KR900007887A - 변성폴리올레핀 입자 및 그의 제조 방법 - Google Patents
변성폴리올레핀 입자 및 그의 제조 방법 Download PDFInfo
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- KR900007887A KR900007887A KR1019890016881A KR890016881A KR900007887A KR 900007887 A KR900007887 A KR 900007887A KR 1019890016881 A KR1019890016881 A KR 1019890016881A KR 890016881 A KR890016881 A KR 890016881A KR 900007887 A KR900007887 A KR 900007887A
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- Prior art keywords
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- acrylate
- ethylenically unsaturated
- meth
- polyolefin particles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
Claims (13)
- (A) 폴레올레핀 입자 100중량부와, (B) 카르복시기함유 에틸렌성 불포화 화합물 또는 그 카르복시산 무수물, 또는 그 카르복시산 유도체, 수산기 함유 에틸렌성 불포화 화합물 , 아미노기 함유 에틸렌성 불포화 화합물 및 글리시딜기 함유 에틸렌성 불포화화합물들로 이루어지는 그룹에서 선택한 적어도 하나의 에틸렌성 불포화 화합물 0.01~50중량부를, (c) 20℃에서 물에 대한 용해도가 0.5중량% 이하이고, 상기 폴리올레핀을 팽윤시킬 수 있는 상온에서 액상인 매체 10중량부~50중량부와, (D) 라디칼 개시제 0.01~10중량부의 존재하에서 접촉시켜, 반응시키는 것을 특징으로 하는 변성폴리올레핀 입자의 제조방법.
- 제1항에서, 상기 폴리올레핀 입자의 평균입경이 10~5,000μ의 범위내인 것이 특징인 변성 폴리올레핀 입자의 제조방법.
- 제1항에서, 상기 폴리올레핀 입자가 탄소수가 2~20인 α-올레핀의 단독중합체 또는 공중합체로 된 것이 특징인 변성 폴리올레핀 입자의 제조방법.
- 제1항에서, 상기 에틸렌성 불포화 화합물이 아크릴산, 메타크릴산, 말레인산, 푸마르산 테트라히드로프탈산, 이타콘산, 시트라콘산, 크로톤산 및 엔도시스-비시클로[2,2,1]헵트-5-엔-2,8-디카르복시산과, 이들 카르복시산의 무수물, 산할라이드, 아미드, 이미드 또는 이들 카르복산의 에스테르로 이루어지는 그룹에서 선택된 카르복시기 함유 에틸렌성 불포화 화합물 또는 그 카르복시산 무수물 또는 그 카르복시산 유도체인 것이 특징인 변성 폴리올레핀 입자의 제조방법.
- 제1항에서 상기 에틸렌성 불포화 화합물이, 히드록시에틸(메타)아크릴레이트, 2-히드록시-프로필(메타)아크릴레이트, 3-히드록시프로필(메타)아크릴레이트, 2-히드록시-3-페녹시프로필(메타)아크릴레이트, 3-클로로-2-히드록시프로필(메타)아크릴레이트, 트리메틸올프로판 모노(메타)아크릴레이트, 펜타에리트리톨로모(메타)아크릴레이트, 글리세린 모노(메타) 아크릴레이트, 펜타에리트리톨 모노(메타)아크릴레이트 , 부탄디올 모노(메타)아크릴레이트, 폴리에틸렌 글리콜 모노(메타)아크릴레이트, 2-(6-히드록시헥사노일옥시)에틸 아크릴레이트, 10-운데센-1-올, 1-옥텐-3-올, 2-메탄올-노르보넨, 히드록시스티렌, 히드록시에텔 비닐에테르, 히드록시부틸 비닐에테르, N-메틸올아크릴아미드, 2-(메타)아크릴로일옥시에틸 애시드 포스페인트, 글리세린 모노알린 에테르, 알릴알콜 알릴옥시에탄올, 2-부텐-1, 4-디올 및 글리세린 모노알콜로 이루어지는 그룹에서 선택한 수산기 함유 에틸렌성 불포화 화합물인 것이 특징인 변성 폴리올레핀 입자의 제조방법.
- 제1항에 있어서, 상기 에틸렌성 불포화 화합물이 에틸렌성 이중결합과 식(식에서, R1은 수소원자, 메틸기 또는 에틸기이고, R2는 할로겐원자, 탄소수가 1~12인 알킬기, 또는 탄소수가 6~12인 시클로알킬기이다)로 표시되는 적어도 하나의 아미노기를 분자내에 갖는 아미노기 함유 에틸렌성 불포화 화합물인 것이 특징인 변성 폴리올레핀 입자의 제조방법.
- 제1항에 있어서, 상기 아미노기함유 에틸렌성 불포화 화합물이, 아크릴산 아미노에틸 아크릴산 프로필아미노에틸, 메타크릴산 디메틸아미노에틸, 아크릴산 아미노프로필, 메타크릴산 페닐아미노에틸, 메타크릴산 시클로헥실아미노에틸, 메타크릴로일옥시에틸 애시드 포스페이트, 모노에탄올 아민 하파솔트, N-비닐디에틸아민, N-아세틸비닐아민, 알릴아민, 메탈릴아민, N-메틸아크릴아민, N,N-디메틸아크릴아민, N,N-디메틸아미노프로필아미드, 아크릴아미드, N-메탈아크릴 아미드, p-아미노스티렌, 6-아미노헥실숙신이미드 및 2-아미노에틸숙신이미드로 이루어지는 그룹에서 선택한 것이 특징인 변성 폴리올레핀 입자의 제조방법.
- 제1항에 있어서, 상기 에틸렌성 불포화 화합물이, 알릴 글리시딜 에테르, 2-메틸알릴 글리시딜 에테르 및 비닐 글리시딜 에테르로 이루어지는 그룹에서 선택한 것이 특징인 변성 폴리올레핀 입자의 제조방법.
- 제1항에 있어서, 상기 상온에서 액상인 매체가 벤젠, 미네랄 스피리트, 톨루엔, 클로로벤젠, 0-디클로로벤젠, 크실렌, n-헥산, n-헵탄, n-옥탄, 사염화탄소 및 1,3,3-트리클로로알렌으로 이루어지는 그룹에서 선택한 것이 특징인 변성 폴리올레핀 입자의 제조방법.
- 제1항에서, 상기 접촉 및 반응이, 상기 폴리올레핀 입자들이 서로 융착되지 않고, 사용된 라디칼 매시제가 분해되는 온도에서 행하는 것이 특징인 변성 폴리올레핀 입자의 제조방법.
- 제10항에서, 상기 접촉 및 반응이, 1~150℃ 범위내의 온도에서 행하는 것이 특징인 변성 폴리올레핀입자의 제조방법.
- 제1항의 방법에 의해 제조된 변성 폴리올레핀 입자.
- (a) 평균입경이 100~5,000μ의 범위내이고 (b) 기하표준편차가 1과 2사이이며, (c) 입경 10μ 이하의 입자의 함량이 20중량% 이하이고, (d) 카르복시기 또는 그 무수물기 또는 그의 유도기, 수산기, 아미노기 및 글리시딜기로 이루어지는 그룹에서 선택한 극성기들에 의해 변성된 것이 특징은 변성 폴리올레핀입자.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (15)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP294061 | 1988-11-21 | ||
| JP63-294062 | 1988-11-21 | ||
| JP294065 | 1988-11-21 | ||
| JP63-294064 | 1988-11-21 | ||
| JP63294065A JPH02140203A (ja) | 1988-11-21 | 1988-11-21 | 顆粒状変性ポリオレフィン粒子 |
| JP294063 | 1988-11-21 | ||
| JP63294061A JP2768475B2 (ja) | 1988-11-21 | 1988-11-21 | 変性ポリオレフィン粒子の製造法 |
| JP63-294061 | 1988-11-21 | ||
| JP63-294065 | 1988-11-21 | ||
| JP63294063A JP2769706B2 (ja) | 1988-11-21 | 1988-11-21 | 変性ポリオレフィン粒子の製造法 |
| JP63-294063 | 1988-11-21 | ||
| JP63294062A JP2769705B2 (ja) | 1988-11-21 | 1988-11-21 | 変性ポリオレフィン粒子の製造法 |
| JP294064 | 1988-11-21 | ||
| JP63294064A JPH02140202A (ja) | 1988-11-21 | 1988-11-21 | 変性ポリオレフィン粒子 |
| JP294062 | 1988-11-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR900007887A true KR900007887A (ko) | 1990-06-02 |
| KR920005384B1 KR920005384B1 (ko) | 1992-07-02 |
Family
ID=27530837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019890016881A Expired KR920005384B1 (ko) | 1988-11-21 | 1989-11-21 | 변성 폴리올레핀입자 및 그의 제조방법 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5523358A (ko) |
| EP (1) | EP0370753B1 (ko) |
| KR (1) | KR920005384B1 (ko) |
| AT (1) | ATE117324T1 (ko) |
| DE (1) | DE68920709T2 (ko) |
| ES (1) | ES2069595T3 (ko) |
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| US4230830A (en) * | 1979-03-30 | 1980-10-28 | E. I. Du Pont De Nemours And Company | Adhesive blends containing thermally grafted ethylene polymer |
| DE3021105A1 (de) * | 1980-06-04 | 1982-01-21 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von polarmodifiziertem polypropylen und seine verwendung |
| DE3033001A1 (de) * | 1980-09-02 | 1982-04-01 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von anhydrid- oder carboxylgruppen enthaltenden ethylen-pfropfcopolymerisaten |
| US4806581A (en) * | 1983-10-12 | 1989-02-21 | Occidental Chemical Corporation | Graft polymers of polymerizable monomers and olefin polymers |
| US4536545A (en) * | 1983-10-12 | 1985-08-20 | Occidental Chemical Corporation | Graft polymers of polymerizable monomers and olefin polymers |
| US4661549A (en) * | 1983-10-12 | 1987-04-28 | Occidental Chemical Corporation | Graft polymers of polymerizable monomers and olefin polymers |
| US4927888A (en) * | 1986-09-05 | 1990-05-22 | The Dow Chemical Company | Maleic anhydride graft copolymers having low yellowness index and films containing the same |
| IT1184307B (it) * | 1985-01-08 | 1987-10-28 | Dutral Spa | Procedimento per innestare monomeri insaturi su polimeri olefinici |
| US4895909A (en) * | 1987-02-19 | 1990-01-23 | The Dow Chemical Company | Imbiber polymers alkylated after polymerization |
| DE3725059A1 (de) * | 1987-07-29 | 1989-02-09 | Roehm Gmbh | Polymere fliessverbesserer fuer mitteldestillate |
| US5001197A (en) * | 1989-05-10 | 1991-03-19 | Exxon Chemical Patents Inc. | Polypropylene composition and method for functionalization of polypropylene |
| JPH0311986A (ja) * | 1989-06-05 | 1991-01-21 | Sankyo Seiki Mfg Co Ltd | 電磁駆動装置の速度信号検出装置 |
| JP3011986U (ja) | 1994-12-02 | 1995-06-06 | 有限会社西栄鉄工所 | インペラとポンプの構造 |
-
1989
- 1989-11-21 ES ES89312044T patent/ES2069595T3/es not_active Expired - Lifetime
- 1989-11-21 EP EP89312044A patent/EP0370753B1/en not_active Expired - Lifetime
- 1989-11-21 AT AT89312044T patent/ATE117324T1/de not_active IP Right Cessation
- 1989-11-21 DE DE68920709T patent/DE68920709T2/de not_active Expired - Fee Related
- 1989-11-21 KR KR1019890016881A patent/KR920005384B1/ko not_active Expired
-
1994
- 1994-04-22 US US08/235,419 patent/US5523358A/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100423346B1 (ko) * | 2001-08-29 | 2004-03-18 | 주식회사 코오롱 | 광디바이스용 보호막 형성 재료로 유용한 열경화성 수지조성물 |
Also Published As
| Publication number | Publication date |
|---|---|
| US5523358A (en) | 1996-06-04 |
| ES2069595T3 (es) | 1995-05-16 |
| EP0370753A2 (en) | 1990-05-30 |
| EP0370753B1 (en) | 1995-01-18 |
| DE68920709D1 (de) | 1995-03-02 |
| KR920005384B1 (ko) | 1992-07-02 |
| DE68920709T2 (de) | 1995-06-01 |
| EP0370753A3 (en) | 1990-08-22 |
| ATE117324T1 (de) | 1995-02-15 |
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