KR800000037B1 - Preparation of soy sauce powder - Google Patents
Preparation of soy sauce powder Download PDFInfo
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- KR800000037B1 KR800000037B1 KR7900942A KR790000942A KR800000037B1 KR 800000037 B1 KR800000037 B1 KR 800000037B1 KR 7900942 A KR7900942 A KR 7900942A KR 790000942 A KR790000942 A KR 790000942A KR 800000037 B1 KR800000037 B1 KR 800000037B1
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- KR
- South Korea
- Prior art keywords
- soy sauce
- medium
- wheat bran
- inoculated
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 235000013555 soy sauce Nutrition 0.000 title claims abstract description 17
- 239000000843 powder Substances 0.000 title abstract description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 16
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000013736 caramel Nutrition 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001506 calcium phosphate Substances 0.000 claims abstract description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 5
- 239000008103 glucose Substances 0.000 claims description 5
- 238000001256 steam distillation Methods 0.000 claims description 5
- 241000894006 Bacteria Species 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 235000019764 Soybean Meal Nutrition 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 239000004455 soybean meal Substances 0.000 claims description 4
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 3
- 229940078499 tricalcium phosphate Drugs 0.000 claims description 3
- 229910000391 tricalcium phosphate Inorganic materials 0.000 claims description 3
- 235000019731 tricalcium phosphate Nutrition 0.000 claims description 3
- 241000980809 Aspergillus aureus Species 0.000 claims description 2
- 238000000605 extraction Methods 0.000 claims description 2
- 235000015099 wheat brans Nutrition 0.000 abstract description 6
- 244000068988 Glycine max Species 0.000 abstract description 4
- 235000010469 Glycine max Nutrition 0.000 abstract description 4
- 241000228212 Aspergillus Species 0.000 abstract description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 244000063299 Bacillus subtilis Species 0.000 abstract 1
- 235000014469 Bacillus subtilis Nutrition 0.000 abstract 1
- 229910000389 calcium phosphate Inorganic materials 0.000 abstract 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 abstract 1
- 244000005700 microbiome Species 0.000 abstract 1
- 235000013923 monosodium glutamate Nutrition 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 229940073490 sodium glutamate Drugs 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 6
- 239000000796 flavoring agent Substances 0.000 description 4
- 238000000855 fermentation Methods 0.000 description 3
- 230000004151 fermentation Effects 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 230000000968 intestinal effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000013322 soy milk Nutrition 0.000 description 2
- 240000006439 Aspergillus oryzae Species 0.000 description 1
- 235000002247 Aspergillus oryzae Nutrition 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- -1 aliphatic amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 239000002636 mycotoxin Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 108700012359 toxins Proteins 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
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- Seasonings (AREA)
Abstract
Description
본 발명은 밀기울 배지에 아스페르기루스 오리자(Aspergillus Oryzae)이나, 밀기울과 대두박의 동량 혼합 배지에 나토(Natto)균을 각각 접종 발효하여 수증기 증류하고 에텔로 추출 농축한후 식염, 제3인산칼슘, 포도당, 구루타민산나트륨 및 카라멜을 혼합하여 분말간장을 제조하는 방법에 관할 것이다.The present invention is inoculated and fermented by inoculation of Nato bacteria into the same mixed medium of bran and soybean meal in Aspergillus Oryzae in wheat bran medium, steam distillation, and then concentrated by extraction with ether, triphosphate. It will be directed to a method of making powdered soy sauce by mixing calcium, glucose, sodium gurutamate and caramel.
종래의 간장은 대두, 소맥 기타 곡류를 원료로 하여 발효과정을 거쳐서 제조하였기 때문에 간장의 성숙기간이 오래 걸릴 뿐만 아니라 제조상 여러 처리과정에서 인체에 유해할 중금속류나 메주의 발효과정에서 부생되는 것으로 알려진 마이코톡신(Mycotoxine)과 아프라톡신(Afratoxine) 같은 유해독소 등이 함유될 가능성이 있을뿐만 아니라 액체로 되여 있기 때문에 보관하는데도 큰 용기가 필요하며 협소한 도시생활에 장독이란 많은 면적을 차지하고 필요에 따라 소량식 휴대하기 어려운 결점이 있다.Conventional soy sauce is made from soybeans, wheat and other grains through fermentation, so it takes a long time to mature soybeans and is known to be a byproduct of fermentation of heavy metals and meju that may be harmful to humans in various processes. In addition to the possibility of containing harmful toxins such as Mycotoxine and Afratoxine, they are liquid and require large containers for storage. There is a drawback that is difficult to carry.
또한 종래에는 장유를 분말로 하기 위하여 저온건조 또는 진공 농축 등을 한바 있으나 가온 진공농축은 완전 탈수가 불가능할 뿐만 아니라 제품되는 동안 장유의 향미가 손실되는 등의 결점이 있었고 방화 건조하는 방법등도 알러졌으나 조작이 복잡할뿐만 아니라 고유의 장유향미가 변질되는 우려등이 있는 결점들이 많았다.In addition, in the past, low temperature drying or vacuum concentration was used to make soymilk as a powder. However, heated vacuum concentration is not only impossible to dehydrate completely, but also has a drawback such as loss of flavor of soymilk during production. In addition to the complexity of the operation, there were many defects such as the inherent flavor of the intestinal fragrance.
또할 일본 특허공보 소 50-18,076호에 장유유에서 수증기 증류 또는 알콜증류할 증류물을 장유를 건조가공할 것이나, 간장에 직접 첨가 사용하는 방법이 소개되었으나 장유유중 불량할 취기가 혼입되거나 증류물이 지방유, 스테아린산, 고급지방산, 불용성팔미친산으로 구성되어 있어 특수할 취향을 기대할 수 없는 문제점 등이 있는 것이다.In addition, Japanese Patent Publication No. 50-18,076 introduces a method of drying the enteric oil for steam distillation or alcohol distillation from the entertained oil, but using the direct addition to the soy sauce. This fatty oil, stearic acid, higher fatty acids, insoluble palmitic acid is composed of problems that can not expect a special taste.
본 발명은 이러할 종래의 결점들을 제거하기 위하여 종래의 장유향미를 그대로 지속하고 아주 간편하게 즉석 분말 간장을 제조하는 방법으로 밀기울배지에 아스페르기루스 오리자균을 접종하거나 또는 밀기울과 대두박의 중량 비율을 1 : 1 한 배지에 나토균을 접종하여 29-42℃에서 75시간 발효하여서 얻은 발효물을 물로 침적 여과한 침출액을 수증기 증류하고 이 증류액을 에텔로 추출 농축하여 부향제인 유상물을 얻은다음 식염, 제3인산칼슘, 포도당, 구루타민산 나트륨 및 카라멜을 혼합하여 분말 간강을 제조하는 방법이다.The present invention is to inoculate the Aspergillus Aureus bacteria in the bran medium or to maintain the conventional intestinal flavor in order to remove these drawbacks, and very simply prepare instant powder soy sauce or the weight ratio of bran and soybean meal 1 : 1 After inoculating NATO bacteria in one medium and fermenting the obtained fermented product for 75 hours at 29-42 ° C., the leachate obtained by distillation and filtering the leachate with water was steam-distilled, and the distillate was extracted with ether, concentrated to obtain an oil as a flavoring agent, and then A method of producing powdered liver by mixing tricalcium phosphate, glucose, sodium gurutamate and caramel.
여기에서 발효물을 수증기 증류하고 에텔로 추출하여 얻은 유상물은 다음 일반식(1)의 이소프로필 아크릴레이트(Isopropylacrylate)인 고분자계의 화합물로 추정되며, 유상액체이나 4℃ 이하에서 고화되고 담황색 고체로 특이할 취기가 있고 물, 알콜, 크로로포롬, 에텔에 잘 녹으며 IR 스펙트럼의 흡수대가 2,800㎝-1(-CH2-),2,860㎝-1(-O-CH2-), 1,690㎝-1(> C==0), 1,110-1,040㎝-1(지방족아민계) 1,040-1,200㎝-1(치오케톤계)이다.The oil obtained by steam distillation of the fermented product and extracted with ether is estimated to be a high molecular compound which is isopropyl acrylate (I) of the following general formula (1), solidified at 4 ° C. or lower, and pale yellow solid. It has a characteristic odor and is soluble in water, alcohol, chromophore and ether, and absorption band of IR spectrum is 2,800 cm -1 (-CH 2- ), 2,860 cm -1 (-O-CH 2- ), 1,690 cm -1 (> C == 0) and 1,110-1,040 cm -1 (aliphatic amine) 1,040-1,200 cm -1 (chioketone system).
상기 식에서In the above formula
R나 R1은 동일하거나 서로 상이한 것으로 치오케톤류, 지방족아민류이고 n은 정수이다.R and R 1 are the same or different from each other, such as chioketones and aliphatic amines, and n is an integer.
이리하여 제조된 분말간장을 적당량의 물에 용해하면 색상과 향취가 좋은 액체간장이 되여 각종 요리에 사용할 수 있고 제조공정이 아주 간편하면서 간장의 성숙기간이 생략되므로 단시간에 대량생산할 수 있을뿐 아니라 종래의 간장과 같은 인체에 유해할 부산물이 생길 우려가 없다.Thus dissolved powdered soy sauce becomes liquid soy sauce with good color and odor, so it can be used in various dishes, and the manufacturing process is very simple, so that the mature period of soy sauce is omitted, so that it can be mass-produced in a short time. There is no risk of harmful by-products such as soy sauce.
본 발명의 분말 간장은 액체간장에 비하여 부피가 적고 항산화적(抗酸化的)이며 장독대 없이 좁은 공간에 보관할 수 있으며 운반과 취급이 간편하고 편하게 휴대하며 사용할 수 있고 특히 장독대의 제거로 도시안의 주택생활을 개선할 수 있다.The powdered soy sauce of the present invention is less bulky, antioxidant, and can be stored in a narrow space without a long reading table, and is easy to carry and handle. Can be improved.
본 발명의 실시예를 들면 다음과 같다.Examples of the present invention are as follows.
[실시예 1]Example 1
밀기울 1,000g의 배지에 아스페르기루스 오리자균을 접종하거나 또는 밀기울 500g과 대두박 500g을 혼합할 배지에 나토균을 접종시켜 29-42℃에서 75시간 발효시킨다.Inoculate Aspergillus Bacillus in 1,000 g of wheat bran or inoculate NATO in medium to mix 500 g of wheat bran and 500 g of soybean meal and ferment for 75 hours at 29-42 ° C.
발효하여서 얻은 발효물을 물로 침적 여과하여 얻은 침출액을 수증기 증류하고 이 증류액을 에텔로 추출하여 에텔의 취기가 없을 때까지 증발 농축하여 본 발명의 부향제인 유상물 3.6g을 얻는다.The leachate obtained by immersing the fermented product obtained by fermentation by water filtration is steam distilled, the distillate is extracted with ether, and concentrated by evaporation until there is no odor of ether, to obtain 3.6 g of oil as a fragrance of the present invention.
[실시예 2]Example 2
정제된 식염을 130℃에서 2시간 건조하여 600g을 취하고 여기에 제3인산칼슘 2g, 포도당 60g, 구루타민산나트륨 130g 및 카라멜 210g을 혼합하고 실시예(1)에서 얻은 부향제인 유상물 0.2mg을 혼합하여 혼합기에서 잘 혼합하면 즉석 분말간장이 된다.The purified salt was dried at 130 ° C. for 2 hours to obtain 600 g, to which 2 g of tricalcium phosphate, 60 g of glucose, 130 g of sodium gurutamate and 210 g of caramel were mixed, and 0.2 mg of an oil, which is a fragrance obtained in Example (1), was obtained. Mix well and mix well in the mixer to make instant powder soy sauce.
[실시예 3]Example 3
실시예(2)에서와 같이 정제된 식염 738g을 취하고 CMC 27g 포도당 28g의 분말 혼합물을 실시예(1)에서 수증기 증류하여 얻은 증류액 280ml에 카라멜 240g을 용해할 용액에 혼가하여 잘 혼합하던 페이스트상의 간장이 된다.738 g of purified salt was taken as in Example (2), and a powder mixture of 28 g of CMC 27 g of glucose was mixed with a solution to dissolve 240 g of caramel in 280 ml of a distillate obtained by steam distillation in Example (1). It becomes soy sauce.
이 페이스트 간장 22g을 물 100ml에 용해하면 재래식 간장이 된다.When 22g of this paste soy sauce is dissolved in 100ml of water, it becomes conventional soy sauce.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR7900942A KR800000037B1 (en) | 1979-03-27 | 1979-03-27 | Preparation of soy sauce powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR7900942A KR800000037B1 (en) | 1979-03-27 | 1979-03-27 | Preparation of soy sauce powder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR800000037B1 true KR800000037B1 (en) | 1980-01-28 |
Family
ID=19211199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR7900942A Expired KR800000037B1 (en) | 1979-03-27 | 1979-03-27 | Preparation of soy sauce powder |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR800000037B1 (en) |
-
1979
- 1979-03-27 KR KR7900942A patent/KR800000037B1/en not_active Expired
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