JPS63196696A - Method for increasing washing power of liquid soap - Google Patents
Method for increasing washing power of liquid soapInfo
- Publication number
- JPS63196696A JPS63196696A JP2940087A JP2940087A JPS63196696A JP S63196696 A JPS63196696 A JP S63196696A JP 2940087 A JP2940087 A JP 2940087A JP 2940087 A JP2940087 A JP 2940087A JP S63196696 A JPS63196696 A JP S63196696A
- Authority
- JP
- Japan
- Prior art keywords
- liquid soap
- fatty acid
- soap
- liquid
- detergency
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000344 soap Substances 0.000 title claims description 36
- 239000007788 liquid Substances 0.000 title claims description 28
- 238000000034 method Methods 0.000 title claims description 9
- 238000005406 washing Methods 0.000 title description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 22
- 229930195729 fatty acid Natural products 0.000 claims description 22
- 239000000194 fatty acid Substances 0.000 claims description 22
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 12
- -1 fatty acid sodium salt Chemical class 0.000 claims description 12
- 150000004665 fatty acids Chemical class 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 8
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 8
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 8
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000005642 Oleic acid Substances 0.000 claims description 8
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 8
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 8
- 239000003240 coconut oil Substances 0.000 claims description 7
- 235000019864 coconut oil Nutrition 0.000 claims description 7
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 7
- 230000002708 enhancing effect Effects 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000271 synthetic detergent Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000003568 Sodium, potassium and calcium salts of fatty acids Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000013966 potassium salts of fatty acid Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、水に薄めた場合も充分な洗浄力を有させる液
体石鹸の洗浄力増強方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a method for enhancing the detergency of liquid soap, which provides sufficient detergency even when diluted with water.
（従来の技術）
従来の液体石鹸は、やし油の脂肪酸カリウム塩に合成洗
剤を加えた複合石鹸が主であり、該やし油の脂肪酸カリ
ウム塩の洗浄力は弱くて安全性のみで使用されており洗
浄効果としては合成洗剤の域を出ていないものであった
が、出願人は脂肪酸ナトリウム塩とやし油の脂肪酸カリ
ウム塩とを適切な混合比をもって配合することで液体石
鹸を得ることが出来る点に着目して、オレイン酸の脂肪
酸ナトリウム塩とやし油の脂肪酸カリウム塩との混合液
により石鹸本来の使い方である原液を付けてのもみ洗い
に極めて優れた洗浄効果を奏する液体石鹸を生成してい
る。又、粉末石鹸は、脂肪酸ナトリウム塩に洗濯用補助
剤（ビルグー）として炭酸塩（主に炭酸ソーダ）を多量
に加え洗浄効果を上げているのが実状である。(Prior art) Conventional liquid soaps are mainly complex soaps made by adding synthetic detergent to fatty acid potassium salts in coconut oil.The detergent power of fatty acid potassium salts in palm oil is weak and is used only for safety reasons. However, the applicant obtained a liquid soap by blending sodium salts of fatty acids and potassium salts of fatty acids from coconut oil in an appropriate mixing ratio. Focusing on the ability to do this, we have created a liquid that has an extremely excellent cleaning effect when massaging the undiluted solution, which is the original use of soap, by using a mixture of fatty acid sodium salt of oleic acid and fatty acid potassium salt of coconut oil. producing soap. In addition, powdered soap is actually made by adding a large amount of carbonate (mainly soda carbonate) to fatty acid sodium salt as a washing aid (bilgu) to improve its cleaning effect.
（発明が解決しようとする問題点）
脂肪酸ナトリウム塩と脂肪酸カリウム塩との混合液であ
る液体石鹸は１．水に薄めて使用する場合には、その優
れた洗浄力が軽減されて合成洗剤の洗浄力よりもやや劣
ってしまう問題点が生じていた。又、補助剤の炭酸塩は
、水湿性が良く水に溶けやすい性質があるものの、一旦
石鹸に混入した場合、石鹸と水分とを吸収して固まり、
これを粉末石値とした場合に水溶性が悪くなる。又、液
体石鹸に炭酸塩を混入、する場合には液体の粘度が高く
なり、低温時にはゼリー状となって容器からの取出が困
難となる。そこで、液体石鹸と粉末状の炭酸塩とをそれ
ぞれ小袋に詰めて使用直前に混合させ洗浄力を高める方
法が生み出されたが、使用上面倒であった。(Problems to be Solved by the Invention) A liquid soap that is a mixture of fatty acid sodium salt and fatty acid potassium salt has the following problems:1. When used diluted with water, the problem arises that its excellent cleaning power is reduced and the cleaning power is slightly inferior to that of synthetic detergents. In addition, carbonates as adjuvants have good water-wet properties and are easily soluble in water, but once mixed into soap, they absorb soap and water and solidify.
When this is taken as a powder stone value, the water solubility becomes poor. Furthermore, when carbonate is mixed into liquid soap, the viscosity of the liquid increases, and at low temperatures it becomes jelly-like, making it difficult to remove it from the container. Therefore, a method was developed in which liquid soap and powdered carbonate were packed in sachets and mixed immediately before use to increase cleaning power, but this method was cumbersome to use.
本発明は、上記の点に鑑みなされたものであって、液体
石鹸の原液での使用に際しての高い洗浄力に加えて、水
に薄める場合も合成洗剤よりも高い洗浄力を有し陸つ水
溶性である液体石鹸を得るための液体石鹸の洗浄力増強
方法を提供することを目的とする。The present invention was made in view of the above points, and in addition to the high detergency when used as a liquid soap in its pure form, it also has a higher detergency than synthetic detergents when diluted with water, and is a water-soluble detergent. An object of the present invention is to provide a method for enhancing the detergency of liquid soap to obtain a liquid soap that has a high level of cleansing properties.
（問題点を解決するための手段）
上記目的を達成するための本発明の要旨とするところは
、オレイン酸の脂肪酸ナトリウム塩とやし浦の脂肪酸を
鹸化した脂肪酸カリウム塩とを適宜比率で混合してなる
液体石鹸に対して、熔かした極めて少量の炭酸塩を攪拌
しながら徐々に加えた後にｐＨを低く抑えて弱アルカリ
性にする仕上げをしたことを特徴とする液体石鹸の洗浄
力増強方法にある。(Means for Solving the Problems) The gist of the present invention to achieve the above object is to mix a fatty acid sodium salt of oleic acid and a fatty acid potassium salt obtained by saponifying Yashiura fatty acid in an appropriate ratio. A method for enhancing the detergency of liquid soap, which comprises gradually adding a very small amount of melted carbonate to the liquid soap with stirring, and then finishing the soap to make it slightly alkaline by keeping the pH low. It is in.
（作 用）
従って本発明の洗浄力増強方法によれば、オレイン酸の
脂肪酸ナトリウム塩とやし油の脂肪酸カリウム塩の混合
による液体石鹸であるから、極めて洗浄力が高い液体石
鹸であり、１％程度の炭酸塩であれば攪拌しつつ混入す
ることで容易に液体状態を維持出来、弱アルカリ性に仕
上げることで手荒れ、器物の腐食、損傷等の弊害を無く
して安心して使用出来る。(Function) Therefore, according to the method for enhancing detergency of the present invention, since the liquid soap is a mixture of fatty acid sodium salt of oleic acid and fatty acid potassium salt of coconut oil, it is a liquid soap with extremely high detergency; % of carbonate can be easily maintained in a liquid state by mixing while stirring, and by making it slightly alkaline, it can be used safely without causing problems such as rough hands, corrosion, or damage to equipment.
（実施例）
以下、本発明の実施例を具体的にその製造工程において
説明する。(Example) Hereinafter, an example of the present invention will be specifically described in terms of its manufacturing process.
液体石鹸は、高級オレイン酸に低濃度の水酸化ナトリう
ムを加え鹸化した脂肪酸ナトリウム塩に、やし油の脂肪
酸を鹸化したカリウム塩を加えて攪拌するものであり（
ｐＨ１０，３程度に仕上げる）、粘度が低く、流動性が
大で、透明な淡黄色であって、−５℃でもシャーベット
状で凍り、他のナトリウム塩の水溶液と異なり、厳寒に
おいても充分使用可能なものである。オレイン酸は、分
解脂肪酸であるが、塩析不要でそのままで鹸化可能であ
って、作業能率が良く臭いやぬるつきが少なく、更には
融点が低いので液体化しやすい、尚、脂肪酸ナトリウム
塩と脂肪酸カリウム塩との比率は純石鹸成分中、洗浄力
を高めるナトリウム塩を８０％程度までとすることが出
来るが、それ以下としても構わない、又、溶液中、純石
鹸分が２０％以上の場合は、３％未満のエチルアルコー
ルを加えてナトリウム塩とカリウム塩とを均一に混和さ
せるものとする。Liquid soap is made by adding potassium salt, which is made by saponifying the fatty acids in coconut oil, to fatty acid sodium salt, which is made by saponifying high oleic acid with a low concentration of sodium hydroxide, and stirring the mixture (
It has a low viscosity, high fluidity, and is transparent and light yellow in color. It freezes like a sherbet even at -5℃, and unlike other aqueous solutions of sodium salts, it can be used even in severe cold. It is something. Oleic acid is a decomposed fatty acid, but it can be saponified as it is without the need for salting out, has good working efficiency, has little odor or sliminess, and has a low melting point, so it is easy to liquefy. The ratio of sodium salt to enhance detergency in pure soap ingredients can be up to about 80%, but it may be less than that, and if the pure soap content in the solution is 20% or more. shall add less than 3% ethyl alcohol to uniformly mix the sodium and potassium salts.
以上のような成分の液体石鹸にぬるま湯で溶かした１％
の炭酸塩（炭酸ソーダ等）を攪拌しながら徐々に加えて
いくが、該溶液はアルカリ性が強くなって９８１１前後
に上昇するから、クエン酸で所定ｐＨの弱アルカリ性に
仕上げる作業を行う、（尚、液体石鹸中に、オレイン酸
以外の油脂の脂肪酸ナトリウム塩が含有しているもの、
例えば、オレイン酸の脂肪酸ナトリウム塩６５％程、や
し油の脂肪酸カリウム塩２５％程、塩析を施した融点の
低い油脂（菜種油等）の脂肪酸ナトリウム塩１０％程度
の比率とした液体石鹸は、炭酸塩の混入によって、粘性
が大となり、ネパリが発生しやすいので注意する。）従
って、本実施例による洗浄力増強方法であれば用途も広
くなり、台所川石Ｍ（業務用）としても活用出来る。又
、他の用途に利用する際に、液体石鹸に炭酸塩を増１ｉ
（例えば３％程度）することも可能であるが、この場合
、無理に弱アルカリとして組織を分解させずして、液性
をアルカリ性のまま仕上げるものとする。1% liquid soap with the above ingredients dissolved in lukewarm water
Carbonates (soda carbonate, etc.) are gradually added while stirring, but the alkalinity of the solution increases to around 9811, so the pH is adjusted to a slightly alkaline level with citric acid. , liquid soap containing fatty acid sodium salts of fats and oils other than oleic acid,
For example, a liquid soap with a ratio of about 65% fatty acid sodium salt of oleic acid, about 25% fatty acid potassium salt of coconut oil, and about 10% fatty acid sodium salt of low melting point oil (rapeseed oil, etc.) that has been salted out. Be careful, as the incorporation of carbonate increases the viscosity and tends to cause nepal. ) Therefore, the cleaning power enhancement method according to this embodiment has a wide range of uses, and can also be used as a kitchen Kawaishi M (for commercial use). Also, when using liquid soap for other purposes, add 1 i of carbonate to liquid soap.
(for example, about 3%), but in this case, the liquid should be finished as alkaline without forcibly making it a weak alkali and decomposing the tissue.
（発明の効果）
以上説明してきた如く本発明によれば、１％程度の炭酸
塩を加えることで、石鹸の発泡力を増加させ、而も水に
薄めても高い洗浄力を発揮し、頑固な油汚れ、アカ汚れ
も奇麗に洗い落とすものであり、手や器物（洗濯物）に
対する弊害も皆無とするといった効果を奏する。更に、
炭酸塩を加えても液体石鹸は液状のままであるから、洗
濯量に応じて石鹸の増量が適宜行え、香料の点でも扮石
鹸等と異なり効果は著しい。(Effects of the Invention) As explained above, according to the present invention, by adding about 1% of carbonate, the foaming power of soap is increased, and even when diluted with water, it exhibits high detergency, and It also cleans away oil stains and dirt, and has the effect of eliminating any harmful effects on hands and utensils (laundry). Furthermore,
Even when carbonate is added, liquid soap remains liquid, so the amount of soap can be increased as needed depending on the amount of laundry, and unlike soaps made of soap, it has a remarkable effect in terms of fragrance.
特許、出願人 水本克治Patent, applicant: Katsuji Mizumoto
Claims (1)
化した脂肪酸カリウム塩とを適宜比率で混合してなる液
体石鹸に対して、溶かした極めて少量の炭酸塩を攪拌し
ながら徐々に加えた後にｐＨを低く抑えて弱アルカリ性
にする仕上げをしたことを特徴とする液体石鹸の洗浄力
増強方法。A very small amount of dissolved carbonate is gradually added with stirring to a liquid soap made by mixing a fatty acid sodium salt of oleic acid and a fatty acid potassium salt obtained by saponifying the fatty acid of coconut oil in an appropriate ratio. A method for enhancing the detergency of liquid soap, characterized by having a finish that suppresses the amount of water and makes it slightly alkaline.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2940087A JPS63196696A (en) | 1987-02-10 | 1987-02-10 | Method for increasing washing power of liquid soap |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2940087A JPS63196696A (en) | 1987-02-10 | 1987-02-10 | Method for increasing washing power of liquid soap |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63196696A true JPS63196696A (en) | 1988-08-15 |
Family
ID=12275090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2940087A Pending JPS63196696A (en) | 1987-02-10 | 1987-02-10 | Method for increasing washing power of liquid soap |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63196696A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5052327A (en) * | 1990-07-19 | 1991-10-01 | Forrest Comfort | Inboard/outboard and outboard guiding safety device and method |
| JPH0790299A (en) * | 1993-09-24 | 1995-04-04 | Fudo Kagaku:Kk | Paste-like potassium soap for washing |
-
1987
- 1987-02-10 JP JP2940087A patent/JPS63196696A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5052327A (en) * | 1990-07-19 | 1991-10-01 | Forrest Comfort | Inboard/outboard and outboard guiding safety device and method |
| JPH0790299A (en) * | 1993-09-24 | 1995-04-04 | Fudo Kagaku:Kk | Paste-like potassium soap for washing |
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