JPS6147592A - Condemiless condensate purifying facility - Google Patents

Condemiless condensate purifying facility

Info

Publication number
JPS6147592A
JPS6147592A JP59168395A JP16839584A JPS6147592A JP S6147592 A JPS6147592 A JP S6147592A JP 59168395 A JP59168395 A JP 59168395A JP 16839584 A JP16839584 A JP 16839584A JP S6147592 A JPS6147592 A JP S6147592A
Authority
JP
Japan
Prior art keywords
condensate
filter
purification equipment
equipment
filter medium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP59168395A
Other languages
Japanese (ja)
Other versions
JPH0448198B2 (en
Inventor
進 堀内
浜本 雅啓
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP59168395A priority Critical patent/JPS6147592A/en
Publication of JPS6147592A publication Critical patent/JPS6147592A/en
Publication of JPH0448198B2 publication Critical patent/JPH0448198B2/ja
Granted legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00Energy generation of nuclear origin
    • Y02E30/30Nuclear fission reactors

Landscapes

  • Treatment Of Water By Ion Exchange (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 〔発明の利用分野〕 本発明は復水浄化設備に係ねり、特に原子力発電所等の
給水水質向上の目的で数置さiる復水浄化設備に好適な
フィルタに関するものである。
[Detailed Description of the Invention] [Field of Application of the Invention] The present invention relates to condensate purification equipment, and particularly relates to a filter suitable for several condensate purification equipment for the purpose of improving the quality of water supply to nuclear power plants, etc. It is something.

〔発明の背景〕[Background of the invention]

従来原子力09!屯所等の復水浄化設備では、復水中の
不溶解性物質(以下クラッドと称す)及び溶m性物質(
以下イオンと称す)を除去し、水質を向上する目的で混
床式脱塩装置又は濾過助材型フィルタと混床式脱塩装置
を組合せた復水浄化設備が用いられている。しかしなが
らこれらの装置を連続的に使用するために不可欠なイオ
ン交換樹脂の再生や濾過助材型フィルタの逆洗に伴って
発生する廃棄物量が多いこと、また使用されるイオン交
換樹脂の耐熱特性により処理水の温度が制約されること
から系統の熱サイクルにおける効率が制約を受ける等の
欠点があった。
Conventional nuclear power 09! In condensate purification equipment at military bases, etc., insoluble substances (hereinafter referred to as crud) and soluble substances (crud) are removed from condensate.
In order to remove ions (hereinafter referred to as ions) and improve water quality, a mixed bed desalination device or a condensate purification facility that combines a filter aid type filter and a mixed bed desalination device is used. However, due to the large amount of waste generated due to the regeneration of ion exchange resins and backwashing of filter aids, which are essential for continuous use of these devices, and the heat resistance properties of the ion exchange resins used, There were drawbacks such as the efficiency of the system's thermal cycle being restricted because the temperature of the treated water was restricted.

またが材が2次廃棄物として発生した場合に。Also, when wood is generated as secondary waste.

その処理が難しいという問題点があった。The problem was that it was difficult to process.

これらの欠点を克服するため種々の脱塩装置、フィルタ
において様々な改良が工夫されており、特に2次的な廃
棄物の発生を抑制する目的で、非助材型のフィルタがい
くつか開発されているが、クラッドに対する除去性能に
は優れたものがあるものの、イオンに対する除去性能に
欠けているため、単独では水質基準の厳しい原子力発電
所等の復水浄化設備では十分でなく、混床式脱塩装置と
の組合せが必要となるため、結果的に前記の問題点を完
全に克服した設備の提供は不可能であった。
In order to overcome these drawbacks, various improvements have been made to various desalination equipment and filters, and in particular, some non-auxiliary filters have been developed for the purpose of suppressing the generation of secondary waste. Although some methods have excellent removal performance for crud, they lack removal performance for ions, so they are not sufficient for condensate purification equipment such as nuclear power plants, which have strict water quality standards, and mixed bed type As a result, it has been impossible to provide equipment that completely overcomes the above-mentioned problems because it requires combination with a desalination device.

〔発明の目的〕[Purpose of the invention]

本発明の目的は、既に述べた様なこれまでの復水浄化設
備における問題点に総合的に対処しようということにあ
り、具体的には復水中に含まれるクラッド、イオンとい
う性状の異なる不純物いずれもが除去可能であり、かつ
設備を連続的に使用するために行なう再生、逆洗操作の
際に発生する廃棄物発生量が最/I)化でき、かつ高温
での使用条件に耐えられることから系統全体の熱効率向
上が計れる様な復水浄化設備を提供することにある。
The purpose of the present invention is to comprehensively address the problems in conventional condensate purification equipment as already mentioned. The amount of waste generated during regeneration and backwashing operations performed for continuous use of equipment can be minimized, and it can withstand high-temperature usage conditions. Our objective is to provide condensate purification equipment that can improve the thermal efficiency of the entire system.

〔発明の概要〕[Summary of the invention]

本発明の復水浄化設備を構成する主要要素であるイオン
クラッドフィルタは、これまでの各種脱塩装置及びフィ
ルタ類がそれぞれに持つ欠点を補えるものであり、その
主要購成部材として非助材型の多孔性を有する繊維状又
は膜状の濾材を採泪し、さらに本濾材にイオン交換能力
が可能である呼処理したことを特徴としている。
The ion clad filter, which is the main element constituting the condensate purification equipment of the present invention, can compensate for the drawbacks of various conventional desalination equipment and filters, and is a non-auxiliary material type as the main purchased component. The filter material is characterized in that it uses a fibrous or membrane-like filter medium having a porosity of 100%, and is further treated to have an ion exchange ability.

〔発明の実施例〕[Embodiments of the invention]

以下、本発明の一実施例を第1図により説明する。第1
図は標準的なりMRプラン1−の概略系統構成において
本発明による復水浄化設備を採用した場合の1例を示す
ものである。
An embodiment of the present invention will be described below with reference to FIG. 1st
The figure shows an example of the case where the condensate purification equipment according to the present invention is employed in the general system configuration of the standard MR Plan 1-.

原子炉1によって発生された蒸気は高圧タービン2及び
低圧タービン3を駆動した後、復水器4において冷却さ
れる。冷却された復水は復水ポンプ5により移送され空
気抽出器6を経て1本発明にて紹介した復水浄化設備7
に供給される。復水浄化設備7において、復水中に原子
炉1以降にて含有されたクラッド、イオンが除去され、
浄化された復水は低圧給水加熱器8及び高圧給水加熱器
9を経て再び原子炉1に供給される。
Steam generated by the nuclear reactor 1 drives a high pressure turbine 2 and a low pressure turbine 3, and then is cooled in a condenser 4. The cooled condensate is transferred by a condensate pump 5 and passes through an air extractor 6 to the condensate purification equipment 7 introduced in the present invention.
supplied to In the condensate purification equipment 7, crud and ions contained in the condensate after the reactor 1 are removed,
The purified condensate is supplied to the reactor 1 again through the low-pressure feedwater heater 8 and the high-pressure feedwater heater 9.

本発明による復水浄化設備7は先に述べたように、従来
の温床式脱塩装置等に比べより高温下においても安定し
た性能が得られるため、復水浄化設備7を第1図に示す
系統中の位置でなく、第1図中に示す低圧給水加熱器8
と高圧給水加熱器9の間に置くことも可能である。
As mentioned above, the condensate purification equipment 7 according to the present invention can obtain stable performance even at higher temperatures than conventional hotbed desalination equipment, etc. Therefore, the condensate purification equipment 7 is shown in FIG. Low pressure feed water heater 8 shown in Figure 1, not located in the system.
and the high-pressure feed water heater 9.

第2図は本発明による復水浄化設備の系統構成を示すも
のである。イオンクラッドフィルタ3の復水入口4より
入った復水は濾材10を通過し。
FIG. 2 shows the system configuration of the condensate purification equipment according to the present invention. Condensate entering from the condensate inlet 4 of the ion clad filter 3 passes through the filter medium 10.

ここにおいてその中に含有するクラッド、イオンを除去
された後、復水出口5より排出される。イオンクラッド
フィルタ3は使用されるに従い、その内で構成される濾
材10にクラッド及びイオンを蓄積していく。主にクラ
ッドによる物理的な濾材10の差圧上昇は差圧計8によ
り監視され、一方主にイオンによる化学的な濾材10の
イオン交換能力低下は復水出口5の下流に設けられた電
導度肝9により監視される。濾材1oの長期使用におけ
る性能安定性を確保するため、差圧計8又は電導度肝9
のいずれかが各々所定の値に迄上昇した場合、濾材10
の再生又は逆洗の操作を実施する。再生操作は再生用酸
タンク1及び再生用荷性タンク2よりイオンクラッドフ
ィルタ3に酸及びアルカリを別々に注入し、これにより
濾材10のイオン交換能力を活性化させることで行なえ
る。
Here, after the crud and ions contained therein are removed, the condensate is discharged from the condensate outlet 5. As the ion clad filter 3 is used, cladding and ions accumulate in the filter medium 10 formed therein. The increase in the physical differential pressure of the filter medium 10 mainly due to crud is monitored by the differential pressure gauge 8, while the chemical decrease in the ion exchange capacity of the filter medium 10 mainly due to ions is monitored by the conductivity gauge 9 installed downstream of the condensate outlet 5. monitored by In order to ensure performance stability during long-term use of the filter medium 1o, a differential pressure gauge 8 or a conductivity gauge 9
If either of them rises to a predetermined value, the filter medium 10
Carry out regeneration or backwashing operations. The regeneration operation can be performed by separately injecting acid and alkali into the ion clad filter 3 from the regeneration acid tank 1 and the regeneration loading tank 2, thereby activating the ion exchange ability of the filter medium 10.

一方逆洗操作は加圧タンク11に蓄圧された加圧空気を
イオンクラッドフィルタ3に供給し、濾材10に対し通
常運転時の採水と逆方向の流れを作ることにより実施可
能である。
On the other hand, the backwashing operation can be carried out by supplying pressurized air stored in the pressurized tank 11 to the ion clad filter 3 and creating a flow against the filter medium 10 in the opposite direction to the water sampling during normal operation.

構成又は逆洗の操作により発生した廃液は、廃液受タン
ク6に収集され、移送ポンプ7によりさらに下流の処理
設備へと移送される。
Waste liquid generated by the construction or backwashing operation is collected in a waste liquid receiving tank 6 and transferred by a transfer pump 7 to a further downstream processing facility.

〔発明の効果〕〔Effect of the invention〕

本発明で紹介したが材の持つ特徴から、多孔性という物
理的性質によるクラッドに対する高除去性能に合せ、濾
材に付与したイオン交換能力という化学的性質によりイ
オンに対しても高い除去性能を得ることが可能であり、
単独の装置によりクラッド、イオンのいずれに対しても
満足すべき性能が得られる。
As introduced in the present invention, due to the characteristics of the material, it is possible to obtain high removal performance for crud due to the physical property of porosity, and high removal performance for ions due to the chemical property of ion exchange ability imparted to the filter material. is possible,
A single device provides satisfactory performance for both cladding and ions.

また、これまでの復水浄化設備で用いられている温床式
脱塩装置と比較しまた場合、先に述べた濾材の多孔性と
いう物理的性質がイオン交換能力という化学的性質に極
めて効果的に作用するため、装置のイオン交換能力が使
用中に飽和に達した際に行なう再生操作において、必要
とする酸及びアルカリの量が、装置の使用経歴における
等価のイオン負荷に換算して、1/10以下で十分であ
る。
In addition, compared to the hotbed desalination equipment used in conventional condensate purification equipment, the physical property of the porosity of the filter media mentioned above has an extremely effective effect on the chemical property of ion exchange capacity. Therefore, in the regeneration operation performed when the ion exchange capacity of the device reaches saturation during use, the amount of acid and alkali required is 1/1 of the equivalent ion load over the history of the device. 10 or less is sufficient.

このため長期的に見ると再生に必要な薬品の量を著しく
低減することが可能となり、同時に2次的に発生する再
生廃液も比例して低減される。特に原子力発電所の復水
浄化設備から発生する再生廃液は放射能を有しており、
その処理には多大な手間がかかることから、本発明によ
る再生廃液低減の効果は極めて大きいものが期待される
Therefore, in the long run, it becomes possible to significantly reduce the amount of chemicals required for regeneration, and at the same time, the amount of secondary regeneration waste liquid is also reduced proportionally. In particular, recycled waste fluid generated from condensate purification equipment at nuclear power plants has radioactivity.
Since the treatment requires a lot of effort, the present invention is expected to have an extremely large effect in reducing recycled waste liquid.

また先に述べた本発明の主要梠成部材である改良型瀘材
は、そのイオン交換能力の基である素材中に固定したイ
オン交換基の熱的安定性において従来のイオン交換樹脂
のそれと比べて優れており。
In addition, the improved filter material, which is the main barrier material of the present invention, has a thermal stability of the ion exchange group fixed in the material, which is the basis of its ion exchange ability, compared to that of conventional ion exchange resin. It is excellent.

この特長から従来のイオン交換樹脂を用いている温床式
脱塩装置や粉末樹脂を演過助材として用いたフィルタに
比べ、より高温の条件下においても性能を発揮すること
ができる。この特長から例えば原子力発電所の復水浄化
設備において、これ迄の温床式脱塩装置に代わり本発明
にて紹介する設備を設置する場合、復水器出口から低圧
タービン熱交換層迄をこれ迄よりも高い温度とすること
が可能となり、プラント全体の熱効率が向上できるとい
う大きな効果が得られることになる。
Because of this feature, compared to conventional hotbed desalination equipment that uses ion exchange resin or filters that use powdered resin as a performance aid, it can demonstrate performance even under higher temperature conditions. Because of this feature, for example, when installing the equipment introduced in this invention in place of the conventional hotbed type desalination equipment in condensate purification equipment of a nuclear power plant, the equipment introduced in this invention can be installed from the condenser outlet to the low-pressure turbine heat exchange layer. This makes it possible to raise the temperature to a higher temperature than the previous one, which has the great effect of improving the thermal efficiency of the entire plant.

また、従来の原子力発電所でより高い水質の維持を目的
として、フィルタと温床式脱塩装置を組み合わせた様な
復水浄化設備に比べ、本発明によれば1種類の装置によ
り目的が達成されるため、配置スペースの縮小、経済性
向上が期待できる。
Furthermore, compared to conventional condensate purification equipment that combines a filter and a hotbed desalination equipment for the purpose of maintaining higher water quality in nuclear power plants, the present invention achieves the objective with a single type of equipment. Therefore, it is expected that the installation space will be reduced and economical efficiency will be improved.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は標準的なりMR型原子力発電所の全体系統の中
における本発明の復水浄化設備の位置付けを示す系統図
であり、第2図は前記復水浄化設備の系統植成を示すも
のである。 第1図で1・・・原子炉、4・・・復水器、7川復水浄
化設備。 第2図で1・・・再生用酸タンク、2・・・再生用苛性
タンク、3・・・イオンクラッドフィルタ。 図面の痒:!!:(内容(こ変更なし)4 l 目 $ 2 目 手続補正魯(方式) 1.118′1庁長 官 志賀  学 殿1j;件の表
示 昭和59年1.1J許願第168395  ぢ発 明 
の 名 称 コノデミレス破水浄化設備補正をする者 J:件との関係 ′特許出願人 名 輌(5101株式会旺 日 立 製 作所代   
理   人 居  岨〒1001東京都千代田区丸の内−丁目5番1
号委任状 (2)DI書に最初に添付した明細書の浄書・別紙の通
り(内容に変更なし)。 (3)願書に最初に添付した図面の浄書・別紙の通り 
(内容に変更なし)。 (4)委任状を別紙の通り提出する。 以上
Fig. 1 is a system diagram showing the position of the condensate purification equipment of the present invention in the overall system of a standard MR type nuclear power plant, and Fig. 2 shows the system layout of the condensate purification equipment. It is. In Figure 1, 1...nuclear reactor, 4...condenser, 7 river condensate purification equipment. In Fig. 2, 1... acid tank for regeneration, 2... caustic tank for regeneration, 3... ion clad filter. Drawing itching:! ! : (Contents (no change) 4 l item $ 2 item procedural amendment (method) 1.118'1 Director General Manabu Shiga 1j; Indication of the matter 1980 1.1 J Patent Application No. 168395 Invention Invention
Name: Person who amends Conodemires Water Purification Equipment
Satoshi Hitori Aya 5-1 Marunouchi-chome, Chiyoda-ku, Tokyo 1001
Power of attorney (2) As per the engraving and attachment of the specification originally attached to the DI document (no changes to the contents). (3) As per the engraving and attached sheet of the drawing originally attached to the application.
(No change in content). (4) Submit the power of attorney as attached. that's all

Claims (1)

【特許請求の範囲】[Claims] 1、多孔性を有する繊維状又は膜状の濾材より構成され
る復水浄化フィルタにおいて、公知の不溶解性物質を除
去する能力を有する前記濾材に、さらに溶解性物質を除
去する能力を付与し、復水中の不溶解性及び溶解性の不
純物を合せて除去する能力を持ち、かつ前記濾材を廃棄
物として処理する場合、熱分解等により容易に処理可能
であることを特徴とするコンデミレス復水浄化設備。
1. In a condensate purification filter composed of a porous fibrous or membrane-like filter medium, the filter medium, which has the ability to remove known insoluble substances, is further given the ability to remove soluble substances. , a condensate-less condensate having the ability to remove both insoluble and soluble impurities in the condensate, and when the filter medium is treated as waste, it can be easily treated by thermal decomposition etc. Purification equipment.
JP59168395A 1984-08-11 1984-08-11 Condemiless condensate purifying facility Granted JPS6147592A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59168395A JPS6147592A (en) 1984-08-11 1984-08-11 Condemiless condensate purifying facility

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59168395A JPS6147592A (en) 1984-08-11 1984-08-11 Condemiless condensate purifying facility

Publications (2)

Publication Number Publication Date
JPS6147592A true JPS6147592A (en) 1986-03-08
JPH0448198B2 JPH0448198B2 (en) 1992-08-06

Family

ID=15867319

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59168395A Granted JPS6147592A (en) 1984-08-11 1984-08-11 Condemiless condensate purifying facility

Country Status (1)

Country Link
JP (1) JPS6147592A (en)

Also Published As

Publication number Publication date
JPH0448198B2 (en) 1992-08-06

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