JPS643148A - Production of 2,6-naphthalenedicarboxylic acid - Google Patents

Production of 2,6-naphthalenedicarboxylic acid

Info

Publication number
JPS643148A
JPS643148A JP62159217A JP15921787A JPS643148A JP S643148 A JPS643148 A JP S643148A JP 62159217 A JP62159217 A JP 62159217A JP 15921787 A JP15921787 A JP 15921787A JP S643148 A JPS643148 A JP S643148A
Authority
JP
Japan
Prior art keywords
compound
solvent
dimethylnaphthalene
oxidizing
molecular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62159217A
Other languages
Japanese (ja)
Other versions
JPH013148A (en
JP2611232B2 (en
Inventor
Yoshiaki Kano
Masahiko Yamada
Motohiro Oguri
Kenji Kasano
Masaru Uemura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHINKYOWA PETROCHEM CO Ltd
Original Assignee
SHINKYOWA PETROCHEM CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHINKYOWA PETROCHEM CO Ltd filed Critical SHINKYOWA PETROCHEM CO Ltd
Priority to JP62159217A priority Critical patent/JP2611232B2/en
Publication of JPS643148A publication Critical patent/JPS643148A/en
Publication of JPH013148A publication Critical patent/JPH013148A/en
Application granted granted Critical
Publication of JP2611232B2 publication Critical patent/JP2611232B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

PURPOSE: To obtain the titled compound in high yield keeping the concentration of the raw material compound in the reaction system at a high level, by oxidizing 2,6-dimethylnaphthalene raw material with molecular O2 in the presence of a catalyst containing Co, Mn and Br using a specific mixture as a solvent.
CONSTITUTION: The objective compound is produced by oxidizing 2,6- dimethylnaphthalene with molecular O2 in a solvent composed of an aliphatic carboxylic acid (e.g. acetic acid) and an aromatic compound of formula (X is halogen; n is 0W3) (e.g. o-dichlorobenzene) in the presence of a catalyst containing CO (e.g. cobalt acetate), Mn (e.g., manganese acetate) and Br (e.g. NaBr) at 120W160°C for 0.15W5hr under a reaction system pressure above the vapor pressure of the reaction mixture and keeping the O2 partial pressure to usually ≤0.5kg/cm2, preferably ≥1.0kg/cm2, The volume ratio of the aliphatic carboxylic acid to the compound of formula in the above mixed solvent is 1 to 0.5W10. The productivity per unit amount of solvent can be improved.
COPYRIGHT: (C)1989,JPO&Japio
JP62159217A 1987-06-26 1987-06-26 Method for producing 2,6-naphthalenedicarboxylic acid Expired - Lifetime JP2611232B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62159217A JP2611232B2 (en) 1987-06-26 1987-06-26 Method for producing 2,6-naphthalenedicarboxylic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62159217A JP2611232B2 (en) 1987-06-26 1987-06-26 Method for producing 2,6-naphthalenedicarboxylic acid

Publications (3)

Publication Number Publication Date
JPS643148A true JPS643148A (en) 1989-01-06
JPH013148A JPH013148A (en) 1989-01-06
JP2611232B2 JP2611232B2 (en) 1997-05-21

Family

ID=15688889

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62159217A Expired - Lifetime JP2611232B2 (en) 1987-06-26 1987-06-26 Method for producing 2,6-naphthalenedicarboxylic acid

Country Status (1)

Country Link
JP (1) JP2611232B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02164844A (en) * 1988-12-19 1990-06-25 Nkk Corp Method for producing naphthoic acids and/or naphthalene polycarboxylic acids
US5523473A (en) * 1992-12-30 1996-06-04 Nippon Shokubai Co., Ltd. Method of producing naphthalenedicarboxylic acids and diaryldicarboxylic acids

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4975563A (en) * 1972-11-25 1974-07-20
JPS5217453A (en) * 1975-07-30 1977-02-09 Mitsui Petrochem Ind Ltd Process for preparation of 2,6- naphthalenedicarboxylic acid
JPS61286342A (en) * 1985-06-13 1986-12-16 Mitsubishi Gas Chem Co Inc Production of acyloxynaphthoic acid

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4975563A (en) * 1972-11-25 1974-07-20
JPS5217453A (en) * 1975-07-30 1977-02-09 Mitsui Petrochem Ind Ltd Process for preparation of 2,6- naphthalenedicarboxylic acid
JPS61286342A (en) * 1985-06-13 1986-12-16 Mitsubishi Gas Chem Co Inc Production of acyloxynaphthoic acid

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02164844A (en) * 1988-12-19 1990-06-25 Nkk Corp Method for producing naphthoic acids and/or naphthalene polycarboxylic acids
US5523473A (en) * 1992-12-30 1996-06-04 Nippon Shokubai Co., Ltd. Method of producing naphthalenedicarboxylic acids and diaryldicarboxylic acids

Also Published As

Publication number Publication date
JP2611232B2 (en) 1997-05-21

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