KR100795970B1 - Shopping softener composition used in dyeing process and manufacturing method thereof - Google Patents
Shopping softener composition used in dyeing process and manufacturing method thereof Download PDFInfo
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- KR100795970B1 KR100795970B1 KR1020070113830A KR20070113830A KR100795970B1 KR 100795970 B1 KR100795970 B1 KR 100795970B1 KR 1020070113830 A KR1020070113830 A KR 1020070113830A KR 20070113830 A KR20070113830 A KR 20070113830A KR 100795970 B1 KR100795970 B1 KR 100795970B1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
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Abstract
본 발명은 저온에서 사용가능한 쇼핑(Soaping) 유연제에 관한 것으로, 더욱 상세하게는 종래 염색과정 중 이루어지던 고온 쇼핑과 유연제의 사용으로 인해 에너지 낭비, 작업시간의 장기화 및 복잡한 공정으로 인한 제품 불량률 문제를 해결하기 위해, 폴리옥시에틸렌 트리데실 에테르(Polyoxyethylene tridecyl ether), 폴리옥시에틸렌 세틸 에테르(Polyoxyethylene cethyl ether) 포스페이트(Phosphate), 폴리옥시에틸렌 라우릴 에테르(Polyoxyethylene lauryl ether)와, 디프로필렌 글리콜(Dipropylene glycol), 실록산(Siloxane) 또는 실리콘 디 메틸 하이드로프로필렌(Silicones di-Me, 3-hydroxypropyl) 중 선택되는 어느 1종 이상 것과, 물(H2O) 의 혼합으로 조성하여 별도의 유연제를 사용하지 않고도 쇼핑처리가 가능하여 복잡한 공정을 단순화시킬 수 있으며, 무엇보다도 종래에 높은 온도에서만 가능하던 쇼핑처리과정을 저온에서 가능하게 함으로써 작업시간의 단추뿐만 아니라 에너지를 절약함으로써 생산성 향상의 효과를 갖는 쇼핑유연제 조성물 및 이를 제조하는 방법에 관한 것이다.The present invention relates to a shopping softener that can be used at low temperatures, and more particularly to the problem of product waste rate due to energy waste, prolonged working hours and complicated processes due to the use of high temperature shopping and softeners that have been conventionally made during the dyeing process. To solve this problem, polyoxyethylene tridecyl ether, polyoxyethylene cethyl ether phosphate, polyoxyethylene lauryl ether, and dipropylene glycol ), Any one or more selected from siloxane (Siloxane) or silicon dimethyl hydropropylene (Silicones di-Me, 3-hydroxypropyl), and a mixture of water (H 2 O) to make a shopping without using a separate softener Can be processed to simplify complex processes, and above all, only at high temperatures The present invention relates to a shopping softener composition having an effect of improving productivity by saving energy as well as a button of working time by enabling a shopping process at a low temperature, and a method of manufacturing the same.
Description
본 발명은 편직물의 염색과정 중 쇼핑(Soaping) 처리과정에서 저온상태로 사용가능한 쇼핑유연제 조성물 및 그 제조방법에 관한 것이다.The present invention relates to a shopping softener composition which can be used at a low temperature in a shopping process during dyeing of a knitted fabric, and a method of manufacturing the same.
일반적으로 편직물의 염색과정은 염액을 준비하는 과정과, 원사를 사용하여 얇게 편직하고, 그 편직물을 봉제하는 봉제공정과, 그 봉제된 편직물을 정련하여 수세, 탈수하는 공정과, 매염제를 이용하여 편직물을 매염하는 공정과, 앞서 준비한 염액에 편직물을 침지시키고, 그 편직물이 침지된 염액을 60℃까지 상승시켜 그 상승된 온도에서 1시간 동안 염색하는 염색공정과, 염액의 온도가 상온 근처까지 떨어질 수 있도록 방치 냉각하는 공정과, 유연제가 첨가된 90℃ 정도의 고온의 물에서 1시간 이상 쇼핑(Soaping) 처리하는 수세과정과, 수세과정을 거친 편직물을 탈수한 후 자연건조하는 건조과정을 거쳐 완성되며, 여기서 쇼핑(Soaping) 처리과정은 직물을 염색한 후 원단에 남아 있는 염료잔액, 오염물질을 제거(정련)하여 견 뢰도를 높이기 위해 세척하는 단계를 의미하는 것으로, 종래의 경우에는 유연제를 투입하여 높은 온도에서 쇼핑처리함으로써 온도 상승에 따른 에너지 소비 문제와 공정의 복잡하여 작업성이 떨어질 뿐만 아니라 제품의 불량률이 높다는 문제가 있었다.In general, the process of dyeing the knitted fabrics is to prepare a salt solution, to knit thinly using a yarn, to sew the knitted fabrics, to rinse, wash and dewater the sewn knitted fabrics, and to use a mordant. The dyeing process of immersing the knitted fabric in the previously prepared salt solution, raising the salt solution immersed in the knitted fabric to 60 ° C., and dyeing at the elevated temperature for 1 hour, and the temperature of the salt solution may drop to near room temperature. It is completed through the process of leaving it to cool, washing with water for more than 1 hour in a high temperature water of 90 ° C. with a softening agent, and drying after dehydrating the knitted fabric after washing with water. Here, the shopping process is performed to dye the fabric and to remove it from the dye residue and contaminants remaining on the fabric (refining) to increase the fastness. To mean the stage, there is a problem in the case of the prior art In the softening process by the shop at a temperature in the complexity of the energy consumption problem and the process according to the temperature increase as well as decrease the workability high defect rate of products.
상기와 같은 문제를 해결하기 위한 본 발명의 목적은 고온에서 처리하는 것이 아닌 저온에서도 처리가능함으로써, 온도 상승에 따른 연료소비 및 작업시간의 장기화 문제를 해결하고, 종래 쇼핑처리 후 사용하던 유연제가 필요 없으며, 공정을 단순화시킴으로써 제품 불량률을 줄일 수 있는 저온에서도 사용가능한 쇼핑제 조성물 및 이의 제조방법을 제공하는 것이다.The object of the present invention for solving the above problems is that it can be processed at low temperatures, not at high temperatures, thereby solving the problem of fuel consumption and prolonged working time due to temperature rise, and needing a softener used after the conventional shopping treatment. It is to provide a shopping composition and a method for manufacturing the same can be used even at low temperatures that can reduce the product defect rate by simplifying the process.
상기와 같은 목적을 달성하기 위해, 본 발명은 직물의 염색 후 원단에 남아 있는 염료잔액, 오염물질을 제거(정련)하여 견뢰도를 높이기 위한 염색공정에 사용되는 쇼핑유연제로서, 폴리옥시에틸렌 트리데실 에테르(Polyoxyethylene tridecyl ether) 3 ~ 25중량%와,In order to achieve the above object, the present invention is a shopping softener used in the dyeing process for increasing the fastness by removing (refining) dye residues and contaminants remaining on the fabric after dyeing the fabric, polyoxyethylene tridecyl ether (Polyoxyethylene tridecyl ether) 3 to 25% by weight,
폴리옥시에틸렌 세틸 에테르(Polyoxyethylene cethyl ether) 포스페이트(Phosphate) 1 ~ 10중량%와,1 to 10% by weight of polyoxyethylene cethyl ether phosphate (Phosphate),
폴리옥시에틸렌 라우릴 에테르(Polyoxyethylene lauryl ether) 2 ~ 20중량%,Polyoxyethylene lauryl ether 2 to 20% by weight,
디프로필렌 글리콜(Dipropylene glycol), 실록산(Siloxane) 또는 실리콘 디 메틸 하이드로프로필렌(Silicones di-Me, 3-hydroxypropyl) 중 선택되는 어느 1종 이상인 9 ~ 34중량%와,9 to 34% by weight of any one or more selected from dipropylene glycol, siloxane (Siloxane) or silicon dimethyl hydropropylene (Silicones di-Me, 3-hydroxypropyl),
물(H2O) 60 ~ 85중량%의 혼합으로 조성되는 염색공정에 사용되는 쇼핑유연제 조성물과,Shopping softener composition used in the dyeing process is composed of a mixture of water (H 2 O) 60 to 85% by weight,
이와 같은 조성물을 제조하기 위한 방법으로서, 교반기에 순차적으로 폴리옥시에틸렌 트리데실 에테르(Polyoxyethylene tridecyl ether), 폴리옥시에틸렌 세틸 에테르(Polyoxyethylene cethyl ether) 포스페이트(Phosphate), 폴리옥시에틸렌 라우릴 에테르(Polyoxyethylene lauryl ether)와 디프로필렌 글리콜(Dipropylene glycol), 실록산(Siloxane) 또는 실리콘 디 메틸 하이드로프로필렌(Silicones di-Me, 3-hydroxypropyl) 중 선택되는 어느 1종 이상을 투입하여 10 ~ 60분간 1차 교반하고, 여기에 물(H2O)을 투입하여 30분 ~ 1.5시간 2차 교반하여 이루어지는 염색공정에 사용되는 쇼핑유연제 제조방법을 발명의 주요 기술적 구성으로 한다.As a method for preparing such a composition, polyoxyethylene tridecyl ether, polyoxyethylene cethyl ether phosphate, polyoxyethylene lauryl ether ether and dipropylene glycol, siloxane (Siloxane) or silicon dimethyl hydropropylene (Silicones di-Me, 3-hydroxypropyl) is added at least one selected from the first stirring for 10 to 60 minutes, here the input of water (H 2 O) to the stirred for 30 minutes ~ 1.5 hours 2 car will be shopping softener production method used in the dyeing process comprising a major technical constitution of the invention.
이하, 상기한 기술적 구성에 대해 더욱 상세히 살펴보도록 한다.Hereinafter, the technical configuration will be described in more detail.
일반적인 염색처리과정은 염색 포트에 염료, 물, 조제(소다회), 원단을 투입하고, 히터가 가동되면서 포트에 투입된 물을 가열하여 포트의 온도를 상승시키고, 염색이 완료되면 포트에서 물을 제거한 후, 물을 분사하여 세척한 후에, 다시 그 포트에 물, 유연제, 쇼핑제를 투입하여 5℃/분 온도로 상승시켜 90 ~ 98℃까지 온도를 상승시키고, 이와 같은 상승한 온도 상태에서 1 ~ 1.5시간 가량 쇼핑처리하고, 이와 같이 쇼핑처리가 완료되면, 물로 세척하여 탈수하는 과정을 통해 원단의 염색이 완성된다.In general dyeing process, dye, water, preparation (soda ash), and fabric are added to the dyeing pot, and the water is heated in the pot by heating the heater to increase the temperature of the pot. After spraying and washing with water, add water, softener, and shopping agent to the pot, and then raise the temperature to 5 ° C / min to raise the temperature to 90 ° C to 98 ° C, and at this elevated temperature for 1 to 1.5 hours. When the shopping process is about, and the shopping process is completed in this way, the dyeing of the fabric is completed through the process of washing with water and dehydration.
여기에서 쇼핑처리과정을 살펴보면 물, 유연제, 쇼핑제를 투입한 후 90 ~ 98℃까지 온도를 상승시켜 쇼핑처리가 이루어짐으로써 장시간의 작업시간을 요구하게 되고, 또한 온도를 높이기 위한 연료의 낭비는 그대로 생산비 상승으로 이어져 생산자에게 많은 부담을 안겨주게 된다. 그러나 본 발명에서는 온도를 55 ~ 60℃까지 상승시키고, 쇼핑과정에 소요되는 시간도 20시간 내외로 단축함으로써 연료의 사용 및 작업시간의 단축으로 인한 많은 생산성 향상에 기여할 수 있으며, 이와 같은 생산성 향상을 위해서는 상기한 본 발명의 쇼핑유연제의 기술적 구성을 필요로 한다.Looking at the shopping process here, after adding water, a softener, and a shopping agent, the temperature is increased to 90-98 ° C., and the shopping process is required, which requires a long working time and waste of fuel to increase the temperature. This leads to an increase in production costs, which puts a lot of pressure on producers. In the present invention, however, the temperature is increased to 55 to 60 ° C., and the time required for the shopping process is also reduced to about 20 hours, thereby contributing to the improvement of productivity due to the use of fuel and the reduction of working time. In order to require the above technical configuration of the shopping softener of the present invention.
본 발명의 쇼핑유연제의 구성으로는 폴리 옥시에틸렌 트리데실 에테르, 폴리옥시세틸알콜 포스페이트, 폴리 옥시라우릴 에테르, 디프로필렌글리콜 및 실록산 또는 실리콘 디 메틸하이드로 프로필렌과 물(H2O)의 혼합으로 조성된다.The composition of the shopping softener of the present invention includes polyoxyethylene tridecyl ether, polyoxycetyl alcohol phosphate, poly oxylauryl ether, dipropylene glycol and siloxane or silicone dimethylhydropropylene and water (H 2 O). It is created.
상기 폴리옥시에틸렌 트리데실 에테르(Polyoxyethylene Tridecyl Ether)는 C12H24 - O(C2H4O)nH(n은 3 내지 10의 정수, pH 5.0 ~ 7.0)인 Ethylene Oxid 부가물로 서, 염색조제, 실리콘 유화제로 사용되는 것으로, 본 발명에서는 세정분산 및 재부착방지기능을 갖는다.The polyoxyethylene tridecyl ether (Polyoxyethylene Tridecyl Ether) C 12 H 24 -O (C 2 H 4 O) n H (n is an integer of 3 to 10, pH 5.0 ~ 7.0) as an ethylene ethylene adduct adduct, used as a dyeing aid, silicone emulsifier, in the present invention It has the function of cleaning dispersion and reattachment prevention.
그 폴리옥시에틸렌 트리데실 에테르의 사용량은 쇼핑유연제 전체함량에 대해 3중량% 미만으로 사용하는 경우에는 세정기능이 떨어지고, 25중량%를 초과하여 사용할 경우에는 칼라 변색의 문제가 발생하므로, 상기 폴리 옥시에틸렌 트리데실 에테르는 전체 쇼핑유연제 함량에 대해 3 ~ 25중량%로 사용하는 것이 바람직하다.The amount of the polyoxyethylene tridecyl ether used is less than 3% by weight relative to the total amount of the shopping softener, so that the cleaning function is poor, and when used in excess of 25% by weight, color discoloration occurs. Ethylene tridecyl ether is preferably used at 3 to 25% by weight based on the total shopping softener content.
상기 폴리옥시에틸렌 세틸 에테르(Polyoxyethylene Cethyl Ether) 포스페이트(Phosphate)는 C16H33(OCH2CH2)2OH의 분자식을 갖는 분산제로서, 원단이 손상되는 것을 방지하고 유연 효과를 갖도록 한다. 그 사용량은 1 ~ 10중량%로서, 1중량% 미만인 경우에는 유연효과가 떨어지고 원단이 손상될 가능성이 있고, 10중량%를 초과하게 되는 경우에는 칼라 변색의 문제가 있으므로 상기 폴리옥시세틸알콜 포스페이트는 쇼핑유연제 전체함량에 대해 1 ~ 10중량%로 사용하는 것이 바람직하다.The polyoxyethylene cetyl ether (Phosphate) is a dispersant having a molecular formula of C 16 H 33 (OCH 2 CH 2 ) 2 OH, to prevent damage to the fabric and have a softening effect. The amount of the polyoxycetyl alcohol phosphate is 1 to 10% by weight, and less than 1% by weight, the softening effect may be reduced and the fabric may be damaged, and when the amount is more than 10% by weight, color discoloration may occur. Is preferably used in an amount of 1 to 10% by weight based on the total amount of the shopping softener.
상기 폴리옥시에틸렌 라우릴 에테르는(Polyoxyethylene Lauryl Ether)는 C12H25 - O(C2H4O)nH(n은 3 내지 20의 정수, PH는 5.5 내지 7.0)인 Ethylene Oxid 부가물로서, 습윤제, 세정제, 유화 안정제로 사용되는 것으로, 본 발명에서는 유화분산과 세정기능을 갖는다. The polyoxyethylene lauryl ether is C 12 H 25 -O (C 2 H 4 O) n H (n is an integer of 3 to 20, PH is 5.5 to 7.0) as an ethylene ethylene adduct adduct It is used as a humectant, a detergent, an emulsion stabilizer, and in the present invention, it has an emulsion dispersion and a washing function.
그 폴리옥시에틸렌 라우릴 에테르를 쇼핑유연제 전체함량에 대해 2중량% 미 만인 경우에는 유화, 미부착 염료의 세정과 분산에 문제가 있고, 20중량%를 초과하게 되는 경우에는 칼라 변색의 문제가 있으므로, 상기 폴리옥시세틸알콜 포스페이트는 쇼핑유연제 전체함량에 대해 2 ~ 20중량%로 사용하는 것이 바람직하다.If the polyoxyethylene lauryl ether is less than 2% by weight based on the total amount of the shopping softener, there is a problem in washing and dispersing the emulsified and unattached dye, and in the case of exceeding 20% by weight, there is a problem of color discoloration. The polyoxycetyl alcohol phosphate is preferably used in 2 to 20% by weight based on the total amount of the shopping softener.
상기 디 프로필렌글리콜(Dipropylene glycol), 실록산(Siloxane) 또는 실리콘 디 메틸하이드로 프로필렌(Silicones di-Me, 3-hydroxypropyl)은 잔류형 유연효과를 갖는 성분으로서, 그 사용량은 9 ~ 34중량%이다. 9중량% 미만인 경우에는 유연효과가 떨어지는 문제가 있고, 35중량%를 초과하게 되는 경우에는 제품 성능의 미비로 쇼핑력 약화 문제가 있으므로, 상기 성분들은 쇼핑유연제 전체함량에 대해 9 ~ 34중량%로 사용하는 것이 바람직하다.The dipropylene glycol, siloxane (Siloxane) or silicon dimethylhydropropylene (Silicones di-Me, 3-hydroxypropyl) is a component having a residual softening effect, the amount is used 9 to 34% by weight. If it is less than 9% by weight, there is a problem that the softening effect is lowered, and if it exceeds 35% by weight, there is a problem of weakening shopping power due to lack of product performance, so the components are 9 to 34% by weight relative to the total content of the shopping softener It is preferable to use.
상기 물(H2O)은 전체 함량에 대해 60 ~ 85중량%의 범위로 사용되는 것으로, 60중량% 미만인 경우에는 제품의 외관 및 안정성에 문제가 있고, 85중량%를 초과하게 되는 경우에는 제품 성능의 미비로 쇼핑력 약화 문제가 있으므로, 상기 물(H2O)은 쇼핑유연제 전체함량에 대해 60 ~ 85중량%로 사용하는 것이 바람직하다.The water (H 2 O) is used in the range of 60 to 85% by weight based on the total content, when less than 60% by weight has a problem in the appearance and stability of the product, when the product exceeds 85% by weight Since there is a weakening of the shopping power due to the lack of performance, the water (H 2 O) is preferably used at 60 to 85% by weight based on the total amount of the shopping softener.
상기 쇼핑유연제의 제조는 교반기에 폴리 옥시에틸렌 트리데시 에테르, 폴리옥시세틸알콜 포스페이, 폴리 옥시라우릴 에테르, 디프로필렌글리콜, 실록산 또는 실리콘 디 메틸하이드로 프로필렌 중 선택되는 어느 1종 이상을 순차적으로 투입하여 10 ~ 60분간 교반하고, 여기에 물(H2O)을 투입 후 30분 ~ 1.5시간 동안 교반하여 제조되는 것으로, 물을 나중에 투여하는 이유는 유화 안정성 때문이다.The manufacturing of the shopping softener may be carried out sequentially in the stirrer any one or more selected from polyoxyethylene tridecyl ether, polyoxycetyl alcohol phosphate, poly oxylauryl ether, dipropylene glycol, siloxane or silicone dimethylhydropropylene. It is prepared by stirring for 10 to 60 minutes, and after adding water (H 2 O) to it for 30 minutes to 1.5 hours, the reason for administering water later is because of emulsion stability.
그리고, 상기 폴리 옥시에틸렌 트리데시 에테르, 폴리옥시세틸알콜 포스페 이, 폴리 옥시라우릴 에테르, 디프로필렌글리콜, 실록산 또는 실리콘 디 메틸하이드로 프로필렌 중 선택되는 어느 1종 이상을 교반기에 투입한 후 교반은 100 ~ 150rpm속도로 이루어지는 것으로, 10분 미만의 교반은 제품 교반이 원활히 이루어지지 않고 원료의 혼합 안정성이 떨어지는 문제가 있고, 60분 이상의 교반은 제품 유화 안정성이 떨어지는 문제가 있으므로, 상기 교반 시간은 10 ~ 60분간 유지하는 것이 바람직하다.Then, any one or more selected from the above polyoxyethylene tridecyl ether, polyoxycetyl alcohol phosphate, poly oxylauryl ether, dipropylene glycol, siloxane, or silicon dimethylhydropropylene is added to the stirrer and stirred. Silver is composed of 100 ~ 150rpm speed, less than 10 minutes of stirring is not smooth product stirring and there is a problem of poor mixing stability of the raw material, 60 minutes or more stirring has a problem of poor product emulsification stability, the stirring time is It is preferable to hold for 10 to 60 minutes.
그리고, 물을 투입한 후 다시 한번 교반과정을 거치게 되며, 이때 교반시간을 30분 미만으로 유지하는 경우에는 제품 교반이 원활히 이루어지지 않고 원료의 혼합 안정성이 떨어지는 문제가 있고, 1.5시간을 초과하게 되는 경우에는 제품 유화 안정성이 떨어지는 문제가 있으므로, 상기 물을 투입한 후 교반 시간은 30분 ~ 1.5시간으로 유지하는 것이 바람직하다.Then, after the water is put into the stirring process once again, at this time, if the stirring time is maintained less than 30 minutes there is a problem that the mixing stability of the raw material is not smoothly made and the mixing stability is lowered, exceeding 1.5 hours In this case, since there is a problem that the product emulsification stability is poor, it is preferable to maintain the stirring time after 30 minutes to 1.5 hours after the water is added.
이상에서 살펴본 바와 같이, 본 발명에 따른 저온 쇼핑제는 종래 쇼핑처리 후 유연제를 사용하지 않아도 되고, 고온에서 쇼핑(soaping) 처리하기 위해 온도를 상승시킴으로써 작업시간의 장기화 및 에너지 소비로 인한 작업성 저하 및 생산비 상승 문제를 해소할 수 있다.As described above, the low-temperature shopping agent according to the present invention does not need to use a softener after the conventional shopping treatment, and increases the temperature to process the shopping at high temperatures, thereby reducing workability due to prolonged working time and energy consumption. And the problem of rising production costs.
그리고 종래의 경우 고온에서 쇼핑제를 사용함으로써 작업 공정이 복잡하여 그에 따른 제품이 불량률이 높았으나, 저온 쇼핑제를 사용함으로써 공정의 단순화로 인한 불량률 감소효과를 가져온다.In the conventional case, the shopping process is used at a high temperature, so that the work process is complicated, and thus the defect rate of the product is high. However, by using the low temperature shopping agent, the defect rate is reduced due to the simplification of the process.
또한 섬유공업에 있어서 일반적으로 높은 비용 수익을 얻기 위해 제조비용 절감 및 환경보호 비용 절감에 따른 경쟁력 상승에 중요한 작용을 준다.In addition, the textile industry generally plays an important role in increasing competitiveness by reducing manufacturing costs and environmental protection costs in order to obtain high cost returns.
이상에서 살펴 본 염색공정에 사용되는 쇼핑유연제의 기술적 구성에 대해 실시 예를 통해 더욱 구체적으로 살펴보도록 한다.The technical configuration of the shopping softener used in the dyeing process described above will be described in more detail through examples.
쇼핑유연제Shopping softener 조성물 - 실시 예 1 Composition-Example 1
폴리옥시에틸렌 트리데실 에테르(Polyoxyethylene tridecyl ether) 8㎏, 폴리옥시에틸렌 세틸 에테르(Polyoxyethylene cethyl ether) 포스페이트(Phosphate) 5㎏, 폴리옥시에틸렌 라우릴 에테르(Polyoxyethylene lauryl ether) 5㎏, 디프로필렌 글리콜(Dipropylene glycol) 15㎏, 물(H2O) 67ℓ를 혼합하여 조성한다.8 kg polyoxyethylene tridecyl ether, 5 kg polyoxyethylene cethyl ether phosphate, 5 kg polyoxyethylene lauryl ether, dipropylene glycol 15 kg of glycol) and 67 l of water (H 2 O) are mixed.
쇼핑유연제Shopping softener 조성물 - 실시 예 2 Composition-Example 2
폴리옥시에틸렌 트리데실 에테르(Polyoxyethylene tridecyl ether) 8㎏, 폴리옥시에틸렌 세틸 에테르(Polyoxyethylene cethyl ether) 포스페이트(Phosphate) 2㎏, 폴리옥시에틸렌 라우릴 에테르(Polyoxyethylene lauryl ether) 3㎏, 디프로필렌 글리콜(Dipropylene glycol) 5㎏, 실록산(Siloxane) 5㎏ 물(H2O) 77ℓ를 혼합하여 조성한다.8 kg polyoxyethylene tridecyl ether, 2 kg polyoxyethylene cethyl ether phosphate, 3 kg polyoxyethylene lauryl ether, dipropylene glycol 77 kg of glycol (5g) and 5kg of siloxane (Siloxane) (H 2 O) are mixed.
쇼핑유연제Shopping softener - 실시 예 3 Example 3
상기 실시 예1의 성분 및 성분비율을 이용하여 제조하는 것으로, 먼저 교반기에 폴리옥시에틸렌 트리데실 에테르(Polyoxyethylene tridecyl ether), 폴리옥시에틸렌 세틸 에테르(Polyoxyethylene cethyl ether) 포스페이트(Phosphate), 폴리옥시에틸렌 라우릴 에테르(Polyoxyethylene lauryl ether), 디프로필렌 글리콜(Dipropylene glycol)를 순차적으로 투입하여 100rpm으로 60분간 1차 교반을 하고, 여기에 물(H2O)을 투입하여 100rpm으로 1시간 30분 동안 2차 교반한 후 투명도를 확인 후 Q.C 및 포장한다.Prepared using the components and component ratios of Example 1, first, polyoxyethylene tridecyl ether (polyoxyethylene tridecyl ether), polyoxyethylene cetyl ether (Phosphate), polyoxyethylene la Polyoxyethylene lauryl ether and dipropylene glycol were added sequentially, followed by first stirring at 100 rpm for 60 minutes, and water (H 2 O) was added thereto at 100 rpm for 1 hour 30 minutes. After stirring, the transparency is checked, and then packed with QC.
쇼핑유연제Shopping softener - 실시 예 4 Example 4
상기 실시 예3과 동일방법으로 제조하는 것으로, 다만 그 성분 및 성분비율을 실시 예2를 이용하였으며 1차 교반을 150rpm으로 60분간 실시하였으며, 물 투입후 2차 교반을 120rpm으로 1시간 30분 동안 진행하여 투명도 확인 후 Q.C 및 포장한다.The preparation was carried out in the same manner as in Example 3, except that the ingredients and the proportions were used in Example 2, and the first stirring was performed at 150 rpm for 60 minutes, and the second stirring was performed at 120 rpm for 1 hour and 30 minutes after adding water. Proceed with QC and packaging after checking transparency.
시험 예 1: 색상발현, Test Example 1: Color Expression, 백장오염도White Sea Pollution Degree 및 And 세탁견뢰도Color fastness
상기 실시 예 3의 쇼핑유연제와 종래 쇼핑제를 이용하여 염색과정을 거친 원단의 색상발현(도1), 염색이 되지 않은 백(흰색)장부분의 오염도(도2), 세제를 넣 어 빨래할 때 견디는 정도인 세탁견뢰도(도3)를 육안 비교하였으며, 그 결과 본 발명에 따른 쇼핑유연제는 종래 쇼핑제와 색상발현, 백장오염도, 세탁견뢰도 측면에서 거의 차이가 없음을 관찰할 수 있었다.Using the shopping softener and the conventional shopping agent of the third embodiment, the color expression of the fabric that has been dyed (Fig. 1), the degree of contamination of the undyed bag (white) sheet (Fig. 2), and detergent When compared to the wash fastness of the degree of endurance (Fig. 3) was visually compared, as a result, the shopping softener according to the present invention was observed that there is almost no difference in terms of conventional shopping agent, color expression, whiteness pollution, washing fastness.
상기 원단의 색상발현은 적색의 반응성염료(SUNFIX SUPRA RED SS: (주)오영화학) 4%로 염색된 원단에 실시 예 3의 쇼핑유연제와 일반쇼핑제(P-SH: (주)우인화학)를 1g/ℓ로 처리하여 비교한 것이고, 상기 백장오염도는 쇼핑 과정에서 탈락되는 염료의 쇼핑력을 오염도에 따라 판별하기 위해 백색포와 함께 쇼핑 처리한 원단을 비교한 것이다. 그리고 상기 세탁견뢰도는 쇼핑 처리후 Washing 견뢰도를 측정하여 미부착 염료의 잔류시 나타날 수 있는 색상 견뢰도를 측정하기 위해 백색 면포로 오염도를 측정한 것이다.The color expression of the fabric is a shopping softener and a general shopping agent (P-SH: Wooin Chemical Co., Ltd.) of a fabric dyed in 4% of red dyes (SUNFIX SUPRA RED SS: Ohyoung Chemical Co., Ltd.) It is compared to the treated by 1g / ℓ, the degree of contamination of the white cloth is compared with the fabric processed shopping with white cloth in order to determine the shopping power of the dye removed during the shopping process according to the degree of contamination. And the wash fastness is to measure the color fastness to the color fastness that may appear when the remaining unattached dye by measuring the washing fastness after the shopping treatment to measure the contamination with a white cotton cloth.
이와 같은 비교시험을 통해 본 발명에 따른 쇼핑유연제는 종래 쇼핑제와 기능적 차이가 없음에도, 유연제를 따로 사용하여야 하는 점, 고온에서의 처리를 위한 많은 에너지가 필요하고, 그에 따른 공정의 복잡하다는 점, 작업효율의 저하로 인한 제품불량률이 높다는 점 등의 종래 쇼핑제의 문제를 해결하는 장점이 있음을 확인하였다.Through such a comparative test, the shopping softener according to the present invention does not have a functional difference with the conventional shopping agent, but a softener must be used separately, a lot of energy is required for treatment at a high temperature, and the process is complicated. In addition, it was confirmed that there is an advantage in solving the problems of the conventional shopping system, such as a high product defect rate due to a decrease in the work efficiency.
도 1은 본 발명에 따른 저온쇼핑유연제와 일반 쇼핑제의 색상발현 상태를 비교한 사진.1 is a photograph comparing the color expression state of the low-temperature shopping softener and the general shopping agent according to the present invention.
도 2는 본 발명에 따른 저온쇼핑유연제와 일반 쇼핑제의 백장오염도 상태를 비교한 사진.Figure 2 is a photograph comparing the degree of white contaminants of the low temperature shopping softener and the general shopping agent according to the present invention.
도 3은 본 본 발명에 따른 저온쇼핑유연제와 일반 쇼핑제의 색상견뢰도 상태를 비교한 사진.Figure 3 is a photograph comparing the color fastness state of the low-temperature shopping softener and the general shopping agent according to the present invention.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101147339B1 (en) | 2011-05-09 | 2012-05-22 | 차두형 | Color depening agent for reactive dyestuff |
| KR101215488B1 (en) | 2011-05-06 | 2012-12-26 | (재)한국섬유소재연구소 | Softness agent composition having good stability at low temperature using for dyeing processes and method thereof |
| KR101705089B1 (en) | 2015-08-25 | 2017-02-09 | 최윤정 | String processing equipment and processing methods for fabric |
| KR101876314B1 (en) * | 2018-02-07 | 2018-07-09 | 강인숙 | Softening agent with low yellowing characteristic and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000004967A (en) * | 1996-03-29 | 2000-01-25 | 이노우에 노리유끼 | Water- and oil-repellent composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000004967A (en) * | 1996-03-29 | 2000-01-25 | 이노우에 노리유끼 | Water- and oil-repellent composition |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101215488B1 (en) | 2011-05-06 | 2012-12-26 | (재)한국섬유소재연구소 | Softness agent composition having good stability at low temperature using for dyeing processes and method thereof |
| KR101147339B1 (en) | 2011-05-09 | 2012-05-22 | 차두형 | Color depening agent for reactive dyestuff |
| KR101705089B1 (en) | 2015-08-25 | 2017-02-09 | 최윤정 | String processing equipment and processing methods for fabric |
| KR101876314B1 (en) * | 2018-02-07 | 2018-07-09 | 강인숙 | Softening agent with low yellowing characteristic and preparation method thereof |
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