JPS6328659B2 - - Google Patents
Info
- Publication number
- JPS6328659B2 JPS6328659B2 JP55175962A JP17596280A JPS6328659B2 JP S6328659 B2 JPS6328659 B2 JP S6328659B2 JP 55175962 A JP55175962 A JP 55175962A JP 17596280 A JP17596280 A JP 17596280A JP S6328659 B2 JPS6328659 B2 JP S6328659B2
- Authority
- JP
- Japan
- Prior art keywords
- cobalt
- manganese
- content
- catalyst
- heavy metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 claims description 54
- 239000011572 manganese Substances 0.000 claims description 45
- 238000007254 oxidation reaction Methods 0.000 claims description 44
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 42
- 230000003647 oxidation Effects 0.000 claims description 42
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 37
- 238000004821 distillation Methods 0.000 claims description 35
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims description 30
- 229910001385 heavy metal Inorganic materials 0.000 claims description 28
- 239000010941 cobalt Substances 0.000 claims description 27
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 27
- 229910017052 cobalt Inorganic materials 0.000 claims description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 22
- 238000009835 boiling Methods 0.000 claims description 22
- 229910052748 manganese Inorganic materials 0.000 claims description 21
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 230000002378 acidificating effect Effects 0.000 claims description 16
- 239000000284 extract Substances 0.000 claims description 16
- 229910052759 nickel Inorganic materials 0.000 claims description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 claims description 15
- 238000002485 combustion reaction Methods 0.000 claims description 14
- 239000000047 product Substances 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 13
- 239000011651 chromium Substances 0.000 claims description 12
- 239000010936 titanium Substances 0.000 claims description 12
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003729 cation exchange resin Substances 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 9
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 8
- 239000011707 mineral Substances 0.000 claims description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims description 8
- 239000011733 molybdenum Substances 0.000 claims description 8
- 229910052720 vanadium Inorganic materials 0.000 claims description 8
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 230000032050 esterification Effects 0.000 claims description 7
- 238000005886 esterification reaction Methods 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910001415 sodium ion Inorganic materials 0.000 claims description 7
- -1 aliphatic monocarboxylic acid Chemical class 0.000 claims description 6
- 239000007791 liquid phase Substances 0.000 claims description 6
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical compound CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 claims description 5
- 150000004679 hydroxides Chemical class 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- 239000011260 aqueous acid Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 229940071125 manganese acetate Drugs 0.000 claims description 4
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 claims description 4
- 229940011182 cobalt acetate Drugs 0.000 claims description 3
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 150000002697 manganese compounds Chemical class 0.000 claims description 3
- 230000001172 regenerating effect Effects 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 150000001869 cobalt compounds Chemical class 0.000 claims description 2
- 238000007865 diluting Methods 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims description 2
- 239000000706 filtrate Substances 0.000 claims 3
- 238000010438 heat treatment Methods 0.000 claims 3
- 229910000831 Steel Inorganic materials 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 2
- 239000010959 steel Substances 0.000 claims 2
- SVMCDCBHSKARBQ-UHFFFAOYSA-N acetic acid;cobalt Chemical compound [Co].CC(O)=O SVMCDCBHSKARBQ-UHFFFAOYSA-N 0.000 claims 1
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 claims 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical class [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 claims 1
- 229940078494 nickel acetate Drugs 0.000 claims 1
- 239000000243 solution Substances 0.000 description 50
- 239000011734 sodium Substances 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- 239000001632 sodium acetate Substances 0.000 description 9
- 235000017281 sodium acetate Nutrition 0.000 description 9
- 239000002956 ash Substances 0.000 description 8
- 239000012141 concentrate Substances 0.000 description 8
- 238000010828 elution Methods 0.000 description 8
- 150000001768 cations Chemical class 0.000 description 7
- 238000000605 extraction Methods 0.000 description 7
- 230000008929 regeneration Effects 0.000 description 7
- 238000011069 regeneration method Methods 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 235000010755 mineral Nutrition 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- 238000010626 work up procedure Methods 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- MZZUATUOLXMCEY-UHFFFAOYSA-N cobalt manganese Chemical class [Mn].[Co] MZZUATUOLXMCEY-UHFFFAOYSA-N 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000010763 heavy fuel oil Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 150000002816 nickel compounds Chemical class 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 238000003969 polarography Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- REIDAMBAPLIATC-UHFFFAOYSA-M 4-methoxycarbonylbenzoate Chemical compound COC(=O)C1=CC=C(C([O-])=O)C=C1 REIDAMBAPLIATC-UHFFFAOYSA-M 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000004525 petroleum distillation Methods 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000000247 postprecipitation Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02Â -Â B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Description
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ããïŒ Co 25ppm Mn 2ppm Ni 10ppm æŒåºãå§ãŸããŸã§äº€æäœãè² è·ããã«ã¯æº¶æ¶²
4.7ã䜿çšããã次ãã§äº€æäœãVEâæ°Ž250ml
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4.7ã䜿çšããã次ãã§äº€æäœãVEâæ°Ž250ml
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ãã次ã®æº¶æ¶²ã䜿çšããïŒ å è¡å®éšããã®åããåâåã³åŸæµåºç©ãã©ã¯
ã·ãšã³ 390ml 1gåœãéé¢ã®é ¢é ž15gãå«ã18ïŒ é ¢é žãããªãŠ
ã 溶液 200ml VEâæ°Ž 210ml 溶é¢ã«éããŠæ¬¡ã®æº¶æ¶²ãåŸãããïŒåæµåºç©ã
ã©ã¯ã·ãšã³ 80ml Na+ã®å°ãªãäž»ãã©ã¯ã·ãšã³ 400ml Na+ã«å¯ãã åŸæµåºç©ãã©ã¯ã·ãšã³ 320ml äž»ãã©ã¯ã·ãšã³ã¯æ¬¡ã®ãã®ãå«ãã§ããïŒ Co 21.5gïŒ Mn 1.9gïŒ Ni 10.2gïŒ Fe ïŒ5ppm Cr ïŒ5ppm Mo ïŒ5ppm  ïŒ5ppm Cu ïŒ5ppm Ti ïŒ5ppm Na 240ppm
ãã次ã®æº¶æ¶²ã䜿çšããïŒ å è¡å®éšããã®åããåâåã³åŸæµåºç©ãã©ã¯
ã·ãšã³ 390ml 1gåœãéé¢ã®é ¢é ž15gãå«ã18ïŒ é ¢é žãããªãŠ
ã 溶液 200ml VEâæ°Ž 210ml 溶é¢ã«éããŠæ¬¡ã®æº¶æ¶²ãåŸãããïŒåæµåºç©ã
ã©ã¯ã·ãšã³ 80ml Na+ã®å°ãªãäž»ãã©ã¯ã·ãšã³ 400ml Na+ã«å¯ãã åŸæµåºç©ãã©ã¯ã·ãšã³ 320ml äž»ãã©ã¯ã·ãšã³ã¯æ¬¡ã®ãã®ãå«ãã§ããïŒ Co 21.5gïŒ Mn 1.9gïŒ Ni 10.2gïŒ Fe ïŒ5ppm Cr ïŒ5ppm Mo ïŒ5ppm  ïŒ5ppm Cu ïŒ5ppm Ti ïŒ5ppm Na 240ppm
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ïœâãã·ããŒã«åã³ïŒåã¯ïœâãã«ã€ã«é žã¡
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ãŸãããããïŒmgïŒãããå°ãªãéã®éãã¯ã
ã ãã¢ãªããã³ããããžãŠã ãéŒåã³ãã¿ã³ãå«
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ïŒé ãŸã§ã®ããããïŒé ã«èšèŒã®æ¹æ³ã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2950318A DE2950318C2 (de) | 1979-12-14 | 1979-12-14 | Gewinnung und Wiederverwendung von Kobalt- oder Kobalt und Manganverbindungen aus dem Witten-DMT-Prozeà |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56100636A JPS56100636A (en) | 1981-08-12 |
| JPS6328659B2 true JPS6328659B2 (ja) | 1988-06-09 |
Family
ID=6088460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17596280A Granted JPS56100636A (en) | 1979-12-14 | 1980-12-15 | Method of recovering and reusing heavy metal oxidation catalyst from wittenndmttmethod |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4410449A (ja) |
| JP (1) | JPS56100636A (ja) |
| DE (1) | DE2950318C2 (ja) |
| IN (1) | IN152932B (ja) |
| SU (1) | SU1053735A3 (ja) |
| ZA (1) | ZA807808B (ja) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4894477A (en) * | 1986-10-14 | 1990-01-16 | Hoechst Celanese Corporation | Process for regenerating a carbonylation catalyst solution to remove corrosion metals and carbonylation of methanol to acetic acid |
| US4786621A (en) * | 1987-06-17 | 1988-11-22 | Amoco Corporation | Process for recovery of cobalt and manganese for oxidation residue incinerator ash |
| US5414106A (en) * | 1994-02-14 | 1995-05-09 | Hoechst Celanese Corporation | Process for recovering dimethyl terephthalate |
| US5980750A (en) * | 1998-07-06 | 1999-11-09 | Mobile Process Technology, Co. | Process for the purification of waste wash water |
| JP2003531919A (ja) * | 1998-10-12 | 2003-10-28 | ã·ãšã«ã»ã€ã³ã¿ãŒãã·ãšãã«ã»ãªãµãŒãã»ããŒãã¹ãããã€ã»ããŒã»ãŽãšãŒ | ïŒâããããã·ãããããŒã«æ°Žæ§æº¶æ¶²ããã³ãã«ããŸãã¯ããžãŠã ã«ã«ããã«ååç©ãé€å»ããæ¹æ³ |
| DE10008904A1 (de) * | 2000-02-25 | 2001-09-06 | Degussa | Verfahren zur RÃŒckgewinnung von Katalysator-Ãbergangsmetallen aus salzhaltigen Reaktionsgemischen |
| KR100662146B1 (ko) * | 2005-09-07 | 2006-12-27 | ííìì íí 죌ìíì¬ | í ë ííì° ì ì¡°ê³µì ìì ë°ìëë íꞰ묌ì ì²ëŠ¬ë°©ë² |
| CN102824919A (zh) * | 2011-06-14 | 2012-12-19 | éžç倧åç³åæéå ¬åž | äžç§ptaçäº§è£ çœ®äžéäœæ°§åå¬ååçæ¹æ³ |
| WO2018151733A1 (en) * | 2017-02-20 | 2018-08-23 | Rohm And Haas Company | Activation energy reducers for catalytic oxidation of gaseous mixtures |
| CN110818559A (zh) * | 2019-11-26 | 2020-02-21 | åéçŸå·æ°æææéå ¬åž | äžç§åè¯äžé žé 粟éŠæ¯æ¶²æ®æž£çåæ¶å©çšæ¹æ³ |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1014477A (en) | 1961-11-09 | 1965-12-22 | Snia Viscosa | Process for the recovery of cobalt catalysts |
| US3341470A (en) * | 1963-02-27 | 1967-09-12 | Standard Oil Co | Chemical process |
| US3873468A (en) * | 1970-12-09 | 1975-03-25 | Kuraray Yuka Kk | Method of removing substance harmful to oxidation reaction in the production of benzenecarboxylic acids by oxidation |
| US3780096A (en) * | 1971-07-01 | 1973-12-18 | United States Steel Corp | Process for recovering cobalt and manganese oxidation catalysts |
| GB1460941A (en) | 1973-03-30 | 1977-01-06 | Matsuyama Petrochemicals Inc | Method of recovering cobalt and or manganese-bromine liquid- phase oxidation catalyst |
| JPS549596B2 (ja) * | 1973-04-20 | 1979-04-25 | ||
| US4096340A (en) * | 1975-06-03 | 1978-06-20 | Teijin Hercules Chemical Co., Ltd. | Process for the preparation of dimethyl terephthalate |
| JPS54133495A (en) * | 1978-04-10 | 1979-10-17 | Asahi Chem Ind Co Ltd | Recovering method for liquid phase oxidation catalyst |
| DE2923681C2 (de) * | 1979-06-12 | 1981-11-05 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Gewinnung und Wiederverwendung von Schwermetalloxidationskatalysator aus dem Wittem-DMT-Prozeà |
-
1979
- 1979-12-14 DE DE2950318A patent/DE2950318C2/de not_active Expired
-
1980
- 1980-07-23 IN IN840/CAL/80A patent/IN152932B/en unknown
- 1980-12-10 SU SU803247249A patent/SU1053735A3/ru active
- 1980-12-12 ZA ZA00807808A patent/ZA807808B/xx unknown
- 1980-12-15 JP JP17596280A patent/JPS56100636A/ja active Granted
-
1982
- 1982-08-12 US US06/407,619 patent/US4410449A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56100636A (en) | 1981-08-12 |
| US4410449A (en) | 1983-10-18 |
| DE2950318C2 (de) | 1982-02-25 |
| IN152932B (ja) | 1984-05-05 |
| DE2950318B1 (de) | 1981-04-02 |
| SU1053735A3 (ru) | 1983-11-07 |
| ZA807808B (en) | 1982-01-27 |
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