KR102122204B1 - Environment-friendly ceiling material and manufacturing method thereof - Google Patents

Environment-friendly ceiling material and manufacturing method thereof Download PDF

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KR102122204B1
KR102122204B1 KR1020180083279A KR20180083279A KR102122204B1 KR 102122204 B1 KR102122204 B1 KR 102122204B1 KR 1020180083279 A KR1020180083279 A KR 1020180083279A KR 20180083279 A KR20180083279 A KR 20180083279A KR 102122204 B1 KR102122204 B1 KR 102122204B1
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김성래
엄수현
김영섭
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김성래
엄수현
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    • C04B14/46Rock wool ; Ceramic or silicate fibres
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
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    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B9/00Ceilings; Construction of ceilings, e.g. false ceilings; Ceiling construction with regard to insulation
    • E04B9/04Ceilings; Construction of ceilings, e.g. false ceilings; Ceiling construction with regard to insulation comprising slabs, panels, sheets or the like
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Abstract

본 발명은 친환경 천장재 및 이의 제조방법에 관한 것으로, 더욱 상세하게는 자연 유래 재료를 사용하여 불연성 및 내수성이 우수하도록 하는 친환경 천장재 및 이의 제조방법에 관한 것이다.
이러한 본 발명은, 질석 250~350중량부, 미네랄울 150~250중량부 중 어느 하나 이상이 혼합된 혼합물을 제조하는 제1단계; 혼합물 100중량부에 대하여, 소듐 실리케이트 25~35중량부, 리튬 실리케이트 10~20중량부, 수용성 에폭시 5~10중량부, 흄드 실리카 15~20중량부 및 중탄 20~30중량부를 포함하는 불연수지 300~400중량부를 혼합하여 불연조성물을 제조하는 제2단계; 불연조성물 100중량부에 대하여, 솔잎분말, 왕겨분말 및 톱밥분말 중에서 하나이상 이상으로 이루어진 친환경분말 150~200중량부를 혼합한 후 성형함으로써 천장재를 제조하는 제3단계;를 포함하는 것으로, 제2단계의 불연수지는, 장석 20~25중량부를 더 포함하는 것을 특징으로 하는 친환경 천장재 및 이의 제조방법을 기술적 요지로 한다.
The present invention relates to an eco-friendly ceiling material and a method for manufacturing the same, and more particularly, to an eco-friendly ceiling material and a method for manufacturing the same, using natural-derived materials to provide excellent incombustibility and water resistance.
In the present invention, the first step of preparing a mixture of any one or more of 250 to 350 parts by weight of vermiculite, 150 to 250 parts by weight of mineral wool; Non-combustible resin 300 containing 25 to 35 parts by weight of sodium silicate, 10 to 20 parts by weight of lithium silicate, 5 to 10 parts by weight of water-soluble epoxy, 15 to 20 parts by weight of fumed silica, and 20 to 30 parts by weight of coal based on 100 parts by weight of the mixture A second step of preparing an incombustible composition by mixing ˜400 parts by weight; A third step of manufacturing a ceiling material by mixing and forming 150 to 200 parts by weight of an eco-friendly powder composed of at least one of pine needle powder, rice husk powder, and sawdust powder with respect to 100 parts by weight of the non-combustible composition. The non-combustible resin is an environmentally friendly ceiling material characterized in that it further comprises 20-25 parts by weight of feldspar and a method for manufacturing the same.

Description

친환경 천장재 및 이의 제조방법{Environment-friendly ceiling material and manufacturing method thereof}Environmental-friendly ceiling material and manufacturing method thereof

본 발명은 친환경 천장재 및 이의 제조방법에 관한 것으로, 더욱 상세하게는 자연 유래 재료를 사용하여 불연성 및 내수성이 우수하도록 하는 친환경 천장재 및 이의 제조방법에 관한 것이다.The present invention relates to an eco-friendly ceiling material and a method for manufacturing the same, and more particularly, to an eco-friendly ceiling material and a method for manufacturing the same, using natural-derived materials to provide excellent incombustibility and water resistance.

일반적으로 천장재는 천장을 마감하기 위해 사용되는 것으로, 2004년 이전에 생산 및 설치된 천장재는 인체에 유해한 석면이 함유되어 환경부 규제에 따라 교체 시공되고 있었다.In general, ceiling materials are used to finish the ceiling, and the ceiling materials produced and installed before 2004 contain asbestos harmful to the human body, and were replaced by the Ministry of Environment.

특히 학교나 공공 건물과 같은 대형 건물에는 천장재가 많이 사용될 수밖에 없기 때문에 유해물질이 함유된 천장재의 교체 철거 후에도 완전한 석면의 제거는 되지 않고 있는 실정이다.In particular, since large amounts of ceiling materials are inevitably used in large buildings such as schools and public buildings, complete removal of asbestos is not possible even after removal and replacement of ceiling materials containing harmful substances.

이런 실정을 해결해 보고자, 인체에 무해하고 설치시 방음 및 보온의 기능도 겸비한 자연 유래 재료를 이용한 천장재의 기술에 대한 방향이 두각을 나타내고 있었다.In order to solve this situation, the direction of the technology of ceiling materials using materials derived from nature that are harmless to the human body and also have soundproofing and heat preservation functions during installation was prominent.

하지만 자연 유래 재료는 불에 타기 쉬워 천장재로 적용하기에 어려움이 있어 왔으므로, 자연 유래 재료를 사용하여 불연 성능을 우수하도록 하는 새로운 방식의 천장재에 대한 기술개발 연구가 절실히 요구되는 시점이다.However, since natural-derived materials are easily burned, it has been difficult to apply them as ceiling materials, so it is desperately required to develop and research new types of ceiling materials that use natural-derived materials to improve the non-combustible performance.

국내 공개특허공보 제10-2015-0144519호, 2015.12.28.자 공개.Publication of Korean Patent Publication No. 10-2015-0144519, Dec. 28, 2015.

본 발명은 상기한 문제점을 해소하기 위하여 발명된 것으로, 자연 유래 재료를 사용하여 불연성 및 내수성이 우수하도록 하는 친환경 천장재 및 이의 제조방법을 제공하는데 그 목적이 있다.The present invention was invented in order to solve the above-mentioned problems, and has an object to provide an eco-friendly ceiling material and a method for manufacturing the same, which are made of natural non-combustible materials and excellent water resistance.

상기의 목적을 달성하기 위한 본 발명은, 질석 250~350중량부, 미네랄울 150~250중량부 중 어느 하나 이상이 혼합된 혼합물을 제조하는 제1단계; 상기 혼합물 100중량부에 대하여, 소듐 실리케이트 25~35중량부, 리튬 실리케이트 10~20중량부, 수용성 에폭시 5~10중량부, 흄드 실리카 15~20중량부 및 중탄 20~30중량부를 포함하는 불연수지 300~400중량부를 혼합하여 불연조성물을 제조하는 제2단계; 및 상기 불연조성물 100중량부에 대하여, 솔잎분말, 왕겨분말 및 톱밥분말 중에서 하나 이상으로 이루어진 친환경분말 150~200중량부를 혼합한 후 성형함으로써 천장재를 제조하는 제3단계;를 포함하는 것으로, 상기 제2단계의 불연수지는, 장석 20~25중량부를 더 포함하는 것을 특징으로 하는 친환경 천장재의 제조방법을 기술적 요지로 한다.The present invention for achieving the above object, the first step of producing a mixture of any one or more of 250 to 350 parts by weight of vermiculite, 150 to 250 parts by weight of mineral wool; Non-flammable resin containing 25 to 35 parts by weight of sodium silicate, 10 to 20 parts by weight of lithium silicate, 5 to 10 parts by weight of water-soluble epoxy, 15 to 20 parts by weight of fumed silica, and 20 to 30 parts by weight of medium carbon based on 100 parts by weight of the mixture A second step of preparing an incombustible composition by mixing 300 to 400 parts by weight; And a third step of manufacturing a ceiling material by mixing and forming 150 to 200 parts by weight of an eco-friendly powder composed of at least one of pine needle powder, rice husk powder and sawdust powder with respect to 100 parts by weight of the non-combustible composition. The non-flammable resin in the second stage is a technical point of the method for manufacturing an eco-friendly ceiling material, which further comprises 20-25 parts by weight of feldspar.

그리고 상기의 목적을 달성하기 위한 본 발명은, 상기의 제조방법에 의해 제조되는 것을 특징으로 하는 친환경 천장재 또한 기술적 요지로 한다.And the present invention for achieving the above object is also made of an environmentally friendly ceiling material characterized in that it is manufactured by the above manufacturing method.

상기 과제의 해결 수단에 의한 본 발명에 따른 친환경 천장재 및 이의 제조방법은, 솔잎, 왕겨 및 톱밥 등 자연 유래 재료 고유의 특성을 그대로 표현할 수 있을 뿐만 아니라, 불연성 및 내수성을 향상시킬 수 있는 효과가 있다.The eco-friendly ceiling material according to the present invention and a method for manufacturing the same according to the present invention by the solving means of the above-described subject can not only express the characteristics inherent to natural-derived materials such as pine needles, chaff, and sawdust, but also have the effect of improving non-combustibility and water resistance. .

도 1은 본 발명의 바람직한 제1실시예에 따른 천장재.
도 2는 본 발명의 바람직한 제2실시예에 따른 천장재.
도 3은 본 발명의 바람직한 제3실시예에 따른 천장재.
도 4는 본 발명의 바람직한 제4실시예에 따른 천장재.
도 5는 본 발명의 바람직한 제5실시예에 따른 천장재.
도 6은 본 발명의 바람직한 실시예에 따른 설치도.
1 is a ceiling material according to a first preferred embodiment of the present invention.
2 is a ceiling material according to a second preferred embodiment of the present invention.
3 is a ceiling material according to a third preferred embodiment of the present invention.
4 is a ceiling material according to a fourth preferred embodiment of the present invention.
5 is a ceiling material according to a fifth preferred embodiment of the present invention.
6 is an installation diagram according to a preferred embodiment of the present invention.

이하, 본 발명의 바람직한 실시예를 첨부한 도면을 참조하여 상세하게 설명하면 다음과 같다.Hereinafter, with reference to the accompanying drawings, preferred embodiments of the present invention will be described in detail.

먼저, 제1단계는 질석 250~350중량부, 미네랄울 150~250중량부 중 어느 하나 이상이 혼합된 혼합물을 제조하는 단계이다. (S1)First, the first step is a step of preparing a mixture of any one or more of 250 to 350 parts by weight of vermiculite and 150 to 250 parts by weight of mineral wool. (S1)

즉 제1단계는 완성되는 천장재 물성의 기반을 안정적으로 잡아주기 위한 것으로, 질석 250~350중량부 및 미네랄울 150~250중량부 중 어느 하나 이상을 혼합함으로써, 혼합물을 형성하는 단계를 의미한다.That is, the first step is to stably hold the base of the properties of the finished ceiling material, and refers to a step of forming a mixture by mixing any one or more of 250 to 350 parts by weight of vermiculite and 150 to 250 parts by weight of mineral wool.

첫째, 질석은 무독성/무취의 성질을 가지고, 다공성으로 이루어져 경량이며, 열전도율이 낮아 불연 및 단열 효과를 개선할 수 있도록 하는 구성이다.First, vermiculite has a non-toxic/odorless property, and is made of porosity, lightweight, and has a low thermal conductivity, so that it can improve the non-combustible and insulating effect.

즉 질석은 천연상태에서 운모와 비슷한 외관을 지닌 편상함수 광물의 미분으로써, 100~1,200℃로 가열시 8~30배로 팽창되는 성질을 가지는바, 밀도는 0.07~0.30g/㎤로 무수한 기공에 의한 다공질 구조로 경량성이 있고, 열전도율이 0.06㎉/mh℃ 이하의 단열을 가져 보온성이 좋으며, 1,400±50℃의 내화성을 가질 뿐만 아니라, 절연성을 가진다.That is, vermiculite is a fine powder mineral having a similar appearance to mica in its natural state, and has a property of expanding 8 to 30 times when heated to 100 to 1,200°C. The density is 0.07 to 0.30 g/cm 3 and is caused by countless pores. The porous structure has light weight, heat conductivity of 0.06 ㎉/mh℃ or less, and has good heat retention, as well as fire resistance of 1,400±50℃, and insulation.

이처럼 질석은 최적의 절연성을 지닌 것으로, 흡수력과 이온 교환 능력도 좋으며, 화학적으로 독성이 없으며 안정되어 있다.As described above, vermiculite has optimal insulation, has good absorption and ion exchange ability, is chemically non-toxic and stable.

제1단계에서 사용되는 질석은 내부가 비어있는 중공구조를 가지는 미립자 형태의 미분이기 때문에 250중량부 미만이면 작업성은 개선될 수 있으나 불연 및 단열면에서 원하는 물성의 천장재를 얻을 수 없고, 350중량부를 초과하면 불연 및 단열효과는 개선될 수 있으나 질석의 과다 사용으로 작업성 저하로 인한 물성이 나빠질 우려가 있으므로, 질석은 250~350중량부의 범위로 첨가되는 것이 바람직하다.Since vermiculite used in the first step is a fine powder in the form of fine particles having a hollow structure inside, workability may be improved if it is less than 250 parts by weight, but the ceiling material of desired properties cannot be obtained from non-combustible and insulating surfaces, and 350 parts by weight If exceeded, the non-combustible and insulating effect may be improved, but it is preferable that the vermiculite is added in the range of 250 to 350 parts by weight since there is a possibility that physical properties due to deterioration of workability may be deteriorated due to excessive use of vermiculite.

참고로, 질석의 크기는 작으면 작을수록 응용성이 좋지만 여러가지 요인을 고려하여 0.5~1㎜의 범위인 것이 바람직하다. 만약 질석의 크기가 0.5㎜ 미만이면 천장재의 피막 표면상태가 다소 거칠어지는 문제점이 있으며, 1㎜를 초과하면 건물의 천장에 시공된 천장재에 크랙이 발생할 문제점이 있으므로, 질석은 0.5~1㎜(바람직하게는, 0.8㎜) 범위의 크기를 가지는 것이 바람직하다.For reference, the smaller the size of vermiculite, the better the applicability, but is preferably in the range of 0.5 to 1 mm considering various factors. If the size of vermiculite is less than 0.5 mm, there is a problem that the surface condition of the ceiling material becomes somewhat rough, and if it exceeds 1 mm, there is a problem of cracking in the ceiling material installed on the ceiling of the building, so vermiculite is 0.5 to 1 mm (preferably Preferably, it has a size in the range of 0.8 mm).

둘째, 미네랄울은 무기섬유로써 내열성이 우수하고, 흡음성능 및 난연성능이 매우 좋아 천장재의 물성을 향상시키는 구성이다.Second, mineral wool is an inorganic fiber that has excellent heat resistance and excellent sound absorption and flame retardant properties to improve the properties of ceiling materials.

특히 본 발명에서 미네랄울을 사용한 이유는, 최근 폴리우레탄 발포체와 같은 유기성 소재같은 경우 미세하지만 휘발성 유기물인 가스를 방출하게 되어 주변환경을 해치는 것으로 확인되면서 사용이 자제되어왔으므로, 이를 대체하기 위한 방법이 강구되어 왔기 때문이다.Particularly, the reason why mineral wool is used in the present invention is that it has been discouraged from being used as it has been confirmed that it harms the surrounding environment by emitting gas, which is a fine but volatile organic material, in the case of organic materials such as polyurethane foams. Because it has been taken.

본 발명의 제1단계에서와 같이 질석 250~350중량부와 미네랄울 150~250중량부를 혼합했을 때, 질석에 비해 높은 입자 밀도, 높은 압력저항 및 기계적 손상에 따른 높은 저항성을 가진 미네랄울의 특성을 발휘함으로써, 중량을 나타내는 밀도 또한 적어 천장재의 전체적인 무게를 절감할 수 있는 효과가 있다.When mixing 250-350 parts by weight of vermiculite and 150-250 parts by weight of mineral wool as in the first step of the present invention, the characteristics of mineral wool with high particle density, high pressure resistance and high resistance to mechanical damage compared to vermiculite By exerting, the density representing the weight is also small, thereby reducing the overall weight of the ceiling material.

아울러 이렇게 불연조성물을 제조하기 전에 질석과 미네랄울을 먼저 혼합하는 과정을 거치는 이유는, 질석과 미네랄울 간 최적의 혼합비율을 얻어 천장재에 내열성, 흡음성 및 불연성 등 다양한 물성을 안정적으로 제공할 수 있도록 하기 위함이다.In addition, the reason for the process of first mixing the vermiculite and the mineral wool before preparing the non-combustible composition is to obtain an optimal mixing ratio between the vermiculite and the mineral wool so that various properties such as heat resistance, sound absorption and non-combustibility can be stably provided to the ceiling material. It is to do.

이때 미네랄울이 150중량부 미만이면 천장재에 높은 압력저항 및 기계적 손상에 따른 높은 저항성을 부여할 수 없고, 250중량부를 초과하면 질석과의 혼화력이 좋지 못해 물성 효과 측면에서 탁월성이 나타나지 않기 때문에, 미네랄울은 150~250중량부의 범위로 첨가되는 것이 바람직하다.At this time, if the mineral wool is less than 150 parts by weight, high pressure resistance and high resistance due to mechanical damage cannot be imparted to the ceiling material. The mineral wool is preferably added in the range of 150 to 250 parts by weight.

단, 제1단계에서는 경우에 따라 질석 250~350중량부, 미네랄울 150~250중량부 중 어느 하나를 단독으로도 사용 가능하다.However, in the first step, any one of 250 to 350 parts by weight of vermiculite and 150 to 250 parts by weight of mineral wool may be used alone.

다음으로, 제2단계는 혼합물 100중량부에 대하여, 소듐 실리케이트 25~35중량부, 리튬 실리케이트 10~20중량부, 수용성 에폭시 5~10중량부, 흄드 실리카 15~20중량부, 중탄 20~30중량부 및 장석 20~25중량부를 포함하는 불연수지 300~400중량부를 혼합하여 불연조성물을 제조하는 단계이다. (S2)Next, the second step is based on 100 parts by weight of the mixture, 25 to 35 parts by weight of sodium silicate, 10 to 20 parts by weight of lithium silicate, 5 to 10 parts by weight of water-soluble epoxy, 15 to 20 parts by weight of fumed silica, 20 to 30 parts of medium carbon This is a step of preparing a non-combustible composition by mixing 300 to 400 parts by weight of a non-combustible resin containing 20 to 25 parts by weight of feldspar and feldspar. (S2)

상세하게는 제2단계는 혼합물과 불연수지의 혼합과정으로 안정적인 물성을 지닌 불연조성물을 얻기 위한 것으로, 제1단계에서 준비된 혼합물 100중량부에, 소듐 실리케이트 25~35중량부, 리튬 실리케이트 10~20중량부, 수용성 에폭시 5~10중량부, 흄드 실리카 15~20중량부, 중탄 20~30중량부 및 장석 20~25중량부로 이루어진 불연수지 300~400중량부를 혼합함으로써 불연조성물을 얻는 단계라 할 수 있다.Specifically, the second step is to obtain a non-combustible composition having stable physical properties by mixing the mixture with the non-combustible resin, 100 parts by weight of the mixture prepared in the first step, 25 to 35 parts by weight of sodium silicate, and 10 to 20 parts of lithium silicate. It can be said to be a step of obtaining an incombustible composition by mixing 300 to 400 parts by weight of an incombustible resin consisting of 5 parts by weight of water, 5 to 10 parts by weight of water-soluble epoxy, 15 to 20 parts by weight of fumed silica, 20 to 30 parts by weight of heavy coal and 20 to 25 parts by weight of feldspar. have.

여기서 불연수지가 300중량부 미만으로 첨가되면 천장재에 불연 성능을 부여하기엔 미미한 양이어서 화재시 사고의 위험성이 도사릴 수 있으며, 400중량부를 초과하면 불연수지의 양이 과도하게 많아져 시공되는 천장재의 외관이 불량해지므로, 불연수지는 300~400중량부로 포함되는 것이 바람직하다.Here, if less than 300 parts by weight of non-flammable resin is added, it is insignificant to impart non-flammable performance to the ceiling material, and there is a danger of accident in case of fire. When it exceeds 400 parts by weight, the amount of non-flammable resin is excessively large, and Since the appearance is poor, it is preferable that the non-combustible resin is contained in 300 to 400 parts by weight.

첫째, 소듐 실리케이트는 구성 성분들 간의 결합력을 증대시키기 위한 구성이다.First, sodium silicate is a component for increasing the bonding force between the components.

말하자면 소듐 실리케이트는 규산염의 한 종류로써, 규산염은 살리실산의 수소원자가 금속원자로 치환된 물질이다. 다시 말하자면 소듐 실리케이트는 살리실산의 수소원자가 나트륨으로 치환된 물질이라 할 수 있다.That is, sodium silicate is a type of silicate, and silicate is a substance in which the hydrogen atom of salicylic acid is replaced with a metal atom. In other words, sodium silicate is a substance in which the hydrogen atom of salicylic acid is replaced with sodium.

여기서 소듐 실리케이트가 25중량부 미만이면 그 함량이 너무 적어 다른 구성 성분들과의 결합력을 증대시키기 어렵고, 35중량부를 초과하면 pH가 9.0 이상으로 높아져 알칼리성이 강해져 천장재로써의 역할을 할 수 없게 만든다.Here, if the sodium silicate is less than 25 parts by weight, its content is too small to increase the binding strength with other components, and when it exceeds 35 parts by weight, the pH is increased to 9.0 or higher, and alkalinity becomes strong, making it impossible to function as a ceiling material.

둘째, 리튬 실리케이트는 몰비가 크고 침투성을 지닌 수용성 무기질로써, 온도 변화에도 점성을 안정되게 유지하여 시공된 천장재의 경질성과 경도를 강화시키는 구성이다.Second, lithium silicate is a water-soluble inorganic material having a large molar ratio and permeability, and is a composition that strengthens the rigidity and hardness of the constructed ceiling material by stably maintaining viscosity even with temperature changes.

리튬 실리케이트를 사용하는 이유는 유해물질이 없고, 고온 열화에서도 천장재의 불연 성능을 안정되게 유지해주며, 부식을 방지할 뿐만 아니라 완성된 천장재의 표면강도를 강화시켜주기 때문이다.The reason for using the lithium silicate is that there are no harmful substances, it keeps the nonflammable performance of the ceiling material stably even at high temperature deterioration, and it not only prevents corrosion, but also strengthens the surface strength of the finished ceiling material.

이때 리튬 실리케이트가 10중량부 미만이면 천장재의 불연 성능이 저하되고 구성성분들 간의 결합력이 낮아져 점성이 저하될 수 있고, 20중량부를 초과하면 여름철 기온에서 작업할 때 불연수지에 침전물이 발생할 뿐만 아니라 불규칙한 점도 형성으로 도막의 박리가 발생할 수 있으므로, 10~20중량부의 범위로 첨가되는 것이 바람직하다.At this time, if the lithium silicate is less than 10 parts by weight, the non-combustible performance of the ceiling material decreases and the bonding strength between components decreases, and the viscosity may decrease. Since peeling of the coating film may occur due to viscosity formation, it is preferably added in a range of 10 to 20 parts by weight.

셋째, 수용성 에폭시는 친환경분말에 불연수지를 접합시키기 위한 접착기능을 수행하는 것으로, 천장재 시공시 유해물질이 발생하지 않아 작업자의 작업 환경 개선 및 화재 발생시에도 유해물질이 발생하지 않게 함으로써, 안정성을 도모하기 위한 구성이다.Third, water-soluble epoxy performs an adhesive function for bonding non-combustible resins to eco-friendly powders, and does not generate harmful substances during construction of ceiling materials, thereby improving the working environment of workers and preventing harmful substances from occurring in the event of fire, thereby promoting stability. It is a configuration to do.

이러한 수용성 에폭시가 5중량부 미만이면 불연조성물과 친환경분말 간의 혼화력을 균일하게 이루지 못하는 문제점이 있고, 수용성 에폭시가 10중량부를 초과하면 수용성 에폭시의 양이 과도하게 많아져 불연조성물이 불연 성능을 발휘하기에 미미한 문제점이 있으므로, 5~10중량부의 범위로 첨가되는 것이 바람직하다.If the water-soluble epoxy is less than 5 parts by weight, there is a problem that the miscibility between the non-combustible composition and the eco-friendly powder is not uniformly achieved. When the water-soluble epoxy exceeds 10 parts by weight, the amount of the water-soluble epoxy is excessively large, so that the non-combustible material exhibits non-combustible performance. Since there are minor problems below, it is preferable to be added in a range of 5 to 10 parts by weight.

넷째, 흄드 실리카는 건물에 천장재 시공 후 콘크리트 천장과 분리되는 현상을 방지하고, 천장으로의 부착력을 향상시키기 위한 구성이다.Fourth, fumed silica is a structure to prevent the phenomenon of separation from the concrete ceiling after the ceiling material construction in the building, and to improve the adhesion to the ceiling.

말하자면 흄드 실리카가 15중량부 미만이면 천장으로부터 탈락되는 현상을 방지하기에 미미하고, 20중량부를 초과하면 천장재의 형태로 성형될 때 물성이 너무 뻑뻑해져 제품성이 좋지 않게 되므로, 15~20중량부의 범위로 포함되도록 하는 것이 바람직하다.In other words, if the fumed silica is less than 15 parts by weight, it is insignificant to prevent the phenomenon of falling off from the ceiling, and if it exceeds 20 parts by weight, the physical properties become too stiff when molded in the form of a ceiling material, resulting in poor product properties. It is desirable to be included in the range.

다섯째, 중탄은 안료의 역할을 하는 것으로, 천장재에 색상을 부여할 수 있도록 하는 구성이다.Fifth, medium coal plays the role of a pigment, and is a structure that can impart color to the ceiling material.

이때 중탄의 함량이 20중량부 미만이면 안료에 의한 기능이 미미해질 우려가 있고, 30중량부를 초과하면 천장재의 물성이나 외관이 불량해질 우려가 있으므로, 중탄은 20~30중량부로 포함되는 것이 바람직하다.At this time, if the content of the coal is less than 20 parts by weight, there is a concern that the function by the pigment may be insignificant, and if it exceeds 30 parts by weight, the physical properties or appearance of the ceiling material may be poor, so the coal is preferably included in 20 to 30 parts by weight. .

여섯째, 장석은 본 발명에 중요한 구성인바, 알루미늄 규산염광물로써, 모스 굳기는 6이고, 비중은 2~2.7, 쪼개짐의 방향은 90°를 이루며, 흰색, 회색, 짙은 갈색 등을 띄는 것으로, 천장재의 점력과 강도를 향상시킴으로써 내수성이 증가될 수 있도록 하는 구성이다.Sixth, feldspar is an important component of the present invention, and is an aluminum silicate mineral, with a Mohs hardening of 6, specific gravity of 2 to 2.7, and a direction of splitting of 90°, showing white, gray, dark brown, etc. It is a configuration that can increase the water resistance by improving the over-strength.

특히 기존에 통상적으로 사용되어오던 천장재의 경우, 내수성이 부족하여 결로현상 등으로 인한 수분 발생시 천장재가 물에 녹아 그 역할을 제대로 수행하지 못할 뿐만 아니라, 천장으로부터 천장재가 박리되는 사례가 많았으나, 본 발명에서는 장석을 첨가함으로써 내수성 향상을 통하여 상기의 사례에 따른 개선을 도모하고자 한 것이다.In particular, in the case of ceiling materials that have been used in the past, water resistance is insufficient, and when moisture is generated due to condensation, the ceiling material is not dissolved properly in water, and in many cases, the ceiling material is peeled from the ceiling. In the present invention, by adding feldspar, it is intended to improve the water resistance by improving the water resistance.

본 발명의 발명자가 무수한 실험을 해본 결과, 장석이 20중량부 미만으로 첨가되면 천장재의 조직이 치밀하지 못할 뿐만 아니라 이로 인해 천장재의 내수성을 만족시킬 수 없음이 확인되었고, 장석이 25중량부를 초과하여 첨가되면 물성은 다소 강화될 수 있을지는 모르나 시공 후 주름 또는 균열이 발생되면서 시공성이 나쁜 단점이 있음이 확인되었으므로, 장석은 20~25중량부로 첨가되는 것이 바람직함을 알 수 있었다.As a result of numerous experiments conducted by the inventors of the present invention, it was confirmed that when feldspar was added in an amount of less than 20 parts by weight, the structure of the ceiling material was not dense, and thus water resistance of the ceiling material could not be satisfied, and feldspar exceeded 25 parts by weight. When added, the physical properties may be somewhat enhanced, but it was confirmed that there is a disadvantage in that the workability is poor as wrinkles or cracks are generated after construction, and thus it was found that feldspar is preferably added in an amount of 20 to 25 parts by weight.

부가적으로, 장석은 100~200mesh의 크기인 것을 사용하는 것이 좋은데, 100mesh 미만의 입자를 가지면 입자가 너무 커 성형성을 보조해줄 수 없을 뿐만 아니라, 내수성 향상에 기여를 하지 못한다는 단점이 있고, 200mesh를 초과하는 입자를 가지면 오히려 입자가 너무 작아서 작업과정 중 장석의 손실률이 높아진다는 단점이 있기 때문이다.Additionally, it is recommended to use feldspar having a size of 100 to 200 mesh. If the particles have a particle size of less than 100 mesh, the particles are too large to support moldability, and also have the disadvantage of not contributing to the improvement of water resistance. This is because having a particle exceeding the rather small particle has a disadvantage that the loss rate of feldspar increases during the working process.

마지막으로, 제3단계는 불연조성물 100중량부에 대하여, 솔잎분말, 왕겨분말 및 톱밥분말 중에서 하나 이상으로 이루어진 친환경분말 150~200중량부를 혼합한 후 성형함으로써 천장재를 제조하는 단계이다. (S3)Finally, the third step is a step of manufacturing a ceiling material by mixing and molding 150 to 200 parts by weight of an eco-friendly powder composed of at least one of pine needle powder, rice husk powder and sawdust powder with respect to 100 parts by weight of the non-combustible composition. (S3)

즉 제3단계는 불연조성물 100중량부에 친환경분말 150~200중량부를 혼합함으로써 금형 등의 틀에 투입하여 압축 성형함으로써, 천장에 부착되는 판재 형상으로 제조하는 단계를 말한다.That is, the third step refers to a step of manufacturing in a plate-like shape attached to the ceiling by inserting 150 to 200 parts by weight of the eco-friendly powder into 100 parts by weight of the non-combustible composition and then compressing the mixture into a mold or the like.

첫째, 솔잎은 각피와 표피 뿐만 아니라 표피 내부에 내표피를 하나 더 가지고 있어 수분 증발이 억제되고, 솔잎에는 송진이라는 수지가 내포되어 있는데, 송진은 수분 증발량을 더 감소시킬 뿐만 아니라 상처를 보호해주고 병원균 침입을 막아주는 작용을 한다.First, since pine needles have an inner epidermis inside the epidermis as well as the epidermis and the epidermis, moisture evaporation is suppressed, and pine needles contain a resin called pine resin, which further reduces moisture evaporation and protects wounds and pathogens. It acts to prevent intrusion.

이러한 솔잎은 피톤치드의 주성분인 테르텐이 가장 많이 함유되어 살균과 방부의 역할을 한다. 그리고 신체의 중추신경을 자극해서 기분을 좋게 만들어 우울한 마음을 없애주는 역할도 한다.These pine needles contain most of the main ingredient of phytoncide, terten, which acts as a sterilizer and antiseptic. In addition, it stimulates the central nervous system of the body to make you feel good and to remove the depressed mind.

즉 피톤치드라 함은 식물이 균, 곰팡이, 곤충, 해충을 쫓고 자신의 바로 옆에서 다른 식물이 자라지 못하도록 내뿜은 다양한 휘발성 물질을 통틀어 일컫는 것으로, 공기 중으로 날아가는 휘발성 성분인 테르텐은 침엽수에 가장 많으며 약리작용과 향기가 좋다.In other words, phytoncide refers to a variety of volatile substances emitted by plants to chase bacteria, fungi, insects, and pests and prevent other plants from growing right next to them. And the fragrance is good.

더구나 솔잎의 구조는 표피와 내표피로 이루어져 건조에 강하고 영하의 날씨에도 얼지않는 특성이 있고, 송진으로 불리는 기름 성분이 채워져 있어 불연조성물과 혼합될 때 경화를 촉진시켜 솔잎분말의 혼합량에 따라 경화속도를 조절할 수 있을 뿐만 아니라 불연성으로 자연스럽게 이루게 된다. 이에 따라 솔잎의 향기는 그대로 유지되고, 인체의 유해한 질병의 방지에도 도움이 되며, 내외장재의 특수한 역할을 향상시키게 되는 것이다.Moreover, the structure of the pine needles is composed of the epidermis and the inner epidermis, which is resistant to drying and does not freeze in sub-zero weather, and is filled with an oil component called rosin, which accelerates hardening when mixed with non-combustible compositions, thus accelerating the curing speed according to the mixed amount of the pine needle powder. In addition to being able to control, it is naturally achieved with non-combustibility. Accordingly, the fragrance of pine needles is maintained as it is, and it helps to prevent harmful diseases of the human body, and improves the special role of interior and exterior materials.

상술된 이유로 본 발명의 제3단계에서는 솔잎분말이 150~250중량부(바람직하게는, 200중량부) 범위로 첨가되는 것이 좋은데, 이는 150중량부 미만이면 피톤치드 함량이 미달되어 천장재에 자연성분을 충분히 공급하기 어렵고, 250중량부를 초과하면 솔잎분말이 너무 많이 첨가되어 오히려 물성이 좋지 않아지기 때문이다.For the above-described reason, in the third step of the present invention, it is preferable that pine needle powder is added in a range of 150 to 250 parts by weight (preferably, 200 parts by weight). If it is less than 150 parts by weight, the phytoncide content is insufficient and natural ingredients are added to the ceiling material. This is because it is difficult to supply sufficiently, and if it exceeds 250 parts by weight, too much pine needle powder is added, so that physical properties are not good.

참고로, 솔잎분말이 100㎛ 미만의 크기를 가지면 입자 자체가 너무 미세하여 혼합시 날림 현상 등으로 인하여 외부로 유출될 위험이 높고, 200㎛를 초과하는 크기를 가지면 입자가 너무 커 혼화력이 좋지 못하므로, 솔잎분말의 입자는 100~200㎛(더욱 바람직하게는 150㎛) 범위의 크기를 가지는 것이 바람직하다.For reference, if the pine needle powder has a size of less than 100 µm, the particles themselves are too fine, so there is a high risk of leaking to the outside due to the blowing phenomenon when mixing, and if the size exceeds 200 µm, the particles are too large and the mixing ability is good. Since it is not possible, it is preferable that the particles of pine needle powder have a size in the range of 100 to 200 μm (more preferably 150 μm).

둘째, 왕겨는 외피와 내피 구조로 형성되어있고, 그 사이에 다공성 실리카를 포함하고 있어 바이러스, 해충, 박테리아 등으로부터 보호하는 작용을 한다.Second, rice husks are formed in the outer and endothelial structures and contain porous silica between them to protect them from viruses, pests and bacteria.

특히 이 실리카는 벼가 익을수록 왕겨 쪽으로 이동된다. 이러한 왕겨는 다음과 같은 특징이 있다. 첫째, 왕겨는 다공성 구조로 이루어져 단열 및 흡음성이 좋고 비중이 낮으며, 열전도율이 0.048w/mk로 단열 효능이 우수하다. 둘째, 왕겨는 실리카와 셀룰로오스와 독특하게 결합되어 물의 침투와 곰팡이 분해가 잘되지 않는다. 셋째, 왕겨의 실리카는 음이온과 원적외선이 방출되어 혈액순환을 촉진하고 피로회복에 효과적일 뿐만 아니라, 엔돌핀의 분비를 활성화시켜준다. 이는 피부를 보습해 주는 역할도 한다. 넷째, 왕겨는 불에 잘타지 않으며 부패도 잘되지 않는다.In particular, the more the rice is cooked, the more it moves to the chaff. The chaff has the following characteristics. First, rice husk is made of a porous structure, has good heat insulation and sound absorption, has a low specific gravity, and has excellent thermal insulation efficiency with a thermal conductivity of 0.048w/mk. Second, rice husk is uniquely combined with silica and cellulose, so water penetration and mold decomposition are not good. Third, the chaff's silica releases negative ions and far infrared rays to promote blood circulation and to relieve fatigue, as well as to activate endorphin secretion. It also serves to moisturize the skin. Fourth, chaff is not well-burned, and corruption is not good.

여기서 왕겨분말을 100중량부 미만으로 첨가하면 솔잎분말 및 톱밥분말과의 혼화력이 좋지 못하고, 이와 달리 200중량부를 초과하여 첨가하면 솔잎분말 및 톱밥분말이 첨가되는 양이 상대적으로 작아져 천장재의 물성을 만족할 수 없으므로, 왕겨분말은 100~200중량부(바람직하게는, 150중량부)의 범위로 첨가되는 것이 바람직하다.Here, if less than 100 parts by weight of rice husk powder is added, the miscibility with pine needle powder and sawdust powder is not good. On the other hand, when it is added in excess of 200 parts by weight, the amount of pine needle powder and sawdust powder added is relatively small, so the properties of the ceiling material Since it is not satisfactory, the chaff powder is preferably added in a range of 100 to 200 parts by weight (preferably, 150 parts by weight).

부가적으로, 왕겨가 100㎛ 미만 크기로 분쇄되면 입자가 너무 미세해 손실률이 높고, 200㎛를 초과하는 크기로 분쇄되면 오히려 입자가 너무 커져버려 천장재로 제조 후 천장에 견고하게 시공하기 쉽지 않아 그 표면이 매끄럽지 않게 되므로, 왕겨분말은 100~200㎛(가장 바람직하게는 150㎛) 크기로 분쇄되는 것이 바람직하다.Additionally, if the chaff is crushed to a size of less than 100 μm, the loss rate is high because the particles are too fine. Since the surface is not smooth, it is preferable that the chaff powder is crushed to a size of 100 to 200 μm (most preferably 150 μm).

셋째, 톱밥은 나무에서 발생하는 피톤치드가 건물 전체에 퍼지도록 은은한 나무향기가 생기도록 해주는 작용을 한다.Third, sawdust acts to create a subtle wood scent that spreads phytoncide from the trees throughout the building.

여기서 톱밥은 습도 조절 능력이 탁월하고, 단열성이 우수하며, 벌레도 잘 접근하지 않는다. 특히 톱밥은 실내 공기를 정화시켜 신선한 공기를 만들어줘 공기의 질을 좋게하여 아토피, 천식, 불면증 환자에게 도움을 준다. 추가적으로, 톱밥은 방음 효과도 탁월해 주위의 소음도 축소시켜준다.Here, sawdust has excellent humidity control ability, excellent insulation, and does not easily access insects. In particular, sawdust purifies the indoor air to make fresh air, which improves the air quality, helping patients with atopy, asthma, and insomnia. Additionally, sawdust is also excellent in sound insulation, reducing ambient noise.

이런 특징을 가지는 톱밥분말은 100~200중량부의 범위로 포함될 수 있는데, 톱밥분말이 100중량부 미만이면 습도 조절 능력이 부족하여 천장재 시공 후 결로현상이 발생할 우려가 있고, 200중량부를 초과하면 그 이하의 양을 첨가한 것과 비교하여 더 탁월한 효과가 발현되지 않음이 확인되므로, 100~200중량부(바람직하게는, 150중량부)로 첨가되는 것이 바람직하다.Sawdust powder having this feature may be included in the range of 100 to 200 parts by weight. If the sawdust powder is less than 100 parts by weight, there is a risk of moisture condensation due to insufficient humidity control ability, and if it exceeds 200 parts by weight or less Since it is confirmed that the more excellent effect is not expressed compared to the amount of added, it is preferable to add 100 to 200 parts by weight (preferably, 150 parts by weight).

톱밥분말 역시, 솔잎분말과 왕겨분말과 마찬가지로 200㎛ 미만 크기를 가지면 날림현상이 발생하여 시료 손실량이 커져 생산성이 좋지 않고, 300㎛를 초과하는 크기를 가지면 벽지 스프레이 시공시 벽 표면에 부드럽게 발리지 않으므로, 200~300㎛(더욱 바람직하게는 250㎛)의 범위의 입자 크기를 가지도록 분쇄되는 것이 바람직하다.Sawdust powder, like pine needle powder and rice husk powder, has a size of less than 200㎛, causing a phenomenon of flying, which results in a large loss of sample and poor productivity. If it has a size exceeding 300㎛, it does not spread smoothly on the wall surface during spraying of wallpaper. , It is preferably crushed to have a particle size in the range of 200 ~ 300㎛ (more preferably 250㎛).

단, 제3단계에서는 솔잎분말 150~250중량부, 왕겨분말 100~200중량부 및 톱밥분말 100~200중량부 중 어느 하나를 단독으로 사용할 수도 있다.However, in the third step, any one of 150-250 parts by weight of pine needle powder, 100-200 parts by weight of rice husk powder, and 100-200 parts by weight of sawdust powder may be used alone.

이하, 본 발명의 바람직한 실시예에 따라 제조되는 천장재의 실시예는 다음과 같이 다양하게 변경 가능하다.Hereinafter, the embodiment of the ceiling material manufactured according to the preferred embodiment of the present invention can be variously changed as follows.

도 1은 본 발명의 바람직한 제1실시예에 따른 천장재이다. 도 1을 참조하면, 제2단계 및 제3단계의 내용은 동일하게 진행하되, 제1단계에서 질석만을 사용하여 제조된 천장재 시편을 나타낸 것임을 알 수 있다.1 is a ceiling material according to a first preferred embodiment of the present invention. Referring to FIG. 1, it can be seen that the contents of the second and third steps proceed in the same manner, but the ceiling material specimens manufactured using only vermiculite in the first step are shown.

도 2는 본 발명의 바람직한 제2실시예에 따른 천장재이다. 도 2를 참조하면, 제2단계 및 제3단계의 내용은 동일하게 진행하되, 제1단계에서 질석과 미네랄울을 함께 사용하여 제조된 천장재 시편을 나타낸 것임을 알 수 있다.2 is a ceiling material according to a second preferred embodiment of the present invention. Referring to FIG. 2, it can be seen that the contents of the second and third steps proceed in the same way, but the ceiling material specimens produced by using vermiculite and mineral wool together in the first step are shown.

도 3은 본 발명의 바람직한 제3실시예에 따른 천장재이다. 도 3을 참조하면, 제1단계 및 제2단계의 내용은 동일하게 진행하되, 제3단계에서 솔잎분말만을 사용하여 제조된 천장재 시편을 나타낸 것임을 알 수 있다.3 is a ceiling material according to a third preferred embodiment of the present invention. Referring to FIG. 3, it can be seen that the contents of the first and second steps are the same, but the ceiling material specimens manufactured using only the pine needle powder in the third step are shown.

도 4는 본 발명의 바람직한 제4실시예에 따른 천장재이다. 도 4를 참조하면, 제1단계 및 제2단계의 내용은 동일하게 진행하되, 제3단계에서 톱밥분말만을 사용하여 제조된 천장재 시편을 나타낸 것임을 알 수 있다.4 is a ceiling material according to a fourth preferred embodiment of the present invention. Referring to Figure 4, it can be seen that the contents of the first step and the second step are the same, but the third stage shows the specimen of the ceiling material manufactured using only sawdust powder.

도 5는 본 발명의 바람직한 제5실시예에 따른 천장재이다. 도 5를 참조하면, 제1단계 및 제2단계의 내용은 동일하게 진행하되, 제3단계에서 왕겨분말만을 사용하여 제조된 천장재 시편을 나타낸 것임을 알 수 있다.5 is a ceiling material according to a fifth preferred embodiment of the present invention. Referring to FIG. 5, it can be seen that the contents of the first step and the second step are the same, but the third step shows the specimen of the ceiling material manufactured using only rice husk powder.

도 6은 본 발명의 바람직한 실시예에 따른 설치도이다. 도 6을 참조하면, 천장재는 스크루 고정박식 또는 접착제 고정방식 등의 다양한 방법으로 천장에 시공 가능함을 나타낸 것이다.6 is an installation diagram according to a preferred embodiment of the present invention. Referring to FIG. 6, the ceiling material shows that it can be installed on the ceiling in various ways, such as a screw fixing type or an adhesive fixing method.

이러한 도 1 내지 도 6에 의거하여, 내비등수성 시험에 따른 내수성 시험을 해본 결과, 천장재에 주름이나 균열이 발생하지 않음을 확인할 수 있었다.Based on these FIGS. 1 to 6, as a result of performing a water resistance test according to the boiling water resistance test, it was confirmed that no wrinkles or cracks were generated in the ceiling material.

이상의 설명은 본 발명의 기술 사상을 예시적으로 설명한 것에 불과한 것으로, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 본 발명의 본질적인 특성에서 벗어나지 않는 범위에서 다양한 수정 및 변형이 가능할 것이다.The above description is merely illustrative of the technical idea of the present invention, and those of ordinary skill in the art to which the present invention pertains will be capable of various modifications and variations without departing from the essential characteristics of the present invention.

따라서 본 발명에 개시된 실시예는 본 발명의 기술 사상을 한정하기 위한 것이 아니라, 설명하기 위한 것이고, 이러한 실시예에 의하여 본 발명의 기술 사상의 범위가 한정되는 것도 아니다.Therefore, the embodiments disclosed in the present invention are not intended to limit the technical spirit of the present invention, but to explain, and the scope of the technical spirit of the present invention is not limited by these embodiments.

본 발명의 보호 범위는 특허청구범위에 의하여 해석되어야 하며, 그와 동등한 범위 내에 있는 모든 기술사상은 본 발명의 권리범위에 포함되는 것으로 해석되어야 할 것이다.The scope of protection of the present invention should be interpreted by the claims, and all technical ideas within the equivalent range should be interpreted as being included in the scope of the present invention.

Claims (2)

질석 250~350중량부, 미네랄울 150~250중량부 중 어느 하나 이상이 혼합된 혼합물을 제조하는 제1단계;
상기 혼합물 100중량부에 대하여, 소듐 실리케이트 25~35중량부, 리튬 실리케이트 10~20중량부, 수용성 에폭시 5~10중량부, 흄드 실리카 15~20중량부 및 중탄 20~30중량부를 포함하는 불연수지 300~400중량부를 혼합하여 불연조성물을 제조하는 제2단계; 및
상기 불연조성물 100중량부에 대하여, 솔잎분말, 왕겨분말 및 톱밥분말 중에서 하나 이상으로 이루어진 친환경분말 150~200중량부를 혼합한 후 성형함으로써 천장재를 제조하는 제3단계;를 포함하는 것으로,
상기 제2단계의 불연수지는,
장석 20~25중량부를 더 포함하는 것을 특징으로 하는 친환경 천장재의 제조방법.
A first step of preparing a mixture of any one or more of vermiculite 250-350 parts by weight and mineral wool 150-250 parts by weight;
Non-flammable resin containing 25 to 35 parts by weight of sodium silicate, 10 to 20 parts by weight of lithium silicate, 5 to 10 parts by weight of water-soluble epoxy, 15 to 20 parts by weight of fumed silica, and 20 to 30 parts by weight of medium carbon based on 100 parts by weight of the mixture A second step of preparing an incombustible composition by mixing 300 to 400 parts by weight; And
The third step of manufacturing a ceiling material by mixing and molding 150 to 200 parts by weight of an eco-friendly powder made of at least one of pine needle powder, rice husk powder and sawdust powder with respect to 100 parts by weight of the non-combustible composition;
The non-combustible resin in the second step,
Method of manufacturing an eco-friendly ceiling material, characterized in that it further comprises 20-25 parts by weight of feldspar.
친환경 천장재에 있어서,
제1항의 제조방법에 의해 제조되는 것을 특징으로 하는 친환경 천장재.
Eco-friendly ceiling material,
Eco-friendly ceiling material, characterized in that manufactured by the manufacturing method of claim 1.
KR1020180083279A 2018-07-18 2018-07-18 Environment-friendly ceiling material and manufacturing method thereof Expired - Fee Related KR102122204B1 (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101160658B1 (en) 2009-12-28 2012-06-28 석동원 Manufacturing method of noninflammable board and noninflammable board manufactured thereby
KR101876205B1 (en) 2017-02-27 2018-07-09 진경인 Non-flammable spray mortar insulation filler, non-flammable board and non-combustible sandwich panel included a pine needle

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Publication number Priority date Publication date Assignee Title
KR101317357B1 (en) * 2011-05-19 2013-10-15 이동희 Manufacture method of inorganic foam using geopolymer as binder
KR20130006015A (en) * 2011-07-08 2013-01-16 (주)바론에스엘 Inorganic composition of incombustible binder, and method for preparation the same and use thereof
KR20150144519A (en) 2014-06-17 2015-12-28 (주)애니우드 Environmental soundproof materials for ceiling

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101160658B1 (en) 2009-12-28 2012-06-28 석동원 Manufacturing method of noninflammable board and noninflammable board manufactured thereby
KR101876205B1 (en) 2017-02-27 2018-07-09 진경인 Non-flammable spray mortar insulation filler, non-flammable board and non-combustible sandwich panel included a pine needle

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