KR20150120662A - Manufacturing method for hemp fabric curtain and hemp fabric curtain using the same - Google Patents
Manufacturing method for hemp fabric curtain and hemp fabric curtain using the same Download PDFInfo
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- KR20150120662A KR20150120662A KR1020140046516A KR20140046516A KR20150120662A KR 20150120662 A KR20150120662 A KR 20150120662A KR 1020140046516 A KR1020140046516 A KR 1020140046516A KR 20140046516 A KR20140046516 A KR 20140046516A KR 20150120662 A KR20150120662 A KR 20150120662A
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- 244000025254 Cannabis sativa Species 0.000 title claims abstract description 77
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 title claims abstract description 76
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 title claims abstract description 76
- 235000009120 camo Nutrition 0.000 title claims abstract description 76
- 235000005607 chanvre indien Nutrition 0.000 title claims abstract description 76
- 239000011487 hemp Substances 0.000 title claims abstract description 76
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000004744 fabric Substances 0.000 title claims description 24
- 238000000034 method Methods 0.000 claims abstract description 26
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003063 flame retardant Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims description 22
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- 230000000845 anti-microbial effect Effects 0.000 claims description 18
- 230000003373 anti-fouling effect Effects 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000011230 binding agent Substances 0.000 claims description 8
- 230000000844 anti-bacterial effect Effects 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 239000004599 antimicrobial Substances 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 229920001661 Chitosan Polymers 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- OBFQBDOLCADBTP-UHFFFAOYSA-N aminosilicon Chemical class [Si]N OBFQBDOLCADBTP-UHFFFAOYSA-N 0.000 claims description 3
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 3
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000001205 polyphosphate Substances 0.000 claims description 3
- 235000011176 polyphosphates Nutrition 0.000 claims description 3
- 238000009991 scouring Methods 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 210000002268 wool Anatomy 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims 1
- 230000000191 radiation effect Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000003086 colorant Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 230000000979 retarding effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 240000000249 Morus alba Species 0.000 description 2
- 235000008708 Morus alba Nutrition 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- 241000269821 Scombridae Species 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 244000144992 flock Species 0.000 description 2
- 238000007602 hot air drying Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000020640 mackerel Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 230000006196 deacetylation Effects 0.000 description 1
- 238000003381 deacetylation reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- RIRRNZUBFFOHHQ-UHFFFAOYSA-M sodium;phosphoric acid;acetate Chemical compound [Na+].CC([O-])=O.OP(O)(O)=O RIRRNZUBFFOHHQ-UHFFFAOYSA-M 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
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Images
Classifications
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47H—FURNISHINGS FOR WINDOWS OR DOORS
- A47H23/00—Curtains; Draperies
- A47H23/02—Shapes of curtains; Selection of particular materials for curtains
- A47H23/08—Selection of particular materials
- A47H23/12—Selection of particular materials the material being paper or cardboard
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47H—FURNISHINGS FOR WINDOWS OR DOORS
- A47H23/00—Curtains; Draperies
- A47H23/02—Shapes of curtains; Selection of particular materials for curtains
- A47H23/08—Selection of particular materials
- A47H23/14—Selection of particular materials the material being woven textile with reinforcing bars, e.g. made of wood
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Curtains And Furnishings For Windows Or Doors (AREA)
Abstract
본 발명은 삼베 커튼 제조방법 및 그에 의해 제조된 삼베 커튼에 관한 것으로, 특히 친환경소재인 삼베에 한지를 배접하여 인간 친화적이면서도 난연성 및 원적외선 방사효과를 주는 삼베 커튼 제조방법 및 그에 의해 제조된 삼베 커튼에 관한 것이다.The present invention relates to a method of manufacturing a hemp curtain and a hemp curtain produced by the method. More particularly, the present invention relates to a hemp curtain which is human-friendly and has a flame retardant and far-infrared radiation effect, .
Description
본 발명은 삼베 커튼 제조방법 및 그에 의해 제조된 삼베 커튼에 관한 것으로, 더욱 상세하게는 친환경소재인 삼베에 한지를 배접하여 인간 친화적이면서도 난연성 및 원적외선 방사효과를 주는 삼베 커튼 제조방법 및 그에 의해 제조된 삼베 커튼에 관한 것이다.
The present invention relates to a method for manufacturing a hemp curtain and a hemp curtain produced by the method. More particularly, the present invention relates to a method for manufacturing a hemp curtain that is human-friendly and imparts flame retardancy and far- It is about a hemp curtain.
삼베는 대마줄기에서 추출된 섬유로 면보다 10배 이상 질기고 경도가 높아 내구성이 뛰어나다. 또한, 항균성과 항독성을 갖고 수분과 열을 조절하는 특성이 있는 대표적 친환경소재에 해당한다.Hemp is a fiber extracted from hemp stem and is ten times more durable than cotton and has high hardness and excellent durability. It is also a representative green material with antibacterial and antioxidant properties controlling moisture and heat.
또한, 한지는 천연소재인 닥나무로 제작되고 여러 겹으로 배접할 경우 견고함을 제공하며, 다양한 색지로 제공될 수 있어서 장식성과 실용성이 뛰어나고 외국인들에게 우리나라 전통문화의 아름다움을 알릴 수 있는 소재에 해당한다.In addition, Hanji is made of natural mackerel, made of natural mackerel. It provides solidity when it is bonded with multiple layers. It can be provided in various colors, so it is excellent in decoration and practicality and it is a material that can inform the beauty of traditional Korean culture to foreigners .
한편, 커튼은 방풍, 차광, 단열, 방음 등을 목적으로 창문에 설치되어 사용되며, 설치 및 사용 구조 등에 따라 좌우로 펼쳐지는 일반 커튼, 차단판이 세로로 다수개 배열된 버티컬 커튼, 회전 롤에 권취되는 롤 커튼 등 다양한 것이 있다.On the other hand, curtains are installed on windows for the purpose of windshields, shading, insulation, soundproofing, etc., and they are used in general curtains spreading to the left and right depending on installation and use structure, vertical curtains in which a plurality of barrier plates are vertically arranged, There are many things such as roll curtain.
종래기술로 개시된 커튼에 대하여 살펴보면, 한국실용신안 공고 제1994-05264호에 이중 커텐지가 개시되어 있는바, 이중 커텐지는 동일한 굵기의 원사를 이용한 직물을 이중으로 결합하여 제공된다.A double curtain is disclosed in Korean Utility Model Publication No. 1994-05264. The curtain is provided by double-joining fabrics using yarns of the same thickness.
그러나 종래의 커튼지는 대부분 화학공정에 의해 만들어지는 합성사인 폴리에스테르 소재가 위사와 경사로 직조되어 있어서, 화재발생시 유독가스가 발생할 수 있는 위험성이 항상 지적되어 왔다.However, conventional curtain fabrics have been woven with wefts and warp yarns, which are synthetic fibers made by chemical processes, and have always been pointed out to be dangerous to generate toxic gases in case of fire.
이에 최근에는 다양한 방염처리 방법이 적용되어 난연성을 부가하고 있지만, 여전히 실내의 장식재로 이용되는 특성을 고려할 때 인간 친화적인 관점에서 친환경 소재를 사용하지는 않고 생산 편의성만 추구되어 온 문제점이 있었다.In recent years, various flame retarding methods have been applied to add flame retardancy. However, considering the characteristics of being used as a decorative material for interior, there has been a problem that the convenience of production has been pursued without using environmentally friendly materials from the viewpoint of human being.
따라서, 종래와 같이 화학공정에 의해 만들어지는 합성사인 폴리에스테르 소재 등을 이용하는 방안 대신, 전술한 바와 같이 커튼 재질로 사용 가능한 삼베에 한지를 배접함으로써 친환경적인 커튼의 제공이 필요하다.
Therefore, it is necessary to provide environmentally friendly curtains by bonding Korean paper to embossable materials usable as a curtain material as described above, instead of using synthetic materials such as polyester materials, which are produced by a chemical process as in the prior art.
본 발명은 전술한 바와 같은 문제점을 해결하기 위한 것으로, 실내의 장식재로 이용되는 커튼의 특성상 인간친화적 소재가 이용되어야 한다는 관점에서 대표적 친환경소재인 삼베와 한지로 이루어지는 커튼을 제공하고, 나아가 난연성이면서도 원적외선 방사 효과 및 항균효과를 주는 커튼을 제공하는 것을 목적으로 한다.
DISCLOSURE OF THE INVENTION It is an object of the present invention to provide a curtain made of hemp and hemp, which is a typical eco-friendly material, from the viewpoint that a human-friendly material should be used due to the characteristics of a curtain used as a decorative material of a room. It is an object of the present invention to provide a curtain which gives a radiation effect and an antibacterial effect.
이를 위해, 본 발명에 따른 삼베 커튼 제조방법은 비이온(nonionic) 정련 침투제를 사용하여 대섬유중량(O.W.F) 1%에 100℃, 10분, 욕비(섬유:물의 비율) 1:10을 기준으로 정련하여 삼베 원단에 흡착된 불순물을 제거하여 삼베 커튼 원단을 준비하는 단계와; 상기 불순물이 제거된 삼베 원단이 커튼 고유의 부드러운 질감을 갖도록 변성 아미노 실리콘(amino silicon) 유연재를 대섬유질량 10%에 35℃, 20분, 욕비 1:10을 기준으로 처리하는 단계와;상기 삼베 커튼 원단에 방염성 및 항균성을 부여하도록 물유리 4종 2ℓ에 화산재분말 200g, 수산화알루미늄 150g, 폴리포스페이트(polyphosphate) 80g과 솔비톨 40g, 닥나무를 분쇄하여 80~100 mesh를 통과한 펄프분말 2.0 Kg을 녹인 방염조성물과, 물과 아교를 3 : 1로 배합시킨 후 200 mesh의 체를 통과한 패각분말 50g 을 넣어 항균성 바인더조성물을 얻고, 방염조성물과 항균성 바인더조성물을 고속으로 회전시키며 물을 주입하여 방염 및 항균성 조성물을 얻어서 삼베 커튼 원단에 코팅하거나 침적시킨 후 고루 펴주는 단계와; 한지에 방오 및 방염성을 부여하도록 키토산(chitosan)이 0.5~1.5w% 범위로 포함되는 초산수용액 100ℓ에 난연제로 폴리인산암모늄 50g, 삼산화안티몬 50g과 난연보조제로서 폴리비닐알콜 100g 을 추가한 후 교반하여 제공되는 방염·방오 코팅액을 얻고 상기 방염·방오 코팅액에 알루미늄,주석,철 중에서 선택되는 매염제를 코팅액 중량의 0.5~3.0w% 범위로 함유시켜 한지 표면에 코팅시킨 후 상기 삼베 커튼 원단 상면에 펴 덮어주는 배접공정을 실시하여 삼베 커튼을 얻는 단계; 및 상기 공정으로 제조된 삼베 커튼을 음지에서 건조하는 단계;를 포함하는 것을 특징으로 한다.For this purpose, the method of manufacturing the hemp curtain according to the present invention is characterized in that a nonionic scouring impregnant is used to measure an owf weight of 1% at 100 ° C for 10 minutes and a bath ratio (ratio of fibers: water) of 1:10 Removing the impurities adsorbed on the hemp fabric to prepare a hemp curtain fabric; Treating the modified amino silicon wool with a large fiber mass of 10% at 35 DEG C for 20 minutes and a bath ratio of 1:10 so that the impregnated hemp fabric has a smooth texture unique to the curtain; In order to impart flame retardancy and antimicrobial properties to the cotton fabric, 2.0 kg of pulp powder passed through 80 to 100 mesh was melted by pulverizing 200 g of ash powder, 150 g of aluminum hydroxide, 80 g of polyphosphate, 40 g of sorbitol, 50 g of shell powder passed through a sieve of 200 mesh was blended with water and glue in a ratio of 3: 1 to obtain an antibacterial binder composition. The flame retardant composition and the antibacterial binder composition were rotated at a high speed, Obtaining an antimicrobial composition to coat or deposit on a hemp curtain fabric and then straighten it; 50 g of ammonium polyphosphate, 50 g of antimony trioxide and 100 g of polyvinyl alcohol as a flame retardant aid were added to 100 L of an aqueous acetic acid solution containing chitosan in an amount of 0.5 to 1.5 wt% so as to impart antifouling and flame retardancy to Korean paper, And a mordant selected from aluminum, tin and iron is added to the flame retardant / antifouling coating liquid in a range of 0.5 to 3.0 wt% based on the weight of the coating liquid, and the coated surface is coated on the surface of Korean paper, A step of applying a glazing process to obtain a hemp curtain; And drying the hemp curtain produced in the process in a shade.
또한, 본 발명에 따른 삼베 커튼은 이상과 같은 삼베 커튼 제조방법에 의해 제조된 것을 특징으로 한다.
In addition, the hemp curtain according to the present invention is characterized by being manufactured by the above-mentioned hemp curtain manufacturing method.
이상과 같은 본 발명은 커튼의 원단으로서 친환경소재인 삼베를 사용하고, 삼베에 한지를 배접하여 커튼을 제공한다. 또한, 불순물을 제거하는 친환경 정련공정, 난연성을 부가하는 방염공정 및 자연건조 공정을 부가한다.As described above, the present invention uses a green cloth, which is an eco-friendly material, as a raw material of a curtain, and a curtain is provided by bonding Korean paper to hemp. Also, an environmentally friendly refining process for removing impurities, a flame retarding process for adding flame retardancy, and a natural drying process are added.
따라서, 친환경적인 소재를 사용함에 따라 인간 친화적인 커튼을 제공함은 물론, 화재에 강한 난연성을 제공하며, 원적외선 방사 및 항균효과를 주어 인체에 유익한 효과를 제공한다.
Accordingly, the use of environmentally friendly materials not only provides human-friendly curtains, but also provides strong flame retardancy to fire, provides far-infrared radiation and antibacterial effect, and provides beneficial effects to human body.
도 1은 본 발명에 따른 삼베 커튼 제조방법을 나타낸 블록도이다.
도 2는 본 발명에 따른 삼베 커튼 제조장치를 나타낸 구성도이다.
도 3은 본 발명에 따른 삼베 커튼을 나타낸 도이다.1 is a block diagram showing a method for manufacturing a hemp curtain according to the present invention.
2 is a block diagram showing an apparatus for manufacturing a hemp curtain according to the present invention.
3 is a view showing a hemp curtain according to the present invention.
이하, 첨부된 도면을 참조하여 본 발명의 바람직한 실시예에 따른 삼베 커튼 제조방법 및 그에 의해 제조된 삼베 커튼에 대해 설명한다.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT Hereinafter, a method of manufacturing a hemp curtain according to a preferred embodiment of the present invention and a hemp curtain produced by the method will be described with reference to the accompanying drawings.
본 발명은 인체 유해성이 우려되는 원료성분을 사용하지 않도록 친환경소재인 삼배에 한지를 배접시켜 커튼을 제공하는 것으로, 닥나무를 채취하여 외피인 껍질을 벗기고 이를 삶아서 공지의 한지를 제작한다.The present invention provides curtains by inserting three-fold Korean paper, which is an eco-friendly material, so as not to use a raw material ingredient that is suspected of being hazardous to human health. The paper is taken out of the mulberry tree, the skin of the outer skin is peeled, and the paper is cooked to make known paper.
또한, 본 발명은 천연펄프인 닥나무를 분쇄하여 80~100mesh를 통과한 펄프분말에 방염제(난연제), 보존제(항균제,방부제) 및 물을 추가하여 천연섬유소가 함유된 방염 및 항균성 조성물을 만든다.The present invention also provides flame retardant and antimicrobial compositions containing natural fiber by adding flame retardant (flame retardant), preservative (antimicrobial agent, preservative) and water to pulp powder which has been pulverized with natural wood pulp and passed through 80 to 100 mesh.
다만, 상기한 방염 및 항균성 조성물에 삼베를 침적시킨 후 고루 펴주면서 그 상면에 닥나무소재를 이용하여 제작되는 통상의 한지를 그대로 배접시키면 화재 취약성이 남아있고 한지의 다공극 구조에 의해 외부의 오염원이 쉽게 점착되어 커튼 표면이 쉽게 오염/변색되는 문제점이 발생한다.However, when the flame-retardant and antimicrobial composition is immersed in the antimicrobial composition and then spread evenly, when the conventional paper made using the mulberry material is applied as it is, the fire fragility remains, and the foreign pollution source The surface of the curtain is easily contaminated / discolored.
이를 위해, 본 발명은 한지에 먼저 방염 및 방오성을 높여주기 위한 전처리 공정이 실시된 후 방염 및 항균 성조성물에 침적되었던 삼베 원단에 배접하고 음지에서 건조하는 방법으로 삼베 커튼을 제공한다.To this end, the present invention provides a hemp curtain by applying a pretreatment process to enhance the flame resistance and antifouling property of Korean paper followed by bonding to a hemp cloth dipped in a flame-retardant and antimicrobial composition, and drying the hemp paper.
또한, 본 발명은 방염 및 항균성 조성물에 사용되는 바인더로서 물과 아교가 3:1로 사용되거나 알파전분(alpha starch)분말, PVA(폴리비닐 알코올), 포리졸, CMC(카복시메틸셀룰로스), 덱스트린(dextrin) 중에서 선택되는 성분이 추가되어 사용된다.The present invention also relates to a binder for use in a flame retardant and antimicrobial composition, wherein the binder is water and glue in a ratio of 3: 1 or an alpha starch powder, PVA (polyvinyl alcohol), polyol, CMC (carboxymethylcellulose) (dextrin) are added and used.
항균보존제는 1200℃의 고온에서 소성시킨 패각분말이나 디 하이드로초산(아세트산)나트륨, 안식향산나트륨(벤조산나트륨), 프록셀 XL-2 중에서 선택되는 1종 또는 2종 이상의 혼합물이 사용된다.
The antimicrobial preservative may be selected from the group consisting of shell powder baked at a high temperature of 1200 DEG C, sodium dihydrogenphosphate (acetic acid), sodium benzoate (sodium benzoate), and a mixture of two or more selected from Forscel XL-2.
이하, 본 발명을 구체적인 실시예에 의해 더욱 상세히 설명한다.Hereinafter, the present invention will be described in more detail with reference to specific examples.
먼저, 도 1에 도시된 바와 같이 본 발명에 따른 삼베 커튼 제조방법은 삼베 원단 세척(S10a), 삼베 소프트 처리(10b) 및 삼베 방염 처리(10c)를 하여 삼베 원단을 준비한다. 또한, 한지 방염 처리(S20)를 하여 한지를 준비한다.First, as shown in FIG. 1, a method for fabricating a hemp curtain according to the present invention includes preparing a hemp cloth by performing a hemp cloth washing (S10a), a hemp softening process (10b), and a hemp flame proofing process (10c). In addition, Hanji is prepared by performing a Hanji flame-proofing process (S20).
다음, 위와 같이 준비된 삼베 원단에 한지를 배접(S30)하여 이들을 합지하고, 합지된 것을 열풍 건조(S40)하여 커튼을 제조한다. 이와 같이 제조된 삼베 커튼은 권취롤러(S50)에 감아 제공된다.
Next, Korean paper is attached to the hemp fabric prepared as described above (S30), the hemp paper is laminated, and the laminate is hot-air dried (S40) to produce a curtain. The hemp curtain thus produced is wound around the take-up roller S50 and provided.
이하, 위와 같은 각 단계의 실시예에 대해 설명한다.Hereinafter, an embodiment of each of the above steps will be described.
삼베 원단을 특수처리하여 원단 표면에 부착된 불순물을 제거하는 실시예An example of removing impurities adhering to the surface of a fabric by specially treating the fabric
본 발명은 비이온(nonionic) 정련 침투제를 사용하여 대섬유중량(O.W.F) 1%에 100℃, 10분, 욕비(섬유:물의 비율) 1:10을 기준으로 정련하여 삼베 원단에 흡착된 불순물을 제거(S10a)한다.The present invention relates to a method of refining a 1% by weight nonwoven (OWF) 1% by using a nonionic scouring impregnant at a temperature of 100 DEG C for 10 minutes and a bath ratio (ratio of fiber to water) of 1:10, (S10a).
이를 통해 삼베 원단의 표백 처리 후 생기는 각종 유해물질과 이물질들은 완전히 제거되는 반면, 삼베 고유의 성분과 효능을 그대로 유지할 수 있는 자연 가공처리가 이루어진다.
Through this process, various harmful substances and foreign substances generated after the bleaching process of the hemp fabric are completely removed, but the natural processing process is carried out to maintain the original ingredients and efficacy of the hemp hemp.
삼베의 경도를 줄여 커튼 고유의 부드러운 질감을 제거하는 실시예Embodiments in which the softness of the curtain is removed by reducing the hardness of the hemp
본 발명은 위와 같이 불순물이 제거된 삼베 원단이 커튼 고유의 부드러운 질감(자연스러운 굴곡 등)을 갖도록 변성 아미노 실리콘(amino silicon) 유연재를 대섬유질량 10%에 35℃, 20분, 욕비 1:10을 기준으로 처리(S10b)한다. In the present invention, in order to have a soft texture (natural bending and the like) unique to the curtain, the modified amino silicon material is immersed in a large fiber mass of 10% at 35 ° C for 20 minutes and at a bath ratio of 1:10 (S10b).
이와 같이 삼베를 부드럽게 처리한 후에는 원심 탈수기를 이용하여 RPM 2000으로 함수율이 50% 이하가 되도록 약 5분간 탈수를 하고, 탈수된 삼베 원단을 열풍 건조기를 이용하여 120℃에서 100분 동안 건조하여 원사의 수축율이 안정되게 하여, 커튼용 삼베 원단을 준비하고 이하의 공정을 수행한다.
After the softness of the hemp was softened, dehydration was performed for about 5 minutes using a centrifugal dehydrator to a water content of 50% or less by using a centrifugal dehydrator. The dehydrated hemp fabric was dried at 120 ° C. for 100 minutes using a hot- The shrinkage ratio of the curtain is stabilized, and the following process is carried out.
삼베에 방염 및 항균성을 확보하기 위한 조성물의 제조 실시예(1)Preparation of a Composition for Ensuring Flame Retardancy and Antimicrobial Resistance to Hemp (1)
삼베에 방염 및 항균성을 부여하기 위한 수단으로서, 물유리 4종 2ℓ에 화산재분말 200g, 수산화알루미늄 150g, 폴리포스페이트(polyphosphate) 80g, 솔비톨 40g, 닥나무를 분쇄하여 80~100mesh를 통과한 펄프분말 2.0 Kg을 녹인 방염조성물을 준비한다.As a means for imparting flame resistance and antimicrobial properties to the hemp pulp, 2.0 kg of pulp powder having passed through 80 to 100 mesh of pulverized wood pulp with 200 g of volcanic ash powder, 150 g of aluminum hydroxide, 80 g of polyphosphate, 40 g of sorbitol, To prepare a flame retardant composition.
다음, 물과 아교가 3:1로 배합된 후 200mesh의 체를 통과한 패각분말 50g을 넣은 항균성 바인더조성물을 얻고, 방염조성물과 항균성 바인더조성물을 고속으로 회전시키며 물을 약간씩 주입하여 점도가 거의 느껴지지 않을 정도의 방염 및 항균성 조성물을 만들어 도 1의 장치에서 삼베를 침적시켜 방염성(S10c)을 갖게 한다.
Next, an antimicrobial binder composition containing 50 g of a shell powder having passed through a 200 mesh sieve after mixing water and glue in a ratio of 3: 1 was obtained. The flame retardant composition and the antimicrobial binder composition were rotated at a high speed, The flame retardant and antimicrobial composition is made so as not to be felt, and the flame retardancy (S10c) is provided by immersing the flock in the apparatus of FIG.
한지의 방오 및 방염성을 확보하기 위한 방염·방오 코팅액의 제조실시예(2)(2) Preparation of Flame Retardant and Antifouling Coating Liquid to Ensure Antifouling and Flame Retardancy of Hanji
탈아세틸화도 100%인 키토산을 1w% 농도의 초산 수용액에 용해하되, 초산수용액 중 키토산이 0.5~1.5w% 범위를 이루어 제공되는 초산수용액 100ℓ에 난연재로 폴리인산암모늄 50g 및 삼산화안티몬 50g과 난연보조제로서 폴리비닐알콜 100g 을 추가한 후 교반하여 방염·방오 코팅액(S20)을 만든다.Chitosan having a degree of deacetylation of 100% is dissolved in a 1 wt% acetic acid aqueous solution. In 100 liters of an aqueous acetic acid solution containing 0.5 to 1.5 wt% of chitosan in aqueous acetic acid solution, 50 g of ammonium polyphosphate and 50 g of antimony trioxide, , 100 g of polyvinyl alcohol is added and stirred to prepare a flame retardant / antifouling coating solution (S20).
상기의 방법으로 제조된 방염·방오 코팅액은 초산의 휘발성으로 인하여 분자량이 저하될 수 있는 가능성을 최소화시키기 위해 용해가 완료된 후 12시간 이내에 사용하는 것이 바람직하며, 한지를 30초 내지 1분 범위로 짧은 시간 동안 침지시켰다가 신속히 압착롤러를 거쳐 삼베에 배접(S30)되게 한다.The flame retardant and antifouling coating liquid prepared by the above method is preferably used within 12 hours after the dissolution is completed in order to minimize the possibility that the molecular weight is lowered due to the volatility of acetic acid. (S30) for a predetermined period of time.
다만, 방염·방오 코팅액에는 매염제로서 알루미늄, 주석, 철 중에서 선택되는 매염제가 코팅액 중량의 0.5~3.0w% 중량으로 매염제를 추가하여 코팅액이 제조될 때 한지에 아름다운 문양이 오래 지속되게 한다.
However, mordants selected from aluminum, tin and iron as a mordant for flame retardant and antifouling coating liquids are added with a mordant in a weight of 0.5-3.0wt% of the weight of the coating liquid, so that a beautiful pattern on the paper is maintained when the coating liquid is prepared.
한편, 도 2는 본 발명에 따른 삼베 커튼을 제조하는 장치를 나타낸 것으로, 제조 실시예(1)에서 얻은 방염 및 항균성 조성물에 삼베를 침적하여 방염 및 항균성을 확보(S10c)한다. 또한, 제조 실시예(2) 공정을 통하여 얻은 방염·방오 코팅액에 한지를 침적하여 방염 및 방오성을 확보(S20)하는 공정을 나타낸다.2 shows an apparatus for producing a hemp curtain according to the present invention. Flame-retarding and antimicrobial properties are secured (S10c) by depositing hemp with the flame-retardant and antimicrobial composition obtained in Production Example (1). Further, the step of depositing Korean paper in the flame retardant / antifouling coating liquid obtained through the production example (2) to secure flame retardancy and antifouling property (S20).
예컨대, 삼베(10)가 감겨진 적치롤(11)에서 텐션롤러(T_R)를 경유하며 제조 실시예(1)에서 얻은 방염 및 항균성 조성물이 담겨진 제1저류조(12)를 거치면서 방염 및 항균성분이 삼베 양측으로 침투된다.For example, when the flame-retarding and antimicrobial agent is passed through the
다음, 가이드롤러를 거쳐 120±10℃ 범위를 유지하는 제1건조로(13)를 50~100 m/min의 속도로 통과시킨다. 제1건조로(13)에는 적외선 램프(13a) 및 열풍기(13b)가 설치되어 있어서 삼베를 살균 건조시킨다.Next, the
한편, 한지(20)가 감겨진 적치롤(21)에서 텐션롤러(T_R)를 경유하며 제조실시예(2)에서 얻은 방염·방오 코팅액이 담겨진 제2저류조(22)를 거치면서 방오 및 방염성 성분이 한지에 침투된다.On the other hand, while passing through the
다음, 가이드롤러를 거쳐 100±10℃ 범위를 유지하는 제2건조로(23)를 50~100m/min의 속도로 통과시킨다. 제2건조로(23) 역시 적외선 램프(13a) 및 열풍기(13b)를 포함하여 한지를 살균 건조시킨다.Next, the
다음, 위와 같이 공급된 삼베와 한지가 가압롤러(30)를 통과하면서 배접되고, 이때 가압롤러(30)의 압력을 조절함으로써 배접된 삼베와 한지(즉, 삼베 커튼)의 두께를 조절한다.Then, the supplied hemp and hemp are passed through the
다음, 삼베와 한지가 배접된 삼베 커튼은 온풍건조로(40)를 거치며 완전 건조되고, 완전 건조된 삼베 커튼은 권취롤러(51)에 감겨 삼베 커튼 원단으로서 납품이 이루어진다.
Next, the hemp curtain to which the hemp and the hemp are bonded is completely dried through the hot
이상과 같은 공정을 거쳐 제공되는 삼베 커튼(50)은 한지의 질감이 그대로 표출되며 실내에서 사용시 흡음, 차음, 난연, 방염, 보온단열기능이 발휘됨은 물론 한지와 삼베 특유의 특성을 잃지 않고 원적외선 방사효과를 부여하면서 실내 인테리어 장식기능을 극대화한다.The surface of the Korean paper curtain (50), which is provided through the above-described process, shows the texture of the Korean paper as it is. When used indoors, it exhibits sound absorption, sound insulation, flame retardance, flame resistance, thermal insulation, Maximize interior decorating while giving effect.
도 3에는 본원에서 제공되는 삼베 커튼(60)이 좌우 방향으로 펼쳐지는 일반적인 방식으로 사용되는 실시양태를 도시한 것이다.3 shows an embodiment in which the hemp curtain 60 provided in the present application is used in a general manner spreading in the left-right direction.
커튼 형태는 일반적인 커튼과 세로로 다수가 배열되어 이루어지는 버티컬 커튼, 회전 롤에 권취되는 롤 커튼 등 다양한 커튼이 있으나, 도 3에 제시된 실시형태는 삼베 커튼(60)를 이용하여 일반적인 형태로 적용된 경우를 예로 든 것이다. The curtain type includes various types of curtains such as a general curtain, a vertical curtain in which a plurality of curtains are vertically arranged, and a roll curtain to be wound around a rotary roll. In the embodiment shown in FIG. 3, For example.
다만, 본 발명에서 제공되는 삼베 커튼은 도 3에 도시된 일반적인 타입 이외에도 롤 블라인드 타입, 판넬 블라인드, 버티칼 타입, 로만 쉐이드 타입 및 주름 타입의 커튼 등 어떠한 형태의 커튼에도 적용될 수 있음은 자명할 것이다.
It should be apparent, however, that the hemp curtain provided in the present invention can be applied to any type of curtain, such as a roll blind type, a panel blind, a vertical type, a roman shade type and a wrinkle type curtain in addition to the general type shown in FIG.
이상과 같이 본 발명은 종래의 커튼은 화학 섬유사가 사용되고 있는 문제점을 개선하여 환경친화적 재질로서 실내에서 원적외선을 방사하는 삼베와 한지를 이용한다.As described above, the present invention improves the problem that the conventional curtain is used with the chemical fiber yarn and uses the hemp and the paper which emit the far-infrared rays in the room as an environment-friendly material.
또한, 삼베에 한지를 배접시켜 제조하되, 삼베 커튼에 방염 및 방오 기능을 부여하기 위해 방염공정 및 방오코팅을 실시하고, 한지 바탕에 다양한 색상 및 무늬를 부가하여 쾌적한 실내공간을 추구하면서도 계절에 적합한 색상을 사용하여 실내 온도를 조절한다.In addition, it is manufactured by inserting Korean paper on the hemp, and the flame-retarding process and the antifouling coating are applied to the hemp curtain to give flame-retarding and anti-fouling function, and various colors and patterns are added to the base paper of Korean paper to provide pleasant interior space. Use the color to adjust the room temperature.
또한, 본 발명의 삼베 커튼은 일반가정, 오피스, 호텔, 스튜디오, 강당, 세미나실, 외국인을 위한 행사장 등에서 널리 사용되어 한지에 표출되는 다양한 색상과 질감의 조화로 삼베와 한지를 세계화하는 용도에 사용될 수 있다.
In addition, the hemp curtain of the present invention is widely used in homes, offices, hotels, studios, auditoriums, seminar rooms, and venues for foreigners, and is used in a variety of colors and textures to be used for globalization of hemp and paper .
이상, 본 발명의 특정 실시예에 대하여 상술하였다. 그러나, 본 발명의 사상 및 범위는 이러한 특정 실시예에 한정되는 것이 아니라, 본 발명의 요지를 변경하지 않는 범위 내에서 다양하게 수정 및 변형이 가능하다는 것을 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자라면 이해할 것이다. The specific embodiments of the present invention have been described above. It is to be understood, however, that the scope and spirit of the present invention is not limited to these specific embodiments, and that various modifications and changes may be made without departing from the spirit of the present invention. If you have, you will understand.
따라서, 이상에서 기술한 실시예들은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에게 발명의 범주를 완전하게 알려주기 위해 제공되는 것이므로, 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야만 하며, 본 발명은 청구항의 범주에 의해 정의될 뿐이다.
Therefore, it should be understood that the above-described embodiments are provided so that those skilled in the art can fully understand the scope of the present invention. Therefore, it should be understood that the embodiments are to be considered in all respects as illustrative and not restrictive, The invention is only defined by the scope of the claims.
10 : 삼베 11 : 삼베 적치롤
12: 제1저류조 13: 제1건조로
20: 한지 21: 한지 적치롤
22: 제2저류조 23: 제2건조로
30: 가압롤러 40: 온풍건조로
50: 삼베 커튼 51: 권취롤러
T_R: 텐션 롤러10: Hemp 11: Hemp roll
12: first storage tank 13: first drying furnace
20: Korean paper 21: Korean paper roll
22: second storage tank 23: second drying furnace
30: pressure roller 40: hot air drying furnace
50: hemp curtain 51: winding roller
T_R: Tension roller
Claims (2)
상기 불순물이 제거된 삼베 원단이 커튼 고유의 부드러운 질감을 갖도록 변성 아미노 실리콘(amino silicon) 유연재를 대섬유질량 10%에 35℃, 20분, 욕비 1:10을 기준으로 처리하는 단계와;
상기 삼베 커튼 원단에 방염성 및 항균성을 부여하도록 물유리 4종 2ℓ에 화산재분말 200g, 수산화알루미늄 150g, 폴리포스페이트(polyphosphate) 80g과 솔비톨 40g, 닥나무를 분쇄하여 80~100 mesh를 통과한 펄프분말 2.0 Kg을 녹인 방염조성물과, 물과 아교를 3 : 1로 배합시킨 후 200 mesh의 체를 통과한 패각분말 50g 을 넣어 항균성 바인더조성물을 얻고, 방염조성물과 항균성 바인더조성물을 고속으로 회전시키며 물을 주입하여 방염 및 항균성 조성물을 얻어서 삼베 커튼 원단에 코팅하거나 침적시킨 후 고루 펴주는 단계와;
한지에 방오 및 방염성을 부여하도록 키토산(chitosan)이 0.5~1.5w% 범위로 포함되는 초산수용액 100ℓ에 난연제로 폴리인산암모늄 50g, 삼산화안티몬 50g과 난연보조제로서 폴리비닐알콜 100g 을 추가한 후 교반하여 제공되는 방염·방오 코팅액을 얻고 상기 방염·방오 코팅액에 알루미늄,주석,철 중에서 선택되는 매염제를 코팅액 중량의 0.5~3.0w% 범위로 함유시켜 한지 표면에 코팅시킨 후 상기 삼베 커튼 원단 상면에 펴 덮어주는 배접공정을 실시하여 삼베 커튼을 얻는 단계; 및
상기 공정으로 제조된 삼베 커튼을 음지에서 건조하는 단계;를 포함하는 것을 특징으로 하는 삼베 커튼 제조방법.Using a nonionic scouring impregnant, the fibers were refined to a large fiber weight (OWF) of 1% at a temperature of 100 ° C for 10 minutes and a bath ratio (fiber: water ratio) of 1:10 to remove impurities adsorbed on the fabric, Preparing a curtain fabric;
Treating the modified amino silicon wool with a large fiber mass of 10% at 35 DEG C for 20 minutes and a bath ratio of 1:10 so that the impregnated hemp fabric has a smooth texture inherent to the curtain;
In order to impart flame retardancy and antimicrobial properties to the hemp cloth, 200 g of powder of volcanic ash, 150 g of aluminum hydroxide, 80 g of polyphosphate, 40 g of sorbitol and 2.0 kg of pulp powder passed through 80-100 mesh were pulverized 50 g of shell powder passed through a sieve of 200 mesh was blended with water and glue 3: 1 to obtain an antibacterial binder composition, and the flame retardant composition and the antibacterial binder composition were rotated at a high speed, And an antimicrobial composition to coat or deposit on a hemp curtain fabric and then straighten the hemp curtain;
50 g of ammonium polyphosphate, 50 g of antimony trioxide and 100 g of polyvinyl alcohol as a flame retardant aid were added to 100 L of an aqueous acetic acid solution containing chitosan in an amount of 0.5-1.5 wt% so as to impart antifouling and flame retardancy to Korean paper, followed by stirring And a mordant selected from aluminum, tin and iron is added to the flame retardant / antifouling coating liquid in a range of 0.5 to 3.0 wt% based on the weight of the coating liquid, and the coated surface is coated on the surface of Korean paper, A step of applying a glazing process to obtain a hemp curtain; And
And drying the hemp curtain produced in the process in a shade.
A hemp curtain which is manufactured by the hemp curtain manufacturing method as in the above item 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020140046516A KR20150120662A (en) | 2014-04-18 | 2014-04-18 | Manufacturing method for hemp fabric curtain and hemp fabric curtain using the same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020140046516A KR20150120662A (en) | 2014-04-18 | 2014-04-18 | Manufacturing method for hemp fabric curtain and hemp fabric curtain using the same |
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| Publication Number | Publication Date |
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| KR20150120662A true KR20150120662A (en) | 2015-10-28 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1020140046516A Withdrawn KR20150120662A (en) | 2014-04-18 | 2014-04-18 | Manufacturing method for hemp fabric curtain and hemp fabric curtain using the same |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017146282A1 (en) * | 2016-02-24 | 2017-08-31 | 박통령 | Method for manufacturing hemp fiber fabric |
| KR101896928B1 (en) * | 2018-03-26 | 2018-09-10 | 주식회사 제이엔티코퍼 | Bag type products using binding materials of recycling leather and korean paper |
| CN116063644A (en) * | 2022-11-18 | 2023-05-05 | 现代纺织技术创新中心(鉴湖实验室) | A kind of polyurethane flame retardant foam and preparation method thereof |
| CN116289322A (en) * | 2023-03-13 | 2023-06-23 | 浙江理工大学 | A kind of preparation method of cationic hydrophobic microcapsule flame retardant paper |
| CN116834416A (en) * | 2023-06-15 | 2023-10-03 | 浙江新中纺实业有限公司 | Antibacterial curtain fabric and preparation method thereof |
-
2014
- 2014-04-18 KR KR1020140046516A patent/KR20150120662A/en not_active Withdrawn
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017146282A1 (en) * | 2016-02-24 | 2017-08-31 | 박통령 | Method for manufacturing hemp fiber fabric |
| KR101896928B1 (en) * | 2018-03-26 | 2018-09-10 | 주식회사 제이엔티코퍼 | Bag type products using binding materials of recycling leather and korean paper |
| CN116063644A (en) * | 2022-11-18 | 2023-05-05 | 现代纺织技术创新中心(鉴湖实验室) | A kind of polyurethane flame retardant foam and preparation method thereof |
| CN116289322A (en) * | 2023-03-13 | 2023-06-23 | 浙江理工大学 | A kind of preparation method of cationic hydrophobic microcapsule flame retardant paper |
| CN116834416A (en) * | 2023-06-15 | 2023-10-03 | 浙江新中纺实业有限公司 | Antibacterial curtain fabric and preparation method thereof |
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