JPS63197689A - Transfer foil having vapor-deposited metallic layer with difference in luster - Google Patents
Transfer foil having vapor-deposited metallic layer with difference in lusterInfo
- Publication number
- JPS63197689A JPS63197689A JP62030590A JP3059087A JPS63197689A JP S63197689 A JPS63197689 A JP S63197689A JP 62030590 A JP62030590 A JP 62030590A JP 3059087 A JP3059087 A JP 3059087A JP S63197689 A JPS63197689 A JP S63197689A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- anchor coat
- varnish
- vapor
- transfer foil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/38207—Contact thermal transfer or sublimation processes characterised by aspects not provided for in groups B41M5/385 - B41M5/395
- B41M5/38214—Structural details, e.g. multilayer systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/426—Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、部分的に光沢差を有する金属蒸着層を設けた
金属蒸着転写箔に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a metallized transfer foil partially provided with a metallized layer having a difference in gloss.
金属蒸着により、光沢差を設ける手段としては、基材シ
ートに部分的に微小凹凸部と平滑部とを設け、該基材シ
ート上にアンカーコート層、アルミ等の金属蒸着層を設
けた金属蒸着シート、また金属蒸着層の表面を部分的に
薬剤処理を施し、部分的に曇らせ光沢差を設ける技術は
存在していた。As a means of creating a difference in gloss by metal vapor deposition, metal vapor deposition is performed in which a base sheet is partially provided with minute irregularities and smooth parts, and an anchor coat layer and a metal vapor deposited layer such as aluminum are provided on the base sheet. There existed a technique in which the surface of the sheet or the metal vapor deposited layer was partially treated with chemicals to partially cloud the surface and create a difference in gloss.
上記技術は、あくまでも金属蒸着シートに関するもので
、金属蒸着層を被転写体に転写した場合、表面のみに光
沢差を設ける後者の技術においては、反転した基材シー
ト側が露出した状態となり光沢差は生じなくなってしま
う。The above technology is strictly related to metallized sheets; when a metallized layer is transferred to an object, in the latter technique, a difference in gloss is created only on the surface, the reversed base sheet side is exposed, and the difference in gloss is It will no longer occur.
また、部分的に微小凹凸部を設けた基材シートを用いる
場合、部分的な面積が細かい場合は非常に難しいものと
なり、そのまま用いることができないものであった。In addition, when using a base sheet partially provided with micro-irregularities, it becomes very difficult to do so if the partial area is small, and it cannot be used as is.
本発明は、１回の蒸着により部分的に光沢差の異なる金
属蒸着転写箔を提供せんとするものである。The present invention aims to provide a metal vapor-deposited transfer foil having partially different gloss differences through one vapor deposition.
基材の片面に剥離ニス層、アンカーカート層、金属蒸着
層、感熱接着剤層を順に設けた金属蒸着転写箔において
、剥離ニス、アンカーコート層の少なくとも一方の層を
、異なる２種以上の材料を部分的に設けることにより解
決した。ここで、剥離ニス層とアンカーコート層の間に
印刷層を設けた構成としてもよい。In a metallized transfer foil in which a release varnish layer, an anchor cart layer, a metallized layer, and a heat-sensitive adhesive layer are sequentially provided on one side of a base material, at least one of the release varnish and the anchor coat layer is made of two or more different materials. The problem was solved by partially providing . Here, a printing layer may be provided between the release varnish layer and the anchor coat layer.
本発明で用いる基材としては、ナイロンフィルム、ボ１
エステルフィルムが適当で、また、剥離ニス層に用いる
剥離ニスとしては、熱可塑性樹脂をビヒクルとした透明
なもので、例えば熱可塑性アクリル系樹脂、セルロース
系樹脂、ゴム系樹脂を主成分とするものである。さらに
、アンカーコート層に用いるアンカー剤は、例えばウレ
タン系樹脂、アクリル−ウレタン系樹脂、ウレタン系樹
脂、ニトロセルロース、ポリエステル等を主成分に含む
ものである。アンカーコート層上に設ける金属蒸着層と
しては、一般的なアルミ蒸着層で、その厚さは、４００
〜６００人であり、さらに、感熱接着剤層としては、例
えば被転写体がポリエチレン製品である場合は、環化ゴ
ム系樹脂、アクリル樹脂製品である場合は、アクリル系
樹脂、紙製品の場合は、塩ビー酢ビ共重合体系樹脂等、
それぞれ接着力の適した樹脂を主成分とした接着層を設
ければよい。As the base material used in the present invention, nylon film,
Ester film is suitable, and the release varnish used for the release varnish layer is a transparent one with a thermoplastic resin vehicle, for example, one whose main component is a thermoplastic acrylic resin, cellulose resin, or rubber resin. It is. Furthermore, the anchor agent used in the anchor coat layer contains, for example, urethane resin, acrylic-urethane resin, urethane resin, nitrocellulose, polyester, etc. as a main component. The metal vapor deposition layer provided on the anchor coat layer is a general aluminum vapor deposition layer, and its thickness is 400 mm.
~600 people, and as a heat-sensitive adhesive layer, for example, if the object to be transferred is a polyethylene product, cyclized rubber resin, if it is an acrylic resin product, acrylic resin, if it is a paper product, , vinyl chloride vinyl acetate copolymer resin, etc.
An adhesive layer mainly composed of a resin with suitable adhesive strength may be provided.
次に図面に基づき本発明の詳細な説明する。Next, the present invention will be explained in detail based on the drawings.
第１図は、本発明の一実施例を示す断面図で、基材１０
の片面に１種の剥離ニスから剥離ニス層１２、印刷層１
３、異なる２種のアンカー剤からなるアンカーコート層
１４、アルミニウム蒸着層１６および感熱接着層１日を
設けた光沢差を有する金属蒸着転写箔である。FIG. 1 is a sectional view showing one embodiment of the present invention, in which a base material 10
A release varnish layer 12 and a printing layer 1 from one type of release varnish on one side of the
3. It is a metal vapor-deposited transfer foil having a difference in gloss, which is provided with an anchor coat layer 14 made of two different types of anchor agents, an aluminum vapor-deposited layer 16, and a heat-sensitive adhesive layer.
また、第２図に示すように剥離ニス層１２を異なる２種
の剥離ニスから構成し、アンカーコート層１４を１種の
アンカー剤としたもの、および第３図に示すように剥離
ニス層１２、アンカーコート層１４をそれぞれ２種の剥
離ニス、アンカー剤を用いた光沢差を有する金属蒸着転
写箔である。Further, as shown in FIG. 2, the release varnish layer 12 is composed of two different types of release varnish and the anchor coat layer 14 is one type of anchor agent, and as shown in FIG. , the anchor coat layer 14 is a metal vapor-deposited transfer foil having different gloss levels using two types of release varnish and anchor agent, respectively.
剥離ニス層、アンカーコート層を２種以上の材料を設け
る手段として、それぞれ部分的に設ける必要はなく、一
つを全面に設け、その上の他の材料を部分的に設けた構
成としてもよい。As a means of providing two or more materials for the release varnish layer and the anchor coat layer, it is not necessary to provide each layer partially, but it is also possible to provide one layer over the entire surface and partially provide the other material on top of it. .
剥離ニス層およびアンカーコート層の少なくとも一層が
異なる２種以上の材料からなるので、剥離ニス層とアン
カーコート層とにより、アンカーコート層の状態が異な
るので一回の蒸着でも、アンカーコート層、剥離ニス層
の少なくとも一方の部分的に設けた模様に合った光沢差
が生じる。Since at least one of the release varnish layer and the anchor coat layer is made of two or more different materials, the state of the anchor coat layer is different depending on the release varnish layer and the anchor coat layer. A difference in gloss is generated that matches the pattern provided partially on at least one of the varnish layers.
ポリエステルフィルムからなる基材の片面に剥離ニス（
アクリル系樹脂が主成分）からなる剥離ニス層を設け、
さらに該剥離ニス層の下面に、２種のアンカー剤、アク
リル系アンカー剤（リオペット）、アクリル−ウレタン
系アンカー剤（ＫＯ７９）、いずれも東洋インキ製造■
からなるアンカーコート層を設けた後、アルミ蒸着層（
５００人）を設け、さらに、アクリル系樹脂をバインダ
ーとした接着剤からなる感熱接着層を設は転写箔を製造
した。Release varnish (
A release varnish layer consisting of acrylic resin as the main component is provided,
Furthermore, two types of anchor agents, an acrylic anchor agent (Liopet) and an acrylic-urethane anchor agent (KO79), both manufactured by Toyo Ink, are applied to the lower surface of the release varnish layer.
After providing an anchor coat layer consisting of
A heat-sensitive adhesive layer made of an adhesive using an acrylic resin as a binder was further provided to produce a transfer foil.
上記アルミ蒸着層の輝度感は、アンカーコート層として
、アクリル系アンカー剤を用いたものよりアクリル・ウ
レタン系アンカー剤を用いた方が低下した。The brightness of the aluminum vapor deposited layer was lower when an acrylic/urethane anchor agent was used as the anchor coat layer than when an acrylic anchor agent was used.
また、剥離ニスとして２種のアクリル系ニス（ＴＲ−０
７、ＴＲ−１７いずれも東洋インキ製造■製）を用いて
部分的に異なる剥離ニス層を形成した。In addition, two types of acrylic varnish (TR-0
7 and TR-17 (both manufactured by Toyo Ink Manufacturing Co., Ltd.)) were used to form partially different release varnish layers.
この２種の剥離ニスを用いた剥離ニス層上に、アクリル
系アンカー剤（リオペット）のアンカーコート層を設け
、上記と同様にアルミ蒸着層、感熱接着剤層を設け、そ
の輝度惑を比較した。剥離ニスとしてＴＲ−１７を用い
た方が、ＴＲ−０７を用いたものより譚度感が良好であ
った。An anchor coat layer of an acrylic anchor agent (Liopet) was provided on the release varnish layer using these two types of release varnish, and an aluminum vapor deposition layer and a heat-sensitive adhesive layer were provided in the same manner as above, and the brightness was compared. . When TR-17 was used as a release varnish, the texture was better than when TR-07 was used.
前記２種の転写箔を被転写体に転写した後も、前記と同
様の光沢差を有するものであった。Even after the two types of transfer foils were transferred to the object to be transferred, the same difference in gloss as described above was observed.
本発明は、以上の構成のように、金属蒸着を行なうに際
し、剥離ニス層および／またはアンカーコート層を２種
以上用いることで、部分的に輝度惑の異なる金属蒸着層
が得られた。In the present invention, as described above, by using two or more kinds of release varnish layers and/or anchor coat layers when performing metal vapor deposition, metal vapor deposited layers having partially different brightness patterns can be obtained.
このように、蒸着後に化学的、あるいは物理的処理を施
さなくとも輝度感の異なる光沢差のある転写箔が得られ
た。In this way, transfer foils with different brightness and gloss differences were obtained without any chemical or physical treatment after vapor deposition.
図面は、本発明の実施例を示すもので、第１図、第２図
、第３図は、本発明の転写箔の断面図である。
１０・・・基材
１２・・・剥離ニス層１
．１４・・・アンカーコート層
１６・・・蒸着層The drawings show examples of the present invention, and FIGS. 1, 2, and 3 are cross-sectional views of the transfer foil of the present invention. 10... Base material 12... Peeling varnish layer 1. 14... Anchor coat layer 16... Vapor deposition layer
Claims (1)
属蒸着層、感熱接着層を順に設けた金属蒸着転写箔にお
いて、剥離ニス層、アンカーコート層の少なくとも一方
の層を、異なる２種以上の材料を部分的に設けた構成と
した光沢差を有する金属蒸着転写箔。(1) In a metallized transfer foil in which a release varnish layer, an anchor coat layer, a metal vapor deposited layer, and a heat-sensitive adhesive layer are sequentially provided on one side of a base material, at least one of the release varnish layer and the anchor coat layer is formed of two different types. A metal vapor-deposited transfer foil having a difference in gloss and having a structure in which the above materials are partially provided.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62030590A JPS63197689A (en) | 1987-02-12 | 1987-02-12 | Transfer foil having vapor-deposited metallic layer with difference in luster |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62030590A JPS63197689A (en) | 1987-02-12 | 1987-02-12 | Transfer foil having vapor-deposited metallic layer with difference in luster |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63197689A true JPS63197689A (en) | 1988-08-16 |
Family
ID=12308080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62030590A Pending JPS63197689A (en) | 1987-02-12 | 1987-02-12 | Transfer foil having vapor-deposited metallic layer with difference in luster |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63197689A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0812701A1 (en) * | 1996-06-10 | 1997-12-17 | Dai Nippon Printing Co., Ltd. | Thermal transfer sheet for printing images with metallic luster |
-
1987
- 1987-02-12 JP JP62030590A patent/JPS63197689A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0812701A1 (en) * | 1996-06-10 | 1997-12-17 | Dai Nippon Printing Co., Ltd. | Thermal transfer sheet for printing images with metallic luster |
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