KR960010896A - 강선의 패턴팅 및 황동 도금 방법 - Google Patents

강선의 패턴팅 및 황동 도금 방법 Download PDF

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KR960010896A
KR960010896A KR1019950029930A KR19950029930A KR960010896A KR 960010896 A KR960010896 A KR 960010896A KR 1019950029930 A KR1019950029930 A KR 1019950029930A KR 19950029930 A KR19950029930 A KR 19950029930A KR 960010896 A KR960010896 A KR 960010896A
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steel wire
brass
molten mixture
seconds
coated
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KR100348229B1 (ko
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워만 바그와트 어낸드
프랭클린 리겐바치 에디
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캐쓸린 엠, 이스터링
더 굿이어 타이어 앤드 러버 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26—After-treatment
    • C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
    • C23C2/29—Cooling or quenching
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B1/00—Constructional features of ropes or cables
    • D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
    • D07B1/0606—Reinforcing cords for rubber or plastic articles
    • D07B1/0666—Reinforcing cords for rubber or plastic articles the wires being characterised by an anti-corrosive or adhesion promoting coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/02—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
    • B05C11/023—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface
    • B05C11/025—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface with an essentially cylindrical body, e.g. roll or rod
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/007—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
    • B60C9/0007—Reinforcements made of metallic elements, e.g. cords, yarns, filaments or fibres made from metal
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14—Removing excess of molten coatings; Controlling or regulating the coating thickness
    • C23C2/22—Removing excess of molten coatings; Controlling or regulating the coating thickness by rubbing, e.g. using knives, e.g. rubbing solids
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36—Elongated material
    • C23C2/38—Wires; Tubes
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B1/00—Constructional features of ropes or cables
    • D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
    • D07B1/0606—Reinforcing cords for rubber or plastic articles
    • D07B1/066—Reinforcing cords for rubber or plastic articles the wires being made from special alloy or special steel composition
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B2205/00—Rope or cable materials
    • D07B2205/30—Inorganic materials
    • D07B2205/3021—Metals
    • D07B2205/3025—Steel
    • D07B2205/3035—Pearlite
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B2205/00—Rope or cable materials
    • D07B2205/30—Inorganic materials
    • D07B2205/3021—Metals
    • D07B2205/3085—Alloys, i.e. non ferrous
    • D07B2205/3089—Brass, i.e. copper (Cu) and zinc (Zn) alloys

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  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Thermal Sciences (AREA)
  • Ropes Or Cables (AREA)
  • Coating With Molten Metal (AREA)
  • Chemically Coating (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

타이어와 같은 고무제품을 강화시키는데는 황동으로 코팅된 강선을 사용하는 것이 바람직하다. 상기 강선에 요구되는 높은 인장력 및 인성을 부가하기 위해서는 강선을 패턴팅해야 한다. 패턴팅 및 황동도금은 종래처럼 개별적인 단계를 거쳐 수행된다. 본 발명은 하기의 단계(a) 내지 (d)를 포함하는, 강선을 패턴팅시키는 동시에 황동 도금을 시키는 방법에 관한 것이다: (a)강선을 구리 및 아연의 용융 혼합물에 계속 통과시켜 황동 코팅을 입히고(이때 상기 용융 혼합물은 약 930℃ 및 1100℃ 이내의 온도에서 유지되고, 상기 강선의 상기 용융 혼합물에서의 체류시간은 강철이 오스테나이트화될 수 있기에 충분한 시간인 약 6초 내지 약 15초이다); (b)오스테나이트화된 강선을 용융 혼합물로부터 유출시키면서 과량의 황동을 계속 제거하여 황동 코팅 중량이 강선 1㎏당 황동 약 2 내지 8g 이내인 황동으로 코팅된 강선을 수득하고; (c)상기 황동으로 코팅된 오스테나이트화된 강선을 오스테나이트로부터 펄라이트(pearlite)의 전이가 일어날때까지 약 500 내지 650℃ 이내의 담금 온도로 냉각시키고; (d)패터팅된 황동 도금된 강선을 주위온도로 추가로 냉각시킨다.

Description

강선의 패턴팅 및 황동 도금 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. (a)강선을 구리 및 아연의 용융 혼합물에 계속 통과시켜 황동 코팅을 입히는 단계(이때, 상기 용융 혼합물은 약 930℃ 및 1100℃이내의 온도에서 유지되고, 상기 강선의 상기 용융 혼합물에서의 체류시간은 강철이 오스테나이트화될 수 있기에 충분한 시간인 약 6초 내지 약 15초이다); (b)오스테나이트화된 강선을 용융 혼합물로부터 유출시키면서 과량의 황동을 계속 제거하여 황동 코팅 중량이 강선 1㎏당 황동 약 2 내지 8g이내인 황동으로 코팅된 강선을 수득하는 단계; (c)상기 황동으로 코팅된 오스테나이트화된 강선을 오스테나이트로부터 펄라이트(pearlite)로의 전이가 일어날때까지 불활성 가스 대기 하에서 약 500 내지 650℃이내의 담금 온도로 냉각시키는 단계; 및 (d)패턴팅된 황동 도금된 강선을 주위온도로 추가로 냉각시키는 단계를 특징으로 하는, 강선을 패턴팅시키는 동시에 황동 도금을 시키는 방법.
  2. 제1항에 있어서, 상기 용융 혼합물이 약 60 내지 약 80중량%의 구리 및 약 20 내지 약 40중량%의 아연을 함유하고; 상기 용융 혼합물이 약 950℃ 내지 1025℃내의 온도에서 유지되며; 상기 강선이 용융 혼합물내에서 약 7초 내지 약 10초의 체류시간을 가짐을 특징으로 하는 방법.
  3. 제2항에 있어서, 단계(b)에서 과량의 황동을 오스테나이트화된 강선으로부터 제거시켜 강선 1㎏당 3 내지 4g의 황동 코팅 중량을 갖는 황동으로 코팅된 강선을 수득함을 특징으로 하는 방법.
  4. 제3항에 있어서, 상기 용융 혼합물이 약 62중량% 내지 약 70중량%의 구리 및 약 30중량% 및 약 38중량%의 아연을 함유하고; 상기 용융 혼합물을 약 960 내지 약 980℃의 범위 이내의 온도에서 유지하고; 단계(c)에서 사용된 담금 온도가 약 520 내지 약 600℃ 이내임을 특징으로 하는 방법.
  5. 제3항에 있어서, 상기 강선을 단계(a)에서 용융 혼합물에 통과시키기 전에 초음파 세척법으로 세척하고; 단계(c)에서 사용되는 담금 온도가 약 530 내지 약 550℃이고; 단계(c)에서 오스테나이트로부터 펄라이트로의 전이가 약 0.5초 내지 약 4초 이내에 일어남을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950029930A 1994-09-15 1995-09-14 강선의패턴팅및황동도금방법 Expired - Fee Related KR100348229B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/306290 1994-09-15
US08/306,290 US5437748A (en) 1994-09-15 1994-09-15 Process for patenting and brass plating steel wire
US08/306,290 1994-09-15

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KR960010896A true KR960010896A (ko) 1996-04-20
KR100348229B1 KR100348229B1 (ko) 2002-11-30

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US (1) US5437748A (ko)
EP (1) EP0707090B1 (ko)
JP (1) JPH08100249A (ko)
KR (1) KR100348229B1 (ko)
BR (1) BR9504001A (ko)
CA (1) CA2135031A1 (ko)
DE (1) DE69506361T2 (ko)
ES (1) ES2126837T3 (ko)
TR (1) TR199501096A2 (ko)

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FR2711149A1 (fr) 1993-10-15 1995-04-21 Michelin & Cie Fil en acier inoxydable pour carcasse d'enveloppe de pneumatique.
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US6137060A (en) 1997-05-02 2000-10-24 General Science And Technology Corp Multifilament drawn radiopaque highly elastic cables and methods of making the same
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US6215073B1 (en) 1997-05-02 2001-04-10 General Science And Technology Corp Multifilament nickel-titanium alloy drawn superelastic wire
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EP0885975A1 (fr) * 1997-06-16 1998-12-23 M3D Société Anonyme Procédé de traitement thermique en continu d'un fil ou ruban métallique
EP1365064B1 (en) * 2001-02-21 2016-06-15 Bridgestone Corporation Steel wire and steel cord for reinforcing rubber article, and tire
US20040025987A1 (en) * 2002-05-31 2004-02-12 Bhagwat Anand W. High carbon steel wire with bainitic structure for spring and other cold-formed applications
US20090007997A1 (en) * 2007-07-05 2009-01-08 Thomas Wilson Tyl Methods and Systems for Preventing Iron Oxide Formulation and Decarburization During Steel Tempering
EP2360286A1 (en) 2010-02-15 2011-08-24 Bogumil Miklasz The method of production a coated wire
EP2758554A1 (en) * 2011-09-20 2014-07-30 NV Bekaert SA Quenched and partitioned high-carbon steel wire
DE102011114992B4 (de) * 2011-10-06 2016-05-19 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zum Herstellen eines gehärteten Stahlbauteils
CN102534629A (zh) * 2011-12-21 2012-07-04 南京工程学院 节能环保钢帘线热镀铜锌合金及其热处理生产工艺
CN102605308A (zh) * 2012-04-19 2012-07-25 南京工程学院 钢帘线直接热镀铜锌合金环保生产工艺及装置
CN104451505B (zh) * 2014-10-30 2017-02-15 江苏兴达钢帘线股份有限公司 一种珠光体钢丝的镀黄铜工艺
US20250269689A1 (en) * 2024-02-27 2025-08-28 The Goodyear Tire & Rubber Company Tire reinforced by metal cords

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JPS6046359A (ja) * 1983-08-22 1985-03-13 Kawasaki Steel Corp ステンレス鋼板の表面処理方法
GB8601986D0 (en) * 1986-01-28 1986-03-05 Bekaert Sa Nv Steel wire
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CH675257A5 (ko) * 1988-02-09 1990-09-14 Battelle Memorial Institute
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020070228A (ko) * 2002-08-03 2002-09-05 박영관 인라인스케이트와 스케이트보드의 속도조절장치

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DE69506361D1 (de) 1999-01-14
JPH08100249A (ja) 1996-04-16
CA2135031A1 (en) 1996-03-16
EP0707090A1 (en) 1996-04-17
KR100348229B1 (ko) 2002-11-30
US5437748A (en) 1995-08-01
ES2126837T3 (es) 1999-04-01
BR9504001A (pt) 1996-09-24
EP0707090B1 (en) 1998-12-02
TR199501096A2 (tr) 1996-06-21
DE69506361T2 (de) 1999-06-17

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