JPS64106A - Production of cycloolefin random copolymer - Google Patents

Production of cycloolefin random copolymer

Info

Publication number
JPS64106A
JPS64106A JP62312112A JP31211287A JPS64106A JP S64106 A JPS64106 A JP S64106A JP 62312112 A JP62312112 A JP 62312112A JP 31211287 A JP31211287 A JP 31211287A JP S64106 A JPS64106 A JP S64106A
Authority
JP
Japan
Prior art keywords
cycloolefin
compound
random copolymer
group
aluminoxane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62312112A
Other languages
Japanese (ja)
Other versions
JP2504495B2 (en
JPH01106A (en
Inventor
Naoshi Ishimaru
Toshiyuki Tsutsui
Akinori Toyoda
Norio Kashiwa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Petrochemical Industries Ltd
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Priority to JP62312112A priority Critical patent/JP2504495B2/en
Priority to US07/162,200 priority patent/US5003019A/en
Priority to DE3853843T priority patent/DE3853843T2/en
Priority to CA000560207A priority patent/CA1312695C/en
Priority to EP88301791A priority patent/EP0283164B1/en
Priority to KR1019880002152A priority patent/KR910009376B1/en
Priority to CN88101641A priority patent/CN1017804B/en
Publication of JPH01106A publication Critical patent/JPH01106A/en
Publication of JPS64106A publication Critical patent/JPS64106A/en
Priority to US07/359,131 priority patent/US5008356A/en
Application granted granted Critical
Publication of JP2504495B2 publication Critical patent/JP2504495B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

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  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

PURPOSE: To produce the title polymer of a narrow MW distribution efficiently, by copolymerizing an α-olefin with a cycloolefin in the presence of a catalyst comprising a specified transition metal compound and an aluminoxane.
CONSTITUTION: An α-olefin is copolymerized with a cycloolefin in the presence of a catalyst prepared from a Group IVB transition metal compound (A) having a ligand comprising a polydentate compound having at least two (substituted) conjugated cycloalkadienyl groups bonded together through a lower alkylene group [e.g., ethylenebis(cyclopentadienyl)-zirconium monochloride hydride] and an aluminoxane (B) [e.g., a compound of formula I or II (wherein R is a hydrocarbyl group, preferably, a methyl group, and m is 2 or larger, preferably, 5 or larger)]. According to this process, a cycloolefin random copolymer excellent in polymerization activity and a narrow MW distribution can be produced efficiently.
COPYRIGHT: (C)1989,JPO&Japio
JP62312112A 1987-03-02 1987-12-11 Preparation of cyclic olefin-based random copolymer Expired - Lifetime JP2504495B2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP62312112A JP2504495B2 (en) 1987-03-02 1987-12-11 Preparation of cyclic olefin-based random copolymer
US07/162,200 US5003019A (en) 1987-03-02 1988-02-29 Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers
CA000560207A CA1312695C (en) 1987-03-02 1988-03-01 Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers
EP88301791A EP0283164B1 (en) 1987-03-02 1988-03-01 Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers
DE3853843T DE3853843T2 (en) 1987-03-02 1988-03-01 Cyclic-olefinic static copolymers, olefinic static copolymers and process for the preparation of cyclic-olefinic static copolymers.
KR1019880002152A KR910009376B1 (en) 1987-03-02 1988-03-02 Cyclo-olefinic random copolymer
CN88101641A CN1017804B (en) 1987-03-02 1988-03-02 Preparation method of cycloolefin random copolymer
US07/359,131 US5008356A (en) 1987-03-02 1989-05-31 Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP4515287 1987-03-02
JP62-45152 1987-03-02
JP62312112A JP2504495B2 (en) 1987-03-02 1987-12-11 Preparation of cyclic olefin-based random copolymer

Publications (3)

Publication Number Publication Date
JPH01106A JPH01106A (en) 1989-01-05
JPS64106A true JPS64106A (en) 1989-01-05
JP2504495B2 JP2504495B2 (en) 1996-06-05

Family

ID=26385124

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62312112A Expired - Lifetime JP2504495B2 (en) 1987-03-02 1987-12-11 Preparation of cyclic olefin-based random copolymer

Country Status (1)

Country Link
JP (1) JP2504495B2 (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6466216A (en) * 1987-08-07 1989-03-13 Hoechst Ag Production of olefin polymer
JPH0884952A (en) * 1994-09-14 1996-04-02 Ig Tech Res Inc Coating device
JPH0889868A (en) * 1994-09-26 1996-04-09 Ig Tech Res Inc Coating device
US6969751B2 (en) 2004-04-28 2005-11-29 Korea Kumho Petrochemical Co., Ltd. Method for preparing homo-and co-polymers of cyclic olefin compounds
US6998450B1 (en) 2004-09-16 2006-02-14 Korea Kumho Petrochemical Co., Ltd. Method for preparing a homo-and co-polymers by polymerization of cyclic olefin compounds using fluorine-containing aromatic hydrocarbon compound as catalyst activator
US7091290B2 (en) 2004-04-29 2006-08-15 Korea Kumho Petrochemical Co., Ltd. Method for preparing homo-and co-polymers of cyclic olefin compounds using an organic boron compound as a catalyst activator
WO2006095511A1 (en) 2005-03-07 2006-09-14 Mitsui Chemicals, Inc. Cyclic olefin resin composition, and substrate provided from said resin composition
JP2007314806A (en) * 1994-04-22 2007-12-06 Mitsui Chemicals Inc Production method of cycloolefin copolymer and copolymer produced thereby
WO2008139698A1 (en) 2007-04-27 2008-11-20 Mitsui Chemicals, Inc. Resin composition and molded article obtained from the composition
US8114942B2 (en) 2005-06-30 2012-02-14 Mitsui Chemicals, Inc. Process for producing cycloolefin resin composition, and cycloolefin resin composition
CN102702384A (en) * 2012-05-23 2012-10-03 天津科技大学 Method for removing proteins in chitin material
US8735501B2 (en) 2011-05-31 2014-05-27 Canon Kabushiki Kaisha Composition, method for manufacturing the same, optical element, lens
WO2018181781A1 (en) 2017-03-30 2018-10-04 三井化学株式会社 Cyclic olefin resin composition for molding, molded body, and resin

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9068554B2 (en) 2009-06-09 2015-06-30 James W. Healy Wave energy electrical power generation
US8963352B2 (en) 2009-06-09 2015-02-24 James W. Healy Wave energy electrical power generation

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6035007A (en) * 1983-06-06 1985-02-22 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− Method and catalyst for controlling polyolefin density and molecular weight
JPS61221206A (en) * 1985-03-26 1986-10-01 Mitsui Petrochem Ind Ltd Production of cycloolefin copolymer

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6035007A (en) * 1983-06-06 1985-02-22 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− Method and catalyst for controlling polyolefin density and molecular weight
JPS61221206A (en) * 1985-03-26 1986-10-01 Mitsui Petrochem Ind Ltd Production of cycloolefin copolymer

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6466216A (en) * 1987-08-07 1989-03-13 Hoechst Ag Production of olefin polymer
JP2007314806A (en) * 1994-04-22 2007-12-06 Mitsui Chemicals Inc Production method of cycloolefin copolymer and copolymer produced thereby
JPH0884952A (en) * 1994-09-14 1996-04-02 Ig Tech Res Inc Coating device
US5620517A (en) * 1994-09-14 1997-04-15 Ig-Technical Research Inc. Painting device
JPH0889868A (en) * 1994-09-26 1996-04-09 Ig Tech Res Inc Coating device
US6969751B2 (en) 2004-04-28 2005-11-29 Korea Kumho Petrochemical Co., Ltd. Method for preparing homo-and co-polymers of cyclic olefin compounds
US7091290B2 (en) 2004-04-29 2006-08-15 Korea Kumho Petrochemical Co., Ltd. Method for preparing homo-and co-polymers of cyclic olefin compounds using an organic boron compound as a catalyst activator
US6998450B1 (en) 2004-09-16 2006-02-14 Korea Kumho Petrochemical Co., Ltd. Method for preparing a homo-and co-polymers by polymerization of cyclic olefin compounds using fluorine-containing aromatic hydrocarbon compound as catalyst activator
WO2006095511A1 (en) 2005-03-07 2006-09-14 Mitsui Chemicals, Inc. Cyclic olefin resin composition, and substrate provided from said resin composition
US8114942B2 (en) 2005-06-30 2012-02-14 Mitsui Chemicals, Inc. Process for producing cycloolefin resin composition, and cycloolefin resin composition
WO2008139698A1 (en) 2007-04-27 2008-11-20 Mitsui Chemicals, Inc. Resin composition and molded article obtained from the composition
US8735501B2 (en) 2011-05-31 2014-05-27 Canon Kabushiki Kaisha Composition, method for manufacturing the same, optical element, lens
CN102702384A (en) * 2012-05-23 2012-10-03 天津科技大学 Method for removing proteins in chitin material
WO2018181781A1 (en) 2017-03-30 2018-10-04 三井化学株式会社 Cyclic olefin resin composition for molding, molded body, and resin

Also Published As

Publication number Publication date
JP2504495B2 (en) 1996-06-05

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