JPS6475438A - Production of isopropylnaphthol - Google Patents
Production of isopropylnaphtholInfo
- Publication number
- JPS6475438A JPS6475438A JP62231489A JP23148987A JPS6475438A JP S6475438 A JPS6475438 A JP S6475438A JP 62231489 A JP62231489 A JP 62231489A JP 23148987 A JP23148987 A JP 23148987A JP S6475438 A JPS6475438 A JP S6475438A
- Authority
- JP
- Japan
- Prior art keywords
- palladium
- diisopropylnaphthalene
- oxidation
- acidolysis
- selectivity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE:To obtain the titled compound of high purity in high yield, by oxidizing diisopropylnaphthalene with molecular oxygen in a polar organic solvent in the presence of a palladium catalyst soluble in the reaction mixture followed by acidolysis of the oxidation product. CONSTITUTION:After diisopropylnaphthalene is oxidized with molecular oxygen into diisopropylnaphthalene monohydroperoxide and the product is subjected to acidolysis to give isopropylnaphthol which is used as a feedstock for synthetic resins, synthetic fibers, medicines, agrochemicals, dyes and so on. At this time, the oxidation is carried out in a polar organic solvent, preferably acetonitrile, in the presence of a palladium catalyst soluble in the reaction mixture such as palladium chloride, palladium nitrate, palladium acetate to stop the oxidation reactions at the stage of the above-stated intermediate thereby the yield and selectivity are increased to obtain the subject compound in high yield and selectivity.
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62231489A JPS6475438A (en) | 1987-09-16 | 1987-09-16 | Production of isopropylnaphthol |
| AT92100457T ATE129995T1 (en) | 1987-09-12 | 1988-09-08 | METHOD FOR PRODUCING ISOPROPYLNAPHTHOLS. |
| AT88308294T ATE79865T1 (en) | 1987-09-12 | 1988-09-08 | OXIDATION PROCESSES OF SECONDARY ALKYL-SUBSTITUTED NAPHTHALINES. |
| DE8888308294T DE3874061T2 (en) | 1987-09-12 | 1988-09-08 | OXIDATION PROCEDURE OF SECOND ALKYL-SUBSTITUTED NAPHTHALINES. |
| EP92100457A EP0484319B1 (en) | 1987-09-12 | 1988-09-08 | A process of producing isopropylnaphthols |
| EP88308294A EP0308133B1 (en) | 1987-09-12 | 1988-09-08 | A method of oxidising secondary alkyl substituted naphthalenes |
| DE3854675T DE3854675T2 (en) | 1987-09-12 | 1988-09-08 | Process for the preparation of isopropylnaphthols. |
| CA000576993A CA1291767C (en) | 1987-09-12 | 1988-09-09 | Method of oxidizing secondary alkyl substituted naphthalenes and a process of producing isopropylnaphthols |
| US07/242,163 US4906790A (en) | 1987-09-12 | 1988-09-09 | Method of oxidizing secondary alkyl substituted naphtalenes and a process of producing isopropylnaphthols |
| KR88011752A KR970008990B1 (en) | 1987-09-12 | 1988-09-12 | Method of oxidising secondary alkyl substituted naphthalenes |
| KR1019970012465A KR970011738B1 (en) | 1987-09-12 | 1997-04-04 | Process of producing isopropylnaphthols |
| KR97012466A KR970011739B1 (en) | 1987-09-12 | 1997-04-04 | Process of producing isopropylnaphthols |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62231489A JPS6475438A (en) | 1987-09-16 | 1987-09-16 | Production of isopropylnaphthol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6475438A true JPS6475438A (en) | 1989-03-22 |
Family
ID=16924291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62231489A Pending JPS6475438A (en) | 1987-09-12 | 1987-09-16 | Production of isopropylnaphthol |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6475438A (en) |
-
1987
- 1987-09-16 JP JP62231489A patent/JPS6475438A/en active Pending
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