JPS6411112A - Production of vinyl acetate-acrylic copolymer - Google Patents
Production of vinyl acetate-acrylic copolymerInfo
- Publication number
- JPS6411112A JPS6411112A JP16586987A JP16586987A JPS6411112A JP S6411112 A JPS6411112 A JP S6411112A JP 16586987 A JP16586987 A JP 16586987A JP 16586987 A JP16586987 A JP 16586987A JP S6411112 A JPS6411112 A JP S6411112A
- Authority
- JP
- Japan
- Prior art keywords
- monomer
- series
- unreacted
- cstr
- vinyl acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920006243 acrylic copolymer Polymers 0.000 title 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title 1
- 229920002554 vinyl polymer Polymers 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 6
- 238000003756 stirring Methods 0.000 abstract 4
- 238000001944 continuous distillation Methods 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE:To obtain in high productivity the titled copolymer good in gloss water resistance, weatherability etc., useful for coatings, by continuous polymerization of the raw material monomer in a multi-step continuously stirring type reactor with a plural of stirring tanks connected in series followed by removing the monomer unreacted. CONSTITUTION:A raw material monomer component consisting mainly of vinyl acetate and methyl methacrylate is continuously polymerized in a multi-step continuously stirring type reactor (thereafter CSTR) with a plural of stirring tanks connected in series, followed by removing the monomer unreacted, pref. using a continuous distillation column, thus obtaining the objective copolymer. Preferably, the reactor is such that two or three CSTRs are connected in series with the continuous distillation column 6 for removing the monomer unreacted connected to the final CSTR 4. Said monomer unreacted, after removal, is pref. fed by circulation to the final CSTR for reuse.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16586987A JPS6411112A (en) | 1987-07-02 | 1987-07-02 | Production of vinyl acetate-acrylic copolymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16586987A JPS6411112A (en) | 1987-07-02 | 1987-07-02 | Production of vinyl acetate-acrylic copolymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6411112A true JPS6411112A (en) | 1989-01-13 |
| JPH0428003B2 JPH0428003B2 (en) | 1992-05-13 |
Family
ID=15820530
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16586987A Granted JPS6411112A (en) | 1987-07-02 | 1987-07-02 | Production of vinyl acetate-acrylic copolymer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6411112A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003292503A (en) * | 2002-04-04 | 2003-10-15 | Mitsubishi Rayon Co Ltd | Continuous polymerization method of polymer and the same polymerization equipment |
| JP2006528276A (en) * | 2003-05-16 | 2006-12-14 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Continuous process for the production of polyamides |
| JP2008502744A (en) * | 2004-06-01 | 2008-01-31 | ワッカー ポリマー システムズ ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディトゲゼルシャフト | Non-sticky solid resin of vinyl ester mixed polymer |
| JP2016511284A (en) * | 2013-03-13 | 2016-04-14 | ハネウェル・インターナショナル・インコーポレーテッド | Staged fluorination method and reactor system |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4886990A (en) * | 1972-02-24 | 1973-11-16 | ||
| JPS5441990A (en) * | 1977-09-09 | 1979-04-03 | Shinto Paint Co Ltd | Resin composition |
| JPS5499138A (en) * | 1978-01-20 | 1979-08-04 | Keikou Matsumoto | Decorative aggregateecontaining coating composition |
-
1987
- 1987-07-02 JP JP16586987A patent/JPS6411112A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4886990A (en) * | 1972-02-24 | 1973-11-16 | ||
| JPS5441990A (en) * | 1977-09-09 | 1979-04-03 | Shinto Paint Co Ltd | Resin composition |
| JPS5499138A (en) * | 1978-01-20 | 1979-08-04 | Keikou Matsumoto | Decorative aggregateecontaining coating composition |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003292503A (en) * | 2002-04-04 | 2003-10-15 | Mitsubishi Rayon Co Ltd | Continuous polymerization method of polymer and the same polymerization equipment |
| JP2006528276A (en) * | 2003-05-16 | 2006-12-14 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Continuous process for the production of polyamides |
| JP2008502744A (en) * | 2004-06-01 | 2008-01-31 | ワッカー ポリマー システムズ ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディトゲゼルシャフト | Non-sticky solid resin of vinyl ester mixed polymer |
| JP2016511284A (en) * | 2013-03-13 | 2016-04-14 | ハネウェル・インターナショナル・インコーポレーテッド | Staged fluorination method and reactor system |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0428003B2 (en) | 1992-05-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term | ||
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080513 Year of fee payment: 16 |