JPS6487757A - Production of low hydrogen overvoltage cathode - Google Patents
Production of low hydrogen overvoltage cathodeInfo
- Publication number
- JPS6487757A JPS6487757A JP62245095A JP24509587A JPS6487757A JP S6487757 A JPS6487757 A JP S6487757A JP 62245095 A JP62245095 A JP 62245095A JP 24509587 A JP24509587 A JP 24509587A JP S6487757 A JPS6487757 A JP S6487757A
- Authority
- JP
- Japan
- Prior art keywords
- cathode
- thermal spraying
- hydrogen overvoltage
- soln
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/137—Spraying in vacuum or in an inert atmosphere
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Coating By Spraying Or Casting (AREA)
Abstract
PURPOSE:To produce a low hydrogen overvoltage cathode at a good product yield by coating the fine particles of metals at a specific thickness onto the surface of the cathode base body by a reduced pressure thermal spraying method at the time of producing the cathode to be used in an electrolytic cell for an aq. soln. of alkali metal halide, etc. CONSTITUTION:The surface of the electrode base body made of iron and steel, stainless steel, Ni, Ni alloy, Cu, or Cu alloy in the shape of a perforated plate, expanded metal, net or the like is roughened and cleaned by sandblasting as the low hydrogen overvoltage cathode to be used at the time of generating gaseous H2 by electrolyzing the aq. soln. of the alkali metal halide such as NaCl or the aq. soln. of the alkali metal hydroxide such as NaOH by a diaphragm method or ion exchange membrane method. For example, the Ni or Ni alloy is thermally sprayed under the reduced pressure in the form of 1-200mum fine particles to 10-300mum thickness on the above- mentioned base body in a hermetically closed treatment chamber by an arc thermal spraying method, plasma thermal spraying method, etc., while the inside of the chamber is evacuated to a reduced pressure. The oxidation of the metal to be thermally sprayed during the thermal spraying is prevented and the cathode which is lower in the hydrogen overvoltage than heretofore and has the excellent strength and life is obtd.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62245095A JPS6487757A (en) | 1987-09-28 | 1987-09-28 | Production of low hydrogen overvoltage cathode |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62245095A JPS6487757A (en) | 1987-09-28 | 1987-09-28 | Production of low hydrogen overvoltage cathode |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6487757A true JPS6487757A (en) | 1989-03-31 |
Family
ID=17128532
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62245095A Pending JPS6487757A (en) | 1987-09-28 | 1987-09-28 | Production of low hydrogen overvoltage cathode |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6487757A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5941486A (en) * | 1982-07-30 | 1984-03-07 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | Manufacture of raney nickel clad cathode and product |
| JPS59120276A (en) * | 1982-12-27 | 1984-07-11 | Nippon Kokan Kk <Nkk> | Manufacture of steel pipe having coated inner surface |
| JPS61288060A (en) * | 1985-06-13 | 1986-12-18 | Sumitomo Electric Ind Ltd | Low pressure plasma arc spraying method |
-
1987
- 1987-09-28 JP JP62245095A patent/JPS6487757A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5941486A (en) * | 1982-07-30 | 1984-03-07 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | Manufacture of raney nickel clad cathode and product |
| JPS59120276A (en) * | 1982-12-27 | 1984-07-11 | Nippon Kokan Kk <Nkk> | Manufacture of steel pipe having coated inner surface |
| JPS61288060A (en) * | 1985-06-13 | 1986-12-18 | Sumitomo Electric Ind Ltd | Low pressure plasma arc spraying method |
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