KR960010797A - 분체 도료용 결합제로서의 불포화 폴리에스테르우레탄 아크릴레이트 - Google Patents

분체 도료용 결합제로서의 불포화 폴리에스테르우레탄 아크릴레이트 Download PDF

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KR960010797A
KR960010797A KR1019950029938A KR19950029938A KR960010797A KR 960010797 A KR960010797 A KR 960010797A KR 1019950029938 A KR1019950029938 A KR 1019950029938A KR 19950029938 A KR19950029938 A KR 19950029938A KR 960010797 A KR960010797 A KR 960010797A
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binder
acrylate
meth
component
acid
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KR100392721B1 (ko
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브린되프케 게르하르트
핑크 디트마르
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칼-헤르만 마이어-둘호이어·베른하르트 엠. 베크
훽스트 아크티엔게젤샤프트
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03—Powdery paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2150/00—Compositions for coatings
    • C08G2150/20—Compositions for powder coatings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/92—Polyurethane having terminal ethylenic unsaturation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

용융 온도가 35 내지 180℃인 고형의 불포화 폴리에스테르 우레탄 아크릴레이트를 포함하는 분체 도료용 결합제에 대해 기술하였다.

Description

분체 도료용 결합제로서의 불포화 폴리에스테르우레탄 아크릴레이트
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 용융 온도가 35 내지 180℃인 고형의 불포화 폴리에스테르 우레탄 아크릴레이트를 포함하는 분체 도료용 결합제.
  2. 제1항에 있어서, 하이드록실 함유 불포화 폴리에스테르 (A), 폴리이소시아네이트(B) 및 하이드록시알킬(메트) 아크릴레이트(C)를 반응시킴으로써 제조할 수 있는 결합체.
  3. 제1항에 있어서, 성분(A)가 불포화 디카복실산, 이의 무수물 또는 불포화 디카복실산과 이의 무수물과의 혼합물을, 경우에 따라, 포화 카복실산 및 다가 알콜과 축합시킴으로써 수득할 수 있는 결합제.
  4. 제1항에 있어서, 성분(A)가, 하이드록실가가 10 내지 200㎎ KOH/g이고 산가가 2 내지 60㎎ KOH/g이며 점도가 100,000mPa.s 미만이고 알켄 그룹의 함량이 2 내지 20중량%이며 용융 온도가 50 내지 130℃인 결합제.
  5. 제1항에 있어서, 불포화 폴리에스테르〔성분(A)〕가 말레산 및 푸마르산을 포함하는 하나 이상의 불포화 디카복실산을 사용하여 제조되는 결합제.
  6. 제1항에 있어서, 불포화 폴리에스테르〔성분(A)〕가 네오펜틸글리콜, 에틸렌 글리콜, 디에틸렌 글리콜, 트리메틸을 프로판 및 글리세롤을 포함하는 하나 이상의 다가 알콜을 사용하여 제조되는 결합체.
  7. 제1항에 있어서, 불포화 폴리에스테르〔성분(A)〕가 테레프탈산 및 이소프탈산을 포함하는 하나 이상의 포화 디카복실산을 사용하여 제조되는 결합제.
  8. 제1항에 있어서, 이소포론 디이소시아네이트, 테트라메틸크실릴렌 디이소시아네이트, 디페닐메탄 디이소시아네이트, 디사이클로 헥실메탄 디이소시아네이트, 톨릴렌 디이소시아네이트, 이소시아네이트 함유 이량체(우레트디온) 및 상량체(이소시아누레이트)로 이루어진 그룹으로부터 선택된 하나 이상의 폴리이소시아네이트가 성분(B)로서 사용되는 결합제.
  9. 제1항에 있어서, 하이드록시에틸 아크릴레이트, 하이드록시 프로필 아크릴레이트, 하이드록시부틸 아크릴레이트, 트리메틸올프로판 디아크릴레이트, 펜타에리트리톨 트리아크릴레이트, 하이드록시에틸 (메트)아크릴레이트, 하이드록시프로필 (메트)아크릴레이트, 하이드록시부틸 (메틸)아크릴레이트, 트리메틸올프로판 디(메트)아크릴레이트, 펜타에리트리톨 트리(메트)아크릴레이트, 이들 (메트)아크릴레이트와 ε-카프롤락톤과의 반응 생성물 및 (메트)아크릴산과 에폭사이드 함유 화합물과의 반응 생성물로 이루어진 그룹으로부터 선택된 하나 이상의 화합물이 성분(C)로서 사용되는 결합제.
  10. 제1항에 있어서, 하나 이상의 광개시제를, 분체 도료의 중량을 기준으로 하여, 0.1 내지 10%의 양으로 추가로 함유하는 결합제.
  11. 열 경화되거나, 자외선 또는 전자빔의 조사에 의해 경화되는 분체 도료에서의 제1항에 따르는 결합제의 용도.
  12. 기재를 적외선 조사시킴으로써 경화시키기 전에 용융되는 분체 도료에서의 제1항에 따르는 결합제의 용도.
  13. 목재, 유리, 플라스틱, 금속, 종이 피복용 분체 도료에서의 제1항에 따르는 결합제의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950029938A 1994-09-14 1995-09-14 분말도료용결합제로서의불포화폴리에스테르우레탄아크릴레이트및이를포함하는분말도료 Expired - Fee Related KR100392721B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4432644A DE4432644A1 (de) 1994-09-14 1994-09-14 Ungesättigte Polyesterurethanacrylate als Bindemittel für Pulverlacke
DEP4432644.0 1994-09-14

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KR960010797A true KR960010797A (ko) 1996-04-20
KR100392721B1 KR100392721B1 (ko) 2003-12-24

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US (1) US6284321B1 (ko)
EP (1) EP0702040B1 (ko)
JP (1) JPH08176471A (ko)
KR (1) KR100392721B1 (ko)
AT (1) ATE191227T1 (ko)
BR (1) BR9504009A (ko)
CA (1) CA2157657A1 (ko)
DE (2) DE4432644A1 (ko)
DK (1) DK0702040T3 (ko)
ES (1) ES2144079T3 (ko)
NZ (1) NZ272990A (ko)
PT (1) PT702040E (ko)
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EP0702040B1 (de) 2000-03-29
JPH08176471A (ja) 1996-07-09
BR9504009A (pt) 1996-09-24
DK0702040T3 (da) 2000-07-10
ATE191227T1 (de) 2000-04-15
NZ272990A (en) 1996-05-28
PT702040E (pt) 2000-07-31
KR100392721B1 (ko) 2003-12-24
TW495541B (en) 2002-07-21
DE59508084D1 (de) 2000-05-04
CA2157657A1 (en) 1996-03-15
ES2144079T3 (es) 2000-06-01
EP0702040A3 (ko) 1996-05-01
DE4432644A1 (de) 1996-03-21
US6284321B1 (en) 2001-09-04
EP0702040A2 (de) 1996-03-20

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