KR960037663A - 디히드로피리다지논과 피리다지논 화합물, 이를 포함하는 조성물 및 이를 이용한 균 방제 방법 - Google Patents

디히드로피리다지논과 피리다지논 화합물, 이를 포함하는 조성물 및 이를 이용한 균 방제 방법 Download PDF

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KR960037663A
KR960037663A KR1019960011980A KR19960011980A KR960037663A KR 960037663 A KR960037663 A KR 960037663A KR 1019960011980 A KR1019960011980 A KR 1019960011980A KR 19960011980 A KR19960011980 A KR 19960011980A KR 960037663 A KR960037663 A KR 960037663A
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로스 로날드
마이클 자팩스 에드워드
하워드 사버 스티븐
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마크 에스. 에들러
롬 앤드 하스 캄파니
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    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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    • C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
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    • C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
    • C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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Abstract

디히드로피리다지논 및 피리다지논 화합물의 구조식(1)은 다음과 같다.
여기서, W는 CH3-O-A=C-CO(V)CH3이고 ; n은 0 혹은 1이며 ; A는 N 혹은 CH이고 ; V는 0 혹은 NH이고 ; Y는 O, S, NR1혹은 R6이고, R4및 R5를 갖는 상기 고리 결합은 단일 혹은 이중 결합이고, R4및 R5는 하이드로겐 및 치환되었거나 치환되지 않은 알킬과 아릴 그룹으로부터 독립적으로 선택된다. 상기 화합물 및 이를 함유한 조성물은 살균성 및 살충성을 갖는다.

Description

디히드로피리다지논과 피리다지논 화합물. 이를 포함하는 조성물 및 이를 이용한 균방제 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (20)

  1. 하기 구조식을 갖는 디히드로피리다지논 및 피리다지논 화합물
    단 여기서, W는 CH3-O-A=C-CO(V)CH3이며 ; A는 N 혹은 CH이며 ; V는 0 혹은 NH이며 ; Y는 O, S, NR1혹은 R6이고, R4및 R5를 갖는 고리 결합은 단일 혹은 이중 결합이고 ; n은 0 혹은 1이며 ; X는 하이드로겐(수소), 할로, (C1-C4)알킬, (C1-C4)알콕시 및 -HC=CH-CH=CH-에서 독립적으로 선택되어 나프틸 고리를 형성하고 ; R2는 하이드로겐, (C1-C12)알킬, (C1-C12)알콕시, 할로(C1-C12)알킬, 할로(C1-C12)알콕시, 히드록시(C1-C12)알킬, (C1-C12)알콕시(C1-C12)알킬, (C1-C12)알콕시카보닐(C1-C12)알킬, (C2-C8)알케닐, 할로(C2-C8)알케닐, (C3-C10)알키닐, 할로(C3-C10)알키닐, (C3-C7)시클로알킬, (C3-C7)시클로알킬(C1-C4)알킬, 에폭시(C1-C12)알킬, PO(OR1)2(C1-C12)알킬, R1S(O)2,(C1-C12)알킬, (R1)3Si(C1-C12)알킬, 아릴, 아릴옥시, (C1-C12)알킬, 아릴카보닐(C1-C12)알킬, 아랄킬, 아릴알케닐, 헤테로사이클릭, 헤테로사이클릭(C1-C12)알킬, N-모르폴리노(C1-C12)알킬, N-피페리디닐(C1-C12)알킬로부터 독립적으로 선택되고 ; R1은 (C1-C12)알킬, (C2-C8)알케닐 및 아릴로부터 독립적으로 선택되고 ; R4및 R5는 하이드로겐, 할로 (C1-C8)알킬, (C1-C8)알콕시, 시아노, 할로(C1-C12)알킬, (C2-C8)알케닐, (C3-C10)알키닐, 아릴 및 아랄킬로부터 독립적으로 선택되고 ; R6은 (C1-C12)알킬레닐 및 (C2-C12)알케니레닐로부터 독립적으로 선택된다.
  2. 제1항에 있어서, R4및 R5와 결합된 탄소사이의 고리 결합은 이중 결합임을 특징으로 하는 화합물.
  3. 제2항에 있어서, 상기 A는 CH임을 특징으로 하는 화합물.
  4. 제2항에 있어서, 상기 A는 N임을 특징으로 하는 화합물.
  5. 제3항에 있어서, 상기 V는 O임을 특징으로 하는 화합물.
  6. 제4항에 있어서, 상기 V는 O임을 특징으로 하는 화합물.
  7. 제5항에 있어서, 상기 R4및 R5는 하이드로겐이고,부분은 Y에 대한 메타이며, 그리고, R2는 (C1-C12)알킬, (C2-C8)알케닐, 할로(C1-C12)알킬, 및 할로(C2-C8)알케닐로부터 선택됨을 특징으로 하는 화합물.
  8. 제7항에 있어서, 상기 n=0이고, X는 하이드로겐이고 R2는 에틸, 프로필, 부틸, 비닐, 아릴, 클로로에틸, 플루오로에틸 및 치환된 벤질로 구성되는 그룹으로부터 선택됨을 특징으로 하는 화합물.
  9. 제8항에 있어서, 상기 R2은 할로치환된 벤질, (C1-C4)알킬치환된 벤질, 트리할로치환된 벤질 및 시아노 치환된 벤질로부터 선택됨을 특징으로 하는 화합물.
  10. 제9항에 있어서, 상기 R2는 2-클로로벤질, 3-클로로벤질, 4-클로로벤질, 2-플루오로벤질, 3-플루오로벤질, 4-플루오로벤질, 2-시아노벤질, 3-시아노벤질, 4-시아노벤질 및 4-트리플루오로메틸벤질로부터 선택됨을 특징으로 하는 화합물.
  11. 제6항에 있어서, 상기 R4및 R5는 하이드로겐이고, 상기부분은 Y에 대한 메타이고, R2는 (C1-C12)알킬, (C2-C8)알케닐, 할로(C1-C12)알킬, 할로(C2-C8)알케닐 및 아랄킬로부터 선택됨을 특징으로 하는 화합물.
  12. 제11항에 있어서, 상기 n=0이고, X는 하이드로겐이고 R2는 에틸, 프로필, 부틸, 비닐, 알릴, 클로로에틸, 플루오로에틸 및 치환된 벤질로 구성되는 그룹으로부터 선택됨을 특징으로 하는 화합물.
  13. 제12항에 있어서, 상기 R2는 할로치환된 벤질, (C1-C4)알킬치환된 벤질 및 트리할로치환된 벤질 및 시아노치환된 벤질로 구성되는 그룹으로부터 선택됨을 특징으로 하는 화합물.
  14. 제13항에 있어서, 상기 R2는 2-클로로벤질, 3-클로로벤질, 4-클로로벤질, 2-플루오로벤질, 3-플루오로벤질, 4-플루오로벤질, 2-시아노벤질, 3-시아노벤질, 4-시아노벤질 및 4-트리플루오로메틸벤질로부터 선택됨을 특징으로 하는 화합물.
  15. 농경학적으로 수용가능한 캐리어와 제1항의 화합물를 포함하고, 상기 혼합물에 대한 상기 화합물의 비가 99 : 1∼1 : 4인 식물 균을 방제하기 위한 살균 조성물.
  16. 제15항에 있어서, 상기 화합물에 대한 농학적으로 적합한 캐리어의 비는 10 : 1∼1:3임을 특징으로 하는 조성물.
  17. 제1항의 화합물을 헥타르당 0.005∼50kg의 비로 방제가 필요한 서식지에 적용함을 포함하는 식물 균방제 방법.
  18. 제17항에 있어서, 제1항의 화합물을 헥타르당 0.025∼10kg의 비로 사용함을 특징으로 하는 방법.
  19. 제1항에 화합물 헥타르당 0.005∼10kg의 비로 곤충의 거주지에 적용함을 포함하는 곤충 방제 방법.
  20. 제19항에 있어서, 상기 화합물을 헥타르당 0.01∼1kg의 비로 적용함을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019960011980A 1995-04-21 1996-04-19 디하이드로피리다지논과피리다지논화합물,이를포함하는조성물및이를이용한균방제방법 Expired - Fee Related KR100430695B1 (ko)

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US08/426,514 US5635494A (en) 1995-04-21 1995-04-21 Dihydropyridazinones and pyridazinones and their use as fungicides and insecticides

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CA2174296A1 (en) 1996-10-22
NZ286342A (en) 1998-04-27
CZ110696A3 (en) 1996-11-13
US5635494A (en) 1997-06-03
AR001667A1 (es) 1997-11-26
EP0738716A2 (en) 1996-10-23
HU9601035D0 (en) 1996-06-28
AU713334B2 (en) 1999-12-02
JPH08291147A (ja) 1996-11-05
AU5055096A (en) 1996-10-31
TW499294B (en) 2002-08-21
AR001656A1 (es) 1997-11-26
HUP9601035A2 (en) 1997-04-28
TR199600328A2 (tr) 1996-11-21
ZA963140B (en) 1996-10-21
CO4650121A1 (es) 1998-09-03
BR9602004A (pt) 1998-04-07
CN1124267C (zh) 2003-10-15
IL117865A0 (en) 1996-08-04
HUP9601035A3 (en) 1999-04-28
CN1143637A (zh) 1997-02-26
KR100430695B1 (ko) 2004-07-30
EP0738716A3 (en) 1998-12-30

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