JPS6411110A - Hydrophilicity-hydrophobicity thermoreversible polymeric compound and production thereof - Google Patents
Hydrophilicity-hydrophobicity thermoreversible polymeric compound and production thereofInfo
- Publication number
- JPS6411110A JPS6411110A JP16600987A JP16600987A JPS6411110A JP S6411110 A JPS6411110 A JP S6411110A JP 16600987 A JP16600987 A JP 16600987A JP 16600987 A JP16600987 A JP 16600987A JP S6411110 A JPS6411110 A JP S6411110A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- specific
- polymeric compound
- meth
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title abstract 2
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 abstract 3
- 238000010526 radical polymerization reaction Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- QAFODUGVXFNLBE-UHFFFAOYSA-N 1-methoxybutan-2-amine Chemical compound CCC(N)COC QAFODUGVXFNLBE-UHFFFAOYSA-N 0.000 abstract 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000012662 bulk polymerization Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- -1 vinyl compound Chemical class 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
PURPOSE:To obtain the titled novel compound constituted of specific recurring unit, having specific molecular weight, reversibly soluble in water in the lower temperature region, becoming insoluble in water in the higher temperature region, useful as a light-shielding substance for greenhouse etc., thermosensor, etc., by radical polymerization of a specific vinyl compound. CONSTITUTION:N-1-methoxymethylpropyl (meth)acrylamide of formula I (R is H or methyl) is brought to radical polymerization through e.g. solution polymerization or bulk polymerization process, e.g. using an initiator to obtain the objective polymeric compound constituted of recurring unit of formula II having such molecular weight as to correspond to 0.01-6.0 for the intrinsic viscosity [eta]at 27 deg.C in the form of THF solution. Said starting material of the formula I is a new material, being prepared, e.g., by reaction, in a solvent at 0-10 deg.C, between (meth)acrylic chloride, 2-amino-1-methoxybutane and triethylamine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62166009A JPH0618970B2 (en) | 1987-07-02 | 1987-07-02 | Hydrophilic-hydrophobic thermoreversible material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62166009A JPH0618970B2 (en) | 1987-07-02 | 1987-07-02 | Hydrophilic-hydrophobic thermoreversible material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6411110A true JPS6411110A (en) | 1989-01-13 |
| JPH0618970B2 JPH0618970B2 (en) | 1994-03-16 |
Family
ID=15823202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62166009A Expired - Lifetime JPH0618970B2 (en) | 1987-07-02 | 1987-07-02 | Hydrophilic-hydrophobic thermoreversible material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0618970B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0692506A2 (en) | 1994-07-14 | 1996-01-17 | Miyoshi Yushi Kabushiki Kaisha | Thermo-sensitive polyether polyurethane, production method thereof and thermo-sensitive composition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS491457A (en) * | 1972-04-25 | 1974-01-08 | ||
| JPS4927407A (en) * | 1972-07-08 | 1974-03-11 | ||
| JPS57179211A (en) * | 1981-04-10 | 1982-11-04 | Rohm & Haas | Nonionic or anionic water soluble addition copolymer |
| JPS61225203A (en) * | 1985-03-29 | 1986-10-07 | Agency Of Ind Science & Technol | Thermally reversible hydrophilic and hydrophobic polymer and its production |
| JPS6291509A (en) * | 1985-10-16 | 1987-04-27 | Agency Of Ind Science & Technol | Thermoreversibly hydrophilic and hydrophobic polymer and its production |
-
1987
- 1987-07-02 JP JP62166009A patent/JPH0618970B2/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS491457A (en) * | 1972-04-25 | 1974-01-08 | ||
| JPS4927407A (en) * | 1972-07-08 | 1974-03-11 | ||
| JPS57179211A (en) * | 1981-04-10 | 1982-11-04 | Rohm & Haas | Nonionic or anionic water soluble addition copolymer |
| JPS61225203A (en) * | 1985-03-29 | 1986-10-07 | Agency Of Ind Science & Technol | Thermally reversible hydrophilic and hydrophobic polymer and its production |
| JPS6291509A (en) * | 1985-10-16 | 1987-04-27 | Agency Of Ind Science & Technol | Thermoreversibly hydrophilic and hydrophobic polymer and its production |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0692506A2 (en) | 1994-07-14 | 1996-01-17 | Miyoshi Yushi Kabushiki Kaisha | Thermo-sensitive polyether polyurethane, production method thereof and thermo-sensitive composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0618970B2 (en) | 1994-03-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |