JPS6261533B2 - - Google Patents

Info

Publication number: JPS6261533B2
Authority: JP; Japan
Prior art keywords: aluminum; temperature; aluminosilicate; halogen; zeolite
Prior art date: 1981-04-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP56054460A

Other languages

English (en)

Japanese (ja)

Other versions

JPS57170816A (en

Inventor

Deiton Changu Kurarensu

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ExxonMobil Oil Corp

Original Assignee

Mobil Oil Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-04-13

Filing date

1981-04-13

Publication date

1987-12-22

1981-04-13 Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp

1981-04-13 Priority to JP5446081A priority Critical patent/JPS57170816A/ja

1982-10-21 Publication of JPS57170816A publication Critical patent/JPS57170816A/ja

1987-12-22 Publication of JPS6261533B2 publication Critical patent/JPS6261533B2/ja

Status Granted legal-status Critical Current

Links

HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 31
239000010457 zeolite Substances 0.000 claims description 30
238000000034 method Methods 0.000 claims description 28
229910052782 aluminium Inorganic materials 0.000 claims description 21
229910021536 Zeolite Inorganic materials 0.000 claims description 20
229910000323 aluminium silicate Inorganic materials 0.000 claims description 20
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
229910052736 halogen Inorganic materials 0.000 claims description 12
150000002367 halogens Chemical class 0.000 claims description 12
239000000499 gel Substances 0.000 claims description 8
-1 aluminum halide Chemical class 0.000 claims description 7
239000000460 chlorine Substances 0.000 claims description 7
229910052801 chlorine Inorganic materials 0.000 claims description 6
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
239000011148 porous material Substances 0.000 claims description 6
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
229910001502 inorganic halide Inorganic materials 0.000 claims description 5
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 4
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
229910052794 bromium Inorganic materials 0.000 claims description 4
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 4
239000011630 iodine Substances 0.000 claims description 4
229910052740 iodine Inorganic materials 0.000 claims description 4
229910052901 montmorillonite Inorganic materials 0.000 claims description 4
238000001704 evaporation Methods 0.000 claims description 3
230000008020 evaporation Effects 0.000 claims description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
229910052622 kaolinite Inorganic materials 0.000 claims description 3
229910052680 mordenite Inorganic materials 0.000 claims description 3
229910003910 SiCl4 Inorganic materials 0.000 claims description 2
HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims description 2
229910052621 halloysite Inorganic materials 0.000 claims description 2
229910052900 illite Inorganic materials 0.000 claims description 2
VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims description 2
FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical group Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 claims description 2
238000000151 deposition Methods 0.000 claims 1
239000012013 faujasite Substances 0.000 claims 1
229910052710 silicon Inorganic materials 0.000 claims 1
239000010703 silicon Substances 0.000 claims 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 40
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 22
239000000377 silicon dioxide Substances 0.000 description 20
229910018072 Al 2 O 3 Inorganic materials 0.000 description 15
239000003054 catalyst Substances 0.000 description 11
238000006243 chemical reaction Methods 0.000 description 11
239000002002 slurry Substances 0.000 description 10
239000000203 mixture Substances 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
229910004298 SiO 2 Inorganic materials 0.000 description 8
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
239000004927 clay Substances 0.000 description 8
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
229910003902 SiCl 4 Inorganic materials 0.000 description 6
238000003756 stirring Methods 0.000 description 6
239000000126 substance Substances 0.000 description 6
230000003197 catalytic effect Effects 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
150000002430 hydrocarbons Chemical class 0.000 description 5
239000000047 product Substances 0.000 description 5
239000011734 sodium Substances 0.000 description 5
239000004115 Sodium Silicate Substances 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
239000011780 sodium chloride Substances 0.000 description 4
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
229910052911 sodium silicate Inorganic materials 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
238000004517 catalytic hydrocracking Methods 0.000 description 3
238000006703 hydration reaction Methods 0.000 description 3
238000005984 hydrogenation reaction Methods 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
239000002243 precursor Substances 0.000 description 3
239000006228 supernatant Substances 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
239000003463 adsorbent Substances 0.000 description 2
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
239000008346 aqueous phase Substances 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
238000009835 boiling Methods 0.000 description 2
238000005336 cracking Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
230000036571 hydration Effects 0.000 description 2
239000012500 ion exchange media Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
238000002156 mixing Methods 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000000376 reactant Substances 0.000 description 2
230000008929 regeneration Effects 0.000 description 2
238000011069 regeneration method Methods 0.000 description 2
YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 2
CYNYIHKIEHGYOZ-UHFFFAOYSA-N 1-bromopropane Chemical compound CCCBr CYNYIHKIEHGYOZ-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229910019929 CrO2Cl2 Inorganic materials 0.000 description 1
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
229910003074 TiCl4 Inorganic materials 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
239000011959 amorphous silica alumina Substances 0.000 description 1
229960000892 attapulgite Drugs 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
239000000701 coagulant Substances 0.000 description 1
239000000571 coke Substances 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
238000010908 decantation Methods 0.000 description 1
230000000593 degrading effect Effects 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
229910052675 erionite Inorganic materials 0.000 description 1
238000007701 flash-distillation Methods 0.000 description 1
230000006870 function Effects 0.000 description 1
230000026030 halogenation Effects 0.000 description 1
238000005658 halogenation reaction Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
238000006317 isomerization reaction Methods 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
230000008450 motivation Effects 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000005416 organic matter Substances 0.000 description 1
229910052625 palygorskite Inorganic materials 0.000 description 1
239000008188 pellet Substances 0.000 description 1
FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
DGMKFQYCZXERLX-UHFFFAOYSA-N proglumide Chemical compound CCCN(CCC)C(=O)C(CCC(O)=O)NC(=O)C1=CC=CC=C1 DGMKFQYCZXERLX-UHFFFAOYSA-N 0.000 description 1
238000002407 reforming Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
150000004763 sulfides Chemical class 0.000 description 1
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
229910052815 sulfur oxide Inorganic materials 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
238000009834 vaporization Methods 0.000 description 1
230000008016 vaporization Effects 0.000 description 1

Landscapes

Silicates, Zeolites, And Molecular Sieves (AREA)

JP5446081A 1981-04-13 1981-04-13 Dealuminization of aluminosilicate Granted JPS57170816A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP5446081A JPS57170816A (en)	1981-04-13	1981-04-13	Dealuminization of aluminosilicate

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP5446081A JPS57170816A (en)	1981-04-13	1981-04-13	Dealuminization of aluminosilicate

Publications (2)

Publication Number	Publication Date
JPS57170816A JPS57170816A (en)	1982-10-21
JPS6261533B2 true JPS6261533B2 (fr)	1987-12-22

Family

ID=12971278

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP5446081A Granted JPS57170816A (en)	1981-04-13	1981-04-13	Dealuminization of aluminosilicate

Country Status (1)

Country	Link
JP (1)	JPS57170816A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0725537B2 (ja) *	1988-11-30	1995-03-22	東ソー株式会社	バインダーレスフォージャサイト型ゼオライト成形体の脱アルミニウム方法

1981
- 1981-04-13 JP JP5446081A patent/JPS57170816A/ja active Granted

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
STUDIES IN SURFACE SIENCE AND CATALYSIS=1980 *
ZEOLITE MOLECULAR SIEVES=1974 *

Also Published As

Publication number	Publication date
JPS57170816A (en)	1982-10-21

Publication	Publication Date	Title
US4273753A (en)	1981-06-16	De-aluminization of aluminosilicates
KR910003610B1 (ko)	1991-06-07	제올라이트 베타 및 그 제조방법
US4701313A (en)	1987-10-20	Replacing boron with silicon in zeolite beta using SiCl4
CA1097309A (fr)	1981-03-10	Procede d'obtention de la zeolithe cristalline zsm-34
US7771703B2 (en)	2010-08-10	IZM-1 crystalline solid and a process for its preparation
EP0142313B1 (fr)	1988-12-14	Méthode de préparation d'un catalyseur zéolitique
US4359421A (en)	1982-11-16	Process for making epsilon-caprolactam
JPS59136138A (ja)	1984-08-04	スチ−ム脱活性化された触媒の再活性化方法
CA2063991A1 (fr)	1991-01-08	Zeolite ssz-33
JPH0147518B2 (fr)	1989-10-13
US4515902A (en)	1985-05-07	Hydrocarbon conversion catalyst and process for preparing same
EP0062123B1 (fr)	1986-07-02	Déaluminisation de silicates d'aluminium
JPS6132294B2 (fr)	1986-07-25
EP0055913B1 (fr)	1986-01-15	Procédé de préparation d'un fluidisable catalyseur pour la conversion ou methanole
EP0134331B1 (fr)	1987-07-22	Traitement de zéolites
EP0014291B1 (fr)	1983-02-09	Conversion de charges hydrocarbonées contenant du soufre et de l'azote et catalyseur pour cette conversion
JPS6261533B2 (fr)	1987-12-22
US3475345A (en)	1969-10-28	Catalyst for paraffin isomerization
JPH0672012B2 (ja)	1994-09-14	表層脱アルミニウムゼオライトおよびその製造法
EP0295019A1 (fr)	1988-12-14	Traitement de zéolites du type aluminosilicate
US5238675A (en)	1993-08-24	Gallium zeolites
JPH04227066A (ja)	1992-08-17	ガロアルミノケイ酸塩型の触媒、および炭素原子数２〜７の炭化水素の芳香族化におけるその使用方法
JP2759099B2 (ja)	1998-05-28	炭化水素油の流動接触分解用触媒組成物ならびにそれを用いる流動接解分解法
KR0169726B1 (ko)	1999-01-15	분자당 c5-c7 함유 저급 분획을 방향족화시키는 갈륨 함유 알루미노실리케이트형 촉매
EP0119709B1 (fr)	1988-11-02	Procédé de déparaffinage de fractions d'hydrocarbures