JPS6344246B2 - - Google Patents

Info

Publication number
JPS6344246B2
JPS6344246B2 JP57199362A JP19936282A JPS6344246B2 JP S6344246 B2 JPS6344246 B2 JP S6344246B2 JP 57199362 A JP57199362 A JP 57199362A JP 19936282 A JP19936282 A JP 19936282A JP S6344246 B2 JPS6344246 B2 JP S6344246B2
Authority
JP
Japan
Prior art keywords
cable
termite
hydroxyquinoline
coating layer
proof
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP57199362A
Other languages
Japanese (ja)
Other versions
JPS5990309A (en
Inventor
Setsu Hanai
Fumio Aida
Hiroshi Ishiwatari
Shinji Nakazawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajinomoto Co Inc
Daiichi Kagaku Yakuhin Co Ltd
SWCC Corp
Original Assignee
Ajinomoto Co Inc
Daiichi Kagaku Yakuhin Co Ltd
Showa Electric Wire and Cable Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ajinomoto Co Inc, Daiichi Kagaku Yakuhin Co Ltd, Showa Electric Wire and Cable Co filed Critical Ajinomoto Co Inc
Priority to JP57199362A priority Critical patent/JPS5990309A/en
Priority to GB08330064A priority patent/GB2132482A/en
Publication of JPS5990309A publication Critical patent/JPS5990309A/en
Priority to MY1987442A priority patent/MY8700442A/en
Publication of JPS6344246B2 publication Critical patent/JPS6344246B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Insulated Conductors (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

(発明の技術分野) 本発明は防蟻ケーブルの改良に関するものであ
る。 (発明の技術的背景および問題点) 従来より、土又は砂の中に布設されたケーブル
が白蟻により食害を受ける事故が多く発生してお
り、ケーブルの防蟻対策は長年の課題であつた。 この対策として従来よりアルドリン,デイルド
リン等の塩素系ドリン剤をシース材料に少量添加
する方法がとられてきたが、ドリン剤は食害防止
効果は非常に大きいが、微生物分解性に乏しく、
人体内に蓄積し易いため、ケーブルの加工工程に
おいて環境衛生面に問題を生じ、実用上の使用は
困難となつている。 一方、これに変わるものとしてクロルデンが現
在木材防蟻の用途では主流であり、ケーブル用材
料への添加も検討されてきたが、クロルデンは蒸
気圧が高く混練時およびケーブル被覆時に強い臭
気を伴なうため、これも実用性を有していなかつ
た。 又、無公害防蟻対策として、ケーブル上に蟻が
歯を立てられないようなナイロン―12等を被覆す
る方法があるが、この方法は防蟻効果に問題はな
いものケーブルシースの上にさらに防食層を設け
ねばならないため、ケーブル製造工程が増す点、
さらに材料費自体が高いため、ケーブルの製造コ
ストが高くなる欠点があつた。 (発明の目的および概要) 本発明は前記のような従来の欠点を改良した防
蟻ケーブルを提供するものであつてその要旨とす
るところは、ケーブル線心を覆うゴム、プラスチ
ツクよりなる被覆層部材を、8―ヒドロキシキノ
リン又はその誘導体の1種あいは2種以上を配合
した混和物により形成したことを特徴とすること
にある。 本発明に使用する8―ヒドロキシキノリン又は
その誘導体としては8―ヒドロキシキノリン錫あ
るいは8―ヒドロキシキノリン銅等が殺菌面から
好ましく、特に8―ヒドロキシキノリン錫は熱に
対して安定であるので好ましい。8―ヒドロキノ
リンは金属イオンと容易にキレート化合物を生成
するので、どのような金属キレート化合物でも使
用できる。 被覆層部材を形成するベースポリマーとして
は、汎用で良いが塩化ビニル樹脂(PVC)、低密
度ポリエチレン(LDPE)、高密度ポリエチレン
(HDPE)等が用いられる。 本発明の防蟻ケーブルを製造するにあたつて
は、導体上に常法により絶縁体を押出し被覆し、
次いで常法により8―ヒドロキシキノリン等を添
加した防蟻被覆を施こす。 第1図はこのようにして得られた本発明の防蟻
ケーブルで導体1の上に絶縁体2が設けられ、そ
の上にポリ塩化ビニルあるいはポリエチレン組成
物に0.1〜7重量%、好ましくは1〜3重量%の
8―ヒドロキシキノリン錫を添加した防蟻被覆層
3が設けられている。 あるいは、第2図に示すように、導体1の上に
絶縁体2を被覆した絶縁線心がより合わせられ、
その上に抑えテープ4が巻かれその上に前記鉚蟻
被覆層3が設けられた構造としてもよい。 (発明の実施例) 以下、本発明の一実施例を説明する。 60mmφ×22KVの加橋ポリエチレン絶縁ケーブ
ル上に防蟻被覆層として表に示す配合のものを
1.5mm厚で押出し被覆してケーブル試料を作成し、
シート押出し時の臭気の有無を調べた。熱老化さ
せるものはさせ、これを白蟻の生息する砂丘地帯
の地下1mの個所に松材と共に埋設し、野外実験
を行つた。約1年後に堀り出してケーブル外被に
対する食害の有無を調べ、その結果を表に示し
た。
(Technical Field of the Invention) The present invention relates to improvements in termite-proof cables. (Technical Background and Problems of the Invention) Conventionally, there have been many accidents in which cables installed in soil or sand are damaged by termites, and termite prevention measures for cables have been a long-standing problem. As a countermeasure against this problem, the conventional method has been to add a small amount of chlorine-based detergent agents such as Aldrin and Deildrin to the sheath material, but although the detergent agents have a very large effect on preventing feeding damage, they have poor microbial degradability.
Since it easily accumulates in the human body, it causes problems in terms of environmental hygiene in the cable processing process, making it difficult to use it practically. On the other hand, as an alternative to this, chlordane is currently the mainstream for use in wood termite control, and its addition to cable materials has also been considered, but chlordane has a high vapor pressure and is accompanied by a strong odor during kneading and cable coating. This also had no practical use. In addition, as a non-pollution and termite prevention measure, there is a method of coating the cable with nylon-12, etc., which prevents ants from setting their teeth on the cable, but although this method does not have any problem with the termite prevention effect, it is necessary to coat the cable on top of the cable sheath. The need for an anti-corrosion layer increases the cable manufacturing process;
Furthermore, since the material cost itself is high, there is a drawback that the manufacturing cost of the cable is high. (Object and Summary of the Invention) The present invention provides a termite-proof cable that improves the conventional drawbacks as described above, and the gist thereof is to provide a coating layer member made of rubber or plastic that covers the cable core. is characterized in that it is formed from a mixture of one or more 8-hydroxyquinoline or its derivatives. As the 8-hydroxyquinoline or its derivative used in the present invention, 8-hydroxyquinoline tin or 8-hydroxyquinoline copper is preferable from the viewpoint of sterilization, and 8-hydroxyquinoline tin is particularly preferable because it is stable against heat. Since 8-hydroquinoline easily forms a chelate compound with metal ions, any metal chelate compound can be used. As the base polymer for forming the covering layer member, general-purpose materials such as vinyl chloride resin (PVC), low-density polyethylene (LDPE), and high-density polyethylene (HDPE) are used. In manufacturing the termite-proof cable of the present invention, an insulator is extruded and coated on the conductor using a conventional method.
Next, a termite-proof coating containing 8-hydroxyquinoline or the like is applied by a conventional method. FIG. 1 shows the termite-proof cable of the present invention obtained in this manner, in which an insulator 2 is provided on the conductor 1, and on top of the insulator 2, a polyvinyl chloride or polyethylene composition is added in an amount of 0.1 to 7% by weight, preferably 1% by weight. An anti-termite coating layer 3 containing ~3% by weight of 8-hydroxyquinolinetin is provided. Alternatively, as shown in FIG. 2, an insulated wire core coated with an insulator 2 is twisted onto a conductor 1,
It is also possible to have a structure in which a restraining tape 4 is wound thereon and the acetic ant coating layer 3 is provided thereon. (Embodiment of the invention) An embodiment of the invention will be described below. A material with the composition shown in the table was applied as an anti-termite coating layer on a 60mmφ×22KV cross-linked polyethylene insulated cable.
A cable sample was made by extrusion coating with a thickness of 1.5 mm,
The presence or absence of odor during sheet extrusion was investigated. A field experiment was carried out by allowing the material to undergo heat aging and burying it along with pine wood 1 meter underground in a sand dune area where termites live. After about a year, the cable was excavated and the cable jacket was examined to see if there was any damage to it, and the results are shown in the table.

【表】 (発明の効果) 以上詳述した如く本発明は、ケーブル線心のゴ
ム・プラスチツクよりなる被覆層部材に8―ヒド
ロキシキノリンおよび誘導体を添加すれば、コン
パウンド混練時および電線押出し時に発散する臭
気が極めて少なく、さらに長期的な効果および熱
安定性に優れ、かつ防蟻効果の高いケーブルを提
供できるものである。
[Table] (Effects of the Invention) As detailed above, the present invention provides that, by adding 8-hydroxyquinoline and derivatives to the coating layer member made of rubber or plastic of the cable core, the emitted light is released during compound kneading and wire extrusion. It is possible to provide a cable that has extremely little odor, has excellent long-term effectiveness and thermal stability, and is highly effective against termites.

【図面の簡単な説明】[Brief explanation of drawings]

第1図および第2図は本発明の防蟻ケーブルの
断面図である。 1……導体、2……絶縁体、3……防蟻被覆
層、4……抑えテープ。
1 and 2 are cross-sectional views of the termite-proof cable of the present invention. 1... Conductor, 2... Insulator, 3... Anti-termite coating layer, 4... Suppression tape.

Claims (1)

【特許請求の範囲】[Claims] 1 ケーブル線心を覆うゴム・プラスチツクより
なる被覆層部材を、8―ヒドロキシキノリン又は
その誘導体の1種あるいは2種以上を配合した混
和物により形成したことを特徴とする防蟻ケーブ
ル。
1. An anti-termite cable characterized in that the coating layer member made of rubber or plastic covering the cable core is formed of a mixture of one or more of 8-hydroxyquinoline or its derivatives.
JP57199362A 1982-11-12 1982-11-12 Ant preventive cable Granted JPS5990309A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP57199362A JPS5990309A (en) 1982-11-12 1982-11-12 Ant preventive cable
GB08330064A GB2132482A (en) 1982-11-12 1983-11-10 Anti-termitic composition
MY1987442A MY8700442A (en) 1982-11-12 1987-12-31 Anti-termite compositions containing 8-hydroxyquinoline derivatives and their use

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57199362A JPS5990309A (en) 1982-11-12 1982-11-12 Ant preventive cable

Publications (2)

Publication Number Publication Date
JPS5990309A JPS5990309A (en) 1984-05-24
JPS6344246B2 true JPS6344246B2 (en) 1988-09-05

Family

ID=16406495

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57199362A Granted JPS5990309A (en) 1982-11-12 1982-11-12 Ant preventive cable

Country Status (1)

Country Link
JP (1) JPS5990309A (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5234623U (en) * 1975-09-03 1977-03-11
JPS5759938A (en) * 1980-09-29 1982-04-10 Dainichi Nippon Cables Ltd Electrical insulation composition with improved

Also Published As

Publication number Publication date
JPS5990309A (en) 1984-05-24

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