KR900007887A - 변성폴리올레핀 입자 및 그의 제조 방법 - Google Patents

변성폴리올레핀 입자 및 그의 제조 방법 Download PDF

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KR900007887A
KR900007887A KR1019890016881A KR890016881A KR900007887A KR 900007887 A KR900007887 A KR 900007887A KR 1019890016881 A KR1019890016881 A KR 1019890016881A KR 890016881 A KR890016881 A KR 890016881A KR 900007887 A KR900007887 A KR 900007887A
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acrylate
ethylenically unsaturated
meth
polyolefin particles
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KR920005384B1 (ko
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도시유끼 히로세
하지메 이나가끼
마모루 기오까
아끼노리 도요다
노리오 가시와
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다께바야시 쇼오고
미쓰이세끼유 가가꾸 고오교오 가부시끼가이샤
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Priority claimed from JP63294065A external-priority patent/JPH02140203A/ja
Priority claimed from JP63294061A external-priority patent/JP2768475B2/ja
Priority claimed from JP63294063A external-priority patent/JP2769706B2/ja
Priority claimed from JP63294062A external-priority patent/JP2769705B2/ja
Priority claimed from JP63294064A external-priority patent/JPH02140202A/ja
Application filed by 다께바야시 쇼오고, 미쓰이세끼유 가가꾸 고오교오 가부시끼가이샤 filed Critical 다께바야시 쇼오고
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

내용 없음.

Description

변성 폴리올레핀입자 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. (A) 폴레올레핀 입자 100중량부와, (B) 카르복시기함유 에틸렌성 불포화 화합물 또는 그 카르복시산 무수물, 또는 그 카르복시산 유도체, 수산기 함유 에틸렌성 불포화 화합물 , 아미노기 함유 에틸렌성 불포화 화합물 및 글리시딜기 함유 에틸렌성 불포화화합물들로 이루어지는 그룹에서 선택한 적어도 하나의 에틸렌성 불포화 화합물 0.01~50중량부를, (c) 20℃에서 물에 대한 용해도가 0.5중량% 이하이고, 상기 폴리올레핀을 팽윤시킬 수 있는 상온에서 액상인 매체 10중량부~50중량부와, (D) 라디칼 개시제 0.01~10중량부의 존재하에서 접촉시켜, 반응시키는 것을 특징으로 하는 변성폴리올레핀 입자의 제조방법.
  2. 제1항에서, 상기 폴리올레핀 입자의 평균입경이 10~5,000μ의 범위내인 것이 특징인 변성 폴리올레핀 입자의 제조방법.
  3. 제1항에서, 상기 폴리올레핀 입자가 탄소수가 2~20인 α-올레핀의 단독중합체 또는 공중합체로 된 것이 특징인 변성 폴리올레핀 입자의 제조방법.
  4. 제1항에서, 상기 에틸렌성 불포화 화합물이 아크릴산, 메타크릴산, 말레인산, 푸마르산 테트라히드로프탈산, 이타콘산, 시트라콘산, 크로톤산 및 엔도시스-비시클로[2,2,1]헵트-5-엔-2,8-디카르복시산과, 이들 카르복시산의 무수물, 산할라이드, 아미드, 이미드 또는 이들 카르복산의 에스테르로 이루어지는 그룹에서 선택된 카르복시기 함유 에틸렌성 불포화 화합물 또는 그 카르복시산 무수물 또는 그 카르복시산 유도체인 것이 특징인 변성 폴리올레핀 입자의 제조방법.
  5. 제1항에서 상기 에틸렌성 불포화 화합물이, 히드록시에틸(메타)아크릴레이트, 2-히드록시-프로필(메타)아크릴레이트, 3-히드록시프로필(메타)아크릴레이트, 2-히드록시-3-페녹시프로필(메타)아크릴레이트, 3-클로로-2-히드록시프로필(메타)아크릴레이트, 트리메틸올프로판 모노(메타)아크릴레이트, 펜타에리트리톨로모(메타)아크릴레이트, 글리세린 모노(메타) 아크릴레이트, 펜타에리트리톨 모노(메타)아크릴레이트 , 부탄디올 모노(메타)아크릴레이트, 폴리에틸렌 글리콜 모노(메타)아크릴레이트, 2-(6-히드록시헥사노일옥시)에틸 아크릴레이트, 10-운데센-1-올, 1-옥텐-3-올, 2-메탄올-노르보넨, 히드록시스티렌, 히드록시에텔 비닐에테르, 히드록시부틸 비닐에테르, N-메틸올아크릴아미드, 2-(메타)아크릴로일옥시에틸 애시드 포스페인트, 글리세린 모노알린 에테르, 알릴알콜 알릴옥시에탄올, 2-부텐-1, 4-디올 및 글리세린 모노알콜로 이루어지는 그룹에서 선택한 수산기 함유 에틸렌성 불포화 화합물인 것이 특징인 변성 폴리올레핀 입자의 제조방법.
  6. 제1항에 있어서, 상기 에틸렌성 불포화 화합물이 에틸렌성 이중결합과 식(식에서, R1은 수소원자, 메틸기 또는 에틸기이고, R2는 할로겐원자, 탄소수가 1~12인 알킬기, 또는 탄소수가 6~12인 시클로알킬기이다)로 표시되는 적어도 하나의 아미노기를 분자내에 갖는 아미노기 함유 에틸렌성 불포화 화합물인 것이 특징인 변성 폴리올레핀 입자의 제조방법.
  7. 제1항에 있어서, 상기 아미노기함유 에틸렌성 불포화 화합물이, 아크릴산 아미노에틸 아크릴산 프로필아미노에틸, 메타크릴산 디메틸아미노에틸, 아크릴산 아미노프로필, 메타크릴산 페닐아미노에틸, 메타크릴산 시클로헥실아미노에틸, 메타크릴로일옥시에틸 애시드 포스페이트, 모노에탄올 아민 하파솔트, N-비닐디에틸아민, N-아세틸비닐아민, 알릴아민, 메탈릴아민, N-메틸아크릴아민, N,N-디메틸아크릴아민, N,N-디메틸아미노프로필아미드, 아크릴아미드, N-메탈아크릴 아미드, p-아미노스티렌, 6-아미노헥실숙신이미드 및 2-아미노에틸숙신이미드로 이루어지는 그룹에서 선택한 것이 특징인 변성 폴리올레핀 입자의 제조방법.
  8. 제1항에 있어서, 상기 에틸렌성 불포화 화합물이, 알릴 글리시딜 에테르, 2-메틸알릴 글리시딜 에테르 및 비닐 글리시딜 에테르로 이루어지는 그룹에서 선택한 것이 특징인 변성 폴리올레핀 입자의 제조방법.
  9. 제1항에 있어서, 상기 상온에서 액상인 매체가 벤젠, 미네랄 스피리트, 톨루엔, 클로로벤젠, 0-디클로로벤젠, 크실렌, n-헥산, n-헵탄, n-옥탄, 사염화탄소 및 1,3,3-트리클로로알렌으로 이루어지는 그룹에서 선택한 것이 특징인 변성 폴리올레핀 입자의 제조방법.
  10. 제1항에서, 상기 접촉 및 반응이, 상기 폴리올레핀 입자들이 서로 융착되지 않고, 사용된 라디칼 매시제가 분해되는 온도에서 행하는 것이 특징인 변성 폴리올레핀 입자의 제조방법.
  11. 제10항에서, 상기 접촉 및 반응이, 1~150℃ 범위내의 온도에서 행하는 것이 특징인 변성 폴리올레핀입자의 제조방법.
  12. 제1항의 방법에 의해 제조된 변성 폴리올레핀 입자.
  13. (a) 평균입경이 100~5,000μ의 범위내이고 (b) 기하표준편차가 1과 2사이이며, (c) 입경 10μ 이하의 입자의 함량이 20중량% 이하이고, (d) 카르복시기 또는 그 무수물기 또는 그의 유도기, 수산기, 아미노기 및 글리시딜기로 이루어지는 그룹에서 선택한 극성기들에 의해 변성된 것이 특징은 변성 폴리올레핀입자.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890016881A 1988-11-21 1989-11-21 변성 폴리올레핀입자 및 그의 제조방법 Expired KR920005384B1 (ko)

Applications Claiming Priority (15)

Application Number Priority Date Filing Date Title
JP294061 1988-11-21
JP63-294062 1988-11-21
JP294065 1988-11-21
JP63-294064 1988-11-21
JP63294065A JPH02140203A (ja) 1988-11-21 1988-11-21 顆粒状変性ポリオレフィン粒子
JP294063 1988-11-21
JP63294061A JP2768475B2 (ja) 1988-11-21 1988-11-21 変性ポリオレフィン粒子の製造法
JP63-294061 1988-11-21
JP63-294065 1988-11-21
JP63294063A JP2769706B2 (ja) 1988-11-21 1988-11-21 変性ポリオレフィン粒子の製造法
JP63-294063 1988-11-21
JP63294062A JP2769705B2 (ja) 1988-11-21 1988-11-21 変性ポリオレフィン粒子の製造法
JP294064 1988-11-21
JP63294064A JPH02140202A (ja) 1988-11-21 1988-11-21 変性ポリオレフィン粒子
JP294062 1988-11-21

Publications (2)

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KR900007887A true KR900007887A (ko) 1990-06-02
KR920005384B1 KR920005384B1 (ko) 1992-07-02

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US (1) US5523358A (ko)
EP (1) EP0370753B1 (ko)
KR (1) KR920005384B1 (ko)
AT (1) ATE117324T1 (ko)
DE (1) DE68920709T2 (ko)
ES (1) ES2069595T3 (ko)

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US5523358A (en) 1996-06-04
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EP0370753A2 (en) 1990-05-30
EP0370753B1 (en) 1995-01-18
DE68920709D1 (de) 1995-03-02
KR920005384B1 (ko) 1992-07-02
DE68920709T2 (de) 1995-06-01
EP0370753A3 (en) 1990-08-22
ATE117324T1 (de) 1995-02-15

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