JPS62237946A - 改良水素添加用触媒体 - Google Patents

改良水素添加用触媒体

Info

Publication number: JPS62237946A
Authority: JP; Japan
Prior art keywords: catalyst; hydrogenation; catalyst body; fibers; annular
Prior art date: 1986-03-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP62070551A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0553545B2 (2

Inventor

フエドー、ポツプルスドルフ

チヤールズ、アーサー、スミス

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Union Carbide Corp

Original Assignee

Union Carbide Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-03-27

Filing date

1987-03-26

Publication date

1987-10-17

1987-03-26 Application filed by Union Carbide Corp filed Critical Union Carbide Corp

1987-10-17 Publication of JPS62237946A publication Critical patent/JPS62237946A/ja

1993-08-10 Publication of JPH0553545B2 publication Critical patent/JPH0553545B2/ja

Status Granted legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims description 143
238000005984 hydrogenation reaction Methods 0.000 title claims description 39
239000000835 fiber Substances 0.000 claims description 42
238000000034 method Methods 0.000 claims description 36
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 16
229910052802 copper Inorganic materials 0.000 claims description 16
239000010949 copper Substances 0.000 claims description 16
239000000203 mixture Substances 0.000 claims description 14
239000000377 silicon dioxide Substances 0.000 claims description 13
239000005337 ground glass Substances 0.000 claims description 11
238000006243 chemical reaction Methods 0.000 claims description 10
125000004122 cyclic group Chemical group 0.000 claims description 8
-1 alkyl oxalate Chemical compound 0.000 claims description 7
238000001354 calcination Methods 0.000 claims description 7
239000012784 inorganic fiber Substances 0.000 claims description 4
239000011159 matrix material Substances 0.000 claims description 4
230000003014 reinforcing effect Effects 0.000 claims description 4
235000012239 silicon dioxide Nutrition 0.000 claims 5
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 2
LOMVENUNSWAXEN-NUQCWPJISA-N dimethyl oxalate Chemical group CO[14C](=O)[14C](=O)OC LOMVENUNSWAXEN-NUQCWPJISA-N 0.000 claims 1
239000006185 dispersion Substances 0.000 claims 1
239000002245 particle Substances 0.000 description 9
230000003197 catalytic effect Effects 0.000 description 6
230000000694 effects Effects 0.000 description 6
238000009792 diffusion process Methods 0.000 description 5
239000003365 glass fiber Substances 0.000 description 5
239000000463 material Substances 0.000 description 5
LOMVENUNSWAXEN-UHFFFAOYSA-N Methyl oxalate Chemical compound COC(=O)C(=O)OC LOMVENUNSWAXEN-UHFFFAOYSA-N 0.000 description 3
238000005056 compaction Methods 0.000 description 3
239000010419 fine particle Substances 0.000 description 3
239000000376 reactant Substances 0.000 description 3
230000002787 reinforcement Effects 0.000 description 3
230000035939 shock Effects 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 2
239000004927 clay Substances 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
235000020083 shōchū Nutrition 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
239000005751 Copper oxide Substances 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000013543 active substance Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
238000011021 bench scale process Methods 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
238000012993 chemical processing Methods 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229910000431 copper oxide Inorganic materials 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000012634 fragment Substances 0.000 description 1
238000013467 fragmentation Methods 0.000 description 1
238000006062 fragmentation reaction Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
239000010439 graphite Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000002386 leaching Methods 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000004005 microsphere Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000000465 moulding Methods 0.000 description 1
238000005192 partition Methods 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000011148 porous material Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
238000004901 spalling Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000012546 transfer Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

JP62070551A 1986-03-27 1987-03-26 改良水素添加用触媒体 Granted JPS62237946A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US06/844,559 US4649226A (en)	1986-03-27	1986-03-27	Hydrogenation of alkyl oxalates
US844,559		1986-03-27

Publications (2)

Publication Number	Publication Date
JPS62237946A true JPS62237946A (ja)	1987-10-17
JPH0553545B2 JPH0553545B2 (2)	1993-08-10

Family

ID=25293061

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP62070551A Granted JPS62237946A (ja)	1986-03-27	1987-03-26	改良水素添加用触媒体

Country Status (3)

Country	Link
US (1)	US4649226A (2)
JP (1)	JPS62237946A (2)
CA (1)	CA1284486C (2)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6455742B1 (en)	1999-09-02	2002-09-24	Wisconsin Alumni Research Foundation	Method for catalytically reducing carboxylic acid groups to hydroxyl groups in hydroxycarboxylic acids
JP4802497B2 (ja) *	2002-11-27	2011-10-26	新日本理化株式会社	水素化反応方法
CN101993347B (zh) *	2009-08-31	2013-08-21	中国石油化工股份有限公司	采用草酸酯加氢生产乙二醇的方法
CN101879448B (zh)	2010-06-24	2012-05-23	天津大学	用于草酸酯加氢制乙二醇的规整结构催化剂及其制备方法
CN102451687B (zh) *	2010-10-21	2013-06-05	中国石油化工股份有限公司	一种加氢催化剂及其制备方法和乙二醇的合成方法
CN102125847A (zh) *	2010-12-30	2011-07-20	厦门大学	一种用于制备乙二醇的铜镍硅催化剂及其制备方法
CN102649700B (zh) *	2011-02-25	2014-11-26	中国石油化工股份有限公司	合成乙二醇的方法
CN102649075B (zh) *	2011-02-25	2015-01-07	中国石油化工股份有限公司	草酸酯通过流化床催化反应生成乙二醇的方法
RU2570573C2 (ru) *	2011-02-25	2015-12-10	Чайна Петролеум Энд Кемикал Корпорейшн	Способ получения этиленгликоля
US9102583B2 (en)	2011-02-25	2015-08-11	China Petroleum & Chemical Corporation	Method for producing ethylene glycol from oxalate through the fluidized bed catalytic reaction
CN103467248B (zh) *	2013-09-02	2016-05-04	东华工程科技股份有限公司	一种节能型的酯加氢工艺

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS57180432A (en) *	1981-04-30	1982-11-06	Ube Ind Ltd	Production of catalyst for hydrogenating oxalic acid diester
JPS58207945A (ja) *	1982-05-28	1983-12-03	Ube Ind Ltd	シユウ酸ジエステルの水素添加用触媒
JPS59183832A (ja) *	1983-04-01	1984-10-19	Nippon Shokubai Kagaku Kogyo Co Ltd	ウイスカを含有するヘテロポリ酸系成型触媒組成物

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4042738A (en) *	1975-07-28	1977-08-16	Corning Glass Works	Honeycomb structure with high thermal shock resistance
US4142994A (en) *	1975-10-20	1979-03-06	Filtrol Corporation	Shaped catalyst support
US4022715A (en) *	1975-12-31	1977-05-10	American Cyanamid Company	Process for catalyst materials of increased pore volume and pore diameter
US4112245A (en) *	1976-08-18	1978-09-05	Atlantic Richfield Company	Process for the preparation of ethylene glycol
JPS56141842A (en) *	1980-04-07	1981-11-05	Kanegafuchi Chem Ind Co Ltd	Catalyst formed in novel cylindrical shape
JPS57122940A (en) *	1981-01-26	1982-07-31	Ube Ind Ltd	Hydrogenation catalyst of oxalic diester
BR8201302A (pt) *	1981-03-12	1983-01-25	Union Carbide Corp	Processo para a preparacao de etileno glicol

1986
- 1986-03-27 US US06/844,559 patent/US4649226A/en not_active Expired - Fee Related
1987
- 1987-03-05 CA CA000531215A patent/CA1284486C/en not_active Expired - Lifetime
- 1987-03-26 JP JP62070551A patent/JPS62237946A/ja active Granted

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS57180432A (en) *	1981-04-30	1982-11-06	Ube Ind Ltd	Production of catalyst for hydrogenating oxalic acid diester
JPS58207945A (ja) *	1982-05-28	1983-12-03	Ube Ind Ltd	シユウ酸ジエステルの水素添加用触媒
JPS59183832A (ja) *	1983-04-01	1984-10-19	Nippon Shokubai Kagaku Kogyo Co Ltd	ウイスカを含有するヘテロポリ酸系成型触媒組成物

Also Published As

Publication number	Publication date
JPH0553545B2 (2)	1993-08-10
US4649226A (en)	1987-03-10
CA1284486C (en)	1991-05-28

Publication	Publication Date	Title
EP0949000B1 (en)	2007-06-13	Process for the preparation of fluid bed vinyl acetate catalyst support
EP0428223B1 (en)	1994-07-06	Process for the preparation of extrudates
JPS62237946A (ja)	1987-10-17	改良水素添加用触媒体
US4059544A (en)	1977-11-22	Active material compositions with porous protective sheath and method for preparing
US3962135A (en)	1976-06-08	Shaped catalyst support
EP0297657B1 (en)	1992-07-15	Dehydrogenation catalyst
US4579728A (en)	1986-04-01	Wide pore alumina supports
US5002917A (en)	1991-03-26	Molded articles based on pyrogenically produced titanium dioxide method for their manufacturing and uses
US7351393B1 (en)	2008-04-01	Star shaped alumina extrudates and catalyst based thereon
EP0552287B1 (en)	1995-07-26	Shaped oxidation catalyst structures for the production of maleic anhydride
US3172893A (en)	1965-03-09	Ethylene oxtoationximproved s silver catalyst
US3448060A (en)	1969-06-03	Supported skeletal nickel catalyst
US4579729A (en)	1986-04-01	Wide pore alumina supports
US7244689B2 (en)	2007-07-17	Method of producing alumina-silica catalyst supports
US4729982A (en)	1988-03-08	Bed packing material
US4692423A (en)	1987-09-08	Method for preparing structured catalytic solids
CN1074631A (zh)	1993-07-28	负载型丁烯氧化脱氢制丁二烯催化剂
EP0308140B2 (en)	1995-11-29	Alumina-based catalysts, their production and use
US3933991A (en)	1976-01-20	Sulfuric acid contact process
EP0195013B1 (en)	1990-03-14	Preparation and use of co-formed catalyst
EP0702596B1 (en)	1996-12-18	Catalytic materials comprising layered clay macrospheres
US3472794A (en)	1969-10-14	Ammonia synthesis catalyst
CN1204230C (zh)	2005-06-01	一种异型加氢精制催化剂及其制备方法
JPH0353973B2 (2)	1991-08-16
CA3152991C (en)	2024-02-27	New catalyst system for producing maleic anhydride by means of the catalytic oxidation of n-butane