JPS6289860A - Matted vapor deposited sheet - Google Patents
Matted vapor deposited sheetInfo
- Publication number
- JPS6289860A JPS6289860A JP23073185A JP23073185A JPS6289860A JP S6289860 A JPS6289860 A JP S6289860A JP 23073185 A JP23073185 A JP 23073185A JP 23073185 A JP23073185 A JP 23073185A JP S6289860 A JPS6289860 A JP S6289860A
- Authority
- JP
- Japan
- Prior art keywords
- copolymer resin
- vapor
- vinyl chloride
- vapor deposited
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000004922 lacquer Substances 0.000 claims abstract description 16
- 229920006026 co-polymeric resin Polymers 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 8
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 claims abstract description 6
- 229920001986 Vinylidene chloride-vinyl chloride copolymer Polymers 0.000 claims abstract description 4
- 239000002985 plastic film Substances 0.000 claims abstract description 4
- 229920006255 plastic film Polymers 0.000 claims abstract description 4
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 15
- 235000011613 Pinus brutia Nutrition 0.000 claims description 15
- 241000018646 Pinus brutia Species 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 239000001023 inorganic pigment Substances 0.000 claims description 8
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 claims description 2
- 229920005670 poly(ethylene-vinyl chloride) Polymers 0.000 claims description 2
- 239000000049 pigment Substances 0.000 abstract 2
- 239000010410 layer Substances 0.000 description 23
- 229910052782 aluminium Inorganic materials 0.000 description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
- 239000011888 foil Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000002932 luster Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000005022 packaging material Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000035699 permeability Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000012046 mixed solvent Substances 0.000 description 3
- 235000019504 cigarettes Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 210000002925 A-like Anatomy 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/02—Metal coatings
- D21H19/08—Metal coatings applied as vapour, e.g. in vacuum
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Laminated Bodies (AREA)
- Physical Vapour Deposition (AREA)
- Paper (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はつや消し蒸着シートに関するものであシ、本発
明により得られるつや消し蒸着シートは包装材などに利
用されるものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a matte vapor-deposited sheet, and the matte vapor-deposited sheet obtained by the present invention is used for packaging materials and the like.
（従来技ｆｒ）
従来、包装材特にたばこ用包装材として、アルミ箔はシ
合せ紙が防湿性、保香性にすぐれ、かつ金属特有の色彩
的効果による高級感を有する包装材として用いられてい
た。しかし、近年の蒸着加工技術の進歩により、防湿性
や美観性など包装材として要求される特性がアルミ箔は
り合せ紙に近いアルミ蒸着紙が開発され、たばこ用包装
材として利用されている。(Conventional technology fr) Aluminum foil has traditionally been used as a packaging material, especially for cigarettes, as the laminated paper has excellent moisture resistance and fragrance retention, and has a luxurious feel due to the color effect unique to metal. Ta. However, with recent advances in vapor deposition technology, aluminum vapor-deposited paper has been developed that has properties required for packaging materials, such as moisture resistance and aesthetics, that are similar to those of aluminum foil-laminated paper, and it is now being used as a packaging material for cigarettes.
ところが、これらの族ｆｆ紙は、紙に塗工層（下塗クラ
ッカ一層）を、次いで、その上に金属蒸Ｎ層を形成して
いるので強い金属光沢を有し、従来のつや消しアルミ箔
はシ合せ紙のもつつやの消えた高級感のある金属光沢と
は！Ａなっ友外観を呈する几めに、金属光沢の弱いつや
消し蒸着紙が求められている。However, these Group FF papers have a strong metallic luster because they have a coating layer (one layer of undercoat cracker) on the paper, and then a metal evaporated N layer on top of that, and conventional matte aluminum foil has a strong metallic luster. What a luxurious metallic luster that has lost the luster of the laminated paper! There is a demand for matte metallized paper with a weak metallic luster in order to achieve an A-like appearance.
（発明が解決すべき問題点）
金属光沢の弱いつや消し蒸着紙は、紙に下塗りラッカ一
層を形成させることなく、直接金属蒸着層を設けること
によシ得られるが、この方法で得られたつや消し蒸着紙
は、下塗クラッカ一層を欠く次めに、防湿性が著しく低
下するとともに、外観がつやの消えた金属光沢ではなく
、黒ずんだ色合いとなる欠点を有している〇本発明者ら
は、アルミ箔はシ合せ紙よル安価であり、防湿性などの
包装材料としての特性をもつとともに外観的にはつや消
し蒸着面を有するつや消し蒸着シートを提供するもので
ある。(Problems to be Solved by the Invention) Matte vapor-deposited paper with weak metallic luster can be obtained by directly providing a metal vapor-deposited layer on the paper without forming a single layer of undercoat lacquer. Metallized paper has the disadvantage that it lacks a layer of undercoat cracker, and as a result, its moisture resistance is significantly reduced, and the appearance is not a matte metallic luster, but a dark hue. The foil is less expensive than laminated paper, has properties as a packaging material such as moisture resistance, and provides a matte vapor-deposited sheet having a matte vapor-deposited surface in appearance.
（問題を解決するための手段）
本発明のつや消し蒸着シートは、基材上に設けられた金
属蒸Ｍ層の上面または下面に、無機顔料の微粉末を分散
させ九ラッカーによるマツトラッカー層を形成させるも
のである。(Means for Solving the Problem) The matte vapor-deposited sheet of the present invention has a pine tracker layer formed by dispersing inorganic pigment fine powder on the top or bottom surface of the metal vapor layer provided on the base material. It is something that makes you
本発明で用いられる基材としては、紙が主として用いら
れるが、このほかプラスチックフィルムなども使用する
ことができる。As the base material used in the present invention, paper is mainly used, but other materials such as plastic films can also be used.
マツトラッカー層を形成するために用いられるラッカー
としては、塩化ビニル−酢酸ビニル共重合樹脂系、塩化
ビニリデン−塩化ビニル共重合樹脂系およびエチレン−
酢酸ビニル−塩化ビニル共重合樹脂系の１種または２種
以上の・共重合樹脂よりなるものがあげられろ。これら
共重合樹脂はラッカー用あるいは塗料用として用いられ
るもので、その重合度や重合比率は目的に応じて任意に
選択することができ、また、各共重合樹脂系は目的に応
じて単独であるいは混合して使用することができる。Lacquers used to form the pine tracker layer include vinyl chloride-vinyl acetate copolymer resin systems, vinylidene chloride-vinyl chloride copolymer resin systems, and ethylene-vinyl chloride copolymer resin systems.
Examples include those made of one or more copolymer resins of vinyl acetate-vinyl chloride copolymer resins. These copolymer resins are used for lacquers or paints, and the degree of polymerization and polymerization ratio can be selected arbitrarily depending on the purpose, and each copolymer resin system can be used alone or Can be used in combination.
さらにこれらの共重合樹脂に添加される無機顔料として
は炭酸カルシウム、酸化チタン、酸化アルミニウム、フ
ライアッシュ、カーゼンブラックなどの微粉末が用いら
れるが、アルミ箔はシ合せ紙のつや消し面とほぼ同程度
の外観を有し、かつ、防湿性にもすぐれた効果を得るｔ
めには炭酸カルシウムの使用が好適である。これら無機
顔料微粉末の粒度は５０μ以下のものが好ましく、その
形状は何れでもよい。添加量はラッカー中の固形分に対
して１０〜３０％添加するのが最もすぐれ次効果を有す
る。Furthermore, as inorganic pigments added to these copolymer resins, fine powders such as calcium carbonate, titanium oxide, aluminum oxide, fly ash, and casen black are used, but aluminum foil has almost the same texture as the matte surface of laminated paper. It has a moderate appearance and has an excellent moisture-proofing effect.
Calcium carbonate is preferably used for this purpose. The particle size of these inorganic pigment fine powders is preferably 50 μm or less, and any shape may be used. The best effects can be obtained by adding 10 to 30% of the solid content in the lacquer.
本発明で用いる無機顔料微粉末はラッカー中で分散処理
されることによシ粒子表面には樹脂や溶剤等が吸着され
てコロイド状となシ、溶剤との親和性もよく、均一に分
散されて安定性も良好であり、塗工にさいしても均一に
塗工され、得られるラッカー乾燥被膜（マツトラッカー
層）は柔軟性を有した半透明被膜であシ、必要に応じて
着色あるいは印刷することもできる。When the inorganic pigment fine powder used in the present invention is dispersed in a lacquer, resins, solvents, etc. are adsorbed on the particle surface, forming a colloidal state, and it has good affinity with solvents and is uniformly dispersed. It has good stability and is uniformly applied during coating, and the resulting dry lacquer film (pine tracker layer) is a flexible semi-transparent film, which can be colored or printed if necessary. You can also.
本発明のつや消し蒸着シートは、（１）共重合樹脂系液
に無機顔料の微粉末を分散させてなるラッカーを紙、プ
ラスチックフィルムなどの基材上に下塗りラッカーとし
て塗工したマツトラッカー層を形成し、その上に金属蒸
着層を形成させることにより、（ＩＤ基材上に従来の下
塗りラッカ一層を形成した上に金属蒸着層を形成し、そ
の上に上塗クラッカーとしてマツトラッカー層を形成さ
せることにより 、１１１１）基材上に下塗りラッカー
として塗工したマツトラッカー層を形成し、その上に金
属蒸着層、マツトラッカー層を順次形成させることによ
ル得ることができる。 ；（発明の効果）
本発明のつや消し蒸着シートは、基材上に設けられる金
属蒸着層の上面及び／又は下面に、無機顔料の微粉末を
分散させ九ラッカーによるマツトラッカー層を形成させ
てなるもので１つや消し状の外観を呈するとともに、す
ぐれ九防湿性を有している。を穴、マツトラッカー層は
柔軟性を有するので、型付等の加工が容易で、それらの
加工によっても防湿性は低下せず、さらに着色あるいは
印刷が可能である等の数多くの利点を有する◇
（実施例）
以下の実施例により得られ九つや消し蒸着紙の透湿度お
よび光沢度を測定し、これらをまとめて表−１に記載す
る。なお、従来用いられている光沢アルミ箔およびつや
消しアルミ箔の透湿度および光沢度も同一方法によシ測
定し、これらも表−１に示した。The matte vapor-deposited sheet of the present invention includes (1) a pine tracker layer formed by coating a lacquer made by dispersing fine powder of inorganic pigment in a copolymer resin liquid as an undercoat lacquer on a base material such as paper or plastic film; Then, by forming a metal vapor deposited layer thereon, (forming a conventional base coat lacquer layer on an ID substrate, forming a metal vapor deposit layer on top of the same, and forming a pine tracker layer as a top coat cracker on top of the metal vapor deposit layer) According to 1111), a pine tracker layer coated as a base lacquer is formed on a substrate, and a metal vapor deposited layer and a pine tracker layer are sequentially formed thereon. (Effects of the Invention) The matte vapor-deposited sheet of the present invention is obtained by dispersing fine powder of inorganic pigment on the upper and/or lower surface of the metal vapor-deposited layer provided on the base material to form a pine tracker layer made of lacquer. It has a matte appearance and excellent moisture resistance. Since the pine tracker layer is flexible, it is easy to process such as molding, and these processes do not reduce moisture resistance, and it has many advantages such as being able to be colored or printed.◇ (Example) The moisture permeability and glossiness of nine matte vapor-deposited papers obtained in the following examples were measured, and the results are summarized in Table 1. The moisture permeability and gloss of conventionally used glossy aluminum foil and matte aluminum foil were also measured using the same method, and these are also shown in Table 1.
１例！
基材として坪！ ５４１／ｍ”の中質コート紙な用い、
塩化ビニル−酢酸ビニル共重合靭脂４５、塩化ビニリデ
ン−塩化ビニル共重合樹脂４１およびエチレン−酢酸ビ
ニル−塩化ビニル共重合樹脂１４の割合（重量比）で混
合した共重合樹脂１８．４重量部と、酢酸エチル３６、
メチルエチルケトン３８およびトルエン２６の割合（重
量比）からなる混合溶媒７７重置部との樹脂溶液に５０
μ以下の炭酸カルシウム４．６重量部（固形分に対して
２０％）を添加して調製したマツトラッカーを、下塗９
ラツカーとして約４む曾（乾燥塗膜）の厚さに塗工し死
後、その表面に厚さ２５０〜３５０Ｘのアルミニウム蒸
着層を形成しつや消し蒸着シートを作製した。1 example! Tsubo as a base material! 541/m" medium quality coated paper,
18.4 parts by weight of a copolymer resin mixed at a ratio (weight ratio) of 45 parts of vinyl chloride-vinyl acetate copolymer toughness, 41 parts of vinylidene chloride-vinyl chloride copolymer resin, and 14 parts by weight of ethylene-vinyl acetate-vinyl chloride copolymer resin; , ethyl acetate 36,
50% of the resin solution with 77 overlapping parts of a mixed solvent consisting of 38% of methyl ethyl ketone and 26% of toluene (weight ratio).
A pine tracker prepared by adding 4.6 parts by weight of calcium carbonate (20% based on solid content) of less than μ
It was coated as a lacquer to a thickness of about 4 mm (dry coating), and after death, an aluminum vapor-deposited layer with a thickness of 250 to 350× was formed on the surface to produce a matte vapor-deposited sheet.
実施例２
基材として実施例１と同じ中質コート紙を用い、実施例
１と同じ共重合樹脂２０．７重量部及び混合溶媒７７重
量部からなる樹脂溶液に５０μ以下の炭酸カルシウム２
．３重量部（固形分に対して１０％）を添加して調製し
たマツトラッカーを、下塗りラッカーとして約４ ｇ／
ｒｒ： （乾燥塗膜）の厚さに塗工し、その表面に厚さ
２５０〜３５０Ｘのアルミニウム蒸着にりを形成しつや
消し蒸着シートを作製した。Example 2 Using the same medium-quality coated paper as in Example 1 as the base material, calcium carbonate 2 of 50μ or less was added to a resin solution consisting of 20.7 parts by weight of the same copolymer resin and 77 parts by weight of a mixed solvent.
．． Pine tracker prepared by adding 3 parts by weight (10% based on solids) was used as base lacquer at about 4 g/
rr: (dried coating film), and a matte vapor-deposited sheet was produced by forming an aluminum vapor-deposited paste with a thickness of 250 to 350× on the surface.
実施例３
基材として実施例１と同じ中質コート紙を用い、実施例
１と同じ共重合樹脂１６重量部及び混合溶媒７７重量部
からなる樹脂溶液に５０μ以下の炭酸カルシウム７重量
部（固形分に対して２５％）を添加して調製したマツト
ラッカーを、下塗シラツカ−として約４９／イ（乾燥塗
膜）の厚さに塗工し、その表面に厚さ２５０〜３５０λ
のアルミニウム蒸着層を形成しつや消し蒸着シートを作
製した。Example 3 Using the same medium-quality coated paper as in Example 1 as a base material, 7 parts by weight of calcium carbonate (solid) of 50μ or less was added to a resin solution consisting of 16 parts by weight of the same copolymer resin as in Example 1 and 77 parts by weight of a mixed solvent. A pine tracker prepared by adding 25% to
A matte vapor-deposited sheet was prepared by forming an aluminum vapor-deposited layer.
実施例４
基材として実施例１と同じ中質コート紙を用い、これに
塩化ビニル−酢酸ビニル共重合耐冷下塗クラッカーを約
４ Ｆｌ／ｍ″（乾燥塗膜）の厚さに塗工し、その表面
に厚さ２５０〜３５０Ｘのアルミ蒸着層を形成した。更
にその上に、実施例１と同様のマツトラッカーを上塗り
２ツカ−として約１． ｏ ｇ／ｍ’ （乾燥塗膜）の
厚さに塗工してつや消し蒸着シートを作製した。Example 4 Using the same medium-quality coated paper as in Example 1 as the base material, a vinyl chloride-vinyl acetate copolymer cold-resistant undercoat cracker was applied to the base material to a thickness of about 4 Fl/m'' (dry coating film), An aluminum vapor deposition layer with a thickness of 250 to 350X was formed on the surface.Furthermore, two top coats of the same pine tracker as in Example 1 were applied to a thickness of about 1.0 g/m' (dry coating). A matte vapor-deposited sheet was prepared by coating the film.
表−１ （）内は繰り返し測定（１２回）のバラツキを示す。Table-1 Values in parentheses indicate variations in repeated measurements (12 times).
（注）１．透湿度はＪ Ｉ ５−Ｚ−０２０８、Ｂ条件
（４０Ｃ，９０％ＲＨ）による測定イｌな。(Note) 1. Moisture permeability was measured according to JI 5-Z-0208, B conditions (40C, 90% RH).
２、光沢度はＪ Ｉ ５−Ｚ−８７４１，６０度鏡面光
沢による測定値。2. Glossiness is a value measured by JI 5-Z-8741, 60 degree specular gloss.
３、アルミ箔は軟質で、厚さ約７μである。3. Aluminum foil is soft and has a thickness of about 7μ.
表−１の結果より明らかなように、５０μ以下の炭酸カ
ルシウムを１０〜２５％（固形分に対して）添加したマ
ツトラッカーを塗工し几蒸着紙は透湿度、光沢度ともに
つや消しアルミ箔紙と同等の効果を示す。As is clear from the results in Table 1, the pine tracker coated with 10-25% (based on solid content) of calcium carbonate of 50μ or less is coated with matt aluminum foil paper that has both moisture permeability and gloss. Shows the same effect as.
Claims (1)
を設けた蒸着シートにおいて、塩化ビニル−酢酸ビニル
共重合樹脂系、塩化ビニリデン−塩化ビニル共重合樹脂
系およびエチレン−酢酸ビニル−塩化ビニル共重合樹脂
系から選ばれる共重合樹脂の１種または２種以上に無機
顔料の微粉末を分散させたラツカーによるマツトラッカ
ー層を、少なくとも金属蒸着層の上面または下面に形成
せしめたことを特徴とするつや消し蒸着シート。 ２、無機顔料が炭酸カルシウムである特許請求の範囲第
１項記載のつや消し蒸着シート。[Scope of Claims] 1. In a vapor-deposited sheet in which a metal vapor-deposited layer is provided on a base material such as paper or a plastic film, a vinyl chloride-vinyl acetate copolymer resin system, a vinylidene chloride-vinyl chloride copolymer resin system, and an ethylene-vinyl chloride copolymer resin system are used. A pine tracker layer made of a lacquer in which fine powder of an inorganic pigment is dispersed in one or more copolymer resins selected from the vinyl acetate-vinyl chloride copolymer resin system is formed on at least the upper or lower surface of the metal vapor deposited layer. A matte vapor-deposited sheet that is characterized by: 2. The matte vapor-deposited sheet according to claim 1, wherein the inorganic pigment is calcium carbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23073185A JPS6289860A (en) | 1985-10-15 | 1985-10-15 | Matted vapor deposited sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23073185A JPS6289860A (en) | 1985-10-15 | 1985-10-15 | Matted vapor deposited sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6289860A true JPS6289860A (en) | 1987-04-24 |
| JPH0558060B2 JPH0558060B2 (en) | 1993-08-25 |
Family
ID=16912416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23073185A Granted JPS6289860A (en) | 1985-10-15 | 1985-10-15 | Matted vapor deposited sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6289860A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02190330A (en) * | 1989-01-19 | 1990-07-26 | Toppan Printing Co Ltd | Oxidized silver-like deposition sheet |
| JPH05309807A (en) * | 1991-12-19 | 1993-11-22 | Toppan Printing Co Ltd | Transfer box |
| EP0635582A1 (en) * | 1993-07-23 | 1995-01-25 | Daiwa Seiko Inc. | Article having a decorative metal layer |
| JP2011046204A (en) * | 2004-09-29 | 2011-03-10 | Dainippon Printing Co Ltd | Low gloss metallic luster decorative sheet and laminate comprising the same |
-
1985
- 1985-10-15 JP JP23073185A patent/JPS6289860A/en active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02190330A (en) * | 1989-01-19 | 1990-07-26 | Toppan Printing Co Ltd | Oxidized silver-like deposition sheet |
| JPH05309807A (en) * | 1991-12-19 | 1993-11-22 | Toppan Printing Co Ltd | Transfer box |
| EP0635582A1 (en) * | 1993-07-23 | 1995-01-25 | Daiwa Seiko Inc. | Article having a decorative metal layer |
| JP2011046204A (en) * | 2004-09-29 | 2011-03-10 | Dainippon Printing Co Ltd | Low gloss metallic luster decorative sheet and laminate comprising the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0558060B2 (en) | 1993-08-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |