JPS623590B2 - - Google Patents

Info

Publication number
JPS623590B2
JPS623590B2 JP54010772A JP1077279A JPS623590B2 JP S623590 B2 JPS623590 B2 JP S623590B2 JP 54010772 A JP54010772 A JP 54010772A JP 1077279 A JP1077279 A JP 1077279A JP S623590 B2 JPS623590 B2 JP S623590B2
Authority
JP
Japan
Prior art keywords
electrode
glass
layer
pellet
contact
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP54010772A
Other languages
Japanese (ja)
Other versions
JPS55103762A (en
Inventor
Shigeru Sakashita
Takashi Mizuguchi
Masatake Saito
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Home Electronics Ltd
NEC Corp
Original Assignee
NEC Home Electronics Ltd
Nippon Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Home Electronics Ltd, Nippon Electric Co Ltd filed Critical NEC Home Electronics Ltd
Priority to JP1077279A priority Critical patent/JPS55103762A/en
Publication of JPS55103762A publication Critical patent/JPS55103762A/en
Publication of JPS623590B2 publication Critical patent/JPS623590B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages

Landscapes

  • Electrodes Of Semiconductors (AREA)
  • Die Bonding (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は半導体装置、特にDHDガラス封止ダ
イオードの電極構造に関する。 一般に、DHDガラス封止ダイオードは、半導
体素子〔以下単にペレツトと称する〕の両表面を
ヒートシンクとなる電極リードによつて挾み込む
構造を特徴としている。 この場合、ペレツトは、その表面にバンプと称
される突起状の電極が造られ、裏面には接触抵抗
を低くするため適当な鑞材層が形成されており、
これらのバンプ及び鑞材層面に電極リードを接続
するようにしている。 ところでペレツト裏面に対する鑞材としては、
従来一般に金あるいは金を主体とする合金が用い
られ、次いでこの全面に銀層をメツキにより形成
した後、ペレツトをデユメツト線からなる電極リ
ード間に挾み込み、その周面をガラス管により封
止して組み立てられている。 しかしながら、このように形成されたペレツト
は、ガラス管で封止する際の加熱処理によつて、
金、シリコン、銀、銅等からなる好ましくない合
金が形成されるため電気的特性の点で接触抵抗が
大きくなり、コンタクト不良を発生していた。 又、DHDガラス封止ダイオードは上述のよう
に、ペレツトの両電極を電極リード線で挾み込み
ガラス封止する構造であるから、両電極の電気的
接続は銀バンプ電極をクツシヨン材とした機械的
接続となるため、温度サイクル試験や加熱試験等
の熱的環境雰囲気に対してルーズコンタクトの原
因となる欠点を含んでいた。 本発明はかゝる欠点を除去するためになされた
もので、ペレツト裏面の鑞材が剥れたり、ガラス
封止の後のルーズコンタクトのない電極構造を得
ることにある。 本発明の要旨とするところは、一主面に銀バン
プ電極が形成されたシリコン基板の他主面にCr
の薄層を被着し、Si,Crの強固な接着層を形成
する。更にNi,Agの薄層を逐次被着形成して熱
応力に優れた電極構造を形成する。次にこのよう
に形成した電極構造のSiペレツトの両電極間を
Cu材等からなる電極リードで挾んでガラス封止
する事により、前記Siペレツトの一方に於いて、
柔軟性の銀バンプ電極を電極リードに弾接させ
る。又他方裏面側に於いて、シリコン基板に対し
て熱膨張係数が順次大きく形成されたCr,Ni,
Agの積層電極を他方の電極リードに弾接させ
る。 このように、本発明で得られるDHDガラス封
止ダイオードは、熱応力に優れた弾力性の両電極
で電極リードに当接せしめ、ガラス封止する際の
加熱処理やガラス封止後の熱的環境雰囲気に対し
てもルーズコンタクトの発生しない良好な電極構
造が得られる。 以下本発明の実施例を図面を参照しつつ詳述す
る。 第1図に於て、1はN形シリコン基板であり、
拡散処理によりP形導電層2を形成し、このP形
導電層2に対しバンプ電極3を形成する。4は基
板1表面を覆う絶縁保護膜、例えばSiO2であ
る。シリコン基板1の下面にはCr,Ni,Agの薄
膜層5,6,7が逐次蒸着法により被着されて、
積層電極8が形成される。このシリコン基板1の
下面は上記薄膜層の被着前にエツチング法又はサ
ンドブラスト法により表面をあらし接着強度を高
めるようにしている。 かかる構造に形成されたシリコン基板1は1個
の素子毎に分離され、ペレツト10が形成され
る。このペレツト10は第2図に示すように2個
の電極リード11,12により両主表面から挾み
込むようにし、且つペレツト10がガラス管13
で包囲されるようにして図示しないが、電極リー
ド11の上端より重鍾で加圧しながら約650℃で
加熱し、ガラス管13を溶融せしめてペレツト1
0が封着される。こゝで電極リード11,12と
しては、一般にFe−Ni芯線Cu被覆したジユメツ
ト線が用いられ、これらのリード11,12は一
般にガラス管内にある電極導体部14と外部に出
ているリード部15とは違つた経に形成され、電
極取り出しと封止に適合するよう考慮されてい
る。 本発明は以上のように構成されており、シリコ
ン基板のSiと被着されるCrの強固な密着が得ら
れる。こゝでCrは高融点金属であり、従来の如
くガラス封止する際の加熱処理によつてAu−Si
−MgやAu−Si−Ag−Cu等の多元合金を形成し
て接触抵抗を大きくしたり、コンタクト不良を発
生することがなくなる。又、こゝで特に注目すべ
き点は、シリコン基板に被膜され電極リードに当
接されるCr−Ni−Ag層は、その被膜金属の線膨
張係数が夫々0.84×10-5cm/cm・deg、1.33×10-5
cm/cm・deg、1・97×10-5cm/cm・degと逐次
大きくした金属膜が被覆され熱応力に優れた薄膜
の積層電極を形成したから、ガラス封止の熱処理
や封止後の熱サイクル試験、加熱試験等の熱的環
境雰囲気に対しても、熱疲労を生じて劣化した
り、ルーズコンタクト等の不良を生ずることが解
消される。 尚、本発明で得られたダイオードAと従来のダ
イオードBとの比較試験結果を第1表に示す。
The present invention relates to a semiconductor device, particularly to an electrode structure of a DHD glass-sealed diode. In general, a DHD glass-sealed diode is characterized by a structure in which both surfaces of a semiconductor element (hereinafter simply referred to as pellet) are sandwiched between electrode leads that serve as a heat sink. In this case, a protruding electrode called a bump is formed on the surface of the pellet, and a suitable solder layer is formed on the back surface to reduce contact resistance.
Electrode leads are connected to these bumps and the solder layer surface. By the way, as a solder material for the back side of pellets,
Conventionally, gold or a gold-based alloy was generally used, and then a silver layer was formed on the entire surface by plating, and then the pellet was inserted between electrode leads made of dumet wire, and the surrounding surface was sealed with a glass tube. It has been assembled. However, the pellets formed in this way are heated during sealing in a glass tube.
Since an undesirable alloy consisting of gold, silicon, silver, copper, etc. is formed, contact resistance increases in terms of electrical characteristics, resulting in contact failure. In addition, as mentioned above, the DHD glass-sealed diode has a structure in which both electrodes of the pellet are sandwiched between electrode lead wires and sealed with glass, so the electrical connection between the two electrodes is achieved using a machine using silver bump electrodes as cushioning material. Since it is a physical connection, it has the drawback of causing loose contact in thermal environment atmospheres such as temperature cycle tests and heating tests. The present invention has been made to eliminate such drawbacks, and the object is to obtain an electrode structure that does not cause peeling of the solder material on the back side of the pellet or loose contacts after glass sealing. The gist of the present invention is to provide a silicon substrate with silver bump electrodes formed on one main surface and Cr on the other main surface.
A thin layer of Si and Cr is applied to form a strong adhesive layer. Furthermore, thin layers of Ni and Ag are sequentially deposited to form an electrode structure with excellent thermal stress resistance. Next, the gap between the two electrodes of the Si pellet with the electrode structure formed in this way is
By sandwiching the electrode leads made of Cu material or the like and sealing them with glass, one side of the Si pellets can be
A flexible silver bump electrode is brought into elastic contact with the electrode lead. On the other hand, on the back side, Cr, Ni, and
The Ag laminated electrode is brought into elastic contact with the other electrode lead. As described above, the DHD glass-sealed diode obtained by the present invention has both elastic electrodes with excellent thermal stress in contact with the electrode leads, and is suitable for heat treatment during glass sealing and thermal treatment after glass sealing. A good electrode structure that does not cause loose contact even with respect to the environmental atmosphere can be obtained. Embodiments of the present invention will be described in detail below with reference to the drawings. In FIG. 1, 1 is an N-type silicon substrate,
A P-type conductive layer 2 is formed by diffusion treatment, and a bump electrode 3 is formed on this P-type conductive layer 2. 4 is an insulating protective film covering the surface of the substrate 1, for example, SiO 2 . Thin film layers 5, 6, and 7 of Cr, Ni, and Ag are deposited on the lower surface of the silicon substrate 1 by sequential vapor deposition.
Laminated electrode 8 is formed. The lower surface of the silicon substrate 1 is roughened by etching or sandblasting to increase adhesive strength before the thin film layer is applied thereto. The silicon substrate 1 formed in this structure is separated into individual elements, and pellets 10 are formed. As shown in FIG.
Although not shown, the electrode lead 11 is heated at about 650° C. while being pressurized with a heavy hammer from the upper end of the electrode lead 11 to melt the glass tube 13 and form pellets 1.
0 is sealed. Here, the electrode leads 11 and 12 are generally Fe-Ni core wires coated with Cu, and these leads 11 and 12 generally have an electrode conductor part 14 inside the glass tube and a lead part 15 extending outside. It is designed to have a different diameter than the previous one, and is designed to be suitable for electrode extraction and sealing. The present invention is configured as described above, and strong adhesion between Si of the silicon substrate and Cr to be deposited can be obtained. Here, Cr is a high melting point metal, and Au-Si can be formed by heat treatment during glass sealing as in the past.
- Eliminates the formation of multi-component alloys such as Mg and Au-Si-Ag-Cu, which increases contact resistance and causes contact failure. What is particularly noteworthy here is that the linear expansion coefficient of the Cr-Ni-Ag layer coated on the silicon substrate and in contact with the electrode leads is 0.84 x 10 -5 cm/cm. deg, 1.33×10 -5
cm/cm・deg, 1・97×10 -5 cm/cm・deg Since the metal film is coated with successively larger layers to form a thin film laminated electrode with excellent thermal stress, after heat treatment and sealing for glass sealing. Even in thermal environments such as thermal cycle tests and heating tests, thermal fatigue, deterioration, and defects such as loose contacts can be eliminated. Table 1 shows the results of a comparative test between diode A obtained according to the present invention and conventional diode B.

【表】 第1表に於て、Aは本発明のDHDガラス封止
ダイオードでペレツト裏面電極をCr−Ni−Ag層
で形成したペレツトを用いたものであり、Bは従
来のダイオードで、裏面電極をAu−Ag層で形成
したペレツトを用いたものである。同表から本発
明品は従来のものに比べて、順方向電圧VF値が
低く、そのバラツキがいちじるしく改善されてお
り、又ホツトゼツト試験に於いても、ルーズコン
タクト不良の発生率が皆無であり、コンタクト性
のきわめて良好な電極構造であることが確認され
た。裏面電極の各層の厚みはCr層500〜800Å、
Ni層5000〜6000Å、Ag層はNi層より厚く、例え
ば10000Å形成し、各金属層の線膨張係数に対応
して順次厚く形成することにより良好な結果が得
られた。
[Table] In Table 1, A is a DHD glass-sealed diode of the present invention using a pellet with a Cr-Ni-Ag layer as the pellet backside electrode, and B is a conventional diode with a backside electrode formed of a Cr-Ni-Ag layer. The electrodes are made of pellets made of Au-Ag layers. The table shows that compared to the conventional product, the forward voltage V F value of the product of the present invention is lower, its variation is significantly improved, and there is no occurrence of loose contact defects in the hot-set test. It was confirmed that the electrode structure had extremely good contact properties. The thickness of each layer of the back electrode is 500 to 800 Å for the Cr layer,
Good results were obtained by forming the Ni layer 5000 to 6000 Å thicker, the Ag layer thicker than the Ni layer, for example 10000 Å, and sequentially forming thicker layers corresponding to the coefficient of linear expansion of each metal layer.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明に係る実施例で半導体装置に使
用されるペレツトの縦断面図、第2図は第1図を
使用して得られるDHDガラス封止ダイオードの
縦断面図である。 3……バンプ電極、8……積層電極、10……
半導体素子(ペレツト)、11,12……電極リ
ード、13……ガラス管。
FIG. 1 is a vertical cross-sectional view of a pellet used in a semiconductor device in an embodiment of the present invention, and FIG. 2 is a vertical cross-sectional view of a DHD glass-sealed diode obtained using the method shown in FIG. 3... Bump electrode, 8... Laminated electrode, 10...
Semiconductor element (pellet), 11, 12...electrode lead, 13...glass tube.

Claims (1)

【特許請求の範囲】[Claims] 1 少なくとも一方に積層電極を有する半導体素
子、この半導体素子を挾着する一対の電極リー
ド、及び前記半導体素子と前記一対の電極リード
を外囲し前記電極リードの側面で封着するガラス
管を具備し前記積層電極をCr,Ni,Agの積層に
より形成したことを特徴とするDHDガラス封止
ダイオード。
1 Equipped with a semiconductor element having a laminated electrode on at least one side, a pair of electrode leads that clamp the semiconductor element, and a glass tube that surrounds the semiconductor element and the pair of electrode leads and seals them with the sides of the electrode leads. A DHD glass-sealed diode characterized in that the laminated electrode is formed by laminating Cr, Ni, and Ag.
JP1077279A 1979-01-31 1979-01-31 Dhd glass-sealed diode Granted JPS55103762A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1077279A JPS55103762A (en) 1979-01-31 1979-01-31 Dhd glass-sealed diode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1077279A JPS55103762A (en) 1979-01-31 1979-01-31 Dhd glass-sealed diode

Publications (2)

Publication Number Publication Date
JPS55103762A JPS55103762A (en) 1980-08-08
JPS623590B2 true JPS623590B2 (en) 1987-01-26

Family

ID=11759615

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1077279A Granted JPS55103762A (en) 1979-01-31 1979-01-31 Dhd glass-sealed diode

Country Status (1)

Country Link
JP (1) JPS55103762A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58135942U (en) * 1982-03-09 1983-09-13 富士電機株式会社 glass sealed diode
CN106057789A (en) * 2016-07-01 2016-10-26 天津中环半导体股份有限公司 SMD high-voltage silicon stack and production process thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS518871A (en) * 1974-07-10 1976-01-24 Hitachi Ltd Handotaisochino denkyoku
JPS5165659U (en) * 1974-11-18 1976-05-24

Also Published As

Publication number Publication date
JPS55103762A (en) 1980-08-08

Similar Documents

Publication Publication Date Title
EP0271110B1 (en) Semiconductor device comprising an electrode pad
US4482912A (en) Stacked structure having matrix-fibered composite layers and a metal layer
US3881884A (en) Method for the formation of corrosion resistant electronic interconnections
JPS6038867B2 (en) Isolated semiconductor device
US4042951A (en) Gold-germanium alloy contacts for a semiconductor device
JPH0936186A (en) Power semiconductor module and mounting method thereof
WO2017006916A1 (en) Semiconductor device and method for manufacturing semiconductor device
JPH0439956A (en) Semiconductor device and manufacture thereof
JP4344560B2 (en) Semiconductor chip and semiconductor device using the same
JP3928488B2 (en) Semiconductor device and manufacturing method thereof
JP5494559B2 (en) Semiconductor device and manufacturing method thereof
JP3601529B2 (en) Semiconductor device
JPS623590B2 (en)
KR0146356B1 (en) Brazing material
US3702787A (en) Method of forming ohmic contact for semiconducting devices
CA1153128A (en) Electrical circuit assemblies
US4851301A (en) Solder bonding with improved peel strength
JP2972679B2 (en) Lead frame, resin-encapsulated semiconductor device and method of manufacturing the same
JP2654872B2 (en) Semiconductor device
JPS6312385B2 (en)
JPS60110127A (en) Semiconductor device having laminated metal electrode
JPS60119765A (en) Resin-sealed semiconductor device and lead frame used therefor
JP2008085368A (en) Semiconductor chip and semiconductor device using the same
JPH03238865A (en) Semiconductor element
JPH0794623A (en) Circuit board