JPS64948B2 - - Google Patents
Info
- Publication number
- JPS64948B2 JPS64948B2 JP54124688A JP12468879A JPS64948B2 JP S64948 B2 JPS64948 B2 JP S64948B2 JP 54124688 A JP54124688 A JP 54124688A JP 12468879 A JP12468879 A JP 12468879A JP S64948 B2 JPS64948 B2 JP S64948B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- hydroxy
- compound
- formula
- benzotriazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical group 0.000 claims description 30
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 15
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 125000005647 linker group Chemical group 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 4
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 25
- -1 chlorocarbonyl group Chemical group 0.000 description 23
- 239000012964 benzotriazole Substances 0.000 description 22
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- 238000002844 melting Methods 0.000 description 19
- 230000008018 melting Effects 0.000 description 19
- 229920000642 polymer Polymers 0.000 description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 229920001577 copolymer Polymers 0.000 description 15
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 239000008096 xylene Substances 0.000 description 14
- 239000004922 lacquer Substances 0.000 description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000004611 light stabiliser Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- 239000011541 reaction mixture Substances 0.000 description 9
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000005809 transesterification reaction Methods 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 4
- 229920000877 Melamine resin Polymers 0.000 description 4
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 4
- 239000011368 organic material Substances 0.000 description 4
- FTVFPPFZRRKJIH-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CC1(C)CC(N)CC(C)(C)N1 FTVFPPFZRRKJIH-UHFFFAOYSA-N 0.000 description 3
- HVHUQKKGFXFGBD-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,2,6,6-tetramethylpiperidin-4-yl)phenol Chemical compound C1C(C)(C)NC(C)(C)CC1C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 HVHUQKKGFXFGBD-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- NWHNXXMYEICZAT-UHFFFAOYSA-N 1,2,2,6,6-pentamethylpiperidin-4-ol Chemical compound CN1C(C)(C)CC(O)CC1(C)C NWHNXXMYEICZAT-UHFFFAOYSA-N 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- JDLQSLMTBGPZLW-UHFFFAOYSA-N 1-(1-hydroxyethyl)-2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC(O)N1C(C)(C)CC(O)CC1(C)C JDLQSLMTBGPZLW-UHFFFAOYSA-N 0.000 description 2
- VDVUCLWJZJHFAV-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1 VDVUCLWJZJHFAV-UHFFFAOYSA-N 0.000 description 2
- LCSNESAHHGTVLP-UHFFFAOYSA-N 2-(2,2,6,6-tetramethylpiperidin-4-yl)ethanamine Chemical compound CC1(C)CC(CCN)CC(C)(C)N1 LCSNESAHHGTVLP-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- FJGQBLRYBUAASW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)phenol Chemical compound OC1=CC=CC=C1N1N=C2C=CC=CC2=N1 FJGQBLRYBUAASW-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- 229940126062 Compound A Drugs 0.000 description 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000006286 aqueous extract Substances 0.000 description 2
- 239000000987 azo dye Substances 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229940125782 compound 2 Drugs 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- PHLGWZZBFCDLCH-UHFFFAOYSA-N methyl 4-benzoyl-3-hydroxy-2-methoxybenzoate Chemical compound OC1=C(OC)C(C(=O)OC)=CC=C1C(=O)C1=CC=CC=C1 PHLGWZZBFCDLCH-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 230000000176 photostabilization Effects 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920006324 polyoxymethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- AOSZTAHDEDLTLQ-AZKQZHLXSA-N (1S,2S,4R,8S,9S,11S,12R,13S,19S)-6-[(3-chlorophenyl)methyl]-12,19-difluoro-11-hydroxy-8-(2-hydroxyacetyl)-9,13-dimethyl-6-azapentacyclo[10.8.0.02,9.04,8.013,18]icosa-14,17-dien-16-one Chemical compound C([C@@H]1C[C@H]2[C@H]3[C@]([C@]4(C=CC(=O)C=C4[C@@H](F)C3)C)(F)[C@@H](O)C[C@@]2([C@@]1(C1)C(=O)CO)C)N1CC1=CC=CC(Cl)=C1 AOSZTAHDEDLTLQ-AZKQZHLXSA-N 0.000 description 1
- SZUVGFMDDVSKSI-WIFOCOSTSA-N (1s,2s,3s,5r)-1-(carboxymethyl)-3,5-bis[(4-phenoxyphenyl)methyl-propylcarbamoyl]cyclopentane-1,2-dicarboxylic acid Chemical compound O=C([C@@H]1[C@@H]([C@](CC(O)=O)([C@H](C(=O)N(CCC)CC=2C=CC(OC=3C=CC=CC=3)=CC=2)C1)C(O)=O)C(O)=O)N(CCC)CC(C=C1)=CC=C1OC1=CC=CC=C1 SZUVGFMDDVSKSI-WIFOCOSTSA-N 0.000 description 1
- DGTYATBVKJTCAP-UHFFFAOYSA-N (2,2,6,6-tetramethylpiperidin-4-yl) 3-[3-(benzotriazol-2-yl)-4-hydroxy-5-methylphenyl]propanoate Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C)=CC=1CCC(=O)OC1CC(C)(C)NC(C)(C)C1 DGTYATBVKJTCAP-UHFFFAOYSA-N 0.000 description 1
- GHYOCDFICYLMRF-UTIIJYGPSA-N (2S,3R)-N-[(2S)-3-(cyclopenten-1-yl)-1-[(2R)-2-methyloxiran-2-yl]-1-oxopropan-2-yl]-3-hydroxy-3-(4-methoxyphenyl)-2-[[(2S)-2-[(2-morpholin-4-ylacetyl)amino]propanoyl]amino]propanamide Chemical compound C1(=CCCC1)C[C@@H](C(=O)[C@@]1(OC1)C)NC([C@H]([C@@H](C1=CC=C(C=C1)OC)O)NC([C@H](C)NC(CN1CCOCC1)=O)=O)=O GHYOCDFICYLMRF-UTIIJYGPSA-N 0.000 description 1
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 1
- WWTBZEKOSBFBEM-SPWPXUSOSA-N (2s)-2-[[2-benzyl-3-[hydroxy-[(1r)-2-phenyl-1-(phenylmethoxycarbonylamino)ethyl]phosphoryl]propanoyl]amino]-3-(1h-indol-3-yl)propanoic acid Chemical compound N([C@@H](CC=1C2=CC=CC=C2NC=1)C(=O)O)C(=O)C(CP(O)(=O)[C@H](CC=1C=CC=CC=1)NC(=O)OCC=1C=CC=CC=1)CC1=CC=CC=C1 WWTBZEKOSBFBEM-SPWPXUSOSA-N 0.000 description 1
- VLGJZLAHUNKXKN-UHFFFAOYSA-N (3-ethyl-8,8,10,10-tetramethyl-1,5-dioxa-9-azaspiro[5.5]undecan-3-yl)methanol Chemical compound O1CC(CC)(CO)COC11CC(C)(C)NC(C)(C)C1 VLGJZLAHUNKXKN-UHFFFAOYSA-N 0.000 description 1
- QFLWZFQWSBQYPS-AWRAUJHKSA-N (3S)-3-[[(2S)-2-[[(2S)-2-[5-[(3aS,6aR)-2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl]pentanoylamino]-3-methylbutanoyl]amino]-3-(4-hydroxyphenyl)propanoyl]amino]-4-[1-bis(4-chlorophenoxy)phosphorylbutylamino]-4-oxobutanoic acid Chemical compound CCCC(NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](Cc1ccc(O)cc1)NC(=O)[C@@H](NC(=O)CCCCC1SC[C@@H]2NC(=O)N[C@H]12)C(C)C)P(=O)(Oc1ccc(Cl)cc1)Oc1ccc(Cl)cc1 QFLWZFQWSBQYPS-AWRAUJHKSA-N 0.000 description 1
- IWZSHWBGHQBIML-ZGGLMWTQSA-N (3S,8S,10R,13S,14S,17S)-17-isoquinolin-7-yl-N,N,10,13-tetramethyl-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-amine Chemical compound CN(C)[C@H]1CC[C@]2(C)C3CC[C@@]4(C)[C@@H](CC[C@@H]4c4ccc5ccncc5c4)[C@@H]3CC=C2C1 IWZSHWBGHQBIML-ZGGLMWTQSA-N 0.000 description 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- OHCHSGWRBYWCJD-UHFFFAOYSA-N 1,2,2,6,6-pentamethyl-4-(oxiran-2-ylmethoxy)piperidine Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OCC1OC1 OHCHSGWRBYWCJD-UHFFFAOYSA-N 0.000 description 1
- YWDUWMSSMMJNEP-UHFFFAOYSA-N 1-(4-amino-2,2,6,6-tetramethylpiperidin-1-yl)ethanone Chemical compound CC(=O)N1C(C)(C)CC(N)CC1(C)C YWDUWMSSMMJNEP-UHFFFAOYSA-N 0.000 description 1
- BYRAJSGSAYGRFQ-UHFFFAOYSA-N 1-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)ethanone Chemical compound CC(=O)N1C(C)(C)CC(O)CC1(C)C BYRAJSGSAYGRFQ-UHFFFAOYSA-N 0.000 description 1
- ONBQEOIKXPHGMB-VBSBHUPXSA-N 1-[2-[(2s,3r,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)oxolan-2-yl]oxy-4,6-dihydroxyphenyl]-3-(4-hydroxyphenyl)propan-1-one Chemical compound O[C@@H]1[C@H](O)[C@@H](CO)O[C@H]1OC1=CC(O)=CC(O)=C1C(=O)CCC1=CC=C(O)C=C1 ONBQEOIKXPHGMB-VBSBHUPXSA-N 0.000 description 1
- CFNJOTBXMMKRLL-UHFFFAOYSA-N 1-[4-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)but-2-enyl]-2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1CC=CCN1C(C)(C)CC(O)CC1(C)C CFNJOTBXMMKRLL-UHFFFAOYSA-N 0.000 description 1
- UNILWMWFPHPYOR-KXEYIPSPSA-M 1-[6-[2-[3-[3-[3-[2-[2-[3-[[2-[2-[[(2r)-1-[[2-[[(2r)-1-[3-[2-[2-[3-[[2-(2-amino-2-oxoethoxy)acetyl]amino]propoxy]ethoxy]ethoxy]propylamino]-3-hydroxy-1-oxopropan-2-yl]amino]-2-oxoethyl]amino]-3-[(2r)-2,3-di(hexadecanoyloxy)propyl]sulfanyl-1-oxopropan-2-yl Chemical compound O=C1C(SCCC(=O)NCCCOCCOCCOCCCNC(=O)COCC(=O)N[C@@H](CSC[C@@H](COC(=O)CCCCCCCCCCCCCCC)OC(=O)CCCCCCCCCCCCCCC)C(=O)NCC(=O)N[C@H](CO)C(=O)NCCCOCCOCCOCCCNC(=O)COCC(N)=O)CC(=O)N1CCNC(=O)CCCCCN\1C2=CC=C(S([O-])(=O)=O)C=C2CC/1=C/C=C/C=C/C1=[N+](CC)C2=CC=C(S([O-])(=O)=O)C=C2C1 UNILWMWFPHPYOR-KXEYIPSPSA-M 0.000 description 1
- VLTHAKKFNPUWSB-UHFFFAOYSA-N 1-benzyl-2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1CC1=CC=CC=C1 VLTHAKKFNPUWSB-UHFFFAOYSA-N 0.000 description 1
- COHCRTRMRJCDKH-UHFFFAOYSA-N 1-phenylpiperidin-2-ol Chemical class OC1CCCCN1C1=CC=CC=C1 COHCRTRMRJCDKH-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 1
- IYPXTUIASISGNQ-UHFFFAOYSA-N 2-(3,5-ditert-butyl-2-hydroxyphenyl)benzotriazole-5-carbonyl chloride Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(C=CC3=N2)C(Cl)=O)=C1O IYPXTUIASISGNQ-UHFFFAOYSA-N 0.000 description 1
- VOKZEOBBGHSYNT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-methyl-6-(2,2,6,6-tetramethylpiperidin-4-yl)phenol Chemical compound OC=1C(N2N=C3C=CC=CC3=N2)=CC(C)=CC=1C1CC(C)(C)NC(C)(C)C1 VOKZEOBBGHSYNT-UHFFFAOYSA-N 0.000 description 1
- HINXUKKSARUAGM-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-6-methyl-4-(1,2,2,6,6-pentamethylpiperidin-4-yl)phenol Chemical compound C1C(C)(C)N(C)C(C)(C)CC1C1=CC(C)=C(O)C(N2N=C3C=CC=CC3=N2)=C1 HINXUKKSARUAGM-UHFFFAOYSA-N 0.000 description 1
- FEOLXZHWSNOVFB-UHFFFAOYSA-N 2-cyclohexyl-4-(2,2,6,6-tetramethylpiperidin-4-yl)phenol Chemical compound C1C(C)(C)NC(C)(C)CC1C1=CC=C(O)C(C2CCCCC2)=C1 FEOLXZHWSNOVFB-UHFFFAOYSA-N 0.000 description 1
- HXDLWJWIAHWIKI-UHFFFAOYSA-N 2-hydroxyethyl acetate Chemical compound CC(=O)OCCO HXDLWJWIAHWIKI-UHFFFAOYSA-N 0.000 description 1
- DIHSCSBXGPEHGU-UHFFFAOYSA-N 2-methyl-4-(2,2,6,6-tetramethylpiperidin-4-yl)phenol Chemical compound C1=C(O)C(C)=CC(C2CC(C)(C)NC(C)(C)C2)=C1 DIHSCSBXGPEHGU-UHFFFAOYSA-N 0.000 description 1
- DPJCXCZTLWNFOH-UHFFFAOYSA-N 2-nitroaniline Chemical compound NC1=CC=CC=C1[N+]([O-])=O DPJCXCZTLWNFOH-UHFFFAOYSA-N 0.000 description 1
- AYTSDBGAHOKDHJ-UHFFFAOYSA-N 2-nitrobenzenediazonium Chemical compound [O-][N+](=O)C1=CC=CC=C1[N+]#N AYTSDBGAHOKDHJ-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- UQJGXIKMKWDYHA-UHFFFAOYSA-N 2-tert-butyl-4-(2,2,6,6-tetramethylpiperidin-4-yl)phenol Chemical compound C1=C(O)C(C(C)(C)C)=CC(C2CC(C)(C)NC(C)(C)C2)=C1 UQJGXIKMKWDYHA-UHFFFAOYSA-N 0.000 description 1
- QBWKPGNFQQJGFY-QLFBSQMISA-N 3-[(1r)-1-[(2r,6s)-2,6-dimethylmorpholin-4-yl]ethyl]-n-[6-methyl-3-(1h-pyrazol-4-yl)imidazo[1,2-a]pyrazin-8-yl]-1,2-thiazol-5-amine Chemical compound N1([C@H](C)C2=NSC(NC=3C4=NC=C(N4C=C(C)N=3)C3=CNN=C3)=C2)C[C@H](C)O[C@H](C)C1 QBWKPGNFQQJGFY-QLFBSQMISA-N 0.000 description 1
- IHDBZCJYSHDCKF-UHFFFAOYSA-N 4,6-dichlorotriazine Chemical compound ClC1=CC(Cl)=NN=N1 IHDBZCJYSHDCKF-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QCQCHGYLTSGIGX-GHXANHINSA-N 4-[[(3ar,5ar,5br,7ar,9s,11ar,11br,13as)-5a,5b,8,8,11a-pentamethyl-3a-[(5-methylpyridine-3-carbonyl)amino]-2-oxo-1-propan-2-yl-4,5,6,7,7a,9,10,11,11b,12,13,13a-dodecahydro-3h-cyclopenta[a]chrysen-9-yl]oxy]-2,2-dimethyl-4-oxobutanoic acid Chemical compound N([C@@]12CC[C@@]3(C)[C@]4(C)CC[C@H]5C(C)(C)[C@@H](OC(=O)CC(C)(C)C(O)=O)CC[C@]5(C)[C@H]4CC[C@@H]3C1=C(C(C2)=O)C(C)C)C(=O)C1=CN=CC(C)=C1 QCQCHGYLTSGIGX-GHXANHINSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- OJRUSAPKCPIVBY-KQYNXXCUSA-N C1=NC2=C(N=C(N=C2N1[C@H]3[C@@H]([C@@H]([C@H](O3)COP(=O)(CP(=O)(O)O)O)O)O)I)N Chemical compound C1=NC2=C(N=C(N=C2N1[C@H]3[C@@H]([C@@H]([C@H](O3)COP(=O)(CP(=O)(O)O)O)O)O)I)N OJRUSAPKCPIVBY-KQYNXXCUSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 description 1
- 229940126657 Compound 17 Drugs 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 229920003264 Maprenal® Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- OPFJDXRVMFKJJO-ZHHKINOHSA-N N-{[3-(2-benzamido-4-methyl-1,3-thiazol-5-yl)-pyrazol-5-yl]carbonyl}-G-dR-G-dD-dD-dD-NH2 Chemical compound S1C(C=2NN=C(C=2)C(=O)NCC(=O)N[C@H](CCCN=C(N)N)C(=O)NCC(=O)N[C@H](CC(O)=O)C(=O)N[C@H](CC(O)=O)C(=O)N[C@H](CC(O)=O)C(N)=O)=C(C)N=C1NC(=O)C1=CC=CC=C1 OPFJDXRVMFKJJO-ZHHKINOHSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- LNUFLCYMSVYYNW-ZPJMAFJPSA-N [(2r,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6r)-6-[(2r,3r,4s,5r,6r)-6-[(2r,3r,4s,5r,6r)-6-[[(3s,5s,8r,9s,10s,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,5,6,7,8,9,11,12,14,15,16,17-tetradecahydro-1h-cyclopenta[a]phenanthren-3-yl]oxy]-4,5-disulfo Chemical compound O([C@@H]1[C@@H](COS(O)(=O)=O)O[C@@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1[C@@H](COS(O)(=O)=O)O[C@@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1[C@@H](COS(O)(=O)=O)O[C@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1C[C@@H]2CC[C@H]3[C@@H]4CC[C@@H]([C@]4(CC[C@@H]3[C@@]2(C)CC1)C)[C@H](C)CCCC(C)C)[C@H]1O[C@H](COS(O)(=O)=O)[C@@H](OS(O)(=O)=O)[C@H](OS(O)(=O)=O)[C@H]1OS(O)(=O)=O LNUFLCYMSVYYNW-ZPJMAFJPSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 230000009435 amidation Effects 0.000 description 1
- 238000007112 amidation reaction Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- XRWSZZJLZRKHHD-WVWIJVSJSA-N asunaprevir Chemical compound O=C([C@@H]1C[C@H](CN1C(=O)[C@@H](NC(=O)OC(C)(C)C)C(C)(C)C)OC1=NC=C(C2=CC=C(Cl)C=C21)OC)N[C@]1(C(=O)NS(=O)(=O)C2CC2)C[C@H]1C=C XRWSZZJLZRKHHD-WVWIJVSJSA-N 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 1
- KGNDCEVUMONOKF-UGPLYTSKSA-N benzyl n-[(2r)-1-[(2s,4r)-2-[[(2s)-6-amino-1-(1,3-benzoxazol-2-yl)-1,1-dihydroxyhexan-2-yl]carbamoyl]-4-[(4-methylphenyl)methoxy]pyrrolidin-1-yl]-1-oxo-4-phenylbutan-2-yl]carbamate Chemical compound C1=CC(C)=CC=C1CO[C@H]1CN(C(=O)[C@@H](CCC=2C=CC=CC=2)NC(=O)OCC=2C=CC=CC=2)[C@H](C(=O)N[C@@H](CCCCN)C(O)(O)C=2OC3=CC=CC=C3N=2)C1 KGNDCEVUMONOKF-UGPLYTSKSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920001727 cellulose butyrate Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 229920006184 cellulose methylcellulose Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 229940125773 compound 10 Drugs 0.000 description 1
- 229940125797 compound 12 Drugs 0.000 description 1
- 229940126543 compound 14 Drugs 0.000 description 1
- 229940125758 compound 15 Drugs 0.000 description 1
- 229940126142 compound 16 Drugs 0.000 description 1
- 229940125810 compound 20 Drugs 0.000 description 1
- 229940126086 compound 21 Drugs 0.000 description 1
- 229940126208 compound 22 Drugs 0.000 description 1
- 229940125833 compound 23 Drugs 0.000 description 1
- 229940125961 compound 24 Drugs 0.000 description 1
- 229940125846 compound 25 Drugs 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- JAXFJECJQZDFJS-XHEPKHHKSA-N gtpl8555 Chemical compound OC(=O)C[C@H](N)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](C(C)C)C(=O)N1CCC[C@@H]1C(=O)N[C@H](B1O[C@@]2(C)[C@H]3C[C@H](C3(C)C)C[C@H]2O1)CCC1=CC=C(F)C=C1 JAXFJECJQZDFJS-XHEPKHHKSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 238000003541 multi-stage reaction Methods 0.000 description 1
- LKPFBGKZCCBZDK-UHFFFAOYSA-N n-hydroxypiperidine Chemical compound ON1CCCCC1 LKPFBGKZCCBZDK-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical class [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000005671 trienes Chemical class 0.000 description 1
- ILWRPSCZWQJDMK-UHFFFAOYSA-N triethylazanium;chloride Chemical compound Cl.CCN(CC)CC ILWRPSCZWQJDMK-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D211/40—Oxygen atoms
- C07D211/44—Oxygen atoms attached in position 4
- C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Plural Heterocyclic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Hydrogenated Pyridines (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Description
æ¬çºæã¯çŽ«å€ç·ã«ããå£åããææ©ææãç¹ã«
ææ©ããªããŒçšã®æ°èŠå å®å®å€ã«é¢ãããã®ã§ã
ãããã®å®å®å€ã¯ãã³ãŸããªã¢ãŸãŒã«ãŸãã¯ïŒâ
ããããã·ãã³ãŸããšãã³ãšããªã¢ã«ãã«ãããª
ãžã³èªå°äœãšã®ååçµåç©ã§ããã ïŒâïŒïŒâããããã·ããšãã«ïŒâãã³ãŸããª
ã¢ãŸãŒã«ããã³ïŒâããããã·ãã³ãŸããšãã³ã
ææ©ææã®æçšãªå å®å®å€ã§ããããšã¯ç¥ãããŠ
ããããããã¯çŽ«å€ç·åžåå€ãšããŠäœçšããïŒã
ãªãã¡é«ãšãã«ã®ãŒã®å éåïŒçŽ«å€ç·ïŒããä¿è·
ãã¹ãææ©ææã«å¯ŸããŠæ害äœçšãæããªãç±ã«
å€æããã ããã«ããªã¢ã«ãã«ãããªãžã³ããŸãæçšãªå
å®å®å€ã§ããããšãç¥ãããŠããããããããªã
ãããªã¢ã«ãã«ãããªãžã³ã¯çæ³¢é·ã®å ãåžåã
ãªãããã玫å€ç·åžåå€ãšããŠã¯äœçšããªããã
ã®äœçšã®æ©æ§ã®æ確ãªè§£æã¯ãããŸã§ãªãããŠã
ãªãïŒäŸãã°ãšã€ãïŒãžãšãŒïŒãã©ãŒããã³ãšã€
ãïŒã¢ãŒã«ïŒãã©ãããã³ïŒH.J.Heller.and H.
R.BlattmannïŒïŒããŠã¢ãŒ ã¢ã³ã ã¢ãã©ã€ã
ã±ãã¹ããªãŒïŒPure and Applied
ChemistryïŒïŒ36ïŒ1973ïŒïŒ141â161åç §ã é©ãã¹ãããšã«æ¬çºæè çã¯ãäžæ¹ããã³ãŸã
ãªã¢ãŸãŒã«ãŸãã¯ããããã·ãã³ãŸããšãã³ãã
ããŠä»æ¹ãããªã¢ã«ãã«ãããªãžã³ã®ååçµåç©
ãããšãã®ïŒæåã®åèšããäºæããããããã¯
ããã«å€§ããªå å®å®åäœçšãæããããšãèŠåºã
ãããã®æ§ãªçžä¹äœçšã¯äºæž¬ãåŸãªããã®ã§ãã€
ãã ãããã€ãŠæ¬çºæã¯ãååäžã«å°ãªããšãïŒçš®
ã®ïŒâïŒ2â²âããããã·ããšãã«ïŒâãã³ãŸããª
ã¢ãŸãŒã«åºãŸãã¯å°ãªããšãïŒçš®ã®ïŒâãããã
ã·ãã³ãŸããšãã³åºãšããã«ãŸãå°ããšãïŒçš®ã®
ããªã¢ã«ãã«ãããªãžã³åºãšãåæã«æããåå
ç©ã«é¢ããç¹ã«åŒïŒ¡ãŸãã¯ïŒ¡ïŒ ïŒåŒäžã åŒïŒ¡ã«ãããã®ãã¡ã®ã²ãšã€ã¯æ°ŽçŽ ååã
è¡šããããã€ä»ã®ïŒ²ã¯èªç±åå䟡ãè¡šãããåŒïŒ¡
ã«ãããã¯èªç±åå䟡ãè¡šããã R2ã¯æ°ŽçŽ ååãççŽ ååæ°ïŒãªããïŒã®ã¢ã«
ãã«åºãããã¯ã·ã¯ãããã·ã«åºãè¡šããã䞊ã³
ã«ã R3ã¯æ°ŽçŽ ååãããã¯ççŽ ååæ°ïŒãªããïŒ
ã®ã¢ã«ãã«åºãè¡šãããïŒã§è¡šããããåºãïŒã
ããã¯ïŒåãšæ¬¡åŒïŒ¢ãããããã¯ïŒ¢
XIïŒ ïŒåŒäžã R7ã¯æ°ŽçŽ ååãã¡ãã«åºãã¢ã»ãã«åºããã
ã¯ãã³ãžã«åºãè¡šããã R9ã¯åºâCH2âCHïŒCHâCH2âãè¡šããã
䞊ã³ã« ã¯åº
ææ©ããªããŒçšã®æ°èŠå å®å®å€ã«é¢ãããã®ã§ã
ãããã®å®å®å€ã¯ãã³ãŸããªã¢ãŸãŒã«ãŸãã¯ïŒâ
ããããã·ãã³ãŸããšãã³ãšããªã¢ã«ãã«ãããª
ãžã³èªå°äœãšã®ååçµåç©ã§ããã ïŒâïŒïŒâããããã·ããšãã«ïŒâãã³ãŸããª
ã¢ãŸãŒã«ããã³ïŒâããããã·ãã³ãŸããšãã³ã
ææ©ææã®æçšãªå å®å®å€ã§ããããšã¯ç¥ãããŠ
ããããããã¯çŽ«å€ç·åžåå€ãšããŠäœçšããïŒã
ãªãã¡é«ãšãã«ã®ãŒã®å éåïŒçŽ«å€ç·ïŒããä¿è·
ãã¹ãææ©ææã«å¯ŸããŠæ害äœçšãæããªãç±ã«
å€æããã ããã«ããªã¢ã«ãã«ãããªãžã³ããŸãæçšãªå
å®å®å€ã§ããããšãç¥ãããŠããããããããªã
ãããªã¢ã«ãã«ãããªãžã³ã¯çæ³¢é·ã®å ãåžåã
ãªãããã玫å€ç·åžåå€ãšããŠã¯äœçšããªããã
ã®äœçšã®æ©æ§ã®æ確ãªè§£æã¯ãããŸã§ãªãããŠã
ãªãïŒäŸãã°ãšã€ãïŒãžãšãŒïŒãã©ãŒããã³ãšã€
ãïŒã¢ãŒã«ïŒãã©ãããã³ïŒH.J.Heller.and H.
R.BlattmannïŒïŒããŠã¢ãŒ ã¢ã³ã ã¢ãã©ã€ã
ã±ãã¹ããªãŒïŒPure and Applied
ChemistryïŒïŒ36ïŒ1973ïŒïŒ141â161åç §ã é©ãã¹ãããšã«æ¬çºæè çã¯ãäžæ¹ããã³ãŸã
ãªã¢ãŸãŒã«ãŸãã¯ããããã·ãã³ãŸããšãã³ãã
ããŠä»æ¹ãããªã¢ã«ãã«ãããªãžã³ã®ååçµåç©
ãããšãã®ïŒæåã®åèšããäºæããããããã¯
ããã«å€§ããªå å®å®åäœçšãæããããšãèŠåºã
ãããã®æ§ãªçžä¹äœçšã¯äºæž¬ãåŸãªããã®ã§ãã€
ãã ãããã€ãŠæ¬çºæã¯ãååäžã«å°ãªããšãïŒçš®
ã®ïŒâïŒ2â²âããããã·ããšãã«ïŒâãã³ãŸããª
ã¢ãŸãŒã«åºãŸãã¯å°ãªããšãïŒçš®ã®ïŒâãããã
ã·ãã³ãŸããšãã³åºãšããã«ãŸãå°ããšãïŒçš®ã®
ããªã¢ã«ãã«ãããªãžã³åºãšãåæã«æããåå
ç©ã«é¢ããç¹ã«åŒïŒ¡ãŸãã¯ïŒ¡ïŒ ïŒåŒäžã åŒïŒ¡ã«ãããã®ãã¡ã®ã²ãšã€ã¯æ°ŽçŽ ååã
è¡šããããã€ä»ã®ïŒ²ã¯èªç±åå䟡ãè¡šãããåŒïŒ¡
ã«ãããã¯èªç±åå䟡ãè¡šããã R2ã¯æ°ŽçŽ ååãççŽ ååæ°ïŒãªããïŒã®ã¢ã«
ãã«åºãããã¯ã·ã¯ãããã·ã«åºãè¡šããã䞊ã³
ã«ã R3ã¯æ°ŽçŽ ååãããã¯ççŽ ååæ°ïŒãªããïŒ
ã®ã¢ã«ãã«åºãè¡šãããïŒã§è¡šããããåºãïŒã
ããã¯ïŒåãšæ¬¡åŒïŒ¢ãããããã¯ïŒ¢
XIïŒ ïŒåŒäžã R7ã¯æ°ŽçŽ ååãã¡ãã«åºãã¢ã»ãã«åºããã
ã¯ãã³ãžã«åºãè¡šããã R9ã¯åºâCH2âCHïŒCHâCH2âãè¡šããã
䞊ã³ã« ã¯åº
ãåŒããè¡šãããïŒã§è¡šã
ãããåºã®ãã¡ã®ïŒåãå«æããåºïŒ¡ãããã¯
ãçŽæ¥çµåãŸãã¯çµååºïŒºãã¯ä»¥äžã®åºã®
ãã¡ã®ã²ãšã€ãè¡šããããšãã§ãããïŒ âCH2CH2COââïŒCH2CH2âCOâïŒR15ïŒ
âïŒâCH2CH2âCOââCH2CHïŒOHïŒCH2â
âïŒâCONHâïŒâCOâNHâCH2CH2âïŒ
âCH2CH2ââCOâCH2ââïŒâCH2CH2
âCOââCH2CH2â ïŒR15ã¯æ°ŽçŽ ååãããã¯ããã«åºãè¡šã
ããïŒãã«ããåºïŒ¢ïŒïŒ¢ïŒïŒ¢ãããã¯ïŒ¢XIã«
çµåããŠãããããŸãã¯åºïŒ¡ãåºââCH2â
COâãä»ããŠåºïŒ¢ãããã¯ïŒ¢ã«çµåããŠ
ããååç©ã«é¢ããã åºãåºã«å¯ŸããŠïŒäŸ¡ã®çµååºïŒºãä»ããŠçµ
åããŠããå Žåã¯ã次ã®æ§é ãå¯èœã§ããïŒïŒ¡â
âïŒïŒ¢ââââããã³ïŒ¡âââ
âã ãšïŒ¢ãçŽæ¥çµåã§çµåããŠããå Žåã¯ãããš
é¡äŒŒã®æ§é ãå¯èœã§ããã ãšïŒ¢ãïŒäŸ¡ã®ããªã¢ãžã³åºïŒïŒŽã§è¡šããïŒã
ä»ããŠçµåããŠããå Žåã¯ã次ã®æ§é ãå¯èœã§ã
ãïŒ
ãçŽæ¥çµåãŸãã¯çµååºïŒºãã¯ä»¥äžã®åºã®
ãã¡ã®ã²ãšã€ãè¡šããããšãã§ãããïŒ âCH2CH2COââïŒCH2CH2âCOâïŒR15ïŒ
âïŒâCH2CH2âCOââCH2CHïŒOHïŒCH2â
âïŒâCONHâïŒâCOâNHâCH2CH2âïŒ
âCH2CH2ââCOâCH2ââïŒâCH2CH2
âCOââCH2CH2â ïŒR15ã¯æ°ŽçŽ ååãããã¯ããã«åºãè¡šã
ããïŒãã«ããåºïŒ¢ïŒïŒ¢ïŒïŒ¢ãããã¯ïŒ¢XIã«
çµåããŠãããããŸãã¯åºïŒ¡ãåºââCH2â
COâãä»ããŠåºïŒ¢ãããã¯ïŒ¢ã«çµåããŠ
ããååç©ã«é¢ããã åºãåºã«å¯ŸããŠïŒäŸ¡ã®çµååºïŒºãä»ããŠçµ
åããŠããå Žåã¯ã次ã®æ§é ãå¯èœã§ããïŒïŒ¡â
âïŒïŒ¢ââââããã³ïŒ¡âââ
âã ãšïŒ¢ãçŽæ¥çµåã§çµåããŠããå Žåã¯ãããš
é¡äŒŒã®æ§é ãå¯èœã§ããã ãšïŒ¢ãïŒäŸ¡ã®ããªã¢ãžã³åºïŒïŒŽã§è¡šããïŒã
ä»ããŠçµåããŠããå Žåã¯ã次ã®æ§é ãå¯èœã§ã
ãïŒ
ãåŒããŸãã¯
ãåŒã
ã¢ã«ãã«åºãšããŠã®R2åã³R3ã¯äŸãã°ã¡ãã«
åºããšãã«åºãã€ãœãããã«åºãŸãã¯ç¬¬äžããã«
åºã§ããããã 奜ãŸããåºã¯ããŸãã¯ïŒ¢åºã§ãããã
ããã®äžã§ããR7ãæ°ŽçŽ ååãã¡ãã«åºãŸãã¯
ãã³ãžã«åºãè¡šãããã®ã奜ãŸããã 奜ãŸããçµååºââã¯æ¬¡åŒïŒ âCH2CH2COââïŒâCH2CH2âCOâ
ïŒR15ïŒâïŒâCH2CH2ââCOâCH2ââïŒ
âCH2CH2âCOââCH2CH2â ïŒåŒäžãR15ã¯åèšã®æå³ãè¡šãããïŒã§è¡šã
ãããåºã§ããã æ¬çºæã®ååç©ã®äŸãšããŠäžèšã®åŒã§è¡šããã
ãååç©ããããããïŒ ïŒR7ïŒæ°ŽçŽ ååãã¡ãã«åºããã³ãžã«åºãŸã
ã¯ã¢ã»ãã«åºïŒ ïŒR7ïŒæ°ŽçŽ ååãâ ãããã«åºãŸãã¯ã¢ãª
ã«åºïŒ ïŒR7ïŒæ°ŽçŽ ååãŸãã¯ã¡ãã«åºïŒ ïŒR7ïŒæ°ŽçŽ ååãŸãã¯ã¡ãã«åºïŒ æ¬çºæã®ååç©ã補é ããããã«äœ¿çšããåºçº
ç©è³ªã¯åŒïŒ¡ãŸãã¯ïŒ¡ã«ãããŠãå°ããšãïŒã€
ã®ïŒ²ã¯å®èœæ§ããªã¢ã«ãã«ãããªãžã³èªå°äœãšå
å¿ãããå®èœåºã§ããååç©ã§ããã åºãäŸãã°ãã«ã«ãã³é žåºïŒâCOOHãâ
CH2CH2COOHãŸãã¯âOCH2COOHãããã¯äœ
çŽã¢ã«ãã«ãšã¹ãã«ãŸãã¯ãã®é žå¡©åç©ã§ããå Ž
åã¯ããã®ãããªååç©ïŒ¡ãŸãã¯ïŒ¡ã¯å®èœæ§
æ°Žé žåºãŸãã¯ã¢ããåºäŸãã°ãâOHåºãâ
CH2CH2OHåºãâNH2åºãâCH2NH2åºãŸãã¯
âCH2CH2NH2åºãæããããªã¢ã«ãã«ãããª
ãžã³ååç©ãšåå¿ãããããšãã§ããã åºãã¢ããåºãäŸãã°âNH2åºãâ
CH2NH2åºãŸãã¯âCH2CH2NH2åºã§ããå Žå
ã¯ããã®ãããªååç©ïŒ¡ãŸãã¯ïŒ¡ã¯ãã«ã«ã
ãã·ã«åºãŸãã¯ããããèªå°ãããåºãäŸãã°ã¢
ã«ã³ãã·ã«ã«ããã«åºãŸãã¯ã¯ããã«ã«ããã«åº
ãæããããªã¢ã«ãã«ãããªãžã³ååç©ãšåå¿ã
ããããšãã§ããã ã©ã¡ãã®å Žåã«ãããŠããšã¹ãã«ãŸãã¯ã¢ãã
ã圢æããããã®åå¿ã¯ãšã¹ãã«åãŸãã¯ã¢ãã
åã®æ £çšæ¹æ³ã§è¡ãªãããã ïŒçš®ã®æåã®ãã¡äžæ¹ããšããã·ã¢ã«ãã«åºã
æããä»æ¹ã®æåãâOHåºãŸãã¯âNHåºãæ
ããå Žåã¯ããšãŒãã«åºãŸãã¯ã¢ãã³åºãæãã
çµååºã圢æãããã çµååºãããªã¢ãžã³åºã§ããååç©ã¯ããžã¯ã
ãããªã¢ãžã³ãŸãã¯å¡©åã·ã¢ãã«ãšïœïŒïŒ¡ãŸã
ã¯ïŒ¡ã§è¡šããããååç©ã®OHãŸãã¯NHèªå°
äœããã³ïœïŒããªã¢ã«ãã«ãããªãžã³ã®OHãŸã
ã¯NHèªå°äœãšã®æ®µéåå¿ã«ãã補é ãããã å¡©åã·ã¢ãã«ã®åå¿ã®å Žåã«ã¯ãå¡©åã·ã¢ãã«
ã¯ïŒ¡èªå°äœïŒåœéããã³ïŒ¢èªå°äœïŒåœéãšåå¿ã
ãããããŸãã¯ïŒ¡èªå°äœïŒåœéããã³ïŒ¢èªå°äœïŒ
åœéãšåå¿ãããããšãã§ãããããããªããã
å¡©åã·ã¢ãã«ãèªå°äœïŒåœéããã³ïŒ¢èªå°äœïŒ
åœéãšåå¿ãããæ®ãã®å¡©çŽ ååãã¢ãã³ãã¢ã«
ã³ãŒã«ãŸãã¯ããšããŒã«ãšåå¿ãããããšããŸã
å¯èœã§ããã ãã®åå¿ã«å¿ èŠãªã¿ã€ãããã³ã¿ã€ãã®å®
èœæ§èªå°äœã¯å ¬ç¥ã®ååç©ã§ããã ãããã€ãŠãäŸãã°ãã®ã«ã«ããã·ã«èªå°
äœã¯ç±³åœç¹èš±ç¬¬3766205å·æ现æžã«èšèŒãããŠã
ããã®ã¢ãã³èªå°äœã¯ç±³åœç¹èš±ç¬¬3159646å·
æ现æžã«èšèŒãããŠãããã®ã«ã«ããã·ã«ãŸ
ãã¯ã¢ããèªå°äœã¯ç±³åœç¹èš±ç¬¬2983708å·ã第
3208865å·ãŸãã¯ç¬¬3380961å·æ现æžã«èšèŒãããŠ
ããã ããªã¢ã«ãã«ãããªãžã³ã®ããããã·èªå°äœ
ã¯ãäŸãã°ããã€ãç¹èš±å ¬éå ¬å ±ç¬¬2352658å·ã
第2353538å·ããã³ç¬¬2402636å·ã«èšèŒãããŠã
ããçžåœããã¢ããèªå°äœã¯ãäŸãã°ããã€ãç¹
èš±å ¬éå ¬å ±ç¬¬2040975å·ããã³ç¬¬2352379å·ã«èšèŒ
ãããŠããã ã¿ã€ãã®ã«ã«ããã·ã«èªå°äœã¯ãäŸãã°ãã
ã€ãç¹èš±å ¬éå ¬å ±ç¬¬2337865å·ããã³ç¬¬2719133å·
ã«èšèŒãããŠããã åºãåºã«çŽæ¥çµåã§çµåããŠããååç©
ã¯ãç¹å¥ãªæ¹æ³ã§è£œé ããããããªãã¡ãäŸã
ã°ãïŒâïŒ4â²âããããã·ããšãã«ïŒâïŒïŒïŒïŒ
ïŒïŒïŒâããã©ã¡ãã«ãããªãžã³ãšïœâãããã
ãšãã«âãžã¢ãŸããŠã ååç©ãã«ãããªã³ã°ãã
ãŠçžåœããïœâãããã¢ãŸååç©ãåŸããããå ¬
ç¥ã®éå æ³ã«ããçžåœãããã³ãŸããªã¢ãŸãŒã«ã«
å€æããããšãã§ããããã®æ¹æ³ã«å¿ èŠãªããã
ãã·ããšãã«ãããªãžã³ã¯ããã€ãç¹èš±å ¬éå ¬å ±
第2258086å·ã«èšèŒãããŠããã æ¬çºæã®ååç©ã®è£œé ã«é¢ããæŽã«è©³çŽ°ãªèª¬æ
ã¯ãäžèšã®å®æœäŸäžã§è¡ãªãã æ¬çºæã®æ°èŠååç©ã¯ãå ã®äœçšã«å¯ŸããŠæå
æ§ãæããææ©ææãç¹ã«ææ©ããªããŒçšã®é¡è
ãªå å®å®å€ã§ãããç¹ã«æ¬çºæã®ååç©ã¯ãçæ³¢
é·ã®å ïŒçŽ«å€ç·ïŒã«å¯Ÿãã匷åãªä¿è·äœçšãæã
ãããšãç¹åŸŽãšããã 以äžã«åèšãããã®ã¯ãæ¬çºæã®ååç©ãæ·»å
ããããšã«ãã€ãŠå®å®åãããããªããŒã®äŸã§ã
ãïŒ ïŒ ã¢ããŒããã³ãžâãªã¬ãã€ã³ã®ããªããŒãäŸ
ãã°ããªãšãã¬ã³ïŒæ¶æ©ãããŠãè¯ããïŒãããª
ãããã¬ã³ãããªã€ãœããã¬ã³ãããªã¡ãã«ã
ãâïŒâãšã³ãããªã¡ãã«ãã³ãâïŒâãšã³ã
ããªã€ãœãã¬ã³ãŸãã¯ããªãã¿ãžãšã³ã ïŒ ïŒïŒã«ãããããªããŒã®æ··åç©ãäŸãã°ããª
ãããã¬ã³ãšããªãšãã¬ã³ãŸãã¯ããªã€ãœãã
ã¬ã³ãšã®æ··åç©ããããã¯äŸãã°ç°ãªãå¯åºŠãŸ
ãã¯ç°ãªãã¡ã«ãã€ã³ããã¯ã¹ãæããïŒçš®ã®
ããªãšãã¬ã³ã®æ··åç©ã ïŒ ã¢ããŒããã³ãžâãªã¬ãã€ã³ã®ã³ããªããŒã
äŸãã°ãšãã¬ã³ïŒãããã¬ã³ ã³ããªããŒãã
ããã¬ã³ïŒããâïŒâãšã³ ã³ããªããŒããã
ãã¬ã³ïŒã€ãœããã¬ã³ ã³ããªããŒããšãã¬
ã³ïŒããâïŒâãšã³ ã³ããªããŒããã«ãŸããš
ãã¬ã³ãšãããã¬ã³ããã³ãããµãžãšã³ããžã·
ã¯ããã³ã¿ãžãšã³ãŸãã¯ãšããªãã³ãã«ãã«ã
ã³çã®ãžãšã³ãšã®ã¿ãŒããªããŒã ïŒ ããªã¹ãã¬ã³ã ïŒ ã¹ãã¬ã³ãŸãã¯Î±âã¡ãã«ã¹ãã¬ã³ãšãžãšã³
ãŸãã¯ã¢ã¯ãªã«èªå°äœãšã®ã³ããªããŒãäŸãã°
ã¹ãã¬ã³ïŒãã¿ãžãšã³ãã¹ãã¬ã³ïŒã¢ã¯ãªãã
ããªã«ãŸãã¯ã¹ãã¬ã³ïŒã¢ã¯ãªã«ãããªã«ïŒã¢
ã¯ãªã«é žã¡ãã«ïŒã¹ãã¬ã³ã³ããªããŒããã³ä»
ã®ããªããŒããåŸãããèè¡ææ§æš¹èæ··åç©ã
äŸãã°ããªã¢ã¯ãªã¬ãŒãããžãšã³ããªããŒãŸã
ã¯ãšãã¬ã³ïŒãããã¬ã³ïŒãžãšã³ ã¿ãŒããªã
ãŒïŒããã«ãŸãã¹ãã¬ã³ã®ãããã¯ã³ããªã
ãŒãäŸãã°ã¹ãã¬ã³ïŒãã¿ãžãšã³ïŒã¹ãã¬ã³ã
ã¹ãã¬ã³ïŒã€ãœãã¬ã³ïŒã¹ãã¬ã³ãŸãã¯ã¹ãã¬
ã³ïŒãšãã¬ã³âããã¬ã³ïŒã¹ãã¬ã³ã ïŒ ã¹ãã¬ã³ã®ã°ã©ããã³ããªããŒãäŸãã°ã¹ã
ã¬ã³ã®çµåããããªãã¿ãžãšã³ãã¹ãã¬ã³ãã
ã³ã¢ã¯ãªããããªã«ã®çµåããããªãã¿ãžãšã³
ããã³ããããšïŒïŒã«ãããã³ããªããŒãšã®
ABSããªããŒãšããŠç¥ãããæ··åæš¹æã ïŒ ããã²ã³å«æããªããŒãäŸãã°ããªå¡©åãã
ã«ãããªå¡©åãããªãã³ãããªåŒåããã«ãã
ãªã¯ãããã¬ã³ãå¡©åãŽã ããã³ã³ããªããŒã
äŸãã°å¡©åããã«ïŒå¡©åãããªãã³ãå¡©åãã
ã«ïŒå¡©é žããã«ãŸãã¯å¡©åãããªãã³ïŒé ¢é žã
ãã«ã®ã³ããªããŒã ïŒ Î±ïŒÎ²âäžé£œåé žããã³ãã®èªå°äœããèªå°
ãããããªããŒãäŸãã°ããªã¢ã¯ãªã¬ãŒããã
ã³ããªã¡ã¿ã¢ã¯ãªã¬ãŒããããªã¢ã¯ãªã«ã¢ãã
ããã³ããªã¢ã¯ãªããããªã«ã ïŒ äžé£œåã¢ã«ã³ãŒã«ããã³ã¢ãã³ãããã¯ãã
çã®ã¢ã·ã«èªå°äœãŸãã¯ã¢ã»ã¿ãŒã«ããèªå°ã
ããããªããŒãäŸãã°ãããªããã«ã¢ã«ã³ãŒ
ã«ãããªé ¢é žããã«ãããªã¹ãã¢ãªã³é žãã
ã«ãããªããã«ãã³ãŸãšãŒããããªããã«ãã¬
ãšãŒããããªããã«ããã¬ãŒããããªã¢ãªã«ã
ã¿ã¬ãŒããããªã¢ãªã«ã¡ã©ãã³ããã³ããããš
ä»ã®ããã«ååç©ãšã®ã³ããªããŒãäŸãã°ãšã
ã¬ã³ïŒé ¢é žããã« ã³ããªããŒã 10 ãšããã·ãã®ãã¢ããªããŒããã³ã³ããªã
ãŒãäŸãã°ããªãšãã¬ã³ãªãã·ããããªããã
ã¬ã³ãªãã·ããŸãã¯ããããšãã¹ãŒã°ãªã·ãžã«
ãšãŒãã«ãšã®ã³ããªããŒã 11 ããªã¢ã»ã¿ãŒã«ãäŸãã°ããªãªãã·ã¡ãã¬ã³
ããã«ãŸããšãã¬ã³ãªãã·ããã³ã¢ãããŒãšã
ãŠå«ãããªãªãã·ã¡ãã¬ã³ã 12 ããªããšãã¬ã³ãªãã·ãã 13 ããªãŠã¬ã¿ã³ããã³ããªãŠã¬ã¢ã 14 ããªã«ãŒãããŒãã 15 ããªã¹ã«ãã³ã 16 ãžã¢ãã³ããã³ãžã«ã«ãã³é žããã³ïŒãŸãã¯
ã¢ããã«ã«ãã³é žãŸãã¯çžåœããã©ã¯ã¿ã ãã
èªå°ãããããªã¢ããããã³ã³ããªã¢ãããäŸ
ãã°ããªã¢ããïŒãããªã¢ãã6/6ãããªã¢ã
ã6/10ãããªã¢ãã11ããã³ããªã¢ãã12ã 17 ãžã«ã«ãã³é žããã³ãžã¢ã«ã³ãŒã«ããã³ïŒãŸ
ãã¯ããããã·ã«ã«ãã³é žãŸãã¯çžåœããã©ã¯
ãã³ããèªå°ãããããªãšã¹ãã«ãäŸãã°ããª
ãšãã¬ã³ãã¬ãã¿ã¬ãŒããããªããã¬ã³ãã¬ã
ã¿ã¬ãŒããããã³ããªâïŒïŒïŒâãžã¡ãããŒã«
ã·ã¯ããããµã³ãã¬ãã¿ã¬ãŒãããã³ã³ããªãš
ãŒãã«âãšã¹ãã«ã 18 äžæ¹ã§ã¢ã«ããããä»æ¹ã§ããšããŒã«ãå°¿çŽ
ããã³ã¡ã©ãã³ããèªå°ãããæ¶æ©ããªããŒã
äŸãã°ããšããŒã«âãã«ã ã¢ã«ãããæš¹èãå°¿
çŽ âãã«ã ã¢ã«ãããæš¹èããã³ã¡ã©ãã³âã
ã«ã ã¢ã«ãããæš¹èã 19 ã¢ã«ãããæš¹èãäŸãã°ã°ãªã»ããŒã«ïŒãã¿
ã«é žæš¹èããã³ãã®ã¡ã©ãã³âãã«ã ã¢ã«ãã
ãæš¹èãšã®æ··åç©ã 20 飜åããã³äžé£œåãžã«ã«ãã³é žãšå€äŸ¡ã¢ã«ã³
ãŒã«ãšã®ããã«ååç©ãæ¶æ©å€ãšããã³ããªãš
ã¹ãã«ããèªå°ããããäžé£œåããªãšã¹ãã«æš¹
èããã³ããã«ãã®ããã²ã³ååãå«ãé£çæ§
ã®å€æ§æš¹èã 21 ããªãšããã·ããäŸãã°ãã¹ãŒã°ãªã·ãžã«ãš
ãŒãã«ãŸãã¯èç°åŒãžãšããã·ãããèªå°ãã
ãæ¶æ©ãšããã·ãæš¹èã 22 倩ç¶ã®ããªããŒãäŸãã°ã»ã«ããŒã¹ããŽã ã
ãã³èçœè³ªãªãã³ã«ããçãéååæäœãšããŠ
ååŠå€æ§ããèªå°äœãäŸãã°é ¢é žã»ã«ããŒã¹ã
ããããªã³é žã»ã«ããŒã¹ããã³ã»ã«ããŒã¹ãã
ã¬ãŒããªãã³ã«ã¡ãã«ã»ã«ããŒã¹ã®æ§ãªã»ã«ã
ãŒã¹ãšãŒãã«ã ãããã®ããªããŒäžãç¹ã«éèŠãªãã®ã¯ã©ãã«
ãŒãç¹ã«çŒä»ã©ãã«ãŒã®çµåå€ãšããŠäœ¿çšããã
ãã®ãäŸãã°äžèšãªã¹ãäž18ïŒ19ïŒ20ããã³21ã®
ã°ã«ãŒãã«å±ãããã®ã§ããã æ¬çºæè çã¯ã©ãã«ãŒäžã§ã¯ãããªãžã³å å®å®
å€ãšçŽ«å€ç·åžåå€ãšã®çµåç©ãéåžžã«æçšã§ãã
ããšãèŠåºãããçŒä»ã©ãã«ãŒã®å Žåã«ã¯ããã³
ãŸããªã¢ãŸãŒã«ããã³ãŸããšãã³ããã³ããªã¢ã«
ãã«ãããªãžã³ãããŒã¹ãšããæ £çšã®äœååéå
å®å®å€ã®æ®çºæ§ã¯é倧ãªæè¡äžã®åé¡ãã²ããã
ããæ¬çºæã«ãã€ãŠç°ãªãçš®é¡ã®å å®å®å€ãååŠ
çã«çµåããããšã«ãããäžèšæ®çºæ§ã¯å€§å·Ÿã«æž
å°ããããããã®æ°èŠååç©ã¯çŒä»ã©ãã«ãŒãå®
å®åããããã«ãé©ããã æ¬çºæã®ååç©ã¯ãããªããŒäžã«0.05ãªããïŒ
ééïŒ ã奜ãŸããã¯0.1ãªããïŒééïŒ ã®éã§æ·»
å ããã æ¬çºæã®å å®å®å€ã¯ãããªããŒã®æ圢åã«åŸ®ç²
ç ããªããŒãšæ··åããããããªããŒãŸãã¯ãã®å
é§ç©è³ªã®æº¶èç©ãŸãã¯æº¶æ¶²ãšæ··åããããšã«ãã
ããªããŒäžã«æ·»å ããããã©ã¹ããã¯ç£æ¥ã«ãã
ãå ¬ç¥ãã€æ £çšã®ä»ã®æ·»å å€ãåæã«ããªããŒã«
æ·»å ããããšãå¯èœã§ããããããã®æ·»å å€ã¯ã
äŸãã°ãé žåé²æ¢å€ãéå±äžæŽ»æ§åå€ãä»ã®å®å®
å€ãå¯å¡å€ãæ»å€ãçºæ³¡å€ãé¡æãå å¡«å€ãŸãã¯
ä»ã®å©å€ã§ããããããã®ãããªå ¬ç¥ãã€æ £çšã®
ãã©ã¹ããã¯çšæ·»å å€ã®åã ã®äŸã¯ããã€ãç¹èš±
å ¬éå ¬å ±ç¬¬2349962å·ç¬¬25ã32é ã«åèšãããŠã
ãã ãã®ããã«ããŠå®å®åãããããªããŒã¯éåžžã«
çš®ã ã®åœ¢æ ã§ãäŸãã°ãã€ã«ã ããã¢ã€ããŒãã
ãŒããŸãã¯åœ¢æãšããŠãããã¯ã©ãã«ãŒãæ¥çå€
ãŸãã¯ããã®çµåå€ãšããŠäœ¿çšã§ããã æ¬çºæã®ååç©ã®è£œé ããã³äœ¿çšã«ã€ããŠä»¥äž
ã®å®æœäŸã§èª¬æãããå®æœäŸäžãéšããã³ããŒã»
ã³ãã¯éééšããã³ééïŒ ãè¡šããã枩床ã¯âã
è¡šããã å®æœäŸ ïŒ ïŒâïŒïŒâããããã·âïŒâã¡ãã«âïŒâβâ
ã¡ããã·ã«ã«ããã«âãšãã«âããšãã«ïŒâãã³
ãŸããªã¢ãŸãŒã«ïŒç±³åœç¹èš±ç¬¬3766205å·ã«åŸã€ãŠ
補é ããïŒ46.7ïœããïŒïŒïŒïŒïŒïŒïŒâããã©ã¡
ãã«âïŒâããããã·âãããªãžã³23.6ïœããã³
ãããªãŠã ã¡ããã·ãïŒïœãšãšãã«ããã·ã¬ã³
300mläžã«ãŠç©ãããªçªçŽ æ°æµãéããªããã130
ã135ãã§20æéå ç±ãããçæããã¡ã¿ããŒã«ã¯
é£ç¶çã«çå»ãããåå¿æ··åç©ã宀枩ãŸã§å·åŽ
ããé ¢é žã§é žæ§åããåå100mlã®æ°Žã§ïŒåæœåº
ãããæ°Žæ§æœåºæ¶²ãäžç·ã«ããŠã¢ã³ã¢ãã¢ã§ã¢ã«
ã«ãªæ§ãšããåŸãããæ²æŸ±ãæ¿ŸéããŠéããæ°ŽæŽ
ãã也ç¥ããŠãªã°ãã€ã³ããçµæ¶åãããããã«
ããïŒâïœïŒâããããã·âïŒâã¡ãã«âïŒâ
ãβâïŒïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã
ããªãžãã«ãªãã·ã«ã«ããã«ïŒâãšãã«ãâããš
ãã«ïœâãã³ãŸããªã¢ãŸãŒã«ïŒååç©ïŒïŒãèç¹
131ãã®å®è³ªçã«ç¡è²ç²æ«ã®åœ¢ã§åŸãããã ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãããã
ã·ãããªãžã³ã®ä»£ãã«åœéã®ïŒïŒïŒïŒïŒïŒïŒïŒ
ïŒïŒâãã³ã¿ã¡ãã«âïŒâããããã·ãããªãžã³
ãŸãã¯åœéã®ïŒâãã³ãžã«âïŒïŒïŒïŒïŒïŒïŒâã
ãã©ã¡ãã«âïŒâããããã·ãããªãžã³ã䜿çš
ãããã以å€ã®ç¹ã¯äžèšã®æ¹æ³ã©ããã«è¡ãªã
ã°ãããããèç¹110ã111ãã®ïŒâïœïŒâããã
ãã·âïŒâã¡ãã«âïŒâãβâïŒïŒïŒïŒïŒïŒïŒ
ïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâãããªãžãã«ãªã
ã·âã«ã«ããã«ïŒâãšãã«ãâããšãã«ïœâãã³
ãŸããªã¢ãŸãŒã«ïŒååç©ïŒïŒãŸãã¯èç¹127ã
128ãã®ïŒâïœïŒâããããã·âïŒâã¡ãã«âïŒâ
ãβâïŒïŒâãã³ãžã«âïŒïŒïŒïŒïŒïŒïŒâããã©
ã¡ãã«âïŒâãããªãžãã«âãªãã·ã«ã«ããã«ïŒ
âãšãã«ãâããšãã«ïœâãã³ãŸããªã¢ãŸãŒã«
ïŒååç©ïŒïŒãåŸãããã å®æœäŸ ïŒ ïŒâïŒïŒâããããã·âïŒïŒïŒâãžâ第äžãã
ã«âããšãã«ïŒâãã³ãŸããªã¢ãŸãŒã«âïŒâã«ã«
ãã³é žã¯ãã©ã€ã23.1ïœãå ãã宀枩ã§ãã«ãšã³
300mläžã«æ·»å ããããã®æº¶æ¶²ã«ãã«ãšã³100mläž
ã®ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã¢ããã
ããªãžã³10.1ïœã®æº¶æ¶²ãçŽ30åãããŠæ»Žå ãã次
ãã§åå¿æ··åç©ã宀枩ã§15æéæ¹æãããæ²æ®¿ã
ãå¡©é žå¡©ãæ¿ŸéããŠéãããšã¿ããŒã«200mlãã
ã³æ°Ž200mläžã®æº¶è§£ãããçé žãããªãŠã ã§æº¶æ¶²
ãã¢ã«ã«ãªæ§ãšããåŸãããæ²æ®¿ãæ¿ŸéããŠé
ããæ°ŽæŽãã也ç¥ããŠãã«ãšã³ããçµæ¶åããã
ããã«ããèç¹267ãã®ïŒâïŒïŒâããããã·â
ïŒïŒïŒâãžâ第äžããã«âããšãã«ïŒâãã³ãŸã
ãªã¢ãŸãŒã«âïŒâã«ã«ãã³é žïŒ®âïŒïŒïŒïŒïŒïŒïŒ
ïŒâããã©ã¡ãã«âïŒâãããªãžãã«ïŒâã¢ãã
ïŒååç©ïŒïŒãåŸãããã ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã¢ããã
ããªãžã³ã®ä»£ãã«åœéã®ïŒïŒïŒïŒïŒïŒïŒâããã©
ã¡ãã«âïŒâβâã¢ãããšãã«âãããªãžã³ã䜿
çšãããã以å€ã¯äžèšæ¹æ³ã©ããã«è¡ãªãã°ãè
ç¹228ãã®ïŒâïŒïŒâããããã·âïŒïŒïŒâãžâ第
äžããã«âããšãã«ïŒâãã³ãŸããªã¢ãŸãŒã«âïŒ
âã«ã«ãã³é žïŒ®âãβâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ã¡ãã«âïŒâãããªãžãã«ïŒâãšãã«ãâã¢ã
ãïŒååç©ïŒïŒãåŸãããã å®æœäŸ ïŒ ïŒâããããã·âïŒâã¡ããã·ã«ã«ããã«âã¡
ããã·âãã³ãŸããšãã³57.2ïœãïŒïŒïŒïŒïŒïŒ
ïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâããããã·ãããª
ãžã³36ïœããã³ãããªãŠã ã¡ããã·ã15ïœãšãšã
ã«ããã·ã¬ã³250mläžã«ãŠç©ãããªçªçŽ æ°æµãé
ããªããã130ã135ãã§ïŒæéå ç±ãããçæã
ãã¡ã¿ããŒã«ã¯ãšã¹ãã«äº€æåå¿ã®éãé£ç¶çã«
çå»ããã宀枩ãŸã§å·åŽããåŸãåå¿æ··åç©ãé ¢
é žã§é žæ§åãã次ãã§åå100mlã®æ°Žã§ïŒåæœåº
ãããæ°Žæ§æœåºæ¶²ãäžç·ã«ããŠã¢ã³ã¢ãã¢ã§ã¢ã«
ã«ãªæ§ãšããæ²æ®¿ãæ¿ŸéããŠéããæ°ŽæŽãã也ç¥
ããŠãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ãã
åçµæ¶ãããããã«ããèç¹79ãã®ïŒâãããã
ã·âïŒâïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«
âïŒâãããªãžãã«ãªãã·ã«ã«ããã«âã¡ãã
ã·ïŒâãã³ãŸããšãã³ïŒååç©ïŒïŒãåŸãããã å®æœäŸ ïŒ ïœâãããã¢ããªã³12.5ïœãå ¬ç¥ã®æ¹æ³ã§ãžã¢
ãŸåããåŸããããžã¢ãŸããŠã 塩溶液ããæ°Ž100
mlããã³æ°Žé žåãããªãŠã ïŒïœäžã®ïŒïŒïŒïŒïŒïŒ
ïŒâããã©ã¡ãã«âïŒâïŒ4â²âããããã·ããšã
ã«ïŒâãããªãžã³16.3ïœã®æº¶æ¶²äžã«ïŒã5ãããã³
PH10ã12ã«ãŠæ»Žå ãããã«ãããªã³ã°åå¿çµäº
åŸãåå¿æ··åç©ã®PHãé ¢é žã§ïŒã«èª¿æŽããã¢ãŸæ
æãæ¿ŸéããŠéããã50ãã§ç空也ç¥ããåŸãã¢
ãŸææïŒ19.1ïœïŒããšãã¬ã³ã°ãªã³ãŒã« ã¢ãã¡
ãã«ãšãŒãã«50mläžã«æº¶è§£ããããã®æº¶æ¶²ã«æ°Ž20
mläžã®æ°Žé žåãããªãŠã ïŒïœã®æº¶æ¶²ãå ããæ··å
ç©ã80ãã«å æž©ãããããã©ãžã³æ°Žåç©2.5ïœãã
ã®æž©åºŠã§çŽ15åãããŠæ»Žå ãã次ãã§åå¿æ··åç©
ã80ãã§ããã«ïŒæéæ¹æããããã®éã«åå¿æ··
åç©ã®è²ã¯çŽ«è²ããè¶è²ã«å€åãããæ··åç©ã宀
æž©ãŸã§å·åŽããäºéæ«6.5ïœãçŽ30åãããŠäœåºŠ
ãã«ãããŠå ããã次ãã§åå¿æ··åç©ã60ãã«å
æž©ããäºéæ«ããã«6.5ïœããã³10Næ°Žé žåãã
ãªãŠã 溶液25mlãå ããåŸãããæ··åç©ãããã«
ïŒæéæ¹æãããæ·¡ç·è²ã®åå¿æ··åç©ãæ¿ŸéããŠ
äºéã®ã¹ã©ããžãé€ããæ°·é ¢é žçŽ70mlãåŸã ã«æ¿Ÿ
液ïŒPHãïŒïŒãå ããŠãåŸããã溶液ãéæå
ãã次ãã§ã¢ã³ã¢ãã¢ã§ã¢ã«ã«ãªæ§ã«ãããåŸã
ããæ²æ®¿ãæ¿ŸéããŠéããæ°ŽæŽãã也ç¥ããŠãªã°
ãã€ã³ããçµæ¶åãããããã«ããèç¹178ã
180ãã®ïŒâãïŒâããããã·âïŒâïŒïŒïŒïŒïŒ
ïŒïŒïŒâããã©ã¡ãã«ãããªãžã³âïŒâã€ã«ïŒâ
ããšãã«ãâãã³ãŸããªã¢ãŸãŒã«ïŒååç©ïŒïŒã
åŸãããã ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâïŒ4â²âã
ãããã·ããšãã«ïŒâãããªãžã³ã®ä»£ãã«åœéã®
ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâïŒ3â²âã¡ã
ã«â4â²âããããã·ããšãã«ïŒâãããªãžã³ã
ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâïŒ3â²â第äž
ããã«â4â²âããããã·ããšãã«ïŒâãããªãž
ã³ãïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâïŒ3â²â
ã·ã¯ãããã·ã«â4â²âããããã·ããšãã«ïŒâã
ããªãžã³ãŸãã¯ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«â
ïŒâïŒïŒâããããã·â5â²âã¡ãã«âããšãã«ïŒ
âãããªãžã³ã䜿çšãããã以å€ã¯äžèšã®æ¹æ³ã©
ããè¡ãªãã°ãèç¹219â220ãã®ïŒâãïŒâãã
ããã·âïŒâã¡ãã«âïŒâïŒïŒïŒïŒïŒïŒïŒïŒâã
ãã©ã¡ãã«ãããªãžã³âïŒâã€ã«ïŒâããšãã«ã
ãã³ãŸããªã¢ãŸãŒã«ïŒååç©ïŒïŒãèç¹162ã164ã
ã®ïŒâãïŒâããããã·âïŒâ第äžããã«âïŒâ
ïŒïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«ãããªãžã³âïŒ
âã€ã«ïŒâããšãã«ãâãã³ãŸããªã¢ãŸãŒã«ïŒå
åç©ïŒïŒãèç¹155â156ãã®ïŒâïŒïŒâããããã·
âïŒâã·ã¯ãããã·ã«âïŒâïŒïŒïŒïŒïŒïŒïŒïŒâ
ããã©ã¡ãã«ãããªãžã³âïŒâã€ã«ïŒâããšã
ã«ãâãã³ãŸããªã¢ãŸãŒã«ïŒååç©10ïŒãŸãã¯è
ç¹168ã169ãã®ïŒâãïŒâããããã·âïŒâïŒïŒïŒ
ïŒïŒïŒïŒïŒâããã©ã¡ãã«ãããªãžã³âïŒâã€
ã«ïŒâïŒâã¡ãã«âããšãã«ããã³ãŸããªã¢ãŸãŒ
ã«ïŒååç©11ïŒã倫ã åŸãããã å®æœäŸ ïŒ ïŒâãïŒâããããã·âïŒâã¡ãã«âïŒâ
ïŒïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«ãããªãžã³âïŒ
âã€ã«ïŒâããšãã«ãâãã³ãŸããªã¢ãŸãŒã«ïŒå
åç©ïŒïŒ20ïœãè»é žïŒ98ïŒ ïŒ150mläžã«æº¶è§£ããã
次ãã§35ïŒ ãã«ã ã¢ã«ããã溶液87.4mlã宀枩ã§
çŽïŒæéãããŠæ»Žå ããã次ãã§ãã®æããè¶è²
ããã€ã溶液ãéæµäžã«20æéå ç±ãã宀枩ãŸã§
å·åŽããå·åŽãã飜åçé žã«ãªãŠã 溶液äžã«æ»Žå
ãããçœè²çµæ¶æ²æ®¿ãæ¿ŸéããŠéããæ°ŽæŽãã也
ç¥ããŠãªã°ãã€ã³ããåçµæ¶ãããããã«ããã
èç¹206ã207ãã®ïŒâãïŒâããããã·âïŒâã¡
ãã«âïŒâïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«
âãããªãžã³âïŒâã€ã«ïŒâããšãã«ãâãã³ãŸ
ããªã¢ãŸãŒã«ïŒååç©12ïŒãåŸãããã å®æœäŸ ïŒ ïŒâïŒïŒâããããã·âïŒâã¡ãã«âïŒâβâ
ã¡ããã·âã«ã«ããã«âãšãã«âããšãã«ïŒâã
ã³ãŸããªã¢ãŸãŒã«130.7ïœããã³ïŒïŒïŒâãã¹â
ïŒïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãããã
ã·ãããªãžã³âïŒâã€ã«ïŒâããâïŒâãšã³73.3
ïœããã·ã¬ã³600mläžã«ãŠããªã«ããã¿ã³é žãã
ã©ããã«1.0ïœãå ããåŸãç©ãããªçªçŽ æ°æµã
éããªãã130ã135ãã§24æéå ç±ãããçæã
ãã¡ã¿ããŒã«ã¯é£ç¶çã«çå»ããããã®åŸãªã«ã
ãã¿ã³é žããã©ããã«1.0ïœãå ãããšã¹ãã«äº€
æåå¿ã130ã135ãã§ããã«24æéè¡ãªã€ããã
ã·ã¬ã³ãå åã«çå»ããæ®æž£ããªã°ãã€ã³ããïŒ
ååçµæ¶ãããããã«ããäžèšã®æ§é åŒã§è¡šãã
ãããžãšã¹ãã«ïŒååç©13ïŒãèç¹135ãã®å®è³ªç
ã«ç¡è²ã®çµæ¶ãšããŠåŸãããã å®æœäŸ ïŒ ïŒâããããã·âïŒâã¡ããã·ã«ã«ããã«âã¡
ããã·âãã³ãŸããšãã³30.0ïœããïŒâãããã
ã·ãšãã«âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâ
ããããã·ãããªãžã³10.0ïœããã³ãªã«ããã¿ã³
é žããã©ããã«0.5ïœãšãšãã«ããã·ã¬ã³200mläž
ã«ãŠãç©ãããªçªçŽ æ°æµãéããªãã130ã135ã
ã§15æéå ç±ãããçæããã¡ã¿ããŒã«ã¯ãšã¹ã
ã«äº€æåå¿ã®éãé£ç¶çã«çå»ãããããã«ãªã«
ããã¿ã³é žããã©ããã«0.5ïœéãå ããåŸããš
ã¹ãã«äº€æåå¿ãããã«15æéç¶ãããåå¿æº¶æ¶²
ãéæåããèžçºãããæ®æž£ããã«ãšã³ïŒãããµ
ã³ããåçµæ¶ãããããã«ããäžèšæ§æåŒã§è¡šã
ããããžãšã¹ãã«ïŒååç©14ïŒãèç¹130ãã®é»è²
ããã€ãçµæ¶ãšããŠåŸãããã å®æœäŸïŒïŒäºå±€éå±ã©ãã«ãŒã®å å®å®å ïŒ é å ïœ åºæ¬ã©ãã«ãŒïŒçè²ãããã®ïŒ  1850ã®ããªãšã¹ãã«ããã€ãããã ããŒ
ãã«ïŒDynamit NobelïŒç€Ÿãããã€ã¹ãã«ã
ïŒTroisdorfïŒã西ãã€ãã 54.4ïœ ããã¬ããŒã«ïŒMaprenalïŒMF650ã¡ã©ãã³æš¹
èãã«ã»ã©ãŒããã¹ãïŒCassellaâHoechstïŒ
瀟ããŽã€ãŒã¹ããŒãã³ïŒWiesbadenïŒã西ãã€
ãã 5.5ïœ ãã«ãšã³ 3.7ïœ ïœâãã¿ããŒã« 2.8ïœ é ¢é žããã« 3.7ïœ ã¢ã«ã³ã¢ïŒAlcoaïŒ726ãã¢ã«ã³ã¢ïŒAlcoaïŒ
瀟ããã€ã³æ²³çã®ãã©ã³ã¯ãã«ãã西ãã€ãã
ãã·ã¬ã³ïŒé ¢é žããã«ïŒïŒïŒäžã®40ïŒ ã®ã¢ã«ã
éé ç²åæ£ç©ã 20.7ïœ EAB 551â0.01 ã»ã«ããŒã¹ ã¢ã»ãããã¬
ãŒããã€ãŒã¹ããã³ã±ãã«ã«ïŒEastman
Chem.ïŒç€ŸãããŒã¯ïŒZugïŒãã¹ã€ã¹ã 9.2ïœ 100 ïœ äœ¿çšåã«åºæ¬ã©ãã«ãŒããã·ã¬ã³ïŒé ¢é žããã«
ïŒïŒïŒã®æ··åç©ã§ããªãŒãã«ãã ã¿ã€ãïŒã«ã
ããããŒã¿ã€ã ã15ç§ã«çžåœããç²åºŠãŸã§åžéã
ãã ïœ ã¯ãªã€ã©ãã«ãŒïŒä»äžå¡ïŒ ããããã·ãšãã« ã¢ã¯ãªã¬ãŒãã³ããªããŒã
ããŒã¹ãšããã¢ã¯ãªã«æš¹è 100ïœ æš¹è硬åå€ããã¹ã¢ããŠãŒã«ïŒDesmodurïŒ
ããã€ãšã«ïŒBayerïŒç€Ÿãã¬ãã«ã¯ã»ã³
ïŒLeverkusenïŒã西ãã€ãã 30ïœ æµã調æŽå€ããã±ããŒã« ã·ãŠããã€ã¢ãŒã«
ïŒByketol SpenialïŒããã¯ãŒããªã³ã¯ããã
ïŒBykâMallinckrodtïŒããŽãšãŒãŒã«ïŒWeselïŒã
西ãã€ãã ïŒïœ ãšãã¬ã³ã°ãªã³ãŒã« ã¢ã»ããŒãïŒé ¢é žãã
ã«ïŒãã·ã¬ã³30ïŒ30ïŒ40ã®æº¶åªæ··åç© 53ïœ 186ïœ ç¡¬åå€ã¯äœ¿çšçŽåã«å ãããäžèšïŒïŒã«èšèŒã®
å®å®å€ããŸã䜿çšçŽåã«å ããã ïŒ ãµã³ãã«ã®è£œé 56Ã67mmã®ã¢ã«ãããŠã æ¿ã«æ¥çå€ããã¯ã¿ãŒ
ãã«ãã«ã瀟ïŒMessrs.Dr.HerbertsïŒããã®äž
å¡ç®æ¢å€ïŒãå¡ãã175ãã§15åéçŒä»ããã次ã
ã§é¡æãå«æããåºæ¬ã©ãã«ãŒãåãçŽ15ÎŒïœã®
å¡èã«åŽé§ãã宀枩ã§çæé也ç¥ããåŸãã¯ãªã€
ã©ãã«ãŒãåãçŽ35ÎŒïœã®å¡èã«åŽé§ããããã®
äºå±€ã©ãã«ãŒã80ãã§30åéçŒä»ãããã®ãµã³ã
ã«ãéåžžã®æ°åæ¡ä»¶ïŒ23ãïŒå€§æ°ã®çžå¯Ÿæ¹¿åºŠ50ïŒ ïŒ
ã«ïŒé±éä¿åããã ïŒ èåæ§ ASTM  53â77ã«ããç±³åœããŠãŒâããã«
瀟ïŒMessrs.QâPanel Corp.ïŒããã®QUVæŽé²
è©Šéšè£ 眮äžã§ã®ä¿é²èåè©Šéšããã®è©Šéšã«ãããŠ
ã¯ããµã³ãã«ã60ãã«ããã也ç¥ç¶æ ã§ã®ïŒæé
ããã³ã50âã«ããã湿最ç¶æ ã§ã®ïŒæéã®æ°å
æ¡ä»¶ã«äº€äºã«æŽé²ãããæŽé²ã¯åèš900æéè¡ãª
ã€ãã ïœ ãããªãæŽé² ãµã³ãã«ãåã«åããŠ5ãåŸæãããæç®±ã«å ¥
ããæžå€ã§12ã±æéæŽé²ããã ïŒ ãµã³ãã«ã®è©äŸ¡ 以äžã®é ç®ã«ã€ããŠæž¬å®ããïŒ ïœ DIN67 530ãŸãã¯ASTM  523ã«ããè§
床20ãã«ãããå æ²¢åå°åºŠã ïœ TNOã²ã³å²ãè©äŸ¡ã¹ã±ãŒã«ã«ããã²ã³å²ã
床ã ïœ DIN6174ã«ããç·åçè²çžå·®â³ïŒ¥ ïœ ISOâRecom.R105ïŒããŒãïŒã«ããç°è²ã¹
ã±ãŒã«ïŒgrey scaleïŒã«åºãè²å€åã ïŒ äœ¿çšããå å®å®å€ ïŒå®æœäŸïŒã®ååç©ïŒïŒ ïŒåžè²©ã®çŽ«å€ç·åžåå€ïŒ ïŒããªã¢ã«ãã«ãããªãžã³ãããŒã¹ãšããåžè²©
ã®å å®å®å€ïŒ ïŒ çµæ ïœ ä¿é²èåè©Šéš
åºããšãã«åºãã€ãœãããã«åºãŸãã¯ç¬¬äžããã«
åºã§ããããã 奜ãŸããåºã¯ããŸãã¯ïŒ¢åºã§ãããã
ããã®äžã§ããR7ãæ°ŽçŽ ååãã¡ãã«åºãŸãã¯
ãã³ãžã«åºãè¡šãããã®ã奜ãŸããã 奜ãŸããçµååºââã¯æ¬¡åŒïŒ âCH2CH2COââïŒâCH2CH2âCOâ
ïŒR15ïŒâïŒâCH2CH2ââCOâCH2ââïŒ
âCH2CH2âCOââCH2CH2â ïŒåŒäžãR15ã¯åèšã®æå³ãè¡šãããïŒã§è¡šã
ãããåºã§ããã æ¬çºæã®ååç©ã®äŸãšããŠäžèšã®åŒã§è¡šããã
ãååç©ããããããïŒ ïŒR7ïŒæ°ŽçŽ ååãã¡ãã«åºããã³ãžã«åºãŸã
ã¯ã¢ã»ãã«åºïŒ ïŒR7ïŒæ°ŽçŽ ååãâ ãããã«åºãŸãã¯ã¢ãª
ã«åºïŒ ïŒR7ïŒæ°ŽçŽ ååãŸãã¯ã¡ãã«åºïŒ ïŒR7ïŒæ°ŽçŽ ååãŸãã¯ã¡ãã«åºïŒ æ¬çºæã®ååç©ã補é ããããã«äœ¿çšããåºçº
ç©è³ªã¯åŒïŒ¡ãŸãã¯ïŒ¡ã«ãããŠãå°ããšãïŒã€
ã®ïŒ²ã¯å®èœæ§ããªã¢ã«ãã«ãããªãžã³èªå°äœãšå
å¿ãããå®èœåºã§ããååç©ã§ããã åºãäŸãã°ãã«ã«ãã³é žåºïŒâCOOHãâ
CH2CH2COOHãŸãã¯âOCH2COOHãããã¯äœ
çŽã¢ã«ãã«ãšã¹ãã«ãŸãã¯ãã®é žå¡©åç©ã§ããå Ž
åã¯ããã®ãããªååç©ïŒ¡ãŸãã¯ïŒ¡ã¯å®èœæ§
æ°Žé žåºãŸãã¯ã¢ããåºäŸãã°ãâOHåºãâ
CH2CH2OHåºãâNH2åºãâCH2NH2åºãŸãã¯
âCH2CH2NH2åºãæããããªã¢ã«ãã«ãããª
ãžã³ååç©ãšåå¿ãããããšãã§ããã åºãã¢ããåºãäŸãã°âNH2åºãâ
CH2NH2åºãŸãã¯âCH2CH2NH2åºã§ããå Žå
ã¯ããã®ãããªååç©ïŒ¡ãŸãã¯ïŒ¡ã¯ãã«ã«ã
ãã·ã«åºãŸãã¯ããããèªå°ãããåºãäŸãã°ã¢
ã«ã³ãã·ã«ã«ããã«åºãŸãã¯ã¯ããã«ã«ããã«åº
ãæããããªã¢ã«ãã«ãããªãžã³ååç©ãšåå¿ã
ããããšãã§ããã ã©ã¡ãã®å Žåã«ãããŠããšã¹ãã«ãŸãã¯ã¢ãã
ã圢æããããã®åå¿ã¯ãšã¹ãã«åãŸãã¯ã¢ãã
åã®æ £çšæ¹æ³ã§è¡ãªãããã ïŒçš®ã®æåã®ãã¡äžæ¹ããšããã·ã¢ã«ãã«åºã
æããä»æ¹ã®æåãâOHåºãŸãã¯âNHåºãæ
ããå Žåã¯ããšãŒãã«åºãŸãã¯ã¢ãã³åºãæãã
çµååºã圢æãããã çµååºãããªã¢ãžã³åºã§ããååç©ã¯ããžã¯ã
ãããªã¢ãžã³ãŸãã¯å¡©åã·ã¢ãã«ãšïœïŒïŒ¡ãŸã
ã¯ïŒ¡ã§è¡šããããååç©ã®OHãŸãã¯NHèªå°
äœããã³ïœïŒããªã¢ã«ãã«ãããªãžã³ã®OHãŸã
ã¯NHèªå°äœãšã®æ®µéåå¿ã«ãã補é ãããã å¡©åã·ã¢ãã«ã®åå¿ã®å Žåã«ã¯ãå¡©åã·ã¢ãã«
ã¯ïŒ¡èªå°äœïŒåœéããã³ïŒ¢èªå°äœïŒåœéãšåå¿ã
ãããããŸãã¯ïŒ¡èªå°äœïŒåœéããã³ïŒ¢èªå°äœïŒ
åœéãšåå¿ãããããšãã§ãããããããªããã
å¡©åã·ã¢ãã«ãèªå°äœïŒåœéããã³ïŒ¢èªå°äœïŒ
åœéãšåå¿ãããæ®ãã®å¡©çŽ ååãã¢ãã³ãã¢ã«
ã³ãŒã«ãŸãã¯ããšããŒã«ãšåå¿ãããããšããŸã
å¯èœã§ããã ãã®åå¿ã«å¿ èŠãªã¿ã€ãããã³ã¿ã€ãã®å®
èœæ§èªå°äœã¯å ¬ç¥ã®ååç©ã§ããã ãããã€ãŠãäŸãã°ãã®ã«ã«ããã·ã«èªå°
äœã¯ç±³åœç¹èš±ç¬¬3766205å·æ现æžã«èšèŒãããŠã
ããã®ã¢ãã³èªå°äœã¯ç±³åœç¹èš±ç¬¬3159646å·
æ现æžã«èšèŒãããŠãããã®ã«ã«ããã·ã«ãŸ
ãã¯ã¢ããèªå°äœã¯ç±³åœç¹èš±ç¬¬2983708å·ã第
3208865å·ãŸãã¯ç¬¬3380961å·æ现æžã«èšèŒãããŠ
ããã ããªã¢ã«ãã«ãããªãžã³ã®ããããã·èªå°äœ
ã¯ãäŸãã°ããã€ãç¹èš±å ¬éå ¬å ±ç¬¬2352658å·ã
第2353538å·ããã³ç¬¬2402636å·ã«èšèŒãããŠã
ããçžåœããã¢ããèªå°äœã¯ãäŸãã°ããã€ãç¹
èš±å ¬éå ¬å ±ç¬¬2040975å·ããã³ç¬¬2352379å·ã«èšèŒ
ãããŠããã ã¿ã€ãã®ã«ã«ããã·ã«èªå°äœã¯ãäŸãã°ãã
ã€ãç¹èš±å ¬éå ¬å ±ç¬¬2337865å·ããã³ç¬¬2719133å·
ã«èšèŒãããŠããã åºãåºã«çŽæ¥çµåã§çµåããŠããååç©
ã¯ãç¹å¥ãªæ¹æ³ã§è£œé ããããããªãã¡ãäŸã
ã°ãïŒâïŒ4â²âããããã·ããšãã«ïŒâïŒïŒïŒïŒ
ïŒïŒïŒâããã©ã¡ãã«ãããªãžã³ãšïœâãããã
ãšãã«âãžã¢ãŸããŠã ååç©ãã«ãããªã³ã°ãã
ãŠçžåœããïœâãããã¢ãŸååç©ãåŸããããå ¬
ç¥ã®éå æ³ã«ããçžåœãããã³ãŸããªã¢ãŸãŒã«ã«
å€æããããšãã§ããããã®æ¹æ³ã«å¿ èŠãªããã
ãã·ããšãã«ãããªãžã³ã¯ããã€ãç¹èš±å ¬éå ¬å ±
第2258086å·ã«èšèŒãããŠããã æ¬çºæã®ååç©ã®è£œé ã«é¢ããæŽã«è©³çŽ°ãªèª¬æ
ã¯ãäžèšã®å®æœäŸäžã§è¡ãªãã æ¬çºæã®æ°èŠååç©ã¯ãå ã®äœçšã«å¯ŸããŠæå
æ§ãæããææ©ææãç¹ã«ææ©ããªããŒçšã®é¡è
ãªå å®å®å€ã§ãããç¹ã«æ¬çºæã®ååç©ã¯ãçæ³¢
é·ã®å ïŒçŽ«å€ç·ïŒã«å¯Ÿãã匷åãªä¿è·äœçšãæã
ãããšãç¹åŸŽãšããã 以äžã«åèšãããã®ã¯ãæ¬çºæã®ååç©ãæ·»å
ããããšã«ãã€ãŠå®å®åãããããªããŒã®äŸã§ã
ãïŒ ïŒ ã¢ããŒããã³ãžâãªã¬ãã€ã³ã®ããªããŒãäŸ
ãã°ããªãšãã¬ã³ïŒæ¶æ©ãããŠãè¯ããïŒãããª
ãããã¬ã³ãããªã€ãœããã¬ã³ãããªã¡ãã«ã
ãâïŒâãšã³ãããªã¡ãã«ãã³ãâïŒâãšã³ã
ããªã€ãœãã¬ã³ãŸãã¯ããªãã¿ãžãšã³ã ïŒ ïŒïŒã«ãããããªããŒã®æ··åç©ãäŸãã°ããª
ãããã¬ã³ãšããªãšãã¬ã³ãŸãã¯ããªã€ãœãã
ã¬ã³ãšã®æ··åç©ããããã¯äŸãã°ç°ãªãå¯åºŠãŸ
ãã¯ç°ãªãã¡ã«ãã€ã³ããã¯ã¹ãæããïŒçš®ã®
ããªãšãã¬ã³ã®æ··åç©ã ïŒ ã¢ããŒããã³ãžâãªã¬ãã€ã³ã®ã³ããªããŒã
äŸãã°ãšãã¬ã³ïŒãããã¬ã³ ã³ããªããŒãã
ããã¬ã³ïŒããâïŒâãšã³ ã³ããªããŒããã
ãã¬ã³ïŒã€ãœããã¬ã³ ã³ããªããŒããšãã¬
ã³ïŒããâïŒâãšã³ ã³ããªããŒããã«ãŸããš
ãã¬ã³ãšãããã¬ã³ããã³ãããµãžãšã³ããžã·
ã¯ããã³ã¿ãžãšã³ãŸãã¯ãšããªãã³ãã«ãã«ã
ã³çã®ãžãšã³ãšã®ã¿ãŒããªããŒã ïŒ ããªã¹ãã¬ã³ã ïŒ ã¹ãã¬ã³ãŸãã¯Î±âã¡ãã«ã¹ãã¬ã³ãšãžãšã³
ãŸãã¯ã¢ã¯ãªã«èªå°äœãšã®ã³ããªããŒãäŸãã°
ã¹ãã¬ã³ïŒãã¿ãžãšã³ãã¹ãã¬ã³ïŒã¢ã¯ãªãã
ããªã«ãŸãã¯ã¹ãã¬ã³ïŒã¢ã¯ãªã«ãããªã«ïŒã¢
ã¯ãªã«é žã¡ãã«ïŒã¹ãã¬ã³ã³ããªããŒããã³ä»
ã®ããªããŒããåŸãããèè¡ææ§æš¹èæ··åç©ã
äŸãã°ããªã¢ã¯ãªã¬ãŒãããžãšã³ããªããŒãŸã
ã¯ãšãã¬ã³ïŒãããã¬ã³ïŒãžãšã³ ã¿ãŒããªã
ãŒïŒããã«ãŸãã¹ãã¬ã³ã®ãããã¯ã³ããªã
ãŒãäŸãã°ã¹ãã¬ã³ïŒãã¿ãžãšã³ïŒã¹ãã¬ã³ã
ã¹ãã¬ã³ïŒã€ãœãã¬ã³ïŒã¹ãã¬ã³ãŸãã¯ã¹ãã¬
ã³ïŒãšãã¬ã³âããã¬ã³ïŒã¹ãã¬ã³ã ïŒ ã¹ãã¬ã³ã®ã°ã©ããã³ããªããŒãäŸãã°ã¹ã
ã¬ã³ã®çµåããããªãã¿ãžãšã³ãã¹ãã¬ã³ãã
ã³ã¢ã¯ãªããããªã«ã®çµåããããªãã¿ãžãšã³
ããã³ããããšïŒïŒã«ãããã³ããªããŒãšã®
ABSããªããŒãšããŠç¥ãããæ··åæš¹æã ïŒ ããã²ã³å«æããªããŒãäŸãã°ããªå¡©åãã
ã«ãããªå¡©åãããªãã³ãããªåŒåããã«ãã
ãªã¯ãããã¬ã³ãå¡©åãŽã ããã³ã³ããªããŒã
äŸãã°å¡©åããã«ïŒå¡©åãããªãã³ãå¡©åãã
ã«ïŒå¡©é žããã«ãŸãã¯å¡©åãããªãã³ïŒé ¢é žã
ãã«ã®ã³ããªããŒã ïŒ Î±ïŒÎ²âäžé£œåé žããã³ãã®èªå°äœããèªå°
ãããããªããŒãäŸãã°ããªã¢ã¯ãªã¬ãŒããã
ã³ããªã¡ã¿ã¢ã¯ãªã¬ãŒããããªã¢ã¯ãªã«ã¢ãã
ããã³ããªã¢ã¯ãªããããªã«ã ïŒ äžé£œåã¢ã«ã³ãŒã«ããã³ã¢ãã³ãããã¯ãã
çã®ã¢ã·ã«èªå°äœãŸãã¯ã¢ã»ã¿ãŒã«ããèªå°ã
ããããªããŒãäŸãã°ãããªããã«ã¢ã«ã³ãŒ
ã«ãããªé ¢é žããã«ãããªã¹ãã¢ãªã³é žãã
ã«ãããªããã«ãã³ãŸãšãŒããããªããã«ãã¬
ãšãŒããããªããã«ããã¬ãŒããããªã¢ãªã«ã
ã¿ã¬ãŒããããªã¢ãªã«ã¡ã©ãã³ããã³ããããš
ä»ã®ããã«ååç©ãšã®ã³ããªããŒãäŸãã°ãšã
ã¬ã³ïŒé ¢é žããã« ã³ããªããŒã 10 ãšããã·ãã®ãã¢ããªããŒããã³ã³ããªã
ãŒãäŸãã°ããªãšãã¬ã³ãªãã·ããããªããã
ã¬ã³ãªãã·ããŸãã¯ããããšãã¹ãŒã°ãªã·ãžã«
ãšãŒãã«ãšã®ã³ããªããŒã 11 ããªã¢ã»ã¿ãŒã«ãäŸãã°ããªãªãã·ã¡ãã¬ã³
ããã«ãŸããšãã¬ã³ãªãã·ããã³ã¢ãããŒãšã
ãŠå«ãããªãªãã·ã¡ãã¬ã³ã 12 ããªããšãã¬ã³ãªãã·ãã 13 ããªãŠã¬ã¿ã³ããã³ããªãŠã¬ã¢ã 14 ããªã«ãŒãããŒãã 15 ããªã¹ã«ãã³ã 16 ãžã¢ãã³ããã³ãžã«ã«ãã³é žããã³ïŒãŸãã¯
ã¢ããã«ã«ãã³é žãŸãã¯çžåœããã©ã¯ã¿ã ãã
èªå°ãããããªã¢ããããã³ã³ããªã¢ãããäŸ
ãã°ããªã¢ããïŒãããªã¢ãã6/6ãããªã¢ã
ã6/10ãããªã¢ãã11ããã³ããªã¢ãã12ã 17 ãžã«ã«ãã³é žããã³ãžã¢ã«ã³ãŒã«ããã³ïŒãŸ
ãã¯ããããã·ã«ã«ãã³é žãŸãã¯çžåœããã©ã¯
ãã³ããèªå°ãããããªãšã¹ãã«ãäŸãã°ããª
ãšãã¬ã³ãã¬ãã¿ã¬ãŒããããªããã¬ã³ãã¬ã
ã¿ã¬ãŒããããã³ããªâïŒïŒïŒâãžã¡ãããŒã«
ã·ã¯ããããµã³ãã¬ãã¿ã¬ãŒãããã³ã³ããªãš
ãŒãã«âãšã¹ãã«ã 18 äžæ¹ã§ã¢ã«ããããä»æ¹ã§ããšããŒã«ãå°¿çŽ
ããã³ã¡ã©ãã³ããèªå°ãããæ¶æ©ããªããŒã
äŸãã°ããšããŒã«âãã«ã ã¢ã«ãããæš¹èãå°¿
çŽ âãã«ã ã¢ã«ãããæš¹èããã³ã¡ã©ãã³âã
ã«ã ã¢ã«ãããæš¹èã 19 ã¢ã«ãããæš¹èãäŸãã°ã°ãªã»ããŒã«ïŒãã¿
ã«é žæš¹èããã³ãã®ã¡ã©ãã³âãã«ã ã¢ã«ãã
ãæš¹èãšã®æ··åç©ã 20 飜åããã³äžé£œåãžã«ã«ãã³é žãšå€äŸ¡ã¢ã«ã³
ãŒã«ãšã®ããã«ååç©ãæ¶æ©å€ãšããã³ããªãš
ã¹ãã«ããèªå°ããããäžé£œåããªãšã¹ãã«æš¹
èããã³ããã«ãã®ããã²ã³ååãå«ãé£çæ§
ã®å€æ§æš¹èã 21 ããªãšããã·ããäŸãã°ãã¹ãŒã°ãªã·ãžã«ãš
ãŒãã«ãŸãã¯èç°åŒãžãšããã·ãããèªå°ãã
ãæ¶æ©ãšããã·ãæš¹èã 22 倩ç¶ã®ããªããŒãäŸãã°ã»ã«ããŒã¹ããŽã ã
ãã³èçœè³ªãªãã³ã«ããçãéååæäœãšããŠ
ååŠå€æ§ããèªå°äœãäŸãã°é ¢é žã»ã«ããŒã¹ã
ããããªã³é žã»ã«ããŒã¹ããã³ã»ã«ããŒã¹ãã
ã¬ãŒããªãã³ã«ã¡ãã«ã»ã«ããŒã¹ã®æ§ãªã»ã«ã
ãŒã¹ãšãŒãã«ã ãããã®ããªããŒäžãç¹ã«éèŠãªãã®ã¯ã©ãã«
ãŒãç¹ã«çŒä»ã©ãã«ãŒã®çµåå€ãšããŠäœ¿çšããã
ãã®ãäŸãã°äžèšãªã¹ãäž18ïŒ19ïŒ20ããã³21ã®
ã°ã«ãŒãã«å±ãããã®ã§ããã æ¬çºæè çã¯ã©ãã«ãŒäžã§ã¯ãããªãžã³å å®å®
å€ãšçŽ«å€ç·åžåå€ãšã®çµåç©ãéåžžã«æçšã§ãã
ããšãèŠåºãããçŒä»ã©ãã«ãŒã®å Žåã«ã¯ããã³
ãŸããªã¢ãŸãŒã«ããã³ãŸããšãã³ããã³ããªã¢ã«
ãã«ãããªãžã³ãããŒã¹ãšããæ £çšã®äœååéå
å®å®å€ã®æ®çºæ§ã¯é倧ãªæè¡äžã®åé¡ãã²ããã
ããæ¬çºæã«ãã€ãŠç°ãªãçš®é¡ã®å å®å®å€ãååŠ
çã«çµåããããšã«ãããäžèšæ®çºæ§ã¯å€§å·Ÿã«æž
å°ããããããã®æ°èŠååç©ã¯çŒä»ã©ãã«ãŒãå®
å®åããããã«ãé©ããã æ¬çºæã®ååç©ã¯ãããªããŒäžã«0.05ãªããïŒ
ééïŒ ã奜ãŸããã¯0.1ãªããïŒééïŒ ã®éã§æ·»
å ããã æ¬çºæã®å å®å®å€ã¯ãããªããŒã®æ圢åã«åŸ®ç²
ç ããªããŒãšæ··åããããããªããŒãŸãã¯ãã®å
é§ç©è³ªã®æº¶èç©ãŸãã¯æº¶æ¶²ãšæ··åããããšã«ãã
ããªããŒäžã«æ·»å ããããã©ã¹ããã¯ç£æ¥ã«ãã
ãå ¬ç¥ãã€æ £çšã®ä»ã®æ·»å å€ãåæã«ããªããŒã«
æ·»å ããããšãå¯èœã§ããããããã®æ·»å å€ã¯ã
äŸãã°ãé žåé²æ¢å€ãéå±äžæŽ»æ§åå€ãä»ã®å®å®
å€ãå¯å¡å€ãæ»å€ãçºæ³¡å€ãé¡æãå å¡«å€ãŸãã¯
ä»ã®å©å€ã§ããããããã®ãããªå ¬ç¥ãã€æ £çšã®
ãã©ã¹ããã¯çšæ·»å å€ã®åã ã®äŸã¯ããã€ãç¹èš±
å ¬éå ¬å ±ç¬¬2349962å·ç¬¬25ã32é ã«åèšãããŠã
ãã ãã®ããã«ããŠå®å®åãããããªããŒã¯éåžžã«
çš®ã ã®åœ¢æ ã§ãäŸãã°ãã€ã«ã ããã¢ã€ããŒãã
ãŒããŸãã¯åœ¢æãšããŠãããã¯ã©ãã«ãŒãæ¥çå€
ãŸãã¯ããã®çµåå€ãšããŠäœ¿çšã§ããã æ¬çºæã®ååç©ã®è£œé ããã³äœ¿çšã«ã€ããŠä»¥äž
ã®å®æœäŸã§èª¬æãããå®æœäŸäžãéšããã³ããŒã»
ã³ãã¯éééšããã³ééïŒ ãè¡šããã枩床ã¯âã
è¡šããã å®æœäŸ ïŒ ïŒâïŒïŒâããããã·âïŒâã¡ãã«âïŒâβâ
ã¡ããã·ã«ã«ããã«âãšãã«âããšãã«ïŒâãã³
ãŸããªã¢ãŸãŒã«ïŒç±³åœç¹èš±ç¬¬3766205å·ã«åŸã€ãŠ
補é ããïŒ46.7ïœããïŒïŒïŒïŒïŒïŒïŒâããã©ã¡
ãã«âïŒâããããã·âãããªãžã³23.6ïœããã³
ãããªãŠã ã¡ããã·ãïŒïœãšãšãã«ããã·ã¬ã³
300mläžã«ãŠç©ãããªçªçŽ æ°æµãéããªããã130
ã135ãã§20æéå ç±ãããçæããã¡ã¿ããŒã«ã¯
é£ç¶çã«çå»ãããåå¿æ··åç©ã宀枩ãŸã§å·åŽ
ããé ¢é žã§é žæ§åããåå100mlã®æ°Žã§ïŒåæœåº
ãããæ°Žæ§æœåºæ¶²ãäžç·ã«ããŠã¢ã³ã¢ãã¢ã§ã¢ã«
ã«ãªæ§ãšããåŸãããæ²æŸ±ãæ¿ŸéããŠéããæ°ŽæŽ
ãã也ç¥ããŠãªã°ãã€ã³ããçµæ¶åãããããã«
ããïŒâïœïŒâããããã·âïŒâã¡ãã«âïŒâ
ãβâïŒïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã
ããªãžãã«ãªãã·ã«ã«ããã«ïŒâãšãã«ãâããš
ãã«ïœâãã³ãŸããªã¢ãŸãŒã«ïŒååç©ïŒïŒãèç¹
131ãã®å®è³ªçã«ç¡è²ç²æ«ã®åœ¢ã§åŸãããã ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãããã
ã·ãããªãžã³ã®ä»£ãã«åœéã®ïŒïŒïŒïŒïŒïŒïŒïŒ
ïŒïŒâãã³ã¿ã¡ãã«âïŒâããããã·ãããªãžã³
ãŸãã¯åœéã®ïŒâãã³ãžã«âïŒïŒïŒïŒïŒïŒïŒâã
ãã©ã¡ãã«âïŒâããããã·ãããªãžã³ã䜿çš
ãããã以å€ã®ç¹ã¯äžèšã®æ¹æ³ã©ããã«è¡ãªã
ã°ãããããèç¹110ã111ãã®ïŒâïœïŒâããã
ãã·âïŒâã¡ãã«âïŒâãβâïŒïŒïŒïŒïŒïŒïŒ
ïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâãããªãžãã«ãªã
ã·âã«ã«ããã«ïŒâãšãã«ãâããšãã«ïœâãã³
ãŸããªã¢ãŸãŒã«ïŒååç©ïŒïŒãŸãã¯èç¹127ã
128ãã®ïŒâïœïŒâããããã·âïŒâã¡ãã«âïŒâ
ãβâïŒïŒâãã³ãžã«âïŒïŒïŒïŒïŒïŒïŒâããã©
ã¡ãã«âïŒâãããªãžãã«âãªãã·ã«ã«ããã«ïŒ
âãšãã«ãâããšãã«ïœâãã³ãŸããªã¢ãŸãŒã«
ïŒååç©ïŒïŒãåŸãããã å®æœäŸ ïŒ ïŒâïŒïŒâããããã·âïŒïŒïŒâãžâ第äžãã
ã«âããšãã«ïŒâãã³ãŸããªã¢ãŸãŒã«âïŒâã«ã«
ãã³é žã¯ãã©ã€ã23.1ïœãå ãã宀枩ã§ãã«ãšã³
300mläžã«æ·»å ããããã®æº¶æ¶²ã«ãã«ãšã³100mläž
ã®ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã¢ããã
ããªãžã³10.1ïœã®æº¶æ¶²ãçŽ30åãããŠæ»Žå ãã次
ãã§åå¿æ··åç©ã宀枩ã§15æéæ¹æãããæ²æ®¿ã
ãå¡©é žå¡©ãæ¿ŸéããŠéãããšã¿ããŒã«200mlãã
ã³æ°Ž200mläžã®æº¶è§£ãããçé žãããªãŠã ã§æº¶æ¶²
ãã¢ã«ã«ãªæ§ãšããåŸãããæ²æ®¿ãæ¿ŸéããŠé
ããæ°ŽæŽãã也ç¥ããŠãã«ãšã³ããçµæ¶åããã
ããã«ããèç¹267ãã®ïŒâïŒïŒâããããã·â
ïŒïŒïŒâãžâ第äžããã«âããšãã«ïŒâãã³ãŸã
ãªã¢ãŸãŒã«âïŒâã«ã«ãã³é žïŒ®âïŒïŒïŒïŒïŒïŒïŒ
ïŒâããã©ã¡ãã«âïŒâãããªãžãã«ïŒâã¢ãã
ïŒååç©ïŒïŒãåŸãããã ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã¢ããã
ããªãžã³ã®ä»£ãã«åœéã®ïŒïŒïŒïŒïŒïŒïŒâããã©
ã¡ãã«âïŒâβâã¢ãããšãã«âãããªãžã³ã䜿
çšãããã以å€ã¯äžèšæ¹æ³ã©ããã«è¡ãªãã°ãè
ç¹228ãã®ïŒâïŒïŒâããããã·âïŒïŒïŒâãžâ第
äžããã«âããšãã«ïŒâãã³ãŸããªã¢ãŸãŒã«âïŒ
âã«ã«ãã³é žïŒ®âãβâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ã¡ãã«âïŒâãããªãžãã«ïŒâãšãã«ãâã¢ã
ãïŒååç©ïŒïŒãåŸãããã å®æœäŸ ïŒ ïŒâããããã·âïŒâã¡ããã·ã«ã«ããã«âã¡
ããã·âãã³ãŸããšãã³57.2ïœãïŒïŒïŒïŒïŒïŒ
ïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâããããã·ãããª
ãžã³36ïœããã³ãããªãŠã ã¡ããã·ã15ïœãšãšã
ã«ããã·ã¬ã³250mläžã«ãŠç©ãããªçªçŽ æ°æµãé
ããªããã130ã135ãã§ïŒæéå ç±ãããçæã
ãã¡ã¿ããŒã«ã¯ãšã¹ãã«äº€æåå¿ã®éãé£ç¶çã«
çå»ããã宀枩ãŸã§å·åŽããåŸãåå¿æ··åç©ãé ¢
é žã§é žæ§åãã次ãã§åå100mlã®æ°Žã§ïŒåæœåº
ãããæ°Žæ§æœåºæ¶²ãäžç·ã«ããŠã¢ã³ã¢ãã¢ã§ã¢ã«
ã«ãªæ§ãšããæ²æ®¿ãæ¿ŸéããŠéããæ°ŽæŽãã也ç¥
ããŠãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ãã
åçµæ¶ãããããã«ããèç¹79ãã®ïŒâãããã
ã·âïŒâïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«
âïŒâãããªãžãã«ãªãã·ã«ã«ããã«âã¡ãã
ã·ïŒâãã³ãŸããšãã³ïŒååç©ïŒïŒãåŸãããã å®æœäŸ ïŒ ïœâãããã¢ããªã³12.5ïœãå ¬ç¥ã®æ¹æ³ã§ãžã¢
ãŸåããåŸããããžã¢ãŸããŠã 塩溶液ããæ°Ž100
mlããã³æ°Žé žåãããªãŠã ïŒïœäžã®ïŒïŒïŒïŒïŒïŒ
ïŒâããã©ã¡ãã«âïŒâïŒ4â²âããããã·ããšã
ã«ïŒâãããªãžã³16.3ïœã®æº¶æ¶²äžã«ïŒã5ãããã³
PH10ã12ã«ãŠæ»Žå ãããã«ãããªã³ã°åå¿çµäº
åŸãåå¿æ··åç©ã®PHãé ¢é žã§ïŒã«èª¿æŽããã¢ãŸæ
æãæ¿ŸéããŠéããã50ãã§ç空也ç¥ããåŸãã¢
ãŸææïŒ19.1ïœïŒããšãã¬ã³ã°ãªã³ãŒã« ã¢ãã¡
ãã«ãšãŒãã«50mläžã«æº¶è§£ããããã®æº¶æ¶²ã«æ°Ž20
mläžã®æ°Žé žåãããªãŠã ïŒïœã®æº¶æ¶²ãå ããæ··å
ç©ã80ãã«å æž©ãããããã©ãžã³æ°Žåç©2.5ïœãã
ã®æž©åºŠã§çŽ15åãããŠæ»Žå ãã次ãã§åå¿æ··åç©
ã80ãã§ããã«ïŒæéæ¹æããããã®éã«åå¿æ··
åç©ã®è²ã¯çŽ«è²ããè¶è²ã«å€åãããæ··åç©ã宀
æž©ãŸã§å·åŽããäºéæ«6.5ïœãçŽ30åãããŠäœåºŠ
ãã«ãããŠå ããã次ãã§åå¿æ··åç©ã60ãã«å
æž©ããäºéæ«ããã«6.5ïœããã³10Næ°Žé žåãã
ãªãŠã 溶液25mlãå ããåŸãããæ··åç©ãããã«
ïŒæéæ¹æãããæ·¡ç·è²ã®åå¿æ··åç©ãæ¿ŸéããŠ
äºéã®ã¹ã©ããžãé€ããæ°·é ¢é žçŽ70mlãåŸã ã«æ¿Ÿ
液ïŒPHãïŒïŒãå ããŠãåŸããã溶液ãéæå
ãã次ãã§ã¢ã³ã¢ãã¢ã§ã¢ã«ã«ãªæ§ã«ãããåŸã
ããæ²æ®¿ãæ¿ŸéããŠéããæ°ŽæŽãã也ç¥ããŠãªã°
ãã€ã³ããçµæ¶åãããããã«ããèç¹178ã
180ãã®ïŒâãïŒâããããã·âïŒâïŒïŒïŒïŒïŒ
ïŒïŒïŒâããã©ã¡ãã«ãããªãžã³âïŒâã€ã«ïŒâ
ããšãã«ãâãã³ãŸããªã¢ãŸãŒã«ïŒååç©ïŒïŒã
åŸãããã ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâïŒ4â²âã
ãããã·ããšãã«ïŒâãããªãžã³ã®ä»£ãã«åœéã®
ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâïŒ3â²âã¡ã
ã«â4â²âããããã·ããšãã«ïŒâãããªãžã³ã
ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâïŒ3â²â第äž
ããã«â4â²âããããã·ããšãã«ïŒâãããªãž
ã³ãïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâïŒ3â²â
ã·ã¯ãããã·ã«â4â²âããããã·ããšãã«ïŒâã
ããªãžã³ãŸãã¯ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«â
ïŒâïŒïŒâããããã·â5â²âã¡ãã«âããšãã«ïŒ
âãããªãžã³ã䜿çšãããã以å€ã¯äžèšã®æ¹æ³ã©
ããè¡ãªãã°ãèç¹219â220ãã®ïŒâãïŒâãã
ããã·âïŒâã¡ãã«âïŒâïŒïŒïŒïŒïŒïŒïŒïŒâã
ãã©ã¡ãã«ãããªãžã³âïŒâã€ã«ïŒâããšãã«ã
ãã³ãŸããªã¢ãŸãŒã«ïŒååç©ïŒïŒãèç¹162ã164ã
ã®ïŒâãïŒâããããã·âïŒâ第äžããã«âïŒâ
ïŒïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«ãããªãžã³âïŒ
âã€ã«ïŒâããšãã«ãâãã³ãŸããªã¢ãŸãŒã«ïŒå
åç©ïŒïŒãèç¹155â156ãã®ïŒâïŒïŒâããããã·
âïŒâã·ã¯ãããã·ã«âïŒâïŒïŒïŒïŒïŒïŒïŒïŒâ
ããã©ã¡ãã«ãããªãžã³âïŒâã€ã«ïŒâããšã
ã«ãâãã³ãŸããªã¢ãŸãŒã«ïŒååç©10ïŒãŸãã¯è
ç¹168ã169ãã®ïŒâãïŒâããããã·âïŒâïŒïŒïŒ
ïŒïŒïŒïŒïŒâããã©ã¡ãã«ãããªãžã³âïŒâã€
ã«ïŒâïŒâã¡ãã«âããšãã«ããã³ãŸããªã¢ãŸãŒ
ã«ïŒååç©11ïŒã倫ã åŸãããã å®æœäŸ ïŒ ïŒâãïŒâããããã·âïŒâã¡ãã«âïŒâ
ïŒïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«ãããªãžã³âïŒ
âã€ã«ïŒâããšãã«ãâãã³ãŸããªã¢ãŸãŒã«ïŒå
åç©ïŒïŒ20ïœãè»é žïŒ98ïŒ ïŒ150mläžã«æº¶è§£ããã
次ãã§35ïŒ ãã«ã ã¢ã«ããã溶液87.4mlã宀枩ã§
çŽïŒæéãããŠæ»Žå ããã次ãã§ãã®æããè¶è²
ããã€ã溶液ãéæµäžã«20æéå ç±ãã宀枩ãŸã§
å·åŽããå·åŽãã飜åçé žã«ãªãŠã 溶液äžã«æ»Žå
ãããçœè²çµæ¶æ²æ®¿ãæ¿ŸéããŠéããæ°ŽæŽãã也
ç¥ããŠãªã°ãã€ã³ããåçµæ¶ãããããã«ããã
èç¹206ã207ãã®ïŒâãïŒâããããã·âïŒâã¡
ãã«âïŒâïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«
âãããªãžã³âïŒâã€ã«ïŒâããšãã«ãâãã³ãŸ
ããªã¢ãŸãŒã«ïŒååç©12ïŒãåŸãããã å®æœäŸ ïŒ ïŒâïŒïŒâããããã·âïŒâã¡ãã«âïŒâβâ
ã¡ããã·âã«ã«ããã«âãšãã«âããšãã«ïŒâã
ã³ãŸããªã¢ãŸãŒã«130.7ïœããã³ïŒïŒïŒâãã¹â
ïŒïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãããã
ã·ãããªãžã³âïŒâã€ã«ïŒâããâïŒâãšã³73.3
ïœããã·ã¬ã³600mläžã«ãŠããªã«ããã¿ã³é žãã
ã©ããã«1.0ïœãå ããåŸãç©ãããªçªçŽ æ°æµã
éããªãã130ã135ãã§24æéå ç±ãããçæã
ãã¡ã¿ããŒã«ã¯é£ç¶çã«çå»ããããã®åŸãªã«ã
ãã¿ã³é žããã©ããã«1.0ïœãå ãããšã¹ãã«äº€
æåå¿ã130ã135ãã§ããã«24æéè¡ãªã€ããã
ã·ã¬ã³ãå åã«çå»ããæ®æž£ããªã°ãã€ã³ããïŒ
ååçµæ¶ãããããã«ããäžèšã®æ§é åŒã§è¡šãã
ãããžãšã¹ãã«ïŒååç©13ïŒãèç¹135ãã®å®è³ªç
ã«ç¡è²ã®çµæ¶ãšããŠåŸãããã å®æœäŸ ïŒ ïŒâããããã·âïŒâã¡ããã·ã«ã«ããã«âã¡
ããã·âãã³ãŸããšãã³30.0ïœããïŒâãããã
ã·ãšãã«âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâ
ããããã·ãããªãžã³10.0ïœããã³ãªã«ããã¿ã³
é žããã©ããã«0.5ïœãšãšãã«ããã·ã¬ã³200mläž
ã«ãŠãç©ãããªçªçŽ æ°æµãéããªãã130ã135ã
ã§15æéå ç±ãããçæããã¡ã¿ããŒã«ã¯ãšã¹ã
ã«äº€æåå¿ã®éãé£ç¶çã«çå»ãããããã«ãªã«
ããã¿ã³é žããã©ããã«0.5ïœéãå ããåŸããš
ã¹ãã«äº€æåå¿ãããã«15æéç¶ãããåå¿æº¶æ¶²
ãéæåããèžçºãããæ®æž£ããã«ãšã³ïŒãããµ
ã³ããåçµæ¶ãããããã«ããäžèšæ§æåŒã§è¡šã
ããããžãšã¹ãã«ïŒååç©14ïŒãèç¹130ãã®é»è²
ããã€ãçµæ¶ãšããŠåŸãããã å®æœäŸïŒïŒäºå±€éå±ã©ãã«ãŒã®å å®å®å ïŒ é å ïœ åºæ¬ã©ãã«ãŒïŒçè²ãããã®ïŒ  1850ã®ããªãšã¹ãã«ããã€ãããã ããŒ
ãã«ïŒDynamit NobelïŒç€Ÿãããã€ã¹ãã«ã
ïŒTroisdorfïŒã西ãã€ãã 54.4ïœ ããã¬ããŒã«ïŒMaprenalïŒMF650ã¡ã©ãã³æš¹
èãã«ã»ã©ãŒããã¹ãïŒCassellaâHoechstïŒ
瀟ããŽã€ãŒã¹ããŒãã³ïŒWiesbadenïŒã西ãã€
ãã 5.5ïœ ãã«ãšã³ 3.7ïœ ïœâãã¿ããŒã« 2.8ïœ é ¢é žããã« 3.7ïœ ã¢ã«ã³ã¢ïŒAlcoaïŒ726ãã¢ã«ã³ã¢ïŒAlcoaïŒ
瀟ããã€ã³æ²³çã®ãã©ã³ã¯ãã«ãã西ãã€ãã
ãã·ã¬ã³ïŒé ¢é žããã«ïŒïŒïŒäžã®40ïŒ ã®ã¢ã«ã
éé ç²åæ£ç©ã 20.7ïœ EAB 551â0.01 ã»ã«ããŒã¹ ã¢ã»ãããã¬
ãŒããã€ãŒã¹ããã³ã±ãã«ã«ïŒEastman
Chem.ïŒç€ŸãããŒã¯ïŒZugïŒãã¹ã€ã¹ã 9.2ïœ 100 ïœ äœ¿çšåã«åºæ¬ã©ãã«ãŒããã·ã¬ã³ïŒé ¢é žããã«
ïŒïŒïŒã®æ··åç©ã§ããªãŒãã«ãã ã¿ã€ãïŒã«ã
ããããŒã¿ã€ã ã15ç§ã«çžåœããç²åºŠãŸã§åžéã
ãã ïœ ã¯ãªã€ã©ãã«ãŒïŒä»äžå¡ïŒ ããããã·ãšãã« ã¢ã¯ãªã¬ãŒãã³ããªããŒã
ããŒã¹ãšããã¢ã¯ãªã«æš¹è 100ïœ æš¹è硬åå€ããã¹ã¢ããŠãŒã«ïŒDesmodurïŒ
ããã€ãšã«ïŒBayerïŒç€Ÿãã¬ãã«ã¯ã»ã³
ïŒLeverkusenïŒã西ãã€ãã 30ïœ æµã調æŽå€ããã±ããŒã« ã·ãŠããã€ã¢ãŒã«
ïŒByketol SpenialïŒããã¯ãŒããªã³ã¯ããã
ïŒBykâMallinckrodtïŒããŽãšãŒãŒã«ïŒWeselïŒã
西ãã€ãã ïŒïœ ãšãã¬ã³ã°ãªã³ãŒã« ã¢ã»ããŒãïŒé ¢é žãã
ã«ïŒãã·ã¬ã³30ïŒ30ïŒ40ã®æº¶åªæ··åç© 53ïœ 186ïœ ç¡¬åå€ã¯äœ¿çšçŽåã«å ãããäžèšïŒïŒã«èšèŒã®
å®å®å€ããŸã䜿çšçŽåã«å ããã ïŒ ãµã³ãã«ã®è£œé 56Ã67mmã®ã¢ã«ãããŠã æ¿ã«æ¥çå€ããã¯ã¿ãŒ
ãã«ãã«ã瀟ïŒMessrs.Dr.HerbertsïŒããã®äž
å¡ç®æ¢å€ïŒãå¡ãã175ãã§15åéçŒä»ããã次ã
ã§é¡æãå«æããåºæ¬ã©ãã«ãŒãåãçŽ15ÎŒïœã®
å¡èã«åŽé§ãã宀枩ã§çæé也ç¥ããåŸãã¯ãªã€
ã©ãã«ãŒãåãçŽ35ÎŒïœã®å¡èã«åŽé§ããããã®
äºå±€ã©ãã«ãŒã80ãã§30åéçŒä»ãããã®ãµã³ã
ã«ãéåžžã®æ°åæ¡ä»¶ïŒ23ãïŒå€§æ°ã®çžå¯Ÿæ¹¿åºŠ50ïŒ ïŒ
ã«ïŒé±éä¿åããã ïŒ èåæ§ ASTM  53â77ã«ããç±³åœããŠãŒâããã«
瀟ïŒMessrs.QâPanel Corp.ïŒããã®QUVæŽé²
è©Šéšè£ 眮äžã§ã®ä¿é²èåè©Šéšããã®è©Šéšã«ãããŠ
ã¯ããµã³ãã«ã60ãã«ããã也ç¥ç¶æ ã§ã®ïŒæé
ããã³ã50âã«ããã湿最ç¶æ ã§ã®ïŒæéã®æ°å
æ¡ä»¶ã«äº€äºã«æŽé²ãããæŽé²ã¯åèš900æéè¡ãª
ã€ãã ïœ ãããªãæŽé² ãµã³ãã«ãåã«åããŠ5ãåŸæãããæç®±ã«å ¥
ããæžå€ã§12ã±æéæŽé²ããã ïŒ ãµã³ãã«ã®è©äŸ¡ 以äžã®é ç®ã«ã€ããŠæž¬å®ããïŒ ïœ DIN67 530ãŸãã¯ASTM  523ã«ããè§
床20ãã«ãããå æ²¢åå°åºŠã ïœ TNOã²ã³å²ãè©äŸ¡ã¹ã±ãŒã«ã«ããã²ã³å²ã
床ã ïœ DIN6174ã«ããç·åçè²çžå·®â³ïŒ¥ ïœ ISOâRecom.R105ïŒããŒãïŒã«ããç°è²ã¹
ã±ãŒã«ïŒgrey scaleïŒã«åºãè²å€åã ïŒ äœ¿çšããå å®å®å€ ïŒå®æœäŸïŒã®ååç©ïŒïŒ ïŒåžè²©ã®çŽ«å€ç·åžåå€ïŒ ïŒããªã¢ã«ãã«ãããªãžã³ãããŒã¹ãšããåžè²©
ã®å å®å®å€ïŒ ïŒ çµæ ïœ ä¿é²èåè©Šéš
ãè¡šã
ïœ ãããªãæŽé²è©Šéš
ãè¡šã
å®æœäŸ ïŒïŒ
ãã·ã¬ã³200mläžã®ïŒâïŒïŒâããããã·âïŒ
â第ïŒããã«âïŒâβâã¡ããã·ã«ã«ããã«âãš
ãã«âããšãã«ïŒâãã³ãŸããªã¢ãŸãŒã«21.2ïœå
ã³ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâãã
ããã·ãããªãžã³10.2ïœã130â135âã§ãã ãã
ãªçªçŽ æµäžã§20æéå ç±ããåŸãããã©ããã«ãª
ã«ããã¿ããŒã0.5ïœãæ·»å ããã圢æããã¡ã¿
ããŒã«ãç¶ããŠèžçããŠé€å»ããããã®åŸããã
ã©ããã«ãªã«ããã¿ããŒã0.5ïœãæ·»å ããŠããš
ã¹ãã«äº€æåå¿ã130â135âã§æŽã«20æéå®æœã
ãããã·ã¬ã³ãåºããéããŠé€å»ããæ®çç©ãã
ããµã³ããïŒåºŠåçµæ¶ããããããã«ããèç¹ã
132â133âã§ããïŒâïœïŒâããããã·âïŒâ第
ïŒããã«âïŒâãβâïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒâã
ã³ã¿ã¡ãã«âïŒâãããªãžãã«ãªãã·ã«ã«ãã
ã«ïŒâãšãã«ãâããšãã«ïœâãã³ãŸããªã¢ãŸãŒ
ã«ïŒååç©15ïŒãåŸãã ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâãã
ããã·ãããªãžã³ã®ä»£ããã«åœéã®ïŒâã¢ã»ãã«
âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãããã
ã·ãããªãžã³ãããã¯ïŒâãã³ãžã«âïŒïŒïŒïŒ
ïŒïŒïŒâããã©ã¡ãã«âïŒâããããã·ãããªãž
ã³ã䜿çšãããã以å€ã¯åè¿°ãšåæ§ã®æäœãè¡ãª
ããšãèç¹105â106âã§ããïŒâïœïŒâãããã
ã·âïŒâ第ïŒããã«âïŒâãβâïŒïŒâã¢ã»ãã«
âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãããªãž
ãã«ãªãã·ã«ã«ããã«ïŒâãšãã«ãâããšãã«ïœ
âãã³ãŸããªã¢ãŸãŒã«ïŒååç©16ïŒãããã¯åã
èç¹ã108â109âã§ããïŒâããããã·âïŒâ第
ïŒããã«âïŒâãβâïŒïŒâãã³ãžã«âïŒïŒïŒïŒ
ïŒïŒïŒâããã©ã¡ãã«âïŒâãããªãžãã«ãªãã·
ã«ã«ããã«ïŒâãšãã«ãâããšãã«ïœâãã³ãŸã
ãªã¢ãŸãŒã«ïŒååç©17ïŒãåŸãã å®æœäŸ 10ïŒ ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã¢ããã
ããªãžã³15.6ïœåã³ããªãšãã«ã¢ãã³10.5ïœã宀
æž©ã§ãã«ãšã³300mlã«å°å ¥ãããããªãšã³300mläž
ã®ïŒâïŒïŒâããããã·âïŒâ第ïŒããã«âïŒâ
βâã¯ããã«ã«ããã«âãšãã«ããšãã«ïŒâãã³
ãŸããªã¢ãŸãŒã«35.8ïœã®æº¶æ¶²ãçŽ90åãããŠãã®
溶液ã«æ»Žå ãããã®åŸåå¿æ··åç©ã宀枩ã§10æé
æ¹æãããæ²æ®¿ããããªãšãã«ã¢ãã³å¡©é žå¡©ãã
éããããã«ãšã³ãèžçããé€å»ããåŸãæ®çç©
ããªã°ãã€ã³ããïŒåºŠåçµæ¶ããããããã«ãã
èç¹ã210â211âã§ããïŒâïœïŒâããããã·â
ïŒâ第ïŒããã«âïŒâãβâïŒïŒïŒïŒïŒïŒïŒïŒâ
ããã©ã¡ãã«âïŒâãããªãã«ã¢ããã«ã«ãã
ã«ïŒâãšãã«ãâããšãã«ïœâãã³ãŸããªã¢ãŸãŒ
ã«ïŒååç©18ïŒãåŸãã ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã¢ããã
ããªãžã³ã®ä»£ããã«åœéã®ïŒïŒïŒïŒïŒïŒïŒïŒïŒâ
ãã³ã¿ã¡ãã«âïŒâã¢ãããããªãžã³ãããã¯ïŒ
âã¢ã»ãã«âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒ
âã¢ãããããªãžã³ãããã¯ïŒïŒïŒïŒïŒïŒïŒïŒ
ïŒïŒâãã³ã¿ã¡ãã«âïŒâïœâããã«ã¢ãããã
ãªãžã³ã䜿çšãããã以å€ã¯åè¿°ãšåæ§ã®æäœã
è¡ãªããšãèç¹181â183âã§ããïŒâïœïŒâãã
ããã·âïŒâ第ïŒããã«âïŒâãβâïŒïŒïŒïŒïŒ
ïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâãããªãžãã«ã¢
ããã«ã«ããã«ïŒâãšãã«ãããšãã«ïœâãã³ãŸ
ããªã¢ãŸãŒã«ïŒååç©19ïŒãããã¯èç¹198â199
âã§ããïŒâïœïŒâããããã·âïŒâ第ïŒããã«
âïŒâãβâïŒïŒâã¢ã»ãã«âïŒïŒïŒïŒïŒïŒïŒâ
ããã©ã¡ãã«âïŒâãããªãžãã«ã¢ããã«ã«ãã
ã«ïŒâãšãã«ãããšãã«ïœâãã³ãŸããªã¢ãŸãŒã«
ïŒååç©20ïŒãããã¯èç¹57â60âã§ããïŒâ
ïœïŒâããããã·âïŒâ第ïŒããã«âïŒâãβâ
ïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒââ
ïœâããã«âãããªãžãã«ã¢ããã«ã«ããã«ïŒâ
ãšãã«ãâããšãã«ïœâãã³ãŸããªã¢ãŸãŒã«ïŒå
åç©21ïŒãåŸãã å®æœäŸ 11ïŒ ïŒâïŒïŒâããããã·âïŒâ第ïŒããã«âïŒâ
βâã¡ããã·âã«ã«ããã«âãšãã«âããšãã«ïŒ
âãã³ãŸããªã¢ãŸãŒã«35.3ïœåã³ïŒâã¢ã¶âïŒâ
ãšãã«âïŒâããããã·ã¡ãã«âïŒïŒïŒïŒ10ïŒ10
âããã©ã¡ãã«âïŒïŒïŒâãžãªããµâã¹ãã
ã5.5ããŠã³ãã«ã³27.1ïœãããã¯ïŒâã¢ã¶âïŒâ
ã¢ã»ãã«âïŒâãšãã«âïŒâããããã·ã¡ãã«â
ïŒïŒïŒïŒ10ïŒ10âããã©ã¡ãã«âïŒïŒïŒâãžãªã
ãµâã¹ããã5.5ããŠã³ãã«ã³31.3ïœãå®æœäŸïŒ
ã§èšèŒããããã«ãã·ã¬ã³300mläžã§ãšã¹ãã«äº€
æåå¿ãè¡ãªããã¢ã»ããããªã«ããåçµæ¶ãã
ãšäžèšã®æ§é ãæãããåã èç¹ã93â95âã§ã
ãååç©22ãèç¹ã143â144âã§ããååç©23ã
åŸãã å®æœäŸ 12ïŒ ïŒâïŒïŒâããããã·âïŒâ第ïŒããã«âïŒâ
βâã«ã«ããã·âãšãã«âããšãã«ïŒâãã³ãŸã
ãªã¢ãŸãŒã«17.0ïœåã³ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³
ã¿ã¡ãã«âïŒâã°ãªã·ãžã«ãªãã·ãããªãžã³11.7
ïœããã·ã¬ã³100mläžã§éæµäžã§15æéå ç±ããã
ãã·ã¬ã³ãèžçããŠãæ®çç©ãã¢ã»ããããªã«ã
ãïŒåºŠåçµæ¶ããããããã«ããèç¹ã50â52â
ã§ããïŒâïœïŒâããããã·âïŒâ第ïŒããã«â
ïŒâãβâïŒïŒâããããã·âïŒâãïŒïŒïŒïŒ
ïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâãããªãžãã«ãª
ãã·ãâããããªãªãã·ã«ã«ããã«ïŒâãšãã«ã
ããšãã«ïœâãã³ãŸããªã¢ãŸãŒã«ïŒååç©24ïŒã
åŸãã å®æœäŸ 13ïŒ ïŒâïŒïŒâããããã·âïŒâ第ïŒããã«âïŒâ
βâã¡ããã·âã«ã«ããã«âãšãã«âããšãã«ïŒ
âãã³ãŸããªã¢ãŸãŒã«35.5ïœåã³ïŒâããããã·
ãšãã«âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã
ãããã·ãããªãžã³10.5ïœãå®æœäŸïŒã«èšèŒãã
ããã«ãã·ã¬ã³300mläžã§ãšã¹ãã«äº€æåå¿ãè¡
ãªãããããµã³ããåçµæ¶ãããšãèç¹162â164
âã§ããäžè¿°ã®æ§é ãæããïŒâããããã·ãšã
ã«âïŒâããããã·âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡
ãã«ãããªãžã³ã®ãã¹âïŒÎ²âãïŒâãã³ãŸããª
ã¢ãŸãŒã«âïŒâã€ã«ïŒâïŒâããããã·âïŒâ第
äžããã«âããšãã«ãâããããªããŒãïŒååç©
25ïŒãåŸãã
â第ïŒããã«âïŒâβâã¡ããã·ã«ã«ããã«âãš
ãã«âããšãã«ïŒâãã³ãŸããªã¢ãŸãŒã«21.2ïœå
ã³ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâãã
ããã·ãããªãžã³10.2ïœã130â135âã§ãã ãã
ãªçªçŽ æµäžã§20æéå ç±ããåŸãããã©ããã«ãª
ã«ããã¿ããŒã0.5ïœãæ·»å ããã圢æããã¡ã¿
ããŒã«ãç¶ããŠèžçããŠé€å»ããããã®åŸããã
ã©ããã«ãªã«ããã¿ããŒã0.5ïœãæ·»å ããŠããš
ã¹ãã«äº€æåå¿ã130â135âã§æŽã«20æéå®æœã
ãããã·ã¬ã³ãåºããéããŠé€å»ããæ®çç©ãã
ããµã³ããïŒåºŠåçµæ¶ããããããã«ããèç¹ã
132â133âã§ããïŒâïœïŒâããããã·âïŒâ第
ïŒããã«âïŒâãβâïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒâã
ã³ã¿ã¡ãã«âïŒâãããªãžãã«ãªãã·ã«ã«ãã
ã«ïŒâãšãã«ãâããšãã«ïœâãã³ãŸããªã¢ãŸãŒ
ã«ïŒååç©15ïŒãåŸãã ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâãã
ããã·ãããªãžã³ã®ä»£ããã«åœéã®ïŒâã¢ã»ãã«
âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãããã
ã·ãããªãžã³ãããã¯ïŒâãã³ãžã«âïŒïŒïŒïŒ
ïŒïŒïŒâããã©ã¡ãã«âïŒâããããã·ãããªãž
ã³ã䜿çšãããã以å€ã¯åè¿°ãšåæ§ã®æäœãè¡ãª
ããšãèç¹105â106âã§ããïŒâïœïŒâãããã
ã·âïŒâ第ïŒããã«âïŒâãβâïŒïŒâã¢ã»ãã«
âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâãããªãž
ãã«ãªãã·ã«ã«ããã«ïŒâãšãã«ãâããšãã«ïœ
âãã³ãŸããªã¢ãŸãŒã«ïŒååç©16ïŒãããã¯åã
èç¹ã108â109âã§ããïŒâããããã·âïŒâ第
ïŒããã«âïŒâãβâïŒïŒâãã³ãžã«âïŒïŒïŒïŒ
ïŒïŒïŒâããã©ã¡ãã«âïŒâãããªãžãã«ãªãã·
ã«ã«ããã«ïŒâãšãã«ãâããšãã«ïœâãã³ãŸã
ãªã¢ãŸãŒã«ïŒååç©17ïŒãåŸãã å®æœäŸ 10ïŒ ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã¢ããã
ããªãžã³15.6ïœåã³ããªãšãã«ã¢ãã³10.5ïœã宀
æž©ã§ãã«ãšã³300mlã«å°å ¥ãããããªãšã³300mläž
ã®ïŒâïŒïŒâããããã·âïŒâ第ïŒããã«âïŒâ
βâã¯ããã«ã«ããã«âãšãã«ããšãã«ïŒâãã³
ãŸããªã¢ãŸãŒã«35.8ïœã®æº¶æ¶²ãçŽ90åãããŠãã®
溶液ã«æ»Žå ãããã®åŸåå¿æ··åç©ã宀枩ã§10æé
æ¹æãããæ²æ®¿ããããªãšãã«ã¢ãã³å¡©é žå¡©ãã
éããããã«ãšã³ãèžçããé€å»ããåŸãæ®çç©
ããªã°ãã€ã³ããïŒåºŠåçµæ¶ããããããã«ãã
èç¹ã210â211âã§ããïŒâïœïŒâããããã·â
ïŒâ第ïŒããã«âïŒâãβâïŒïŒïŒïŒïŒïŒïŒïŒâ
ããã©ã¡ãã«âïŒâãããªãã«ã¢ããã«ã«ãã
ã«ïŒâãšãã«ãâããšãã«ïœâãã³ãŸããªã¢ãŸãŒ
ã«ïŒååç©18ïŒãåŸãã ïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã¢ããã
ããªãžã³ã®ä»£ããã«åœéã®ïŒïŒïŒïŒïŒïŒïŒïŒïŒâ
ãã³ã¿ã¡ãã«âïŒâã¢ãããããªãžã³ãããã¯ïŒ
âã¢ã»ãã«âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒ
âã¢ãããããªãžã³ãããã¯ïŒïŒïŒïŒïŒïŒïŒïŒ
ïŒïŒâãã³ã¿ã¡ãã«âïŒâïœâããã«ã¢ãããã
ãªãžã³ã䜿çšãããã以å€ã¯åè¿°ãšåæ§ã®æäœã
è¡ãªããšãèç¹181â183âã§ããïŒâïœïŒâãã
ããã·âïŒâ第ïŒããã«âïŒâãβâïŒïŒïŒïŒïŒ
ïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâãããªãžãã«ã¢
ããã«ã«ããã«ïŒâãšãã«ãããšãã«ïœâãã³ãŸ
ããªã¢ãŸãŒã«ïŒååç©19ïŒãããã¯èç¹198â199
âã§ããïŒâïœïŒâããããã·âïŒâ第ïŒããã«
âïŒâãβâïŒïŒâã¢ã»ãã«âïŒïŒïŒïŒïŒïŒïŒâ
ããã©ã¡ãã«âïŒâãããªãžãã«ã¢ããã«ã«ãã
ã«ïŒâãšãã«ãããšãã«ïœâãã³ãŸããªã¢ãŸãŒã«
ïŒååç©20ïŒãããã¯èç¹57â60âã§ããïŒâ
ïœïŒâããããã·âïŒâ第ïŒããã«âïŒâãβâ
ïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒââ
ïœâããã«âãããªãžãã«ã¢ããã«ã«ããã«ïŒâ
ãšãã«ãâããšãã«ïœâãã³ãŸããªã¢ãŸãŒã«ïŒå
åç©21ïŒãåŸãã å®æœäŸ 11ïŒ ïŒâïŒïŒâããããã·âïŒâ第ïŒããã«âïŒâ
βâã¡ããã·âã«ã«ããã«âãšãã«âããšãã«ïŒ
âãã³ãŸããªã¢ãŸãŒã«35.3ïœåã³ïŒâã¢ã¶âïŒâ
ãšãã«âïŒâããããã·ã¡ãã«âïŒïŒïŒïŒ10ïŒ10
âããã©ã¡ãã«âïŒïŒïŒâãžãªããµâã¹ãã
ã5.5ããŠã³ãã«ã³27.1ïœãããã¯ïŒâã¢ã¶âïŒâ
ã¢ã»ãã«âïŒâãšãã«âïŒâããããã·ã¡ãã«â
ïŒïŒïŒïŒ10ïŒ10âããã©ã¡ãã«âïŒïŒïŒâãžãªã
ãµâã¹ããã5.5ããŠã³ãã«ã³31.3ïœãå®æœäŸïŒ
ã§èšèŒããããã«ãã·ã¬ã³300mläžã§ãšã¹ãã«äº€
æåå¿ãè¡ãªããã¢ã»ããããªã«ããåçµæ¶ãã
ãšäžèšã®æ§é ãæãããåã èç¹ã93â95âã§ã
ãååç©22ãèç¹ã143â144âã§ããååç©23ã
åŸãã å®æœäŸ 12ïŒ ïŒâïŒïŒâããããã·âïŒâ第ïŒããã«âïŒâ
βâã«ã«ããã·âãšãã«âããšãã«ïŒâãã³ãŸã
ãªã¢ãŸãŒã«17.0ïœåã³ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³
ã¿ã¡ãã«âïŒâã°ãªã·ãžã«ãªãã·ãããªãžã³11.7
ïœããã·ã¬ã³100mläžã§éæµäžã§15æéå ç±ããã
ãã·ã¬ã³ãèžçããŠãæ®çç©ãã¢ã»ããããªã«ã
ãïŒåºŠåçµæ¶ããããããã«ããèç¹ã50â52â
ã§ããïŒâïœïŒâããããã·âïŒâ第ïŒããã«â
ïŒâãβâïŒïŒâããããã·âïŒâãïŒïŒïŒïŒ
ïŒïŒïŒïŒïŒâãã³ã¿ã¡ãã«âïŒâãããªãžãã«ãª
ãã·ãâããããªãªãã·ã«ã«ããã«ïŒâãšãã«ã
ããšãã«ïœâãã³ãŸããªã¢ãŸãŒã«ïŒååç©24ïŒã
åŸãã å®æœäŸ 13ïŒ ïŒâïŒïŒâããããã·âïŒâ第ïŒããã«âïŒâ
βâã¡ããã·âã«ã«ããã«âãšãã«âããšãã«ïŒ
âãã³ãŸããªã¢ãŸãŒã«35.5ïœåã³ïŒâããããã·
ãšãã«âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«âïŒâã
ãããã·ãããªãžã³10.5ïœãå®æœäŸïŒã«èšèŒãã
ããã«ãã·ã¬ã³300mläžã§ãšã¹ãã«äº€æåå¿ãè¡
ãªãããããµã³ããåçµæ¶ãããšãèç¹162â164
âã§ããäžè¿°ã®æ§é ãæããïŒâããããã·ãšã
ã«âïŒâããããã·âïŒïŒïŒïŒïŒïŒïŒâããã©ã¡
ãã«ãããªãžã³ã®ãã¹âïŒÎ²âãïŒâãã³ãŸããª
ã¢ãŸãŒã«âïŒâã€ã«ïŒâïŒâããããã·âïŒâ第
äžããã«âããšãã«ãâããããªããŒãïŒååç©
25ïŒãåŸãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¬¡åŒïŒ¡ãããã¯ïŒ¡ïŒ ïŒåŒäžã åŒïŒ¡ã«ãããã®ãã¡ã®ã²ãšã€ã¯æ°ŽçŽ ååã
è¡šããããã€ä»ã®ïŒ²ã¯èªç±åå䟡ãè¡šãããåŒïŒ¡
ã«ãããã¯èªç±åå䟡ãè¡šããã R2ã¯æ°ŽçŽ ååãççŽ ååæ°ïŒãªããïŒã®ã¢ã«
ãã«åºãããã¯ã·ã¯ãããã·ã«åºãè¡šããã䞊ã³
ã« R3ã¯æ°ŽçŽ ååãããã¯ççŽ ååæ°ïŒãªããïŒ
ã®ã¢ã«ãã«åºãè¡šãããïŒã§è¡šããããåºãïŒã
ããã¯ïŒåãšæ¬¡åŒïŒ¢ïŒïŒ¢ïŒïŒ¢ãããã¯ïŒ¢
XIïŒ ïŒåŒäžã R7ã¯æ°ŽçŽ ååãã¡ãã«åºãã¢ã»ãã«åºããã
ã¯ãã³ãžã«åºãè¡šããã R9ã¯åºâCH2âCHïŒCHâCH2âãè¡šããã
䞊ã³ã« ã¯åºãåŒããè¡šãããïŒã§è¡šã ãããåºã®ãã¡ã®ïŒåãå«æããåºïŒ¡ãããã¯
ãçŽæ¥çµåãŸãã¯çµååºïŒºãã¯ä»¥äžã®åºã®
ãã¡ã®ã²ãšã€ãè¡šããããšãã§ãããïŒ âCH2CH2COââïŒCH2CH2âCOâïŒR15ïŒ
âïŒâCH2CH2âCOââCH2CHïŒOHïŒCH2â
âïŒâCONHâïŒâCOâNHâCH2CH2âïŒ
âCH2CH2ââCOâCH2ââïŒâCH2CH2
âCOââCH2CH2â ïŒR15ã¯æ°ŽçŽ ååãããã¯ããã«åºãè¡šã
ããïŒãã«ããåºïŒ¢ïŒïŒ¢ïŒïŒ¢ãããã¯ïŒ¢XIã«
çµåããŠãããããŸãã¯åºïŒ¡ãåºââCH2â
COââãä»ããŠåºïŒ¢ãããã¯ïŒ¢ã«çµåã
ãŠããååç©ã ïŒ ïŒ¢ãŸãã¯ïŒ¢ã®åºã®ïŒçš®ãŸãã¯ïŒçš®ãæã
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ååç©ã ïŒ ïŒçš®ãŸãã¯ïŒçš®ã®ïŒ¡åºãããŸãã¯
XIåºã«å¯ŸããŠçŽæ¥çµåã«ããããŸãã¯æ¬¡åŒïŒ âCH2CH2COââïŒâCH2CH2âCOâ
ïŒR15ïŒâïŒâCH2CH2ââCOâCH2ââïŒ
âCH2CH2âCOââCH2CH2â ïŒåŒäžã R15ã¯ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æå³ãè¡šã
ããïŒã§è¡šããããåºã®ïŒã€ã«ããçµåããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ååç©ã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1008878 | 1978-09-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5549355A JPS5549355A (en) | 1980-04-09 |
| JPS64948B2 true JPS64948B2 (ja) | 1989-01-10 |
Family
ID=4359192
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12468879A Granted JPS5549355A (en) | 1978-09-27 | 1979-09-27 | Novel photoostabilizer compound and stabilization of organic polymer by said compound |
Country Status (4)
| Country | Link |
|---|---|
| US (2) | US4289686A (ja) |
| EP (1) | EP0010516B1 (ja) |
| JP (1) | JPS5549355A (ja) |
| DE (1) | DE2963346D1 (ja) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4402983A (en) * | 1980-09-19 | 1983-09-06 | E. I. Du Pont De Nemours & Co. | Powder coating composition for automotive topcoat |
| DE3264154D1 (en) * | 1981-01-23 | 1985-07-25 | Ciba Geigy Ag | 2-(2-hydroxyphenyl)-benzotriazoles, their use as ultraviolet stabilizers and their preparation |
| JPS58113236A (ja) * | 1981-12-28 | 1983-07-06 | Tounen Sekiyu Kagaku Kk | ããªãªã¬ãã€ã³çµæç© |
| EP0101411B1 (de) * | 1982-08-11 | 1989-01-25 | Ciba-Geigy Ag | Verfahren zur chemischen Bindung von Stabilisatoren an Polymere |
| EP0114029B1 (de) * | 1982-12-16 | 1987-09-16 | Ciba-Geigy Ag | Farbphotographisches Aufzeichnungsmaterial |
| JPS59126439A (ja) * | 1983-01-10 | 1984-07-21 | Adeka Argus Chem Co Ltd | å®å®åé«ååææçµæç© |
| US4785102A (en) * | 1985-08-27 | 1988-11-15 | Ciba-Geigy Corporation | Photolytically cleavable, N-acylated sterically hindered amines |
| GB8626608D0 (en) * | 1986-11-07 | 1986-12-10 | Sandoz Ltd | Organic compounds |
| US4863918A (en) * | 1987-02-06 | 1989-09-05 | Boc, Inc. | Enamine quaternary compounds, methods of making and their use as muscle relaxants |
| US4975489A (en) * | 1987-08-12 | 1990-12-04 | Atochem North America, Inc. | Process for preparing polymer bound hindered amine light stabilizers |
| US4868246A (en) * | 1987-08-12 | 1989-09-19 | Pennwalt Corporation | Polymer bound UV stabilizers |
| US5096977A (en) * | 1987-08-12 | 1992-03-17 | Atochem North America, Inc. | Process for preparing polymer bound UV stabilizers |
| US4857595A (en) * | 1987-08-12 | 1989-08-15 | Pennwalt Corporation | Polymer bound hindered amine light stabilizers |
| US5206378A (en) * | 1987-08-12 | 1993-04-27 | Elf Atochem North America, Inc. | Hydrazido functionalized 2-(2-hydroxyphenyl)-2h-benzotriazoles |
| US4981914A (en) * | 1987-08-12 | 1991-01-01 | Atochem North America, Inc. | Polymer bound UV stabilizers |
| US4859759A (en) * | 1988-04-14 | 1989-08-22 | Kimberly-Clark Corporation | Siloxane containing benzotriazolyl/tetraalkylpiperidyl substituent |
| EP0389427B1 (en) * | 1989-03-21 | 1994-04-27 | Ciba-Geigy Ag | Compounds containing both uv-absorber and 1-hydrocarbyloxy hindered amine moieties and stabilized compositions |
| US5041545A (en) * | 1989-04-06 | 1991-08-20 | Atochem North America, Inc. | 2-hydroxybenzophenone hydrazides and derivatives thereof |
| FR2653768A1 (fr) * | 1989-10-27 | 1991-05-03 | Rhone Poulenc Chimie | Nouveaux composes a motif tetramethylpiperidinyle. |
| DE59109192D1 (de) * | 1990-04-20 | 2000-08-17 | Ciba Sc Holding Ag | Verbindungen aus o-Hydroxyphenyl-1,3,5-triazinen und sterisch gehinderten Aminen |
| DE59107294D1 (de) * | 1990-05-10 | 1996-03-07 | Ciba Geigy Ag | StrahlenhÀrtbare lichtstabilisierte Zusammensetzungen |
| IT1247974B (it) * | 1991-06-04 | 1995-01-05 | Sigma Prod Chim | Derivati di piperidina, loro preparazione e uso |
| DE19738615A1 (de) | 1997-09-04 | 1999-03-11 | Clariant Gmbh | Neue Lichtschutzmittel auf Basis von sterisch gehinderten Aminen |
| US6191199B1 (en) | 1999-05-03 | 2001-02-20 | Ciba Speciatly Chemicals Corporation | Stabilized adhesive compositions containing highly soluble, high extinction photostable hydroxyphenyl-s-triazine UV absorbers and laminated articles derived therefrom |
| US6251173B1 (en) | 1999-10-29 | 2001-06-26 | Lexmark International, Inc. | Ink compositions containing ultraviolet absorbers |
| US6846929B2 (en) * | 2001-04-02 | 2005-01-25 | Ciba Specialty Chemicals Corporation | Benzotriazole/hals molecular combinations and compositions stabilized therewith |
| US11417857B2 (en) * | 2018-01-24 | 2022-08-16 | Samsung Display Co., Ltd. | Heterocyclic compound and electronic apparatus |
| KR20190090415A (ko) * | 2018-01-24 | 2019-08-02 | ìŒì±ëì€íë ìŽ ì£Œìíì¬ | ì ì ì¥ì¹ ë° ìŽì ì ì¡°ë°©ë² |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4127501A (en) * | 1974-09-03 | 1978-11-28 | Eastman Kodak Company | Polychromophoric ultraviolet stabilizers and their use in organic compositions |
| US4191683A (en) * | 1975-05-28 | 1980-03-04 | Ciba-Geigy Corporation | Derivatives of 4-aminopiperidine as stabilizers for polymers |
| JPS583496B2 (ja) * | 1975-08-19 | 1983-01-21 | åžäººæ ªåŒäŒç€Ÿ | ããªãšâãã«ãšã¹ãã«çµæç© |
| DE2719133A1 (de) * | 1976-05-11 | 1977-12-01 | Ciba Geigy Ag | Neue stabilisatoren |
| US4161592A (en) * | 1976-07-08 | 1979-07-17 | Ciba-Geigy Corporation | Piperidinyl-s-triazines |
| US4118369A (en) * | 1976-07-28 | 1978-10-03 | Argus Chemical Corporation | 2,2,6,6-Tetrasubstituted-4-piperidyl carboxy heterocyclic compounds as stabilizers for synthetic polymers |
| US4085089A (en) * | 1976-08-16 | 1978-04-18 | Eastman Kodak Company | Benzotriazole ultraviolet stabilizing compounds and their use in organic compositions |
| US4182703A (en) * | 1978-01-09 | 1980-01-08 | Eastman Kodak Company | Biheterocyclic ultraviolet stabilizers and their use in organic compositions |
-
1979
- 1979-09-17 US US06/076,106 patent/US4289686A/en not_active Expired - Lifetime
- 1979-09-21 DE DE7979810102T patent/DE2963346D1/de not_active Expired
- 1979-09-21 EP EP79810102A patent/EP0010516B1/de not_active Expired
- 1979-09-27 JP JP12468879A patent/JPS5549355A/ja active Granted
-
1983
- 1983-02-28 US US06/470,742 patent/US4481315A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0010516B1 (de) | 1982-07-14 |
| DE2963346D1 (en) | 1982-09-02 |
| US4289686A (en) | 1981-09-15 |
| EP0010516A1 (de) | 1980-04-30 |
| US4481315A (en) | 1984-11-06 |
| JPS5549355A (en) | 1980-04-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS64948B2 (ja) | ||
| EP0427672B1 (en) | Polymer stabilizers containing both hindered amine and hydroxylamine moieties | |
| JP2973120B2 (ja) | â眮æç«äœé害æ§ã¢ãã³å®å®å€ | |
| US5021486A (en) | Hindered amine-substituted malonic acid derivatives of s-triazine | |
| US6562815B1 (en) | Morpholinones as light stabilizers | |
| JPS6341911B2 (ja) | ||
| EP0309400A2 (en) | N-acyloxy hindered amine stabilizers | |
| EP0413665B1 (en) | Polymer stabilizers containing both hindered amine and nitrone moieties | |
| JP3259180B2 (ja) | ïœâããããã·ãã§ãã«âïŒïŒïŒïŒïŒâããªã¢ãžã³åºããã³ããªã¢ã«ãã«ãããªãžã³åºãå«ãååç© | |
| JP2002518488A (ja) | é»å€ããªãããã©ç¬¬äžçŽã¢ã«ãã«ãã§ãã«çœ®æããªã¢ãžã³åã³ããªããžã³çŽ«å€ç·åžåå€ | |
| JP2782449B2 (ja) | ããã©ã¡ãã«ãããªãžãâïœâããªã¢ãžã³ | |
| CA2012506C (en) | Azo compounds containing hindered amine moieties with low basicity | |
| HK97084A (en) | 2-(3.5-disubstituted-2-hydroxyphenyl)-2h-benzotriazoles and stabilized compositions containing them | |
| KR19980081646A (ko) | íŽëŠ¬ìí¬ë êžëŠ¬ìœêž°-íšì ì 첎 ì¥ì ì믌 | |
| CA2012493C (en) | 1-hydrocarbyloxy hindered amine mercaptoacid esters, thioacetals, sulfides and disulfides | |
| EP0389432B1 (en) | Hindered amine derivatives of triazine and hexahydrotriazine | |
| US5026750A (en) | 1-hydrocarbyloxy hindered amine mercaptoacid esters, thioacetals, sulfides and disulfides | |
| US4407993A (en) | Hindered piperidine polymer stabilizers | |
| JPS62116561A (ja) | ããã©ã¢ã«ãã«ãããªãžã³ååç© |