JPS6419037A - Oxidation of 2-chloropropionaldehyde - Google Patents
Oxidation of 2-chloropropionaldehydeInfo
- Publication number
- JPS6419037A JPS6419037A JP17388787A JP17388787A JPS6419037A JP S6419037 A JPS6419037 A JP S6419037A JP 17388787 A JP17388787 A JP 17388787A JP 17388787 A JP17388787 A JP 17388787A JP S6419037 A JPS6419037 A JP S6419037A
- Authority
- JP
- Japan
- Prior art keywords
- indium
- thallious
- chloropropionaldehyde
- catalyst
- chloropropionic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE:To obtain 2-chloropropionic acid which is useful as a synthetic intermediate of agrochemicals under reduced corrosive conditions, practically in high selectivity, by using a specific compound, as a catalyst, to effect liquid-phase oxidation of 2-chloropropionaldehyde with O2. CONSTITUTION:2-Chloropropionaldehyde of formula I is oxidized in a solvent, preferably 2-chloropropionic acid or acetic acid, in a concentration of 5-15wt.%, in the presence of a catalyst of an indium compound such as indium oxide, indium hydroxide, indium sulfate or a thallium compound such as thallious sulfate, thallious oxide, thallious chloride, in liquid phase, using O2 or O2- containing gas, preferably at 40-90 deg.C, at an oxygen partial of 5-100kg/cm<2> to obtain 2-chloropropionic acid of formula II which is useful as an industrial chemical. The amount of the catalyst used is preferably 0.01-5wt.%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17388787A JPS6419037A (en) | 1987-07-14 | 1987-07-14 | Oxidation of 2-chloropropionaldehyde |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17388787A JPS6419037A (en) | 1987-07-14 | 1987-07-14 | Oxidation of 2-chloropropionaldehyde |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6419037A true JPS6419037A (en) | 1989-01-23 |
Family
ID=15968949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17388787A Pending JPS6419037A (en) | 1987-07-14 | 1987-07-14 | Oxidation of 2-chloropropionaldehyde |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6419037A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19843784A1 (en) * | 1998-09-24 | 2000-04-20 | Temic Semiconductor Gmbh | Power amplification circuit for communications signals, has parallel signal paths containing saturation amplifiers with different power output values operated selectively dependent on required power output |
-
1987
- 1987-07-14 JP JP17388787A patent/JPS6419037A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19843784A1 (en) * | 1998-09-24 | 2000-04-20 | Temic Semiconductor Gmbh | Power amplification circuit for communications signals, has parallel signal paths containing saturation amplifiers with different power output values operated selectively dependent on required power output |
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