JPS649952A - Production of optically active penylacetic acid derivative - Google Patents

Production of optically active penylacetic acid derivative

Info

Publication number
JPS649952A
JPS649952A JP62162690A JP16269087A JPS649952A JP S649952 A JPS649952 A JP S649952A JP 62162690 A JP62162690 A JP 62162690A JP 16269087 A JP16269087 A JP 16269087A JP S649952 A JPS649952 A JP S649952A
Authority
JP
Japan
Prior art keywords
optically active
formula
expressed
hydrogen
derivative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62162690A
Other languages
Japanese (ja)
Other versions
JPH0816078B2 (en
Inventor
Norio Kawamura
Kazuki Takemoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP62162690A priority Critical patent/JPH0816078B2/en
Publication of JPS649952A publication Critical patent/JPS649952A/en
Publication of JPH0816078B2 publication Critical patent/JPH0816078B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE:To obtain a compound useful as a synthetic intermediate for medicines and agricultural chemicals in good conversion ate and optical yield, by asymmetrically reducing an olefin derivative with hydrogen in the presence of a metallic catalyst modified with an optically active binaphthyl derivative. CONSTITUTION:An olefin derivative expressed by formula I (R1 and R2 are H or lower alkyl; R3 and R4 are H, halogen, lower alkyl or lower alkoxyl) is reacted with hydrogen in the presence of a metallic catalyst modified with an optically active binaphthyl derivative expressed by formula II (R is lower alkylphenyl, lower alkoxyphenyl or 3-8C cycloalkyl) in a solvent, such as methanol, preferably at 50-100 deg.C under 30-150kg/cm<2> hydrogen pressure to afford the aimed substance expressed by formula III. A transition metal, such as Rh or Ru, is used as a metallic component in the catalyst and the metallic catalyst obtained by a well-known method is used in an amount of preferably 0.1-1mol.% based on the compound expressed by formula I.
JP62162690A 1987-06-29 1987-06-29 Process for producing optically active phenylacetic acid derivative Expired - Lifetime JPH0816078B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62162690A JPH0816078B2 (en) 1987-06-29 1987-06-29 Process for producing optically active phenylacetic acid derivative

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62162690A JPH0816078B2 (en) 1987-06-29 1987-06-29 Process for producing optically active phenylacetic acid derivative

Publications (2)

Publication Number Publication Date
JPS649952A true JPS649952A (en) 1989-01-13
JPH0816078B2 JPH0816078B2 (en) 1996-02-21

Family

ID=15759448

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62162690A Expired - Lifetime JPH0816078B2 (en) 1987-06-29 1987-06-29 Process for producing optically active phenylacetic acid derivative

Country Status (1)

Country Link
JP (1) JPH0816078B2 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6468386A (en) * 1987-09-08 1989-03-14 Takasago Perfumery Co Ltd 2,2'-bis(di-(p-methoxyphenyl)phosphino)-1,1'-binaphthyl
EP0479542A1 (en) * 1990-10-01 1992-04-08 Takasago International Corporation A phosphino binaphthyl compound and transition metal complexes thereof
US5563295A (en) * 1994-03-08 1996-10-08 Takasago International Corporation Process for producing optically active carboxylic acid
US5572585A (en) * 1989-09-28 1996-11-05 Canon Kabushi Kaisha Communication system and call processing method
US5910606A (en) * 1996-01-31 1999-06-08 Hoffmann-La Roche Inc. Process for making α,β-unsaturated carboxylic acids
JP2006346911A (en) * 2005-06-14 2006-12-28 Duplo Corp Bookbinding equipment

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63239245A (en) * 1986-11-14 1988-10-05 Takasago Corp Production of optically active carboxylic acid

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63239245A (en) * 1986-11-14 1988-10-05 Takasago Corp Production of optically active carboxylic acid

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6468386A (en) * 1987-09-08 1989-03-14 Takasago Perfumery Co Ltd 2,2'-bis(di-(p-methoxyphenyl)phosphino)-1,1'-binaphthyl
US5572585A (en) * 1989-09-28 1996-11-05 Canon Kabushi Kaisha Communication system and call processing method
EP0479542A1 (en) * 1990-10-01 1992-04-08 Takasago International Corporation A phosphino binaphthyl compound and transition metal complexes thereof
EP0479542B1 (en) * 1990-10-01 1995-11-29 Takasago International Corporation A phosphino binaphthyl compound and transition metal complexes thereof
US5563295A (en) * 1994-03-08 1996-10-08 Takasago International Corporation Process for producing optically active carboxylic acid
US5910606A (en) * 1996-01-31 1999-06-08 Hoffmann-La Roche Inc. Process for making α,β-unsaturated carboxylic acids
JP2006346911A (en) * 2005-06-14 2006-12-28 Duplo Corp Bookbinding equipment

Also Published As

Publication number Publication date
JPH0816078B2 (en) 1996-02-21

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