KR830006830A - Silver Peroxide Battery Containing Cadmium and Tellurium - Google Patents

Silver Peroxide Battery Containing Cadmium and Tellurium Download PDF

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KR830006830A
KR830006830A KR1019810002276A KR810002276A KR830006830A KR 830006830 A KR830006830 A KR 830006830A KR 1019810002276 A KR1019810002276 A KR 1019810002276A KR 810002276 A KR810002276 A KR 810002276A KR 830006830 A KR830006830 A KR 830006830A
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silver peroxide
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KR840002391B1 (en
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요이찌 오오야
다다요시 스미즈
에이찌 비모도
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후지자끼 아끼라
스미도모 긴소구 교오잔 가부시기가이샤
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/04—Cells with aqueous electrolyte
    • H01M6/045—Cells with aqueous electrolyte characterised by aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/54—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of silver
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0002—Aqueous electrolytes
    • H01M2300/0014—Alkaline electrolytes

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  • Chemical Kinetics & Catalysis (AREA)
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  • General Chemical & Material Sciences (AREA)
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Abstract

내용 없음No content

Description

과산화은 전지Silver peroxide battery

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

과산화은 전지의 안도를 결집하는데 사용되는 장치의 개략도.Schematic diagram of a device used to aggregate the relief of silver cells.

Claims (39)

알칼이 전해액을 함유하고, 주로 과산화은으로 형성된 양극을 가지는 과산화은 전지에서, 과산화과알칼리 전해액의 적어도 하나에 카드뮴성분과 텔루륨성분을 함유함을 특징으로 하는 과산화은 전지.A silver peroxide battery, wherein the alkali contains an electrolyte solution and has a positive electrode formed mainly of silver peroxide, wherein the at least one of the peroxide alkali solution contains a cadmium component and a tellurium component. 과산화은에 카드뮴 성분을 0.03중량%이상의 농도로 함유함을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.The silver peroxide battery according to claim 1, wherein the silver peroxide contains a cadmium component at a concentration of at least 0.03% by weight. 알칼리 전해액에 카드뮴 성분을 0.03g/ℓ이상의 농도로 함유함을 특징으로 하는 특허청구범위 제1항에 다르는 과산화은 전지.A silver peroxide battery according to claim 1, wherein the alkaline electrolyte contains a cadmium component at a concentration of at least 0.03 g / l. 카드뮴 성분이 과산화은에 0.01중량%이상의 농도로 함유되고, 알칼리 전해액에 0.02g/ℓ이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지The silver peroxide battery according to claim 1, wherein the cadmium component is contained in a concentration of 0.01% by weight or more in silver peroxide and in a concentration of 0.02 g / l or more in an alkaline electrolyte. 텔루륨성분이 과산화은에 0.01중량%이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.The silver peroxide battery according to claim 1, wherein the tellurium component is contained in a concentration of 0.01% by weight or more in silver peroxide. 텔루륨 성분이 알칼리 전해액에 0.02g/ℓ이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.The silver peroxide battery according to claim 1, wherein the tellurium component is contained in an alkali electrolyte at a concentration of at least 0.02 g / l. 텔루륨 성분이 과산화은에 0.01중량%이상의 농도로 함유되고 알칼이 전해액에 0.02g/ℓ이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.The silver peroxide battery according to claim 1, wherein the tellurium component is contained in the silver peroxide at a concentration of 0.01% by weight or more and the alkali is contained in the electrolyte at a concentration of at least 0.02 g / l. 카드뮴 성분을 알칼리 전해액에 형수 상태로 첨가시킴을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.The silver peroxide battery according to claim 1, wherein the cadmium component is added to the alkaline electrolyte in the form of water. 과산화은에 카드뮴 성분과 텔루륨 성분의 병합이 수산화알칼리, 질산은 과산화제의 작용에 의한 과산화은 슬러리의 생산과 상기의 성분을 이슬러리에 첨가시키고, 혼합시킴으로서 성취됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.Claim 1, characterized in that the merging of cadmium and tellurium components into silver peroxide is achieved by the production of a silver peroxide slurry by the action of alkali hydroxide and silver nitrate peroxides, and by adding and mixing the above components to the dew slurry. Silver peroxide battery. 과산화은에 카드뮴성분과 텔루륨 성분의 병합이 수산화알칼리, 질산은과 산화제를 작용시켜 과산화은을 만들고, 건조시킨후, 분산매체에 재분산시키고, 상기의 성분을 이 분산액에 첨가시킴으로써 성취됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.The patent is characterized in that the incorporation of cadmium and tellurium components into silver peroxide is effected by the action of alkali hydroxide, silver nitrate and oxidizing agents to produce silver peroxide, drying, redispersing in a dispersion medium and adding the above components to the dispersion Silver peroxide battery according to claim 1. 과산화은에 카드뮴성분과 텔루륨성분의 병합이 수산화알칼리, 질산은과 산화제를 작용시켜 과산화은을 만들고, 이를 건조시키고 다음에 상기의 성분을 건조된 과산화은과 기계적으로 혼합시킴에 의해 성취됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.Claims wherein the combination of cadmium and tellurium components with silver peroxide is achieved by the action of alkali hydroxide, silver nitrate and oxidizing agent to produce silver peroxide, and then drying and then mechanically mixing the above components with dried silver peroxide. Silver peroxide battery according to claim 1. 질산은 용액, 알칼리 용액, 산화제와 물을 사용하여 과산화은을 형성하기 위한 작용은 과산화은 형성을 위한 원재료에 병합된 카드뮴 성분과 텔루륨 선분과 같이 수행됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.The silver peroxide battery according to claim 1, wherein the action for forming silver peroxide using silver nitrate solution, alkaline solution, oxidant and water is performed together with cadmium component and tellurium segment incorporated into raw material for silver peroxide formation. . 카드뮴 성분과 텔루륨 성분이 과산화은에 함유될때, 카드뮴대 텔루륨비가 0.2이상의 양으로 함유됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.The silver peroxide battery according to claim 1, wherein when the cadmium component and the tellurium component are contained in the silver peroxide, the cadmium to tellurium ratio is contained in an amount of 0.2 or more. 상기의 비가 0.5이상임을 특징으로 하는 특허청구범위 제13항에 따르는 과산화은 전지.The silver peroxide battery according to claim 13, wherein the ratio is 0.5 or more. 과산화은에 함유된 카드뮴 성분과 텔루륨 성분의 총량이 10중량%이하임을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.The silver peroxide battery according to claim 1, wherein the total amount of cadmium and tellurium components contained in silver peroxide is 10% by weight or less. 카드뮴성분이 적어도 카드뮴산화물, 수산화카드뮴, 분말상 카드뮴금속, 황화카드뮴, 황산카드뮴염, 질산카드뮴, 스테아린산 카드뮴포름산 카드뮴과셀렌화 카드뮴으로 구성되는 그룹으로 부터하나이상 선택됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.Claim 1 wherein the cadmium component is at least one selected from the group consisting of cadmium oxide, cadmium hydroxide, powdered cadmium metal, cadmium sulfide, cadmium sulfate, cadmium nitrate, cadmium formate cadmium formate and cadmium selenide Silver peroxide battery according to claim. 텔루륨 성분이 적어도 이산화 텔루륨, 과산화텔루륨, 분말상텔루륨금속, 텔루르산, 아텔루르산, 텔루르산의 알칼리염과 아켈루르산의 알칼리염으로 구성되는 그룹으로 부터 하나이상 선택됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.At least one tellurium component selected from the group consisting of at least tellurium dioxide, tellurium peroxide, powdered tellurium metal, telluric acid, at telluric acid, alkali salt of telluric acid and alkali salt of acheluric acid Silver peroxide battery according to claim 1. 카드뮴 성분과 텔루륨 성분이 알칼리 전해액에 함유될때, 각 농도가 0.03g/ℓ이상과 0.01g/ℓ함유됨을 특징으로 하는 특허청구범위 제1항에 따르는 과산화은 전지.The silver peroxide battery according to claim 1, wherein each concentration is 0.03 g / l or more and 0.01 g / l when the cadmium component and the tellurium component are contained in the alkaline electrolyte solution. 카드뮴성분이 0.03-10g/ℓ 범위의 농도로 함유되고, 텔루륨은 0.04-5.0g/ℓ 범위의 농도로 함유됨을 특징으로 하는 특허청구 범위 제14항에 따르는 과산화은 전지.The silver peroxide battery according to claim 14, wherein the cadmium component is contained at a concentration in the range of 0.03-10 g / l, and tellurium is contained at a concentration in the range of 0.04-5.0 g / l. 카드뮴 성분이 알칼리 전해액에 첨가될때 60매쉬이하의 입자크기를 가짐을 특징으로 하는 특허청구범위 제8항에 다르는 과산화은 전지.The silver peroxide battery according to claim 8, wherein the cadmium component has a particle size of 60 mesh or less when added to the alkaline electrolyte. 알칼리 전해액을 함유하고 주로 과산화은으로 형성되는 양극을 가지는 과산화은 전지에서, 과산화은과 알칼리 전해액중 적어도 하나가 카드뮴 성분과 텔루륨성분과 탈륨, 수은, 납, 게르마늄, 이트륨, 주석, 텅스텐, 란타늄, 회토류원소, 아연, 알루미늄, 셀레늄으로 구성되는 그룹으로 부터 선택되는 적어도 하나의 보조성분을 함유함을 특징으로하는 과산화은 전지.In a silver peroxide battery containing an alkaline electrolyte and having a positive electrode formed mainly of silver peroxide, at least one of the silver peroxide and the alkaline electrolyte contains cadmium, tellurium, thallium, mercury, lead, germanium, yttrium, tin, tungsten, lanthanum, and rare earths. A silver peroxide battery, characterized in that it contains at least one auxiliary component selected from the group consisting of elemental, zinc, aluminum, selenium. 카드뮴성분이 과산화은에 0.03중량%이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.The silver peroxide battery according to claim 21, wherein the cadmium component is contained in a concentration of at least 0.03% by weight of silver peroxide. 카드뮴 성분이 알칼리전해액에 0.01g/ℓ이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.A silver peroxide battery according to claim 21, wherein the cadmium component is contained in an alkali electrolyte solution at a concentration of 0.01 g / l or more. 카드뮴 성분이 과산화은에 0.03중량%이상의 농도로 알칼리전해액에 0.01g/ℓ이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.The silver peroxide battery according to claim 21, wherein the cadmium component is contained in a concentration of 0.01 g / l or more in the alkaline electrolyte at a concentration of 0.03% by weight or more in silver peroxide. 텔루륨 성분이 과산화은에 0.01중량%이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.The silver peroxide battery according to claim 21, wherein the tellurium component is contained in a concentration of 0.01% by weight or more in silver peroxide. 텔루륨 성분이 알칼리 전해액에 0.01g/ℓ이상의 농도로 함유됨을 특징으로 하는 특허청구 범위 제21항에 따르는 과산화은 전지.The silver peroxide battery according to claim 21, wherein the tellurium component is contained in an alkali electrolyte solution at a concentration of 0.01 g / l or more. 텔루륨성분이 과산화은에 0.01중량%이상의 농도로 알칼리 전해액에 0.01g/ℓ이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.The silver peroxide battery according to claim 21, wherein the tellurium component is contained in a concentration of 0.01 g / l or more in an alkaline electrolyte at a concentration of 0.01% by weight or more in silver peroxide. 적어도 하나의 보조성분이 과산화은에 0.01중량%이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.The silver peroxide battery according to claim 21, wherein at least one auxiliary component is contained in a concentration of 0.01% by weight or more in silver peroxide. 적어도 하나의 보조성분의 알칼리 전해액에 0.01g/ℓ이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제21항에 다르는 과산화은 전지.The silver peroxide battery according to claim 21, wherein the alkali electrolyte of at least one auxiliary component is contained at a concentration of 0.01 g / l or more. 적어도하나의 보조성분이 과산화은에 0.01중량%이상의 농도로 알칼리 전해액에 0.01g/ℓ이상의 농도로 함유됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.The silver peroxide battery according to claim 21, wherein the at least one auxiliary component is contained in a concentration of 0.01 g / l or more in the alkaline electrolyte at a concentration of 0.01% by weight or more in silver peroxide. 과산화은에 함유된 카드뮴성분, 텔루륨성분과 적어도 하나의 보조성분의 총량이 10중량%이하임을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.The silver peroxide battery according to claim 21, wherein the total amount of cadmium component, tellurium component and at least one auxiliary component contained in silver peroxide is 10% by weight or less. 카드뮴성분과 탈륨, 수은, 주석, 이트륨으로부터 선택된 원소를 함유하는 적어도 하나의 보조성분이 알칼리 전해액에 현수상태로 첨가됨을 특징으로 하는 특허청범위 제21항에 다르는 과산화은 전지.A silver peroxide battery according to Claim 21, wherein at least one auxiliary component containing a cadmium component and an element selected from thallium, mercury, tin and yttrium is added to the alkaline electrolyte in a suspended state. 과산화은에 카드뮴 성분, 텔루륨성분과 적어도 하나의 보조성분의 병합이 수산화 알칼리, 질산은과 산화제의 작용에 의해 솨산화은 슬러리를 만들고, 이 슬러리에 상기의 성분을 첨가시키고, 함께 혼합시켜 성취됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.Incorporation of cadmium, tellurium and at least one auxiliary component into silver peroxide is achieved by the action of alkali hydroxide, silver nitrate and oxidant to form a silver oxide slurry, adding the above components to the slurry and mixing them together. Silver peroxide battery according to claim 21 to claim. 과산화은에 카드뮴성분, 텔루륨성분과 적어도 하나의 보조성분의 벙합이 수산화 알칼리, 질산은과산화제의 작용에 의해 과산화은을 만들고, 이를 건조시키고, 분산매체에 건조된 과산화은을 재분산시킨후, 상기 성분을 이 분산액에 첨가시킴에 의해 성취됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.The combination of cadmium, tellurium and at least one auxiliary component with silver peroxide produces silver peroxide by the action of alkali hydroxide and silver nitrate peroxide, it is dried and redispersed dried silver peroxide in the dispersion medium. A silver peroxide battery according to claim 21, which is achieved by adding to this dispersion. 과산화은에 카드뮴성분,텔루륨성분과 적어도 하나의 보조성분의 병합이 수산화알칼리, 질산은과산화제의 작용에 의해 과산화은을 만들고, 이를 건조시키고, 상기 성분을 건조된 과산화은과 기계적으로 혼합시켜 성취됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.Incorporation of cadmium, tellurium and at least one auxiliary component into silver peroxide is accomplished by the action of alkali hydroxide and silver nitrate peroxidants to form silver peroxide, to dry it, and to mechanically mix the component with dried silver peroxide. Silver peroxide battery according to claim 21 to claim. 질산은 용액, 알칼리 수용액, 산화제와 물을 사용하여 과산화은을 형성시키기 위한 반응이 과산화은 형성을 위한 원재료에 병합되는 카드뮴 성분, 텔루륨성분과 적어도 하나의 보조성분과 같이 수행됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.Claims characterized in that the reaction for forming silver peroxide using a silver nitrate solution, an aqueous alkali solution, an oxidizing agent and water is carried out together with a cadmium component, tellurium component and at least one auxiliary component which is incorporated into the raw material for silver peroxide formation. A silver peroxide battery according to claim 21. 카드뮴성분이 산화카드뮴, 수산화카드뮴, 분말상 카드뮴금속, 황화카드뮴, 황산카드뮴염, 질산카드뮴, 스테아린산 카드뮴, 포름산카드뮴과 셀렌산 카드카드뮴으로 구성되는 그룹으로 부터 선택되는 적어도 하나의 성분으로 됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.The cadmium component is at least one component selected from the group consisting of cadmium oxide, cadmium hydroxide, powdered cadmium metal, cadmium sulfide, cadmium sulfate, cadmium nitrate, cadmium stearate, cadmium formate and cadmium selenite Silver peroxide battery according to claim 21. 텔루륨성분이 이산화 텔루륨, 과산화 텔루륨, 분말상 텔루륨금속, 텔루르산, 이텔루르산, 텔루르산의 알칼리염과 아텔루르산의 알칼리염으로 구성되는 그룹으로 부터선택되는 적어도 하나의 성분으로 됨을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.The tellurium component comprises at least one component selected from the group consisting of tellurium dioxide, tellurium peroxide, powdered tellurium metal, telluric acid, ituric acid, alkali salt of telluric acid and alkali salt of at telluric acid. Silver peroxide battery according to claim 21 characterized in that. 카드뮴성분과 적어도 하나의 보조성분이 알칼리 전해액에 청가될때 입자크기가 60메쉬 이하임을 특징으로 하는 특허청구범위 제21항에 따르는 과산화은 전지.The silver peroxide battery according to claim 21, wherein the cadmium component and at least one auxiliary component have a particle size of 60 mesh or less when clarified in an alkaline electrolyte. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019810002276A 1980-06-23 1981-06-23 Divalent silrer oride cell Expired KR840002391B1 (en)

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JP83974 1980-06-23
JP55083974A JPS5846453B2 (en) 1980-06-23 1980-06-23 Method for producing silver peroxide

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JPS57124853A (en) * 1981-01-26 1982-08-03 Seiko Instr & Electronics Ltd Silver peroxide battery
JPS57124852A (en) * 1981-01-26 1982-08-03 Seiko Instr & Electronics Ltd Silver peroxide battery
JPS57136771A (en) * 1981-01-26 1982-08-23 Seiko Instr & Electronics Ltd Silver peroxide cell
JPS57136770A (en) * 1981-01-26 1982-08-23 Seiko Instr & Electronics Ltd Silver peroxide cell
JPS5894761A (en) * 1981-12-01 1983-06-06 Seiko Instr & Electronics Ltd Silver peroxide cell
JPS59184459A (en) * 1983-04-01 1984-10-19 Sumitomo Metal Mining Co Ltd silver peroxide battery
JP7611850B2 (en) 2019-11-28 2025-01-10 マクセル株式会社 Positive electrode for alkaline battery, alkaline battery and method for producing same
CN115849431B (en) * 2022-10-11 2023-07-18 贵州梅岭电源有限公司 Zinc-silver battery and its high specific capacity AgO cathode material

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Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 19921225

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000