JPS6470465A - Production of 3-ethylpyridine - Google Patents

Production of 3-ethylpyridine

Info

Publication number
JPS6470465A
JPS6470465A JP62227334A JP22733487A JPS6470465A JP S6470465 A JPS6470465 A JP S6470465A JP 62227334 A JP62227334 A JP 62227334A JP 22733487 A JP22733487 A JP 22733487A JP S6470465 A JPS6470465 A JP S6470465A
Authority
JP
Japan
Prior art keywords
ethylpyridine
steam
catalyst
amount
feedstock
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62227334A
Other languages
Japanese (ja)
Inventor
Tetsuo Nakayama
Masahiro Saito
Osamu Tajima
Kazuhiko Tate
Masami Ono
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Steel Works Ltd
National Institute of Advanced Industrial Science and Technology
Original Assignee
Agency of Industrial Science and Technology
Japan Steel Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency of Industrial Science and Technology, Japan Steel Works Ltd filed Critical Agency of Industrial Science and Technology
Priority to JP62227334A priority Critical patent/JPS6470465A/en
Publication of JPS6470465A publication Critical patent/JPS6470465A/en
Pending legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Pyridine Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE:To facilitate high-yield production of the title compound which is used as a feedstock for 3-vinylpyridine used in ion-exchange resins, by demethylation of 2-methyl-5-ethylpyridine in the presence of a Ni catalyst supported with zirconia in the presence of a specific amount of steam. CONSTITUTION:2-Methyl-5-ethylpyridine is brought into contact with a nickel catalyst supported with zirconia (the nickel content is 5-50wt.%) together with steam in an amount of 5-40mol. per mol. of the pyridine, at 250-450 deg.C, preferably 270-400 deg.C to effect selective demethylation in the alpha-position. In this process, 3-ethylpyridine is obtained in much higher yield than in the conventional process, as the high selectivity is maintained under such conditions as the ratio of the steam to the feedstock is remarkably reduced. The catalyst precipitates more reduced amount of carbon than the catalysts in which alumina or silica is used as a support and the catalyst life is reasonably prolonged.
JP62227334A 1987-09-10 1987-09-10 Production of 3-ethylpyridine Pending JPS6470465A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62227334A JPS6470465A (en) 1987-09-10 1987-09-10 Production of 3-ethylpyridine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62227334A JPS6470465A (en) 1987-09-10 1987-09-10 Production of 3-ethylpyridine

Publications (1)

Publication Number Publication Date
JPS6470465A true JPS6470465A (en) 1989-03-15

Family

ID=16859179

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62227334A Pending JPS6470465A (en) 1987-09-10 1987-09-10 Production of 3-ethylpyridine

Country Status (1)

Country Link
JP (1) JPS6470465A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6470147A (en) * 1987-09-10 1989-03-15 Agency Ind Science Techn Steam-dealkylation catalyst

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62227335A (en) * 1986-03-28 1987-10-06 株式会社東芝 Ultrasonic diagnostic apparatus
JPS62227333A (en) * 1986-03-28 1987-10-06 松下電器産業株式会社 Ultrasonic measuring apparatus

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62227335A (en) * 1986-03-28 1987-10-06 株式会社東芝 Ultrasonic diagnostic apparatus
JPS62227333A (en) * 1986-03-28 1987-10-06 松下電器産業株式会社 Ultrasonic measuring apparatus

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6470147A (en) * 1987-09-10 1989-03-15 Agency Ind Science Techn Steam-dealkylation catalyst

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