JPS649207A - Photo-crosslinkable fluorinated styrene polymer - Google Patents
Photo-crosslinkable fluorinated styrene polymerInfo
- Publication number
- JPS649207A JPS649207A JP63019621A JP1962188A JPS649207A JP S649207 A JPS649207 A JP S649207A JP 63019621 A JP63019621 A JP 63019621A JP 1962188 A JP1962188 A JP 1962188A JP S649207 A JPS649207 A JP S649207A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- repeating units
- group
- lower alkyl
- photo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title abstract 4
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 title abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000000524 functional group Chemical group 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000013307 optical fiber Substances 0.000 abstract 1
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PURPOSE:To provide the title polymer having a low refractive index and being useful, for example, as sheath material for optical fibers, which polymer comprises specific repeating units and other repeating units having a photopolymerizable functional group. CONSTITUTION:A fluorinated styrene derivative of formula I [wherein R<1> is H or lower alkyl; R<2> is H or lower polyfluoroalkyl; R<3> is (ether linkage- containing) polyfluoroalkyl; X is -O- or a group of formula II; R<4-5> are each lower alkyl; Y<1-5> are each H or halogen; and m and n are each 0 or 1] is copolymerized with an ethylenically unsaturated monomer having a photopolymerizable functional group of formula III (wherein A is -O-, -CH2-, a group of formula IV, etc.; B is -OCH3-, a group of formula V, etc.; R<6> is H or lower alkyl; Z is a photopolymerizable functional group; l is 0-3; and k is 0 or 1) to produce a photo-crosslinkable fluorinated styrene polymer that comprises repeating units of formula VI and 1-20mol.% photopolymerizable repeating units of formula VII (wherein R<7> is R<6>) and has a weight-average mol.wt. of 1,000-20,000, a melting point of 80 deg.C or below and a refractive index of 1.45 or below.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63019621A JP2509274B2 (en) | 1987-02-03 | 1988-02-01 | Photocrosslinkable fluorine-containing styrene polymer |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62-21699 | 1987-02-03 | ||
| JP2169987 | 1987-02-03 | ||
| JP63019621A JP2509274B2 (en) | 1987-02-03 | 1988-02-01 | Photocrosslinkable fluorine-containing styrene polymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS649207A true JPS649207A (en) | 1989-01-12 |
| JP2509274B2 JP2509274B2 (en) | 1996-06-19 |
Family
ID=26356466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63019621A Expired - Lifetime JP2509274B2 (en) | 1987-02-03 | 1988-02-01 | Photocrosslinkable fluorine-containing styrene polymer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2509274B2 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04169590A (en) * | 1990-10-31 | 1992-06-17 | Shin Etsu Chem Co Ltd | Fluorine-containing organosilicon compounds |
| EP0867441A3 (en) * | 1997-03-28 | 2000-08-02 | Dow Corning Toray Silicone Company Ltd. | Surface treatment agent |
| KR100511100B1 (en) * | 2002-07-12 | 2005-08-31 | 김미화 | Perfluorostyrene compounds, Coating solution and Optical waveguide device using the same |
| KR100653302B1 (en) * | 1999-09-08 | 2006-12-04 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Styrene Derivatives |
| JP5790649B2 (en) * | 2010-06-23 | 2015-10-07 | 旭硝子株式会社 | Curable composition and method for producing cured film |
| CN116354804A (en) * | 2023-03-14 | 2023-06-30 | 杭州瀛拓科技有限公司 | 1,2,4, 5-tetrafluoro-6-vinylbenzene derivative and synthetic method and application thereof |
| WO2025018147A1 (en) * | 2023-07-14 | 2025-01-23 | 日産化学株式会社 | Fluorinated arylsulfonate polymer compound and use of same |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20240329344A1 (en) * | 2023-03-31 | 2024-10-03 | Advanced Semiconductor Engineering, Inc. | Semiconductor package and method for manufacturing the same |
-
1988
- 1988-02-01 JP JP63019621A patent/JP2509274B2/en not_active Expired - Lifetime
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04169590A (en) * | 1990-10-31 | 1992-06-17 | Shin Etsu Chem Co Ltd | Fluorine-containing organosilicon compounds |
| EP0867441A3 (en) * | 1997-03-28 | 2000-08-02 | Dow Corning Toray Silicone Company Ltd. | Surface treatment agent |
| KR100653302B1 (en) * | 1999-09-08 | 2006-12-04 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Styrene Derivatives |
| KR100511100B1 (en) * | 2002-07-12 | 2005-08-31 | 김미화 | Perfluorostyrene compounds, Coating solution and Optical waveguide device using the same |
| JP5790649B2 (en) * | 2010-06-23 | 2015-10-07 | 旭硝子株式会社 | Curable composition and method for producing cured film |
| CN116354804A (en) * | 2023-03-14 | 2023-06-30 | 杭州瀛拓科技有限公司 | 1,2,4, 5-tetrafluoro-6-vinylbenzene derivative and synthetic method and application thereof |
| CN116354804B (en) * | 2023-03-14 | 2025-05-02 | 研一(杭州)新能源科技有限责任公司 | 1,2,4,5-tetrafluoro-6-vinylbenzene derivatives and synthesis methods and applications thereof |
| WO2025018147A1 (en) * | 2023-07-14 | 2025-01-23 | 日産化学株式会社 | Fluorinated arylsulfonate polymer compound and use of same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2509274B2 (en) | 1996-06-19 |
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