JPS6323715A - Deodorizing material - Google Patents
Deodorizing materialInfo
- Publication number
- JPS6323715A JPS6323715A JP61167676A JP16767686A JPS6323715A JP S6323715 A JPS6323715 A JP S6323715A JP 61167676 A JP61167676 A JP 61167676A JP 16767686 A JP16767686 A JP 16767686A JP S6323715 A JPS6323715 A JP S6323715A
- Authority
- JP
- Japan
- Prior art keywords
- water
- ethanol
- complex
- solution
- carboxyphthalocyanine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 21
- 239000000463 material Substances 0.000 title claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 22
- 239000011324 bead Substances 0.000 claims abstract description 21
- 150000004696 coordination complex Chemical class 0.000 claims abstract description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920001577 copolymer Polymers 0.000 claims abstract description 7
- 235000011187 glycerol Nutrition 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 24
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract description 21
- 239000000243 solution Substances 0.000 abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 15
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 abstract description 4
- 150000004698 iron complex Chemical class 0.000 abstract description 3
- 239000007864 aqueous solution Substances 0.000 abstract description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000004332 deodorization Methods 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 235000019645 odor Nutrition 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical group C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 1
- 102000006410 Apoproteins Human genes 0.000 description 1
- 108010083590 Apoproteins Proteins 0.000 description 1
- UJKPHYRXOLRVJJ-MLSVHJFASA-N CC(O)C1=C(C)/C2=C/C3=N/C(=C\C4=C(CCC(O)=O)C(C)=C(N4)/C=C4\N=C(\C=C\1/N\2)C(C)=C4C(C)O)/C(CCC(O)=O)=C3C Chemical compound CC(O)C1=C(C)/C2=C/C3=N/C(=C\C4=C(CCC(O)=O)C(C)=C(N4)/C=C4\N=C(\C=C\1/N\2)C(C)=C4C(C)O)/C(CCC(O)=O)=C3C UJKPHYRXOLRVJJ-MLSVHJFASA-N 0.000 description 1
- 102000016938 Catalase Human genes 0.000 description 1
- 108010053835 Catalase Proteins 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GELXFVQAWNTGPQ-UHFFFAOYSA-N [N].C1=CNC=N1 Chemical compound [N].C1=CNC=N1 GELXFVQAWNTGPQ-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000447 dimerizing effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229960003569 hematoporphyrin Drugs 0.000 description 1
- BTIJJDXEELBZFS-QDUVMHSLSA-K hemin Chemical compound CC1=C(CCC(O)=O)C(C=C2C(CCC(O)=O)=C(C)\C(N2[Fe](Cl)N23)=C\4)=N\C1=C/C2=C(C)C(C=C)=C3\C=C/1C(C)=C(C=C)C/4=N\1 BTIJJDXEELBZFS-QDUVMHSLSA-K 0.000 description 1
- 229940025294 hemin Drugs 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、消臭材料に関する。更に詳しくは、カルボキ
シフタロシアニン金属錯体を消臭成分とする消臭材料に
関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a deodorizing material. More specifically, the present invention relates to a deodorizing material containing a carboxyphthalocyanine metal complex as a deodorizing component.
悪臭を含め各種の臭いを消す方法としては、感覚的消臭
、化学的脱臭、物理・化学的脱臭、物理的吸着脱臭、生
物的脱臭などの方法がとられている９現在、悪臭の消臭
材として最も一般的に用いられているものは活性炭であ
るが、活性炭の作用は物理的吸着脱臭であり、従って吸
着が飽和点に達すると効果が少なくなるばかりではなく
、アンモニアに対する吸着能力が殆んどないなどの欠点
を有している。Methods for eliminating various odors, including malodors, include sensory deodorization, chemical deodorization, physical/chemical deodorization, physical adsorption deodorization, and biological deodorization9. The most commonly used material is activated carbon, but the action of activated carbon is physical adsorption deodorization, so when the adsorption reaches the saturation point, it not only becomes less effective, but also loses its ability to adsorb ammonia. It has disadvantages such as being difficult to use.
［発明が解決しようとする問題点〕
主な悪臭物質の多くは移動性水素を有し、これを脱水素
酸化し、二量化、水溶性化、不揮発化させることにより
消臭が可能と考えられ、生体内酵素が悪臭物質に作用す
る例をいくつかみることができる。これらの反応を行な
う酵素は、ヘマトポリフィリンを含み、アポたん白質と
結合して鉄は３価スピンの電子状態となり、たん白質の
ヒスチジンイミダゾール窒素が第５配位座に配位し寸い
る。[Problems to be solved by the invention] Many of the main malodorous substances have mobile hydrogen, and it is thought that deodorization can be achieved by dehydrogenating, oxidizing, dimerizing, making water-soluble, and non-volatile. , we can see several examples of in-vivo enzymes acting on malodorous substances. The enzymes that carry out these reactions include hematoporphyrin, which binds to apoproteins, causing iron to become in a trivalent spin electronic state, and the histidine imidazole nitrogen of the protein is about to coordinate to the fifth coordination site.
これと類似の触媒活性のあるカルボキシフタロシアニン
金属錯体、例えばオクタカルボキシフタロシアニン鉄錯
体は、カタラーゼと類似の反応機構で分解し、比活性か
ヘミンの約６倍という比較的高い活性を示しいる。Carboxyphthalocyanine metal complexes with similar catalytic activity, such as octacarboxyphthalocyanine iron complexes, are decomposed by a reaction mechanism similar to that of catalase, and exhibit a relatively high specific activity of about 6 times that of hemin.
ところで、かかるカルボキシフタロシアニン金属錯体の
消臭効果は、アンモニアだけにとどまらず、硫化水素な
どの悪臭の除去にも有効であることが本発明者らによっ
て見出されたが、その消臭材料としての取扱いを容易に
するために、それを粒状物に吸着させることが検討され
、粒状物としてスチレン−ジビニルベンゼン共重合体の
マイクロポーラスビーズがここに選択された。By the way, the present inventors have discovered that the deodorizing effect of such a carboxyphthalocyanine metal complex is effective not only in removing ammonia but also in removing bad odors such as hydrogen sulfide. In order to facilitate handling, it was considered to adsorb it onto granules, and microporous beads of styrene-divinylbenzene copolymer were selected here as the granules.
更に、カルボキシフタロシアニン金属錯体の消臭効果は
、水の存在下において十分に発揮されるので、このマイ
クロポーラスビーズの場合にもそこに水分を保持させた
状態で使用されることが好ましく、その場合水分の蒸発
を抑制するために、吸水性物質をそこに共存させて用い
られる。Furthermore, since the deodorizing effect of the carboxyphthalocyanine metal complex is fully exhibited in the presence of water, it is preferable that the microporous beads be used with water retained therein. In order to suppress the evaporation of water, a water-absorbing substance is used in combination.
〔問題点を解決するための手段〕
従って、本発明は消臭材料に係り、この消臭材料は、カ
ルボキシフタロシアニン金属錯体またはこれと吸水性物
質とをスチレン−ジビニルベンゼン、共重合体マイクロ
ポーラスビーズに保持せしめてなる。[Means for Solving the Problems] Therefore, the present invention relates to a deodorizing material, which comprises a carboxyphthalocyanine metal complex or a water-absorbing substance, styrene-divinylbenzene, copolymer microporous beads, etc. It will be held in place.
カルボキシフタロシアニン金属錯体としては、次式で表
される４、４’、４’、４’−テトラカルボキンフタロ
シアニン−金属錯体
あるいは４，５．４’、５’、４’、５”、４”、５１
′−オクタカルボキシフタロシアニン−金属錯体などの
３価鉄、コバルト、ニッケル、銅などの錯体が一般に用
いられる。As the carboxyphthalocyanine metal complex, 4,4',4',4'-tetracarboxyphthalocyanine-metal complex or 4,5.4',5',4',5",4" represented by the following formula , 51
Complexes of trivalent iron, cobalt, nickel, copper, etc., such as '-octacarboxyphthalocyanine-metal complexes, are commonly used.
カルボキシフタロシアニン金属錯体はまた、カルボキシ
ル基との反応性を有する水酸基、アミノ基、エポキシ基
、ピリジニウム基などを有する化合物またはオリゴマー
などとの複合させた形で用いることができる。この場合
には、カルボキシフタロシアニン金属錯体の分子分散性
が良くなったり、マイクロポーラスビーズへの保持も一
層容易に行なわれるようになる。The carboxyphthalocyanine metal complex can also be used in the form of a complex with a compound or oligomer having a hydroxyl group, an amino group, an epoxy group, a pyridinium group, etc. that are reactive with a carboxyl group. In this case, the molecular dispersibility of the carboxyphthalocyanine metal complex is improved and retention in the microporous beads becomes easier.
これらのカルボキシフタロシアニン金属錯体は、好まし
くは吸水性物質と共に用いられる。この吸水性物質とし
ては、グリセリン、エチレングリコール、ポリエチレン
グリコール、ポリビニルアルコール、ポリアクリル酸、
ポリビニルピロリドン、でん粉などが用いられる。These carboxyphthalocyanine metal complexes are preferably used together with a water-absorbing substance. Examples of this water-absorbing substance include glycerin, ethylene glycol, polyethylene glycol, polyvinyl alcohol, polyacrylic acid,
Polyvinylpyrrolidone, starch, etc. are used.
これらの各物質を保持させるスチレン−ビニルベンゼン
共重合体マイクロポーラスビーズは、ジビニルベンゼン
部分がスチレン基体の架橋点として作用する樹脂であっ
て、１６〜１８００人の口径およびＯ，１ｍ Ｑ ／ｇ
以上の細孔容積を有しており、三菱化成工業製品ダイヤ
イオンＨＰシリーズとして市販されている。The styrene-vinylbenzene copolymer microporous beads that hold each of these substances are resins in which the divinylbenzene moiety acts as a crosslinking point for the styrene base, and have a diameter of 16 to 1800 and O, 1m Q /g.
It has the above pore volume and is commercially available as the Diaion HP series manufactured by Mitsubishi Chemical Industries.
マイクロポーラスビーズへの金属錯体の保持は、例えば
力ロボキシフタロシアニン鉄の場合、それの溶液に調製
し、それを用いての浸漬、噴霧などの手段がとられる。In order to retain the metal complex on the microporous beads, for example, in the case of iron loboxyphthalocyanine, a solution thereof is prepared and the beads are immersed or sprayed using the solution.
この溶液は１例えば当量の水酸化カリウムと共に溶解さ
せた溶液として調製され、用いられる。This solution is prepared and used as a solution in which one is dissolved with, for example, an equivalent amount of potassium hydroxide.
浸漬などの実際の処理に際しては、上記金属錯体溶液に
含浸をより円滑に行わせるためのエタノールなどを添加
したものが用いられ、吸水性物質が用いられる場合には
それがエタノールなどと同時に添加される。浸漬後には
約４０〜１５０℃に加熱してエタノールを蒸発せしめ、
その際に一緒に蒸発した分の水を加えて、金属錯体以外
に少量の水酸化カリウム、あるいは更にビーズ量に対し
て約１〜１００重量２の吸水性物質を含有する組成の溶
液をマイクロポーラスビーズ１００ｇ当り約２０ｇ程度
迄含浸させる。During actual treatments such as immersion, the metal complex solution is mixed with ethanol or the like to facilitate smoother impregnation, and if a water-absorbing substance is used, it is added at the same time as ethanol. Ru. After soaking, heat to about 40-150°C to evaporate the ethanol,
At that time, add the water that evaporated together to create a microporous solution containing a small amount of potassium hydroxide in addition to the metal complex, or a water-absorbing substance in an amount of about 1 to 100% by weight2 based on the amount of beads. Impregnate up to about 20g per 100g of beads.
〔作用〕および〔発明の効果〕
本発明に係る消臭材料は、粒状のため任意の容器に収容
して使用することができるので、取扱性の上での利便が
認められる。[Function] and [Effects of the Invention] Since the deodorizing material according to the present invention is in granular form, it can be stored in any container and used, and therefore is convenient in terms of handling.
また、カルボキシフタロシアニン金ａ錯体は、アンモニ
アや硫化水素など移動性水素を有する物質の悪臭分解に
有効に作用するが、その消臭効果はそれが作用する際の
水分量の影響を大きく受ける。Further, the carboxyphthalocyanine gold a complex effectively acts on decomposing bad odors of substances having mobile hydrogen such as ammonia and hydrogen sulfide, but its deodorizing effect is greatly influenced by the amount of water at which it acts.
本発明においては、このように水分量の大きな影響を受
けるカルボキシフタロシアニン金属錯体を水分保持量の
大きいスチレン−ジビニルベンゼン共重合体マイクロポ
ーラスビーズに保持させることにより、それが本来有す
る消臭能力を十分に発揮せしめる消臭材料が提供され、
この消臭材料はアンモニアや硫化水素などの悪臭物質を
有効に消臭せしめるが、その効果は吸水性物質を併用し
たときに一段と顕著である。In the present invention, by retaining the carboxyphthalocyanine metal complex, which is greatly affected by water content, in styrene-divinylbenzene copolymer microporous beads, which have a large water retention capacity, the inherent deodorizing ability of the carboxyphthalocyanine metal complex can be fully utilized. Provides deodorizing materials that exhibit
This deodorizing material effectively deodorizes malodorous substances such as ammonia and hydrogen sulfide, but its effect is even more pronounced when a water-absorbing substance is used in combination.
次に、実施例について本発明を説明する。 Next, the present invention will be explained with reference to examples.
実施例１
オクタカルボキシフタロシアニン鉄錯体５ｇを、これと
当量の水酸化カリウムを溶解させた水溶液中に加え、全
体が１００ｍ １２となる溶液を調製した。Example 1 5 g of octacarboxyphthalocyanine iron complex was added to an aqueous solution in which an equivalent amount of potassium hydroxide was dissolved to prepare a solution having a total volume of 100 m 12 .
スチレン−ジビニルベンゼンマイクロポーラスビーズ（
三菱化成工業製品ダイヤイオンＨＰ−２０）１００ｇを
、上記錯体溶液にエタノール１５ｇを加えた溶液中に浸
漬してから引き上げ、これを１００℃に３時間加熱して
エタノールを蒸発させた。重量差から測定して、エタノ
ールと共に蒸発したと考えられる水を補給して、２０ｇ
の溶液（組成：錯体４．４コ重量％、水酸化カリウム２
．１重量２、水９３．５重量ぶ）をマイクロポーラスビ
ーズに含浸させた。Styrene-divinylbenzene microporous beads (
100 g of Diaion HP-20), a product of Mitsubishi Chemical Industries, was immersed in a solution prepared by adding 15 g of ethanol to the above complex solution, then pulled out, and heated to 100° C. for 3 hours to evaporate the ethanol. Measured from the difference in weight and replenishing the water that is thought to have evaporated together with the ethanol, 20g
solution (composition: 4.4% by weight of complex, 2% potassium hydroxide)
．． 1 weight of water and 93.5 weight of water) were impregnated into the microporous beads.
このようにして鉄錯体を浸漬保持させたマイクロポーラ
スビーズ１ｇを湿度６５％に調整した空気を充満させた
容量５Ωのテフロン製テトラバッグ中に入れ、第１図の
如くにセットして消臭効果の測定を行なった。1 g of microporous beads with the iron complex immersed in this way are placed in a Teflon tetra bag with a capacity of 5Ω filled with air adjusted to a humidity of 65%, and set as shown in Figure 1 to obtain the deodorizing effect. Measurements were made.
即ち、テトラバッグ１中には、所定濃度の悪臭物質を含
有する空気（湿度６５％）が充満されており、このバッ
グ内空気をエアーポンプ２により毎分５Ｑの流量でテフ
ロン製チューブ３，３′を経由して循環させ、悪臭物質
の経時的濃度変化（残留濃度）をコック４から抜き出さ
れた試料について測定した。That is, the tetra bag 1 is filled with air (humidity 65%) containing malodorous substances at a predetermined concentration, and the air inside the bag is pumped through the Teflon tubes 3 and 3 by an air pump 2 at a flow rate of 5Q per minute. ', and the change in the concentration of malodorous substances over time (residual concentration) was measured for the sample taken out from the cock 4.
アンモニアガスについての測定結果は第２図のグラフに
、また硫化水素ガスについての測定結果は第４図のグラ
フにそれぞれ示される。The measurement results for ammonia gas are shown in the graph of FIG. 2, and the measurement results for hydrogen sulfide gas are shown in the graph of FIG. 4.
実施例２
実施例１において、スチレン−ジビニルベンゼンマイク
ロポーラスビーズ（ダイヤイオンＨＰ−２０）１００ｇ
を、錯体溶液（１００ｍ Ｑ ）にエタノール１５ｇお
よびグリセリン２０ｇを加えた溶液中に浸漬してから引
き上げ、これを１００℃に３時間加熱してエタノールを
蒸発させた。重量差から測定して、エタノールと共に蒸
発したと考えられる量の水を補給して、２０ｇの溶液（
組成：錯体３．７重量％、水酸化カリウム１．８重量％
、水７９．７重量％、グリセリン１４６８重量Ｓ）をマ
イクロポーラスビーズに含浸させた。Example 2 In Example 1, 100 g of styrene-divinylbenzene microporous beads (Diaion HP-20)
was immersed in a solution of a complex solution (100 m Q ) to which 15 g of ethanol and 20 g of glycerin were added, then pulled out, and heated to 100° C. for 3 hours to evaporate the ethanol. Measured from the weight difference, add the amount of water that is considered to have evaporated together with the ethanol, and make 20 g of the solution (
Composition: 3.7% by weight of complex, 1.8% by weight of potassium hydroxide
, 79.7% by weight of water, and 1468% by weight of glycerin) were impregnated into microporous beads.
この含浸マイクロポーラスビーズついて、実施例１と同
様の消臭試験が行われた。アンモニアガスについての測
定結果は第３図のグラフに、また硫化水素ガスについて
の測定結果は第５図のグラフにそれぞれ示される。The same deodorizing test as in Example 1 was conducted on the impregnated microporous beads. The measurement results for ammonia gas are shown in the graph of FIG. 3, and the measurement results for hydrogen sulfide gas are shown in the graph of FIG. 5.
第１図は、本発明に係る消臭材料を用いての消臭効果試
験装置の概略図である。第２〜５図は、それぞれ実施例
１〜２の試験結果を示すグラフである。FIG. 1 is a schematic diagram of a deodorizing effect testing apparatus using the deodorizing material according to the present invention. 2 to 5 are graphs showing the test results of Examples 1 to 2, respectively.
Claims (1)
ビニルベンゼン共重合体マイクロポーラスビーズに保持
せしめた消臭材料。 ２、カルボキシフタロシアニン金属錯体および吸水性物
質をスチレン−ジビニルベンゼン共重合体マイクロポー
ラスビーズに保持せしめた消臭材料。 ３、吸水性物質がグリセリンである特許請求の範囲第２
項記載の消臭材料。[Claims] 1. A deodorizing material in which a carboxyphthalocyanine metal complex is held in styrene-divinylbenzene copolymer microporous beads. 2. A deodorizing material in which a carboxyphthalocyanine metal complex and a water-absorbing substance are held in styrene-divinylbenzene copolymer microporous beads. 3. Claim 2 in which the water-absorbing substance is glycerin
Deodorizing materials listed in section.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61167676A JPH07114914B2 (en) | 1986-07-16 | 1986-07-16 | Deodorant material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61167676A JPH07114914B2 (en) | 1986-07-16 | 1986-07-16 | Deodorant material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6323715A true JPS6323715A (en) | 1988-02-01 |
| JPH07114914B2 JPH07114914B2 (en) | 1995-12-13 |
Family
ID=15854153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61167676A Expired - Lifetime JPH07114914B2 (en) | 1986-07-16 | 1986-07-16 | Deodorant material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07114914B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5132799A (en) * | 1989-10-30 | 1992-07-21 | Sanyo Electric Co., Ltd. | Frequency synthesizer-type television signal receiving apparatus comprising AFT function and controlling method therefor |
| JPH05300933A (en) * | 1992-04-27 | 1993-11-16 | Akiyama:Kk | Deodorizing liquid composition for composting feces |
| CN106243117A (en) * | 2016-08-11 | 2016-12-21 | 潘忠宁 | A kind of preparation method of eight carboxyl phthalocyanine copper films |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55163022U (en) * | 1979-05-09 | 1980-11-22 |
-
1986
- 1986-07-16 JP JP61167676A patent/JPH07114914B2/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55163022U (en) * | 1979-05-09 | 1980-11-22 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5132799A (en) * | 1989-10-30 | 1992-07-21 | Sanyo Electric Co., Ltd. | Frequency synthesizer-type television signal receiving apparatus comprising AFT function and controlling method therefor |
| JPH05300933A (en) * | 1992-04-27 | 1993-11-16 | Akiyama:Kk | Deodorizing liquid composition for composting feces |
| CN106243117A (en) * | 2016-08-11 | 2016-12-21 | 潘忠宁 | A kind of preparation method of eight carboxyl phthalocyanine copper films |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07114914B2 (en) | 1995-12-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3029841B2 (en) | Composite adsorbent and method for producing the same | |
| JP6345774B2 (en) | Ammonia adsorbent | |
| Jiang et al. | Facile synthesis of magnetic hybrid Fe3O4/MIL-101 via heterogeneous coprecipitation assembly for efficient adsorption of anionic dyes | |
| JPS6143091B2 (en) | ||
| BR112017009827B1 (en) | ADSORPTION COMPLEX COMPRISING 1-MCP (1-METHYLCYCLOPROPENE) AND A METAL COORDINATION POLYMER NET, KIT TO CONTAIN 1-MCP AND METHOD TO RELEASE 1-MCP FROM AN ADSORPTION COMPLEX FORMULATION KIT | |
| JPH02115020A (en) | Lower aldehyde remover | |
| JPS6323715A (en) | Deodorizing material | |
| JP2701062B2 (en) | Composite adsorbent | |
| JP2000107274A (en) | Deodorizing material and method for producing the same | |
| JPS6357054A (en) | Deodorizing material | |
| JP4011153B2 (en) | Deodorant | |
| JPH0689320B2 (en) | Powder consisting of metal and polybasic acid | |
| Toshima et al. | The removal of nitrogen monoxide by the dry iron (II) complex immobilized on chelate resin. The preparation and characterization of the complex | |
| JPH0580230B2 (en) | ||
| JPH0611292B2 (en) | Deodorant material | |
| JP3854393B2 (en) | Deodorant and deodorant composition | |
| JPS639444A (en) | Deodorizing material | |
| JPH0675589B2 (en) | Sterilizer / deodorant | |
| JPH0252040A (en) | Ethylene adsorbent and method for keeping freshness of plant | |
| JPH0644923B2 (en) | Deodorant material | |
| JPS62231665A (en) | Deodorant composition | |
| JPS63147542A (en) | air purifier | |
| Saeed et al. | Adsorption behaviour of Hg (II) from acetate medium onto PAR-imbedded polyurethane foam | |
| JPS63264139A (en) | Deodorizer and deodorizing material | |
| JPS6340556A (en) | deodorant composition |