizing agents is simply mixed with the composition, it has a strong odor, and the flammability of acetone is 5°C and the ignition point is 500'C.
また酢酸ブヂルは、引火点２２℃、発火点４２０’ｃ、
酢酸エチルの引火点−５℃、発火点４６２℃であるため
引火性が強い。従って、多少不快感があると共に危険で
あり、而も使用中に誤って壜を倒すと液体であるから、
こぼれて衣服や床を汚す虞れがある。Also, butyl acetate has a flash point of 22°C, an ignition point of 420'c,
Ethyl acetate has a flash point of -5°C and an ignition point of 462°C, making it highly flammable. Therefore, it is somewhat uncomfortable and dangerous, and if you accidentally knock the bottle over while using it, it will turn into liquid.
There is a risk of spillage and staining clothes and floors.
また後者は、ゲル化したクリ−１、状であるので、これ
を収容した容器を倒してもこほれる虞れはない。しかし
ながら不透明であるから、美的感の」二ではあまりきれ
いとは言えない。そして成分中アのセトンは、特異な臭
気のある無色液体で、且つ引火性があるので、一種の薬
品的な臭気を有する点に不快をもよおずことがあると共
に危険性がある。Moreover, since the latter is in the form of gelatinized cream, there is no risk of it breaking even if the container containing it is knocked over. However, since it is opaque, it cannot be said to be very aesthetically pleasing. Ingredient A, setone, is a colorless liquid with a unique odor and is flammable, so it has a kind of chemical odor that can be unpleasant and dangerous.
そこで本発明はその目的を達成し、且つ従来技術の問題
点を解決するためにマニキュアエナメル用透明除光剤の
製造方法において、
以下の組成、
ａ） ポリメタクリル酸メチル（メタクリル酸メチル重
合体）を含む陰イオン性エマルジョン高分子物質が３５
．０〜４５．０重量％、ｂ） トリエタノールアミン
、ジェタノールアミン、水酸化カリウム、水酸化ナトリ
ウム等のアルカリ性物質が３．０〜７．０重量％、Ｃ）
プロピレンカーボネート（２オキソ−４メチル１．３
ジオキソラン）物質が５０．０重量％より成り、これら
成分量の配合率の合計が１００重量％になってゲル化し
たものである。Therefore, in order to achieve the object and solve the problems of the prior art, the present invention provides a method for producing a transparent nail polish remover for nail polish enamel, which has the following composition: a) Polymethyl methacrylate (methyl methacrylate polymer) Anionic emulsion polymeric substance containing 35
．． 0 to 45.0% by weight, b) 3.0 to 7.0% by weight of alkaline substances such as triethanolamine, jetanolamine, potassium hydroxide, sodium hydroxide, C)
Propylene carbonate (2oxo-4 methyl 1.3
The gel consists of 50.0% by weight of (dioxolane) substance, and the total blending ratio of these components is 100% by weight.
次に本発明の処方ないし作用を説明すると、次の通りで
ある。Next, the prescription and action of the present invention will be explained as follows.
先ず、基材となるポリメタクリル酸メチル（メタクリル
酸メチル重合体）を含む陰イオン性エマルジョン高分子
物質は不透明であるが、これにトリエタノールアミン、
ジェタノールアミン、水酸化カリウム、水酸化ナトリウ
ム等のアルカリ性物質を加えると透明なゲル化の状態に
なる。そして前記ゲル化したものに、さらに無色無臭の
プロピレンカーボネート（２オキソ−４メチル１．３ジ
オニトソラン）物質を加えて攪拌混合すると、ゲル化し
た透明な除光剤となる。First, the base material, an anionic emulsion polymer material containing polymethyl methacrylate (methyl methacrylate polymer), is opaque, and triethanolamine,
Addition of alkaline substances such as jetanolamine, potassium hydroxide, and sodium hydroxide results in a transparent gel state. When a colorless and odorless propylene carbonate (2oxo-4 methyl 1.3 dionitosolane) substance is further added to the gelled product and mixed with stirring, a transparent gelled light remover is obtained.
以下本発明の詳細な説明する。 The present invention will be explained in detail below.
除光剤の各組成物の最・も好ましい配合率は、ポリメタ
クリル酸メチル（メタクリル酸メチル重合体）を４０．
０重量％、トリエタノールアミン５．０重量％、プロピ
レンカーボネート（２オキソ−４メチル１．３ジオキソ
ラン） ５５．０重量％である。The most preferable blending ratio of each composition of the nail polish remover is 40% polymethyl methacrylate (methyl methacrylate polymer).
0% by weight, triethanolamine 5.0% by weight, and propylene carbonate (2oxo-4 methyl 1.3 dioxolane) 55.0% by weight.
前記組成物中、ポリメタクリル酸メチルユマルジョンを
用いる理由は、他の増粘剤に比べ、当該増粘剤に溶剤を
加えたときに粘度の低下が著しくないことによる。即ち
他の増粘剤を使用するときは、ゲル化したもの＼中に溶
剤を加えたときに著しく粘度の低下してしまう結果とな
る。The reason why polymethyl methacrylate emulsion is used in the composition is that, compared to other thickeners, when a solvent is added to the thickener, the viscosity does not decrease significantly. That is, when other thickeners are used, the viscosity is significantly reduced when a solvent is added to the gelled product.
「ポリメタクリル酸メチル」の構造式
またトリエタノールアミンは、通例ジェタノールアミン
を含むもので、本物質はアンモニアと酸化エチレン（Ｃ
Ｈ２）２０又はエチレンクロルヒドリンとの反応によっ
て得られるアルカノールアミンの混合物であって、主成
分はトリエタノールアミンである。The structural formula of "polymethyl methacrylate" and triethanolamine usually contain jetanolamine, and this substance contains ammonia and ethylene oxide (C
H2)20 or a mixture of alkanolamines obtained by reaction with ethylene chlorohydrin, the main component being triethanolamine.
そして本物質はアミンとアルコールの２つの性質を持っ
ているため反応性に富み、脂肪酸等と反応して、トリエ
タノールアミンせっけんを作り界面活性剤として機能す
る。而も無色又は淡黄色の粘調な液体で吸湿性に冨んで
いる。Since this substance has two properties: amine and alcohol, it is highly reactive, and reacts with fatty acids to form triethanolamine soap, which functions as a surfactant. It is a colorless or pale yellow viscous liquid with high hygroscopic properties.
「トリエタノールアミン」の構造式
％式％）：）
次にプロピレン力−ボネ−１−（２オキソ−４メチル１
．３ジオキソラン）は、プロピレングリコロールと炭酸
との環状エステルで、腐蝕性・吸湿性の少ない無色無臭
の液体物質であり、引火点１３２°Ｃ１発火点５１０℃
である。Structural formula of "triethanolamine" % formula %):) Next, propylene force-bone-1-(2oxo-4methyl1
．． 3 dioxolane) is a cyclic ester of propylene glycol and carbonic acid, and is a colorless and odorless liquid substance with low corrosivity and hygroscopicity, and has a flash point of 132°C and an ignition point of 510°C.
It is.
「プロピレンカーボネ−ｋｌ（２オキソ−４メチル１．
３ジオキソラン）の構造式
％式％
〔発明の効果〕
本発明は−に記構成のように、ポリメタクリル酸メチル
を含む陰イオン性エマルジョン高分子物質にトリエタノ
ールアミン、ジェタノールアミン、水酸化カリウム、水
酸化ナトリウム等アルカリ性の物質を加え、さらにプロ
ピレンカーボネート（２オキソ−４メチル−１，３ジオ
キソラン）を加えることによって無色透明のゲル化の状
態となり、これによって美的感及び清潔感のあるマニキ
ュアエナメル用透明除光剤が得られる。"Propylene carbonate-kl (2oxo-4 methyl 1.
3 dioxolane) [Effects of the Invention] The present invention has the structure described in -, in which triethanolamine, jetanolamine, and potassium hydroxide are added to an anionic emulsion polymeric substance containing polymethyl methacrylate. By adding an alkaline substance such as sodium hydroxide and further adding propylene carbonate (2oxo-4 methyl-1,3 dioxolane), it becomes a colorless and transparent gel, which creates an aesthetically pleasing and clean nail polish enamel. A transparent nail polish remover is obtained.
また無色透明のゲル化物質であるため、使用中に誤って
収容している容器を倒しても液体のようにこぼれて゛衣
服や床を汚すことがなく、且つ引火性の虞れも殆どない
ので安全である。In addition, since it is a colorless and transparent gelatinous substance, even if the container in which it is stored is accidentally knocked over during use, it will not spill like liquid and stain clothes or the floor, and there is almost no risk of flammability. It's safe.
而も無臭であるから、臭いに敏感な人でも不快感や違和
感がなく、誰にでも拒否反応なく使用することができる
。Moreover, since it is odorless, even people who are sensitive to odors will not feel uncomfortable or uncomfortable, and anyone can use it without any negative reactions.
さらに不透明のクリーム状に比べても本発明においては
、無色透明であるから美的感と清潔感において特有の効
果があり、これを使用する女性に好まれ、この種マニキ
ュアエナメル用透明除光剤の製造方法として新規有益で
ある。Furthermore, compared to opaque cream-like products, the present invention is colorless and transparent, so it has a unique effect on aesthetics and cleanliness, and is preferred by women who use it. It is novel and useful as a manufacturing method.
Claims (1)
体）を含む陰イオン性エマルジョン高分子物質が３５．
０〜４５．０重量％、 ｂ）トリエタノールアミン、ジエタノールアミン、水酸
化カリウム、水酸化ナトリウム等 のアルカリ性物質が３．０〜７．０重量％、ｃ）プロピ
レンカーボネート（２オキソ−４メチル１．３ジオキソ
ラン）物質が５０．０重量％より成り、これら成分量の
配合率の合計が１００重量％になってゲル化したことを
特徴とするマニキュアエナメル用透明除光剤の製造方法
。(1) The following composition, a) An anionic emulsion polymer substance containing polymethyl methacrylate (methyl methacrylate polymer) is 35.
0 to 45.0% by weight, b) 3.0 to 7.0% by weight of alkaline substances such as triethanolamine, diethanolamine, potassium hydroxide, sodium hydroxide, c) propylene carbonate (2oxo-4 methyl 1. A method for producing a transparent nail polish remover for nail polish enamel, comprising 50.0% by weight of a substance (3dioxolane), and gelatinized when the total blending ratio of these components is 100% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7331685A JPS61233607A (en) | 1985-04-06 | 1985-04-06 | Production of clear delustering agent for manicure enamel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7331685A JPS61233607A (en) | 1985-04-06 | 1985-04-06 | Production of clear delustering agent for manicure enamel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS61233607A true JPS61233607A (en) | 1986-10-17 |
Family
ID=13514643
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7331685A Pending JPS61233607A (en) | 1985-04-06 | 1985-04-06 | Production of clear delustering agent for manicure enamel |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61233607A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6222709A (en) * | 1985-07-24 | 1987-01-30 | Suhama Kagaku Kk | Nail lacquer remover |
| WO1989007931A1 (en) * | 1988-02-25 | 1989-09-08 | Nikkei New Business Corporation | Manicuring enamel remover |
-
1985
- 1985-04-06 JP JP7331685A patent/JPS61233607A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6222709A (en) * | 1985-07-24 | 1987-01-30 | Suhama Kagaku Kk | Nail lacquer remover |
| WO1989007931A1 (en) * | 1988-02-25 | 1989-09-08 | Nikkei New Business Corporation | Manicuring enamel remover |
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