JPS62250019A - 耐衝撃性ポリスチロ−ル類の製法 - Google Patents

耐衝撃性ポリスチロ−ル類の製法

Info

Publication number: JPS62250019A
Authority: JP; Japan
Prior art keywords: rubber; polymer; styrene; polymerization; carried out
Prior art date: 1986-04-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP62083983A

Other languages

English (en)

Japanese (ja)

Inventor

クラウス・ブロンシユテルト

ハンス・ヘンル

アドルフ・エヒテ

ペーター・クレールナー

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-04-08

Filing date

1987-04-07

Publication date

1987-10-30

1987-04-07 Application filed by BASF SE filed Critical BASF SE

1987-10-30 Publication of JPS62250019A publication Critical patent/JPS62250019A/ja

Status Pending legal-status Critical Current

Links

229920002223 polystyrene Polymers 0.000 title claims description 23
238000004519 manufacturing process Methods 0.000 title claims description 11
229920000642 polymer Polymers 0.000 claims description 32
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 31
238000000034 method Methods 0.000 claims description 28
239000004793 Polystyrene Substances 0.000 claims description 22
238000006116 polymerization reaction Methods 0.000 claims description 17
229920001971 elastomer Polymers 0.000 claims description 14
239000000203 mixture Substances 0.000 claims description 14
239000000178 monomer Substances 0.000 claims description 14
239000005060 rubber Substances 0.000 claims description 13
239000003999 initiator Substances 0.000 claims description 11
238000006243 chemical reaction Methods 0.000 claims description 10
238000003756 stirring Methods 0.000 claims description 9
150000003440 styrenes Chemical class 0.000 claims description 9
150000001993 dienes Chemical class 0.000 claims description 7
125000003396 thiol group Chemical group [H]S* 0.000 claims description 4
239000012986 chain transfer agent Substances 0.000 claims description 2
239000000463 material Substances 0.000 claims description 2
239000002994 raw material Substances 0.000 claims description 2
229920002857 polybutadiene Polymers 0.000 description 13
239000005062 Polybutadiene Substances 0.000 description 12
239000002245 particle Substances 0.000 description 9
239000011541 reaction mixture Substances 0.000 description 8
239000000243 solution Substances 0.000 description 7
239000007787 solid Substances 0.000 description 5
239000002904 solvent Substances 0.000 description 5
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
229920001400 block copolymer Polymers 0.000 description 4
239000002775 capsule Substances 0.000 description 4
239000003921 oil Substances 0.000 description 4
229920003048 styrene butadiene rubber Polymers 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
MBNVSWHUJDDZRH-UHFFFAOYSA-N 2-methylthiirane Chemical compound CC1CS1 MBNVSWHUJDDZRH-UHFFFAOYSA-N 0.000 description 3
-1 butadiene Chemical class 0.000 description 3
229920005669 high impact polystyrene Polymers 0.000 description 3
238000002156 mixing Methods 0.000 description 3
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical group SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
238000007872 degassing Methods 0.000 description 2
239000004797 high-impact polystyrene Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
238000010526 radical polymerization reaction Methods 0.000 description 2
YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
FRQQKWGDKVGLFI-UHFFFAOYSA-N 2-methylundecane-2-thiol Chemical compound CCCCCCCCCC(C)(C)S FRQQKWGDKVGLFI-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
238000010539 anionic addition polymerization reaction Methods 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
230000001588 bifunctional effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000007664 blowing Methods 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000003490 calendering Methods 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000001413 cellular effect Effects 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
239000007771 core particle Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000000635 electron micrograph Methods 0.000 description 1
238000001493 electron microscopy Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000011049 filling Methods 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
150000002432 hydroperoxides Chemical class 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
229920002521 macromolecule Polymers 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
238000011017 operating method Methods 0.000 description 1
229920006280 packaging film Polymers 0.000 description 1
239000012785 packaging film Substances 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
238000012856 packing Methods 0.000 description 1
150000002976 peresters Chemical class 0.000 description 1
150000004978 peroxycarbonates Chemical class 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
239000000523 sample Substances 0.000 description 1
238000010008 shearing Methods 0.000 description 1
238000005245 sintering Methods 0.000 description 1
239000010421 standard material Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
238000012360 testing method Methods 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
VOVUARRWDCVURC-UHFFFAOYSA-N thiirane Chemical compound C1CS1 VOVUARRWDCVURC-UHFFFAOYSA-N 0.000 description 1
150000003553 thiiranes Chemical class 0.000 description 1
150000003573 thiols Chemical group 0.000 description 1
230000009466 transformation Effects 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Graft Or Block Polymers (AREA)

JP62083983A 1986-04-08 1987-04-07 耐衝撃性ポリスチロ−ル類の製法 Pending JPS62250019A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19863611704 DE3611704A1 (de)	1986-04-08	1986-04-08	Verfahren zur herstellung von schlagfestem poly(alkyl)styrol
DE3611704.8		1986-04-08

Publications (1)

Publication Number	Publication Date
JPS62250019A true JPS62250019A (ja)	1987-10-30

Family

ID=6298174

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP62083983A Pending JPS62250019A (ja)	1986-04-08	1987-04-07	耐衝撃性ポリスチロ−ル類の製法

Country Status (5)

Country	Link
US (1)	US4908414A (de)
EP (1)	EP0240903A3 (de)
JP (1)	JPS62250019A (de)
CA (1)	CA1272844A (de)
DE (1)	DE3611704A1 (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2645409B2 (ja) *	1990-01-26	1997-08-25	出光石油化学株式会社	高光沢耐衝撃性スチレン系樹脂組成物
JP2993338B2 (ja) *	1993-10-18	1999-12-20	住友化学工業株式会社	ゴム変性ポリスチレン樹脂組成物、その製造方法及び射出成形品
US20040014877A1 (en) *	2002-07-19	2004-01-22	Null Volker Klaus	White oil as plasticizer in a polystyrene composition and process to prepare said oil
KR20050099526A (ko) *	2003-02-05	2005-10-13	다우 글로벌 테크놀로지스 인크.	비닐 방향족 단량체로부터 제조된 고무 개질 중합체
WO2006122979A2 (en) *	2005-05-20	2006-11-23	Shell Internationale Research Maatschappij B.V.	Use of a fischer-tropsch derived white oil in food contact applications
KR100799605B1 (ko) *	2006-05-04	2008-01-30	제일모직주식회사	내스크래치성이 우수한 수지 조성물
KR100865497B1 (ko) *	2006-12-28	2008-10-27	제일모직주식회사	충격보강제, 그 제조방법 및 이를 이용한 내스크래치성메타크릴레이트계 수지 조성물
US20110226711A1 (en) *	2008-12-04	2011-09-22	Michikazu Okanishi	Transportation tray

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1588456A (de) *	1967-04-07	1970-04-17
DE2613352B2 (de) *	1976-03-29	1980-08-07	Basf Ag, 6700 Ludwigshafen	Verfahren zur Herstellung von schlagfest modifizierten Styrolpolymerisaten
CA1098637A (en) *	1977-03-30	1981-03-31	Lu H. Tung	Preparation of block copolymers and products therefrom
US4169115A (en) *	1977-03-30	1979-09-25	The Dow Chemical Company	Preparation of block copolymers and products therefrom
US4294937A (en) *	1979-06-18	1981-10-13	Shell Oil Company	Impact polymers

1986
- 1986-04-08 DE DE19863611704 patent/DE3611704A1/de not_active Withdrawn
1987
- 1987-03-30 CA CA000533334A patent/CA1272844A/en not_active Expired
- 1987-03-31 EP EP87104723A patent/EP0240903A3/de not_active Withdrawn
- 1987-04-07 JP JP62083983A patent/JPS62250019A/ja active Pending
1989
- 1989-04-14 US US07/338,568 patent/US4908414A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
EP0240903A2 (de)	1987-10-14
US4908414A (en)	1990-03-13
EP0240903A3 (de)	1989-08-30
DE3611704A1 (de)	1987-10-22
CA1272844A (en)	1990-08-14

Publication	Publication Date	Title
EP0143500B2 (de)	2000-07-05	Mit Kautschuk verstärkte monovinylaromatische Polymere mit einziger Bilanz von Glanz und Festigkeit und Verfahren zu ihrer Herstellung
US4335221A (en)	1982-06-15	Preparation of mixtures of linear three-block copolymers, and moldings produced therefrom
KR0178368B1 (ko)	1999-05-15	내충격성 비닐 방향족(공) 중합체의 연속 벌크형 제조방법
TWI410438B (zh)	2013-10-01	製造高衝擊強度之聚苯乙烯之方法及相關組合物
US4567232A (en)	1986-01-28	Continuous preparation of rubber-modified polymers of vinyl-aromatics
KR960000567B1 (ko)	1996-01-09	고무-강화된 모노비닐리덴 방향족 중합체 수지 및 이의 제조방법
EP1003797A1 (de)	2000-05-31	Hochglänzende und hochschlagfeste aromatische monovinylidenpolymere
JPH0141177B2 (de)	1989-09-04
US4294937A (en)	1981-10-13	Impact polymers
US4421895A (en)	1983-12-20	Process for the manufacture of ABS polymers and use thereof in preparation of molded parts
JP3691149B2 (ja)	2005-08-31	ゴム強化ビニル芳香族共重合体の製造方法
US3485894A (en)	1969-12-23	Interpolymers of vinyl arenes and certain block copolymers and process for their preparation
EP0418042B1 (de)	1994-02-16	Monovinylaromat-Polymer mit veränderten Eigenschaften und Verfahren zu seiner Herstellung
US5708081A (en)	1998-01-13	Composition comprising a vinylaromatic polymer and a rubber and process for obtaining it
JPS62250019A (ja)	1987-10-30	耐衝撃性ポリスチロ−ル類の製法
US5756579A (en)	1998-05-26	Rubber-reinforced vinyl aromatic (CO) polymer
US4985503A (en)	1991-01-15	Preparation of impact-resistant poly(alkyl)styrene
AU771477B2 (en)	2004-03-25	High impact monovinylidene aromatic polymers
KR100281344B1 (ko)	2001-02-01	열가소성 성형 재료
US6825271B2 (en)	2004-11-30	Anionically polymerized, impact-resistant polystyrene with capsule particle morphology
CA1079436A (en)	1980-06-10	Polymeric polyblends having improved melt flow
US5112921A (en)	1992-05-12	Impact-resistant thermoplastic molding material and its use
JPS6023693B2 (ja)	1985-06-08	耐衝撃性ポリスチレン組成物の製造方法
CA1175592A (en)	1984-10-02	Continuous preparation of rubber-modified polymers of vinyl-aromatics using a per-ester or diacyl peroxide initiator
EP0069792A1 (de)	1983-01-19	Durchsichtige, schlagzähe Harze und ihr Herstellungsverfahren