KR940010800B1 - Suede fabric making method - Google Patents
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- KR940010800B1 KR940010800B1 KR1019920023401A KR920023401A KR940010800B1 KR 940010800 B1 KR940010800 B1 KR 940010800B1 KR 1019920023401 A KR1019920023401 A KR 1019920023401A KR 920023401 A KR920023401 A KR 920023401A KR 940010800 B1 KR940010800 B1 KR 940010800B1
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- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D23/00—General weaving methods not special to the production of any particular woven fabric or the use of any particular loom; Weaves not provided for in any other single group
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Description
본 발명은 촉감이 유연하고 표면효과가 우수한 스웨드조(SUEDE調) 직물의 제조방법에 관한 것으로, 보다 상세하게는 0.1데니어 이하로 극세화가 가능한 해도형 복합방사섬유와 고수축성 폴리에스터를 혼섬한 이수축 혼섬사를 이용하여 주자직으로 제직한 직물을 호발 및 수축처리를 한후 침포기모기로 기모하고 해성분을 용해제거하여 복합방사섬유를 극세화한 후 염색가공하여 드레이프성(Drapability)이 우수하고 천연 스웨드와 유사한 라이팅 이펙트(Writing effect)가 발현되도록 한 스웨드조 직물의 제조방법에 관한 것이다.The present invention relates to a method of manufacturing a suede fabric (SUEDE®) fabric, which is soft to the touch and excellent in surface effect, and more specifically, to a blend of island-in-the-sea composite spun fiber and a high-shrinkable polyester that can be micronized to 0.1 denier or less. After weaving and shrinking the fabric woven into the main fabric by using shrink horn fiber, brush it with a cotton cloth mosquito, and dissolving and removing sea component to make a fine composite fiber, and then dyeing and processing to have excellent drability and natural The present invention relates to a method of manufacturing a suede-like fabric in which a writing effect similar to suede is expressed.
종래의 스웨드조 직물은 극세섬유를 사용하지 않고 단사섬도 1∼3데니어의 정규합성섬유를 사용하여 제직한 후 기모, 염색가공하여 제조하였으나 이러한 스웨드조 직물은 촉감이 부드럽지 못하고 표면의 라이팅 이펙트가 부족하여 고급스웨드조 원단으로는 부적합하였다.Conventional suede-like fabrics are manufactured by weaving and dyeing after weaving using regular synthetic fibers of 1 ~ 3 denier with single yarn fineness. It was not suitable for high quality suede fabric.
이러한 문제점을 보완하기 위해 일본특개소 51-70366호, 53-2667호, 64-518호에서는 분할형 극세사를 위사로 사용하여 제직한 주자직물(朱子織物)을 기모, 염색하여 스웨드조 직물을 얻었으나 이러한 방법에 의해 얻어진 스웨드조 직물은 유연성과 라이팅 이펙트는 비교적 양호한 반면, 위사로서 극세사 단독으로 사용하였기 때문에 반발감 및 드레이프성이 부족하여 의류로 봉제되었을때 전체적인 외관이 고급스럽지 못하고 태가 잘 나지 않는 단점이 있었다.In order to compensate for this problem, Japanese Patent Laid-Open Nos. 51-70366, 53-2667, and 64-518 used a split microfiber yarn as a weft to raise and suede fabrics by brushing and dyeing runner fabrics. However, the suede-like fabric obtained by this method has a relatively good flexibility and lighting effect, but the microfiber yarn is used as the weft yarn alone, so the overall appearance is not luxurious and the appearance is not good when sewn into clothing due to lack of repulsion and drape. There was this.
또한, 일본특개소 51-60769호에서는 분할형 극세사를 사용하여 트리코트(Tricot) 편물을 제조한 후, 기모 및 용제(Benzyl alcohol) 처리를 하여 분할사를 극세화시켜 스웨드조 편물을 제조하였으나 이러한 방법에 의해 얻어진 스웨드조 편물은 표면촉감은 부드러운 반면 드레이프성과 라이팅 이펙트가 부족하고, 제조공정상 용제를 다량 사용하게 되어 취급이 곤란할 뿐더러 폐수 등에 의한 환경공해 문제가 심각히 대두되고, 수세가 불충분할 경우 잔류용제에 의해 염색트러블(Trouble), 텐터링(Tentering)시 결정화에 의한 촉감저하, 악취 등이 발생하는 단점이 있었다.In addition, Japanese Patent Application Laid-Open No. 51-60769 manufactured a tricot knitted fabric using a split microfiber, and then made a suede-like knitted fabric by making the split yarn micronized by raising and benzyl alcohol treatment. The suede knitted fabric obtained by the method has a soft surface feel but lacks drape and lighting effects, and it is difficult to handle due to the large amount of solvents used in the manufacturing process, and the environmental pollution problem caused by waste water is seriously raised. There was a disadvantage in that the solvent caused a decrease in touch, odor, etc. due to crystallization at the time of dyeing trouble (Trouble), tentering (Tentering).
따라서, 본 발명의 목적은 표면촉감이 부드럽고 드레이프성과 유연성이 우수하며 라이팅 이펙트가 천연스웨드와 비슷하여 의류로 봉제한 후에도 전체적인 외관이 미려한 스웨드조 직물의 제조방법을 제공함에 있다.Accordingly, an object of the present invention is to provide a method of producing a suede-like fabric having a smooth surface feel, excellent drape and flexibility, and a lighting effect similar to that of natural suede, even after sewing with clothing.
상기 목적 뿐만아니라 용이하게 표출되는 또다른 목적을 달성하기 위하여 본 발명에서는 초극세화가 가능한 해도형(海島型) 복합방사섬유와 고수축성 폴리에스터 섬유를 혼섬하여 이수축혼섬사를 제조하고, 이를 위사로 사용하고 정규 폴리에스터 섬유(75데니어 36필라멘트)를 경사로 사용하여 주자직물을 제직한 후, 호발정련, 수축처리하여 위사중의 고수축성 폴리에스터를 수축시켜 직물표면에 해도형 복합섬유 마이크로루우프(Microloop)를 형성시키고 기모한 후 해성분을 용해제거하여 직물표면에 초극세 섬유입모(立毛)를 형성시켜 염색, 가공하여 드레이프성이 우수하고 천연스웨드와 유사한 라이팅 이펙트가 발현되는 스웨드조 직물을 제조한다.In order to achieve the above object as well as another object that is easily expressed in the present invention, the ultra-shrinkable island-like composite spun fiber and the highly shrinkable polyester fiber are mixed to prepare a biaxially blended mixed yarn, which is used as a weft yarn. After weaving the runner fabric using regular polyester fibers (75 denier 36 filaments) as a warp, deburring and shrinking, shrinking the highly shrinkable polyester in the weft yarn, the island-in-the-sea composite fiber microloop After forming and brushing, the sea component is dissolved and removed to form super fine fiber hair on the fabric surface, which is then dyed and processed to produce a suede-like fabric having excellent drape and a lighting effect similar to that of natural suede.
본 발명을 더욱 상세히 설명하면 다음과 같다.The present invention is described in more detail as follows.
본 발명에 사용된 해도형 복합방사섬유는 극세섬유 성분(島成分)으로서 폴리에틸렌 테레프탈레이트(Polyethylene terephthalate)를, 용해 제거성분(海成分)으로서 공중합 개질폴리에스터를 사용하여 특수방수구금을 통해 복합방사하여 극세화후 섬도가 0.1∼0.005데니어 되도록 한 것이다. 극세성유 성분이 0.1데니어를 초과할 경우에는 최종 가공직물의 표면효과가 충분치 못하고 0.005데니어 미만인 경우에는 표면효과는 양호하나 원사의 생산성이 떨어지고 최종 가공직물의 염색 견뢰도가 저하되는 단점이 있다. 용해제거 성분으로 사용된 공중합 개질폴리에스터는 금속술포네이트기(Sulfonate基)를 함유한 유기산을 공중합 시킨 이용성(易溶性)폴리에스터로서 알카리 용해성을 향상시켜 알카리 감량 공정에서 완전히 용해제거 되도록 한 것이다. 금속술포네이트기를 함유한 유기산으로는 5-소듐술포디(2-히드록시에틸) 이소프탈레이트 등을 사용할 수 있으며, 이의 공중합 비율은 전산성분에 대하여 1∼10몰퍼센트(mol%)가 바람직하다. 1몰% 미만인 경우에는 용해제거성분 이외의 성분, 즉 도성분, 고수축성 폴리에스터, 경사 등과의 알칼리 감량속도차가 작아 공정컨트롤이 어렵고 해성분 이외의 성분까지 감량되어 극세섬유의 발현이 어렵고 최종직물의 강도가 저하되는 단점이 있다. 10몰%을 초과하는 경우에는 방사시 사절이 발생할 우려가 있다.The island-in-the-sea composite spun fiber used in the present invention is a composite spun yarn through special waterproofing tool using polyethylene terephthalate as an ultrafine fiber component and copolymer-modified polyester as a dissolution removing component. To make the fineness 0.1 to 0.005 denier after miniaturization. If the ultrafine oil component exceeds 0.1 denier, the surface effect of the final processed fabric is not sufficient, and if the surface effect is less than 0.005 denier, the surface effect is good, but the productivity of the yarn is lowered and the dyeing fastness of the final processed fabric is lowered. Copolymer-modified polyester used as the dissolution removal component is a water-soluble polyester copolymerized with an organic acid containing a metal sulfonate group to improve alkali solubility so as to be completely dissolved in an alkali weight loss process. As the organic acid containing the metal sulfonate group, 5-sodium sulfodi (2-hydroxyethyl) isophthalate or the like can be used, and the copolymerization ratio thereof is preferably 1 to 10 mol% (mol%) based on the total acid component. If it is less than 1 mol%, it is difficult to control the process due to the small alkali loss rate difference between components other than the dissolution removal component, that is, island component, high shrinkable polyester and warp, and it is difficult to express microfibers due to the reduction of components other than sea component. There is a disadvantage that the strength of is lowered. If it exceeds 10 mol%, trimming may occur during spinning.
본 발명에 사용된 고수축성 폴리에스터 섬유는 비수수축률이 10∼50%인 공중합개질 폴리에틸렌 테레프탈레이트 섬유로서 공중합 개질제로는 산성분으로서 이소프탈산, 글리콜성분으로서, 네오펜틸글리콜, 2-2,비스[4-(2 히드록시에톡시)페닐]프로판 등이 사용 가능하며 혼합 사용하여도 좋다. 공중합 비율은 각각의 전모노머성분에 대하여 0.5∼10몰%가 바람직하다. 0.5몰%를 초과할 경우에는 원사의 수축효과가 충분치 못하고 10몰%를 초과할 경우에는 방사시 트러블 발생이 우려되며 원사물성저하가 심해 바람직하지 못하다.The highly shrinkable polyester fiber used in the present invention is a copolymer-modified polyethylene terephthalate fiber having a non-shrinkage ratio of 10 to 50%. As a copolymerization modifier, isophthalic acid as an acid component and neopentyl glycol, 2-2, bis [ 4- (2 hydroxyethoxy) phenyl] propane and the like can be used and may be mixed. As for copolymerization ratio, 0.5-10 mol% is preferable with respect to each total monomer component. If it exceeds 0.5 mol%, the shrinkage effect of the yarn is not sufficient, and if it exceeds 10 mol%, trouble occurs during spinning, and the material property is severely deteriorated, which is not preferable.
고수축 특성을 부여하는 공중합 개질제 성분은 분자주쇄중의 굽은 구조 또는 측쇄의 벌키성을 갖는 구조에 의해 결정화를 억제하는 역할을 하여 습열 또는 건열에 의하여 수축 특성을 발휘하게 된다.The copolymer modifier component that imparts high shrinkage properties serves to suppress crystallization by the curved structure in the molecular backbone or the structure having the bulkyness of the side chain, thereby exhibiting shrinkage characteristics by wet or dry heat.
상기의 고수축성 폴리에스터 섬유와 해도형 복합방사섬유를 1.0~4.0kg/cm2의 고압공기로 혼섬하여 섬유교락수가 20∼200개/m 되는 이수축 혼섬사로 제조하는데, 섬유 교락수가 20개/m 미만일 경우에는 혼섬효과가 불량하여 제직공정에서 작업효율이 저하될 뿐아니라 두섬유가 다시 분리되어 염가공시 균일한 품질을 기대하기 어렵고,200개/m를 초과하는 경우에는 모노필라멘트의 사절이 다수 발생하게 되어 혼섬 작업효율이 저하되고 고수축성 섬유의 수축특성발현이 어렵다.The highly shrinkable polyester fiber and the island-in-the-sea composite spun fiber are mixed with high pressure air of 1.0 to 4.0 kg / cm 2 to produce biaxially blended mixed fiber having 20 to 200 fibers / m, with 20 fibers / If it is less than m, the blending effect is poor, which reduces work efficiency in the weaving process, and it is difficult to expect uniform quality when the two fibers are separated again, and when it exceeds 200 pieces / m, a large number of trimming of the monofilament This results in a decrease in intermixing work efficiency and difficulty in expressing shrinkage characteristics of highly shrinkable fibers.
상기의 이수축 혼성사를 위사로 하고 정규 폴리에스터 섬유(75데니어 36필라멘트)를 경사로 하여 통상의 직기에서 제직하여 주자조직의 직물을 얻는다. 다음으로 호발정련조에서 충분히 호발한 후 수축조에서 90∼100℃의 열수로 5∼30분간 처리하여 섬유를 충분히 수축시킨다. 이렇게 수축처리된 직물을 섬유간 수축특성의 차이로 고수축성 폴리에스터 섬유는 가라앉고 상대적으로 저수축성분인 해도형 복합방사섬유는 표면으로 떠올라 마이크로루우프를 형성한다. 마이크로루우프가 형성된 직물표면을 침포기모기를 이용하여 기모하되 직물내부의 고수축성 폴리에스터 섬유는 기모되지 않도록 통상의 마일드한 조건으로 실시하여 균일한 해도형 복합방사섬유 입모를 형성시키도록 한다.Weaving is carried out in a normal loom with the above-mentioned biaxially blended hybrid yarn as a weft and regular polyester fiber (75 denier 36 filaments) inclined to obtain a woven fabric of runner tissue. Subsequently, after sufficiently calling in the firing tank, the shrinkage of the fiber is sufficiently carried out by treatment with hot water at 90 to 100 ° C. for 5 to 30 minutes in the shrinking tank. In the shrinkage-treated fabric, the high shrinkage polyester fiber sinks due to the difference in shrinkage properties between fibers, and the island-in-the-sea composite spun fiber, which is a relatively low shrinkage component, floats to the surface to form a microloop. The surface of the fabric formed with microloops is brushed using a cloth-immobilized mosquito, but the highly shrinkable polyester fibers inside the fabric are subjected to normal mild conditions so as to form a uniform island-in-the-sea composite fiber composite.
다음으로 수산화나트륨 수용액에 침지, 비등 처리하여 해도형 복합방사섬유중의 해성분을 용해제거시켜 극세섬유화하고 통상의 방법으로 분산염료로 염색하고, 용도에 따라 발수, 유연, 대전방지 등의 수지가공을 실시한다. 이렇게 제조된 스웨드조 직물은 표면에 형성된 극세사 입모에 의한 극히 부드러운 표면촉감과 고수축심사(芯系)에 의한 반발감으로 드레이프성이 뛰어나며 고밀도 수축이 되었기 때문에 직물조직선이 보이지 않고 인열강도 저하가 적은 장점이 있다. 특히, 라이팅 이펙트의 발현이 우수하여 천연스웨드와 유사한 외관을 나타낸다. 라이팅 이펙트는 모우의 눕는 방향에 따라 빛의 반사가 달라져 나타나는 색차에 의한 효과로서, 섬도가 가늘수록 그의 발현이 현저하며 모우를 지지하는 기재(基材)의 색상도 영향을 미친다.Subsequently, it is immersed and boiled in aqueous sodium hydroxide solution to dissolve and remove the sea component in the island-in-the-sea composite spun fiber, to make microfiber, and to dye it with a disperse dye in the usual way. Is carried out. The suede-like fabric produced in this way has excellent drape and extremely high density shrinkage due to extremely soft surface feel due to microfiber hairs formed on the surface, and repulsion feeling due to high shrinkage examination. There is little advantage. In particular, the expression of the lighting effect is excellent, showing a similar appearance to natural suede. The lighting effect is a color difference effect in which the reflection of light varies depending on the lying direction of the cow, and the finer the fineness, the more pronounced the appearance of the base and the color of the base supporting the cow.
본 발명의 스웨드조 직물은 이섬도(異纖度), 이수축성 원사를 사용하였기 때문에 염색시 겉보기 농도가 달라지게 되어 라이팅 이펙트의 상승효과를 기대할 수 있다. 즉, 동일염색 농도하에서 섬도가 가늘수록, 폴리머의 구조가 치밀할수록 겉보기 농도는 저하되므로, 본 발명에서 표면의 입모를 형성하고 있는 극세섬유는 겉보기 농도가 낮아 흐리게 보이고 기재를 이루고 있는 고수축성 폴리에스터 섬유는 구조의 느슨함으로 인해 염착율이 크고 태(太) 섬도이므로 결국 겉보기 농도가 증가하게 되어 상대적으로 진하게 보인다. 따라서 모우가 순방향으로 누운상태에서는 극세섬유에 의한 빛의 반사로 흐리게 보이나, 모우가 기립(起立)하게되면 빛의 흡수효과와 기재의 진한 색상이 나타나 결국 우수한 라이팅 이펙트를 발현하게 된다.Since the suede-like fabric of the present invention uses two fine and bishrinkable yarns, the apparent density is changed during dyeing, and a synergistic effect of the lighting effect can be expected. That is, under the same dyeing concentration, the thinner the fineness and the denser the polymer structure, the lower the apparent concentration. Therefore, in the present invention, the microfibers forming the surface of the hairs have a low apparent density and appear to be blurred and form a highly shrinkable polyester. Because of the looseness of the structure, the fiber has a high dyeing rate and Tae fineness, so that the apparent concentration increases and it appears relatively dark. Therefore, in the state in which the cow is laid down in the forward direction, it is blurred by the reflection of light by the ultrafine fibers, but when the cow stands up, the light absorbing effect and the dark color of the substrate appear, resulting in an excellent lighting effect.
다음의 실시예 및 비교예는 본 발명을 보다 상세히 설명하는 것이지만 본 발명의 범주를 한정하지는 않는다.The following examples and comparative examples further illustrate the invention but do not limit the scope of the invention.
[실시예 1]Example 1
폴리에틸렌 테레프탈레이트를 도성분으로 하고 5-소듐술포 디(2-히드록시에틸)이소프탈레이트[5-sodiumsulfodi (2-hydroxy ethyl) isophthalate]를 테레프탈산에 대해 7몰% 공중합시킨 공중합 폴리에틸렌 테레프탈레이트를 해성분으로 하여 도수(島數) 37개, 용적비 7 : 3, 방사온도 275℃로 해도형 구금을 통해 용융방사하고 1,000m/min의 속도로 권취하여 미연신사를 제조하고 130℃에서 3.5배 연신한 후 150℃의 열판으로 열고정하여 100데니어 30필라멘트의 해도형 복합섬유를 얻었다.Polyethylene terephthalate as an island component and 5-sodium sulfo di (2-hydroxyethyl) isophthalate 7-% by copolymerization of 5-sodiumsulfodi (2-hydroxy ethyl) isophthalate with terephthalic acid After melt-spun through 37 islands, volume ratio 7: 3, spinning temperature 275 ℃ through sea island-type detention, and wound up at a speed of 1,000m / min, undrawn yarn was drawn and stretched 3.5 times at 130 ℃. Heat-fixing was carried out with a hot plate at 150 ° C. to obtain an island-in-the-sea composite fiber having 100 denier 30 filaments.
고수축성 폴리에스터 섬유로는 테레프탈산과 에틸렌글리콜을 주성분으로 하고 공중합 개질제로서 이소프탈산을 전산성분에 대하여 5몰%, 2-2'비스[4-(2 히드록시에톡시)페닐]프로판을 전글리콜성분에 대하여 5몰% 공중합한 고유점도 0.65의 공중합 폴리에스터 칩(Chip)을 275℃에서 방사하고 1,600m/min의 속도로 권취한 후 3배 연신하고 120℃에서 열처리하여 30데니어 12필라멘트의 원사를 얻었다. 해도형 복합섬유와 고수축성 폴리에스터 섬유를 2kg/cm2의 고압 공기로 섬유 교락수 100개/m 되도록 혼섬하여 이수축 혼성사를 얻었다.As the highly shrinkable polyester fiber, terephthalic acid and ethylene glycol are the main components, and isophthalic acid is the copolymerization modifier, 5 mol% of the total acid component, and 2-2'bis [4- (2 hydroxyethoxy) phenyl] propane is all glycol 5 mol% copolymerized polyester chip having an intrinsic viscosity of 0.65 was spun at 275 ° C, wound up at 1,600m / min, stretched three times, and heat-treated at 120 ° C for 30 denier 12 filament yarns. Got. The island-in-the-sea composite fiber and the highly shrinkable polyester fiber were mixed with a high pressure air of 2 kg / cm 2 so that the number of fiber interlocking was 100 / m, thereby obtaining a biaxially blended hybrid yarn.
상기 이수축 혼섬사를 위사로 사용하고 75데니어 36필라멘트의 정규 폴리에스터 섬유를 경사로 사용하여 통상의 직기에서 제직하여 5매 주자직물을 얻고 호발정련조에서 호발한 후 95℃의 열수에서 20분간 수축처리를 하고 실린더로 건조한 다음 침포기모기로 직물표면을 10회 기모한 후 수산화나트륨 3% 수용액에 침지하여 10분간 비등처리하여 해성분을 용해제거하고 통상의 방법에 의하여 적색으로 고압염색하고 실리콘계 유연제로 수지가공하여 스웨드조 직물을 얻었다. 직물의 물성을 평가하여 그 결과를 표 1에 나타내었다.Using the biaxially woven fiber as a weft yarn and weaving in a conventional loom using 75 polyester denier filament regular polyester fiber as a warp yarn, we obtain 5 runner fabrics and shrink in a hot water at 95 ℃ for 20 minutes. After treatment, dry with a cylinder, brush the fabric surface 10 times with a cloth with a mosquito, and soak it in a 3% aqueous solution of sodium hydroxide and boil it for 10 minutes to dissolve and remove the sea component. The resin was processed into a suede-like fabric. The physical properties of the fabric were evaluated and the results are shown in Table 1.
[비교예 1]Comparative Example 1
해도형 복합섬유 대선에 75데니어 72필라멘트의 정류 폴리에스터 섬유와 고수축성 폴리에스테르 섬유를 혼섬한 이수축 혼섬사를 사용한 것 이외에는 실시예 1과 동일하게 실시하였고, 직물의 물성을 평가하여 그 결과를 표 1에 나타내었다.The same procedure as in Example 1 was conducted except that a biaxially blended blend of 75 denier 72 filament rectified polyester fibers and a highly shrinkable polyester fiber was used for the island-in-the-sea composite fiber presidential election. Table 1 shows.
[비교예 2]Comparative Example 2
위사로서 100데니어 36필라멘트의 해도형 복합섬유를 사용한 것 이외에는 실시예 1과 동일하게 실시하였고, 그 결과를 표 1에 나타내었다.Except for using the island-in-the-sea composite fiber of 100 denier 36 filaments as the weft yarn was carried out in the same manner as in Example 1, the results are shown in Table 1.
[표 1]TABLE 1
〈평가방법〉<Assessment Methods>
O 중량 : KS K 0514 직물의 무게측정방법(작은시험편법)O Weight: KS K 0514 Weighing method of fabric (small test piece method)
O 드레이프 계수 : JIS L 1096 유연성 시험방법(드레이프계수법)O Drape Coefficient: JIS L 1096 Flexibility Test Method (Drap Coefficient Method)
O 입모상태, 표면촉감, 라이팅 이펙트 : 관능평가O Hair condition, surface feel, lighting effect: sensory evaluation
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| KR1019920023401A KR940010800B1 (en) | 1992-12-05 | 1992-12-05 | Suede fabric making method |
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| KR1019920023401A KR940010800B1 (en) | 1992-12-05 | 1992-12-05 | Suede fabric making method |
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| KR940010800B1 true KR940010800B1 (en) | 1994-11-16 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2214930A1 (en) * | 1999-12-16 | 2004-09-16 | Kolon Industries, Inc. | A warp knit having an excellent touch, and a process of preparing the same |
| KR100608485B1 (en) * | 2004-12-31 | 2006-08-02 | 주식회사 효성 | Highly wipeable fabric |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR100487169B1 (en) * | 1998-09-10 | 2005-07-18 | 주식회사 새 한 | Manufacturing method of matt polyester fabric having the same texture as used fabric |
| KR200448361Y1 (en) * | 2008-01-23 | 2010-04-07 | (주)가야텍스컴 | Printable microfiber woven fabric with excellent fastness |
| KR100853471B1 (en) * | 2008-03-17 | 2008-08-21 | 주식회사 넥스텍 | Suede Fabric for Artificial Leather |
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1992
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2214930A1 (en) * | 1999-12-16 | 2004-09-16 | Kolon Industries, Inc. | A warp knit having an excellent touch, and a process of preparing the same |
| KR100608485B1 (en) * | 2004-12-31 | 2006-08-02 | 주식회사 효성 | Highly wipeable fabric |
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