JPS6126482B2 - - Google Patents

Info

Publication number: JPS6126482B2
Authority: JP; Japan
Prior art keywords: oxygen; salt mixture; gas; hydrogen chloride; weight
Prior art date: 1977-02-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP1668078A

Other languages

English (en)

Japanese (ja)

Other versions

JPS53124190A (en

Inventor

Ei Rooman Chaaruzu

Teii Furamu Harorudo

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Battelle Memorial Institute Inc

Original Assignee

Battelle Memorial Institute Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-02-18

Filing date

1978-02-17

Publication date

1986-06-20

1977-08-01 Priority claimed from US05/820,733 external-priority patent/US4107280A/en

1978-02-17 Application filed by Battelle Memorial Institute Inc filed Critical Battelle Memorial Institute Inc

1978-10-30 Publication of JPS53124190A publication Critical patent/JPS53124190A/ja

1986-06-20 Publication of JPS6126482B2 publication Critical patent/JPS6126482B2/ja

Status Granted legal-status Critical Current

Links

VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 104
239000007789 gas Substances 0.000 claims description 95
229910000041 hydrogen chloride Inorganic materials 0.000 claims description 68
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 68
229910052760 oxygen Inorganic materials 0.000 claims description 67
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 64
239000001301 oxygen Substances 0.000 claims description 64
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 57
239000000460 chlorine Substances 0.000 claims description 57
229910052801 chlorine Inorganic materials 0.000 claims description 56
150000003839 salts Chemical class 0.000 claims description 54
239000011833 salt mixture Substances 0.000 claims description 53
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 47
238000000034 method Methods 0.000 claims description 44
229910000039 hydrogen halide Inorganic materials 0.000 claims description 32
239000012433 hydrogen halide Substances 0.000 claims description 32
238000006243 chemical reaction Methods 0.000 claims description 30
229910052736 halogen Inorganic materials 0.000 claims description 24
150000002367 halogens Chemical class 0.000 claims description 24
229910052720 vanadium Inorganic materials 0.000 claims description 21
239000003054 catalyst Substances 0.000 claims description 18
230000001590 oxidative effect Effects 0.000 claims description 17
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 14
238000007254 oxidation reaction Methods 0.000 claims description 12
230000003647 oxidation Effects 0.000 claims description 11
230000001172 regenerating effect Effects 0.000 claims description 11
229910052739 hydrogen Inorganic materials 0.000 claims description 9
150000002927 oxygen compounds Chemical class 0.000 claims description 9
229910052794 bromium Inorganic materials 0.000 claims description 8
229910052740 iodine Inorganic materials 0.000 claims description 8
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 8
229910052939 potassium sulfate Inorganic materials 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 7
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 6
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 6
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 6
239000011630 iodine Substances 0.000 claims description 6
230000000694 effects Effects 0.000 claims description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Chemical compound [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 claims description 4
239000007795 chemical reaction product Substances 0.000 claims description 2
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 2
239000007788 liquid Substances 0.000 claims description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 8
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 2
150000001875 compounds Chemical class 0.000 claims 2
230000026030 halogenation Effects 0.000 claims 1
238000005658 halogenation reaction Methods 0.000 claims 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 42
239000000203 mixture Substances 0.000 description 42
239000002253 acid Substances 0.000 description 16
239000006227 byproduct Substances 0.000 description 11
230000008929 regeneration Effects 0.000 description 11
238000011069 regeneration method Methods 0.000 description 11
239000002699 waste material Substances 0.000 description 11
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 10
238000004519 manufacturing process Methods 0.000 description 8
235000011151 potassium sulphates Nutrition 0.000 description 8
150000003467 sulfuric acid derivatives Chemical class 0.000 description 8
239000000243 solution Substances 0.000 description 7
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
229910052936 alkali metal sulfate Inorganic materials 0.000 description 6
238000000926 separation method Methods 0.000 description 6
229910052938 sodium sulfate Inorganic materials 0.000 description 6
235000011152 sodium sulphate Nutrition 0.000 description 6
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
KAQHZJVQFBJKCK-UHFFFAOYSA-L potassium pyrosulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OS([O-])(=O)=O KAQHZJVQFBJKCK-UHFFFAOYSA-L 0.000 description 5
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
150000001340 alkali metals Chemical class 0.000 description 4
238000004140 cleaning Methods 0.000 description 4
230000018044 dehydration Effects 0.000 description 4
238000006297 dehydration reaction Methods 0.000 description 4
-1 hydrogen halides Chemical class 0.000 description 4
MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
150000001805 chlorine compounds Chemical class 0.000 description 3
238000010586 diagram Methods 0.000 description 3
238000007429 general method Methods 0.000 description 3
229910001504 inorganic chloride Inorganic materials 0.000 description 3
150000003112 potassium compounds Chemical class 0.000 description 3
239000000047 product Substances 0.000 description 3
JXAZAUKOWVKTLO-UHFFFAOYSA-L sodium pyrosulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OS([O-])(=O)=O JXAZAUKOWVKTLO-UHFFFAOYSA-L 0.000 description 3
238000011144 upstream manufacturing Methods 0.000 description 3
150000003681 vanadium Chemical class 0.000 description 3
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
229910052770 Uranium Inorganic materials 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
238000007792 addition Methods 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
238000005660 chlorination reaction Methods 0.000 description 2
229910052804 chromium Inorganic materials 0.000 description 2
239000011651 chromium Substances 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
239000012141 concentrate Substances 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
229910001882 dioxygen Inorganic materials 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
239000011133 lead Substances 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
239000011572 manganese Substances 0.000 description 2
239000000155 melt Substances 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
238000012545 processing Methods 0.000 description 2
239000005297 pyrex Substances 0.000 description 2
235000011121 sodium hydroxide Nutrition 0.000 description 2
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
235000019345 sodium thiosulphate Nutrition 0.000 description 2
238000007711 solidification Methods 0.000 description 2
230000008023 solidification Effects 0.000 description 2
239000000126 substance Substances 0.000 description 2
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 2
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 2
IBYSTTGVDIFUAY-UHFFFAOYSA-N vanadium monoxide Chemical group [V]=O IBYSTTGVDIFUAY-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
235000019738 Limestone Nutrition 0.000 description 1
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical class [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
229920001131 Pulp (paper) Polymers 0.000 description 1
239000000370 acceptor Substances 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
239000012267 brine Substances 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
OSVXSBDYLRYLIG-UHFFFAOYSA-N chlorine dioxide Inorganic materials O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 1
235000019398 chlorine dioxide Nutrition 0.000 description 1
230000006735 deficit Effects 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000010291 electrical method Methods 0.000 description 1
238000004134 energy conservation Methods 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
239000003344 environmental pollutant Substances 0.000 description 1
238000003912 environmental pollution Methods 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
229910000042 hydrogen bromide Inorganic materials 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
229910000043 hydrogen iodide Inorganic materials 0.000 description 1
239000012535 impurity Substances 0.000 description 1
230000002452 interceptive effect Effects 0.000 description 1
239000006028 limestone Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
231100000719 pollutant Toxicity 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
150000003682 vanadium compounds Chemical class 0.000 description 1
238000005406 washing Methods 0.000 description 1

Landscapes

Catalysts (AREA)

JP1668078A 1977-02-18 1978-02-17 Method of reprodcing halogen elements selected from chlorine* bromine and iodine from corresponding hydrogen hologenide Granted JPS53124190A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US77028277A	1977-02-18	1977-02-18
US05/820,733 US4107280A (en)	1977-08-01	1977-08-01	Oxidation of hydrogen halides to elemental halogens with catalytic molten salt mixtures

Publications (2)

Publication Number	Publication Date
JPS53124190A JPS53124190A (en)	1978-10-30
JPS6126482B2 true JPS6126482B2 (de)	1986-06-20

Family

ID=27118293

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP1668078A Granted JPS53124190A (en)	1977-02-18	1978-02-17	Method of reprodcing halogen elements selected from chlorine* bromine and iodine from corresponding hydrogen hologenide

Country Status (1)

Country	Link
JP (1)	JPS53124190A (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1207506B (it) *	1985-10-15	1989-05-25	Montedipe Spa	Processo per il recupero dello iodio dallo ioduro sodico.
US5084264A (en) *	1989-12-12	1992-01-28	Battelle Memorial Institute	Process for oxidation of hydrogen halides to elemental halogens
JP4945109B2 (ja) *	2005-10-13	2012-06-06	株式会社東芝	ヨウ化水素製造方法および水素製造方法並びにそれらのための製造装置

1978
- 1978-02-17 JP JP1668078A patent/JPS53124190A/ja active Granted

Also Published As

Publication number	Publication date
JPS53124190A (en)	1978-10-30

Publication	Publication Date	Title
BRPI0714914A2 (pt)	2013-05-28	processos para a produÇço de bromo
US4361487A (en)	1982-11-30	Control of hydrogen sulfide emission from geothermal steam plants with hydrogen peroxide and sodium vanadate
US3971844A (en)	1976-07-27	Method for removing sodium sulfate from aqueous solutions
US6096239A (en)	2000-08-01	Method for removal of sulfur dioxide
US4537835A (en)	1985-08-27	Oxidation of hydrogen halides to elemental halogens
US2810627A (en)	1957-10-22	Recovery of sulfur dioxide from gases and production of ammonium sulphate
US4634582A (en)	1987-01-06	Sulfur dioxide removal process
CA1245831A (en)	1988-12-06	Process for desulphurizing flue gases
US4107280A (en)	1978-08-15	Oxidation of hydrogen halides to elemental halogens with catalytic molten salt mixtures
US6030592A (en)	2000-02-29	Process for the desulfurization of sulfur dioxide-containing gases
US3687615A (en)	1972-08-29	Desulfurization of flue gas
US4269817A (en)	1981-05-26	Production of chlorine from chloride salts
JPS6126482B2 (de)	1986-06-20
US4024219A (en)	1977-05-17	Process for removing nitrogen oxide from a waste gas
US5084264A (en)	1992-01-28	Process for oxidation of hydrogen halides to elemental halogens
US4360508A (en)	1982-11-23	Treatment of effluents
US3883638A (en)	1975-05-13	Process for removing sulfur dioxide and sulfur trioxide from waste gas and producing sulfur therefrom
US4180550A (en)	1979-12-25	Process for purifying a sulfur dioxide containing gas by washing with an ammonia aqueous solution
US3954955A (en)	1976-05-04	Process for working up the wash solution obtained in the washing of SO2 -containing off-gases
US3535083A (en)	1970-10-20	Gas purification
US3925540A (en)	1975-12-09	Production of chlorine dioxide
US3449079A (en)	1969-06-10	Hydrogen halide oxidation in acid medium
US4041142A (en)	1977-08-09	Method for removing sulfur oxide from waste gases and recovering elemental sulfur
US3690824A (en)	1972-09-12	Desulfurization of flue gas
BRPI0712503A2 (pt)	2012-08-28	processo para oxidação catalìtica de sulfeto para sulfato