JPS6234968A - Carbon paste of high resistance - Google Patents
Carbon paste of high resistanceInfo
- Publication number
- JPS6234968A JPS6234968A JP60172487A JP17248785A JPS6234968A JP S6234968 A JPS6234968 A JP S6234968A JP 60172487 A JP60172487 A JP 60172487A JP 17248785 A JP17248785 A JP 17248785A JP S6234968 A JPS6234968 A JP S6234968A
- Authority
- JP
- Japan
- Prior art keywords
- carbon black
- carbon
- binder
- solvent
- carbon paste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 17
- 239000006229 carbon black Substances 0.000 claims abstract description 15
- 239000011230 binding agent Substances 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 238000010521 absorption reaction Methods 0.000 claims abstract description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 6
- 239000011630 iodine Substances 0.000 claims abstract description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 238000001179 sorption measurement Methods 0.000 claims description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 3
- 239000004925 Acrylic resin Substances 0.000 abstract description 2
- 229920000178 Acrylic resin Polymers 0.000 abstract description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 235000019241 carbon black Nutrition 0.000 description 11
- 230000000704 physical effect Effects 0.000 description 6
- 239000006230 acetylene black Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- UAEPNZWRGJTJPN-UHFFFAOYSA-N Methylcyclohexane Natural products CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- -1 methyl ethyl lactone Chemical class 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000002296 pyrolytic carbon Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 229940083466 soybean lecithin Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Non-Adjustable Resistors (AREA)
- Conductive Materials (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は高抵抗カーボンペーストに関する。[Detailed description of the invention] (Industrial application field) The present invention relates to a high resistance carbon paste.
（従来の技術）
従来、高抵抗カーボンペーストは、一般に、導電性カー
ビンブラック、バインダー、溶剤及び添加剤等で構成さ
れており、その導電性カーボンブラックとしては、市販
アセチレンブラック、ファーネスブラック、副生ブラッ
ク等が使用されている。(Prior art) Conventionally, high-resistance carbon paste is generally composed of conductive carbine black, a binder, a solvent, additives, etc. As the conductive carbon black, commercially available acetylene black, furnace black, by-product Black etc. are used.
高抵抗カーボンペーストの要求される導電性範囲が１０
９〜１０６Ω・儂であるため、導電性カーボンブラック
の添加量をかなり少なくする必要がある。そのためにバ
インダーの硬化や溶剤の蒸発の際にカーボンブラックの
分散状態が悪くなり、抵抗値がパラツクなどの欠点がめ
った。すなわち、第１表に従来の導電性カーボンブラッ
クの物性を示したが、これらのものを低添加量で配合す
ると、いずれも抵抗値の安定したものを得ることは困難
であった。The required conductivity range of high resistance carbon paste is 10
Since the resistance is 9 to 10 6 Ω·min, it is necessary to considerably reduce the amount of conductive carbon black added. As a result, the dispersion state of carbon black deteriorated during binder curing and solvent evaporation, resulting in frequent defects such as a resistance value becoming uneven. That is, Table 1 shows the physical properties of conventional conductive carbon blacks, but when these materials are added in low amounts, it is difficult to obtain stable resistance values.
（発明が解決しようとする問題点）
カーボンブラックの分散性を改良し、安定した抵抗値を
もつ高抵抗カーボンペーストを得ることが本発明の目的
である。(Problems to be Solved by the Invention) It is an object of the present invention to improve the dispersibility of carbon black and obtain a high-resistance carbon paste having a stable resistance value.
（問題点を解決するための手段）
本発明は、１１２ｋＮ−加圧下の電気比抵抗０．２００
・偏以下、比表面積４０〜８０ ｍ”／Ｅ！ 、沃素吸
着量５０〜９０〜り及び塩酸吸液量５〜１０１１１４１
５．＠のカーボンブラック、バインダー及び溶剤を含有
してなる高抵抗カーボンペーストである。(Means for solving the problem) The present invention has an electrical specific resistance of 0.200 under 112 kN pressure.
- Specific surface area 40-80 m"/E!, iodine adsorption amount 50-90 m"/E!, hydrochloric acid absorption amount 5-1011141
5. This is a high-resistance carbon paste containing @ carbon black, a binder, and a solvent.
以下さらに本発明について詳しく説明する。The present invention will be further explained in detail below.
本発明で用いるカーボンブラックは従来の導電性カーボ
ンブラックに比べてかなり異なる性状を持つものである
。すなわち、塩酸吸液量が極端に低いため、高抵抗であ
り、カーボンブラックの添加量を増し１０６〜１０９Ω
・儂領域で安定した抵抗値を得ることができるものであ
る。これによって、バインダーの硬化や溶剤の蒸発の際
にカーボンブラックの分散不良を起こすことがないので
、抵抗値のバラツキの少ない安定した抵抗体を得ること
ができる。The carbon black used in the present invention has properties that are considerably different from those of conventional conductive carbon black. In other words, since the amount of hydrochloric acid absorbed is extremely low, the resistance is high, and by increasing the amount of carbon black added,
・It is possible to obtain a stable resistance value in my area. As a result, poor dispersion of carbon black does not occur during hardening of the binder or evaporation of the solvent, so a stable resistor with less variation in resistance value can be obtained.
本発明において、カーボンシラツクの物性を以上のよう
に限定した理由は次の通りである。In the present invention, the reason why the physical properties of carbon silk are limited as described above is as follows.
Ｑ
１１２ ｋｌｌ／ｃｍ”加圧下の電気比抵抗が０．２０
’ｌ”ｃｍをこえ、比表面積が４０ ｍ”／ｇ未満、
沃素吸着量が５０ ｍ９／９未満及び塩酸吸液量５ｍ１
７５１１未満では、導電性付与能力が十分でなくなる。Q 112 kll/cm” Electrical resistivity under pressure is 0.20
more than 'l" cm, specific surface area less than 40 m"/g,
Iodine adsorption amount is less than 50 m9/9 and hydrochloric acid absorption amount is 5 m1
If it is less than 7511, the ability to impart electrical conductivity will not be sufficient.
また、比表面積が８０ ｍ”／ｇをこえ、沃素吸着量が
９０１１１をこえ、塩酸吸液量が１０１１７１５．！ｉ
＋をこえるようになると、バインダーと溶剤に配合して
カーボンペーストを製造する際、その流動性が悪くなり
、かつ、安定した抵抗値のものを得ることが困難となる
。In addition, the specific surface area exceeds 80 m''/g, the iodine adsorption amount exceeds 90111, and the hydrochloric acid absorption amount exceeds 1011715.!i
If it exceeds +, the fluidity becomes poor when a carbon paste is produced by mixing it with a binder and a solvent, and it becomes difficult to obtain a stable resistance value.
本発明に係るカーボンブラックは、例えば次のようＫし
て製造することができる。すなわち、分子中に炭素を結
合した有機高分子物質及び／又は瀝育物と、ボールミル
、振動ミル等の粉砕機で粉砕したものあるいは未粉砕の
アセチレンブラックとの混合物を、５００〜８００℃程
度の不活性ガス算囲気下で熱処理すればよい。このよう
にして製造されたカーボンブラックは、前記した物性を
有すると共に不純物が極めて少ないという利点を有する
。The carbon black according to the present invention can be produced, for example, as follows. That is, a mixture of an organic polymer substance and/or a fermented material having carbon bonded in its molecules and acetylene black that has been ground using a grinder such as a ball mill or a vibration mill, or unpulverized acetylene black, is heated at about 500 to 800°C. Heat treatment may be performed under an atmosphere of inert gas. The carbon black produced in this manner has the above-mentioned physical properties and has the advantage of having extremely few impurities.
本発明の高抵抗カーぜンペーストは、バインター及び溶
剤と共に上記のカーボンシラツクを含み、さらに必要に
より各種添加剤例えば分散剤、沈降防止剤、滑剤などを
含有したものであって、それらの配合成分は、アトライ
ター、サンドミル、ロールミル、ボールミルなどで混合
される。The high-resistance casten paste of the present invention contains the above-mentioned carbon silk together with a binder and a solvent, and further contains various additives such as a dispersant, an anti-settling agent, a lubricant, etc., as necessary. is mixed in an attritor, sand mill, roll mill, ball mill, etc.
カーボンブラックの配合割合は、バインダー１００重量
部に対し、５〜１００重量部の割合であることが好まし
い。５重量部未満では抵抗値のバラツキが大きくなり、
また、１００重量部をこえると抵抗値は安定するがカー
ざンペーストの粘度が大きくなり均一な皮膜状の抵抗体
を得ることが困難となる。The blending ratio of carbon black is preferably 5 to 100 parts by weight based on 100 parts by weight of the binder. If it is less than 5 parts by weight, the resistance value will vary greatly,
If the amount exceeds 100 parts by weight, the resistance value will be stabilized, but the viscosity of the Kazan paste will increase, making it difficult to obtain a uniform film-like resistor.
バインタ９−とじては、被着体の種類や乾燥条件に応じ
てその種類を選定されなげればならないｔζ速乾性のア
クリル樹脂、ビニル樹脂、イム系のものから２液型のア
クリル変性ポリウレタン樹脂、エポキシポリアミＰ樹脂
、シリコーンイムなどが使われる。The type of binder 9 must be selected depending on the type of adherend and drying conditions.Tζ Quick-drying acrylic resin, vinyl resin, im-based resin, or two-component acrylic modified polyurethane resin. , epoxy polyamide P resin, silicone im, etc. are used.
溶剤は、バインダーの種類に応じて樹脂の溶解性のある
ものが選定される。貧溶解性のものはバインダーの凝集
までひき起こし、抵抗値に悪影響を与える。これらのこ
とを配慮すると、トルエン、キシレン、ブタノール、メ
チルエチルクトン、メチル−イソブチルケトン、シクロ
ヘキサンなどの溶剤が好適である。溶剤の添加量は、カ
ーボンペーストの塗布作業性の点を配慮して決定する必
要がめる。A solvent that can dissolve the resin is selected depending on the type of binder. Poorly soluble binders cause aggregation of the binder, which adversely affects the resistance value. Taking these matters into consideration, solvents such as toluene, xylene, butanol, methyl ethyl lactone, methyl isobutyl ketone, and cyclohexane are suitable. The amount of solvent added needs to be determined with consideration to the workability of applying the carbon paste.
添加剤として、フィラーの分散性を良くする分散剤とし
ては、脂肪酸アミド系、エステル系、アルコール系、金
属石鹸、大豆レシチン等が使われる。As an additive, a fatty acid amide type, ester type, alcohol type, metal soap, soybean lecithin, etc. are used as a dispersing agent that improves the dispersibility of the filler.
以下、実施例をあげてさらに詳しく説明する。Hereinafter, the present invention will be explained in more detail with reference to examples.
（実施例）
カーがンブラックの製造
塩化ビニル樹脂（電気化学工業■製：商品名「デンカビ
ニール５ｓ−１０ＤＢ Ｊ ４０重量部、アセチレンブ
ラック（電気化学工業■製：商品名「デンカブラック」
）をが−ルミルにて３時間粉砕したもの１００重量部及
び水１２０重量部を容量１０ノのヘンシェルミキサーに
より、混合・造粒し乾燥して造粒物とした。(Example) Production of Cargan Black Vinyl chloride resin (manufactured by Denki Kagaku Kogyo ■: trade name: Denka Vinyl 5s-10DB J 40 parts by weight, acetylene black (manufactured by Denki Kagaku Kogyo ■: trade name: "Denka Black")
) was pulverized for 3 hours in a galmill, 100 parts by weight and 120 parts by weight of water were mixed and granulated using a Henschel mixer with a capacity of 10 mm, and dried to obtain a granulated product.
これを６００’０の温度に保持したＮ２ガス雰囲気下の
炉内へ供給し１時間焼成して熱分解炭素粉末１１０重量
部を得て本発明に係るカーボンブラックとした。この物
性を第１表に示す。This was fed into a furnace under an N2 gas atmosphere maintained at a temperature of 600'0 and fired for 1 hour to obtain 110 parts by weight of pyrolytic carbon powder, which was used as carbon black according to the present invention. The physical properties are shown in Table 1.
第 １ 表
メタクリル酸メチル（住人化学■製）１８重量部、スチ
レン（１１！気化学工業■ｊ！！り２０重量部、アクリ
ル酸ゾチル（三菱油化■製）５２重量部、アクリル酸（
三菱油化■製）１０重量部、トルエン（三井コークス■
製）１００重量部、ｎ −ｆ ｆｉノール（協和油化■
製）１００重量部の混合物にアゾ♂スイソゾチロニトリ
ル（大塚化学■製；商品名ｒＡ−ＢＮ、Ｊ ）１重量部
を加え、窒素雰囲気中８０℃で５時間、加熱下反応させ
て重合反応を完結した（単量体の反応率９９％）。Table 1: 18 parts by weight of methyl methacrylate (manufactured by Sumima Kagaku ■), 20 parts by weight of styrene (11!Ki Kagaku Kogyo ■j!!ri), 52 parts by weight of zotyl acrylate (manufactured by Mitsubishi Yuka ■), acrylic acid (manufactured by Mitsubishi Yuka ■).
Mitsubishi Yuka ■) 10 parts by weight, toluene (Mitsui Coke ■)
(manufactured by Kyowa Yuka), 100 parts by weight, n-f finol (Kyowa Yuka ■)
1 part by weight of azo♂sisozothyronitrile (manufactured by Otsuka Chemical Ltd.; trade name: rA-BN, J) was added to a mixture of 100 parts by weight (manufactured by Otsuka Chemical Ltd.), and the mixture was reacted under heating at 80°C for 5 hours in a nitrogen atmosphere to cause a polymerization reaction. was completed (monomer reaction rate 99%).
次に、このカーボンペーストを２（）＋ｉ＋Ｘ７０ｇｍ
Ｘ２ｍＫ成型したＡＢＳ製平板（電気化学工業■製；商
品名ｒ（）Ｒ−４０００Ｊ）上に一定厚み０．０５關に
施し、その後２４時間自然乾燥した。この成型物の性能
を評価した。Next, add this carbon paste to 2()+i+X70gm
It was applied to a constant thickness of 0.05 mm on an ABS flat plate (manufactured by Denki Kagaku Kogyo ■; trade name: r()R-4000J) that had been molded by X2mK, and then air-dried for 24 hours. The performance of this molded product was evaluated.
（比較例）
カーざンデラックとして、市販アセチレンブラック及び
副生カーがンブラックを用い、第２表の配合でカーボン
ペーストを実施例と同様に製造して評価した。(Comparative Example) Commercially available acetylene black and by-product carbon black were used as car sanderac, and carbon pastes were produced and evaluated in the same manner as in the examples with the formulations shown in Table 2.
これらの結果を第２表に示す。These results are shown in Table 2.
なお、第１表の物性値測定法と第２表の物性評価法は次
によった。The physical property measurement method in Table 1 and the physical property evaluation method in Table 2 were as follows.
（１） １１２ＫＶａｎ”加圧下の電気比抵抗： Ｊ
ｘｓｘ−１４６９（２）比表面積：カンタソーゾ法（窒
素ガス使用）（３）沃素吸着量： ＪＩＳＫ−１４６９
（４） 塩酸吸液量： 、ｒＩｓｘ−１４６９（５）
ペーストの粘度二Ｂ型粘度計による。(1) Electrical specific resistance under 112KVan” pressure: J
xsx-1469 (2) Specific surface area: Cantasso method (using nitrogen gas) (3) Iodine adsorption amount: JISK-1469
(4) Hydrochloric acid absorption amount: , rIsx-1469 (5)
Viscosity of paste: Measured using a Type 2 B viscometer.
（６）体積固有抵抗；寸法７０Ｘ２０Ｘ肌０５ｔｓｚ（
ｚｘｓｘｗ）の塗面についてマルチメーター（タケダ理
研■製）でその抵抗を測定し次式により体積固有抵抗を
算出した。(6) Volume resistivity; dimensions 70X20X skin 05tsz (
zxsxw) was measured with a multimeter (manufactured by Takeda Riken ■), and the volume resistivity was calculated using the following formula.
但し、ＲＶ：体積固有抵抗（Ω−ｃｔｎ）Ｒ：抵抗値（
Ω）
（発明の効果）
本発明の高抵抗カーボンペーストは、従来品に比べて、
高抵抗となり、しかも抵抗値のバラツキが少ないもので
ある。However, RV: Volume specific resistance (Ω-ctn) R: Resistance value (
Ω) (Effects of the invention) Compared to conventional products, the high resistance carbon paste of the present invention has
It has high resistance and has little variation in resistance value.
Claims (1)
・ｃｍ以下、比表面積４０〜８０ｍ＾２／ｇ、沃素吸着
量５０〜９０ｍｇ／ｇ及び塩酸吸液量５〜１０ｍｌ／５
ｇのカーボンブラック、バインダー及び溶剤を含有して
なる高抵抗カーボンペースト。1. Electrical specific resistance under pressure of 112kg/cm^2 0.2Ω
・cm or less, specific surface area 40-80 m^2/g, iodine adsorption amount 50-90 mg/g, and hydrochloric acid absorption amount 5-10 ml/5
A high-resistance carbon paste containing g carbon black, a binder and a solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60172487A JPS6234968A (en) | 1985-08-07 | 1985-08-07 | Carbon paste of high resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60172487A JPS6234968A (en) | 1985-08-07 | 1985-08-07 | Carbon paste of high resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6234968A true JPS6234968A (en) | 1987-02-14 |
Family
ID=15942894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60172487A Pending JPS6234968A (en) | 1985-08-07 | 1985-08-07 | Carbon paste of high resistance |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6234968A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0617984A1 (en) * | 1993-03-16 | 1994-10-05 | MOTODA ELECTRONICS Co., Ltd. | Methods for dechlorination disposal of polyvinyl chloride wastes and apparatus thereof |
| JP2009140821A (en) * | 2007-12-07 | 2009-06-25 | Honda Motor Co Ltd | Sealing material for polymer electrolyte fuel cell separator, separator seal, and separator |
| JP2011228308A (en) * | 2005-07-06 | 2011-11-10 | Suntech Co Ltd | Method of manufacturing planar heating element, and planar heating element manufactured by the same |
| US8133949B2 (en) | 2007-12-07 | 2012-03-13 | Honda Motor Co., Ltd. | Separator and separator seal for polymer electrolyte fuel cells |
| US11706972B2 (en) * | 2015-09-08 | 2023-07-18 | Universal Display Corporation | Organic electroluminescent materials and devices |
-
1985
- 1985-08-07 JP JP60172487A patent/JPS6234968A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0617984A1 (en) * | 1993-03-16 | 1994-10-05 | MOTODA ELECTRONICS Co., Ltd. | Methods for dechlorination disposal of polyvinyl chloride wastes and apparatus thereof |
| JP2011228308A (en) * | 2005-07-06 | 2011-11-10 | Suntech Co Ltd | Method of manufacturing planar heating element, and planar heating element manufactured by the same |
| JP2009140821A (en) * | 2007-12-07 | 2009-06-25 | Honda Motor Co Ltd | Sealing material for polymer electrolyte fuel cell separator, separator seal, and separator |
| US8133949B2 (en) | 2007-12-07 | 2012-03-13 | Honda Motor Co., Ltd. | Separator and separator seal for polymer electrolyte fuel cells |
| US8795920B2 (en) | 2007-12-07 | 2014-08-05 | Honda Motor Co., Ltd. | Separator and separator seal for polymer electrolyte fuel cells |
| US11706972B2 (en) * | 2015-09-08 | 2023-07-18 | Universal Display Corporation | Organic electroluminescent materials and devices |
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