LT2004094A - Katalizatorių sistemos, skirtos polikondensacijos reakcijoms - Google Patents
Katalizatorių sistemos, skirtos polikondensacijos reakcijomsInfo
- Publication number
- LT2004094A LT2004094A LT2004094A LT2004094A LT2004094A LT 2004094 A LT2004094 A LT 2004094A LT 2004094 A LT2004094 A LT 2004094A LT 2004094 A LT2004094 A LT 2004094A LT 2004094 A LT2004094 A LT 2004094A
- Authority
- LT
- Lithuania
- Prior art keywords
- catalyst systems
- polycondensation reactions
- polycondensation
- heterogeneous
- component
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000006068 polycondensation reaction Methods 0.000 title abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 229920001634 Copolyester Polymers 0.000 abstract 1
- 238000007792 addition Methods 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000002291 germanium compounds Chemical class 0.000 abstract 1
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- -1 polyethylene terephthalate Polymers 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract 1
- 239000005020 polyethylene terephthalate Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000007790 solid phase Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/826—Metals not provided for in groups C08G63/83 - C08G63/86
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/007—Mixed salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Artificial Filaments (AREA)
Abstract
Išradimas susijęs su naujomis katalizatorių sistemomis, skirtomis poliesterių, tinkamų, pavyzdžiui, polietileno terftalato ir jo kopolimerų gamybai, sintezei. Katalizatorių sistema pagal išradimą susideda iš stibio arba germanio junginio, heterogeninio katalizatoriaus komponento ir fosfato rūgšties arba fosfito rūgšties esterio, kaip stabilizatoriaus. Polikondensacijos greitis abejose skystos fazės ir kietos fazės (kietos būsenos) polikondensacijoje gali būti padidintas 30-100 procentų su mažais heterogeninio komponento pridėjimais. ą
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37967602P | 2002-05-09 | 2002-05-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| LT2004094A true LT2004094A (lt) | 2005-04-25 |
| LT5236B LT5236B (lt) | 2005-06-27 |
Family
ID=31715630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LT2004094A LT5236B (lt) | 2002-05-09 | 2004-10-19 | Katalizatorių sistemos, skirtos polikondensacijos reakcijoms |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20060079395A1 (lt) |
| EP (1) | EP1506248B1 (lt) |
| JP (1) | JP2005527697A (lt) |
| KR (1) | KR20050012236A (lt) |
| AT (1) | ATE344817T1 (lt) |
| AU (1) | AU2003282334A1 (lt) |
| CA (1) | CA2483897A1 (lt) |
| DE (1) | DE60309586T2 (lt) |
| LT (1) | LT5236B (lt) |
| MX (1) | MXPA04011110A (lt) |
| TW (1) | TW200528486A (lt) |
| WO (1) | WO2004014982A2 (lt) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE293652T1 (de) | 1999-12-10 | 2005-05-15 | Equipolymers Gmbh | Katalysatorsysteme für polykondensationsreaktionen |
| US6953768B2 (en) | 2002-11-26 | 2005-10-11 | Teck Cominco Metals Ltd. | Multi-component catalyst system for the polycondensation manufacture of polyesters |
| DE10339742B4 (de) * | 2003-08-28 | 2013-09-19 | Uhde Inventa-Fischer Gmbh | Partikuläres titanhaltiges Katalysatorsystem zur Herstellung hochmolekularer Polyester |
| CN100491441C (zh) * | 2006-11-10 | 2009-05-27 | 中国科学院山西煤炭化学研究所 | 一种制备脂肪族低聚碳酸酯多元醇的方法 |
| EP2287225A1 (en) | 2009-08-20 | 2011-02-23 | Saudi Basic Industries Corporation | Process for making polyethylene terephthalate |
| KR101256275B1 (ko) * | 2010-08-03 | 2013-04-18 | 롯데케미칼 주식회사 | 안티몬 아세테이트 촉매를 이용한 폴리에틸렌 이소프탈레이트 및 그 제조방법 |
| WO2012145065A1 (en) * | 2011-02-23 | 2012-10-26 | Cyclics Corporation | Methods for preparation of macrocyclic polyester oligomer via heterogeneous catalysis |
| EP2749584B1 (en) * | 2012-12-29 | 2015-07-15 | Clariant Finance (BVI) Limited | Process for Manufacturing Polyethylene Terephthalate |
| CN115873223B (zh) * | 2022-12-06 | 2024-08-27 | 大连理工大学 | 一种聚对苯二甲酸-碳酸-丁二醇酯的制备方法 |
| CN116284712B (zh) * | 2023-04-26 | 2025-08-29 | 绍兴翔宇绿色包装有限公司 | 一种环保聚酯薄膜及其制备方法 |
Family Cites Families (69)
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|---|---|---|---|---|
| US4080317A (en) * | 1970-10-23 | 1978-03-21 | Ciba-Geigy Ag | High molecular weight polycondensates from solid phase condensation |
| US3897525A (en) * | 1973-03-13 | 1975-07-29 | Passavant Werke | Apparatus for aerating liquids in a tank having wave attenuator |
| GB1421972A (en) * | 1973-07-16 | 1976-01-21 | Ici Ltd | Polyester catalysts |
| US4133800A (en) * | 1974-01-28 | 1979-01-09 | Imperial Chemical Industries Limited | Polyester production |
| DE2412216B2 (de) * | 1974-03-14 | 1979-12-13 | Davy International Ag, 6000 Frankfurt | Verfahren zur Herstellung von linearen Polyestern |
| DE2449162A1 (de) * | 1974-10-16 | 1976-04-22 | Basf Ag | Verfahren zur kontinuierlichen herstellung von linearen polyestern |
| US4122107A (en) | 1976-03-26 | 1978-10-24 | M&T Chemicals Inc. | Reaction products of specific antimony compounds with a carboxylate of zinc calcium or manganese and an alcohol or glycol |
| US4067856A (en) * | 1976-05-21 | 1978-01-10 | Stauffer Chemical Company | Process for preparing polyesters with a catalyst system comprising an antimony-containing poly-condensation catalyst and an ethylenically unsaturated compound |
| US4067857A (en) * | 1976-05-21 | 1978-01-10 | Stauffer Chemical Company | Polyester catalyst system comprising an antimony-containing polycondensation catalyst and an ethylenically unsaturated compound and process employing same |
| DE2626827C2 (de) * | 1976-06-15 | 1986-07-31 | Bayer Ag, 5090 Leverkusen | Stabilisierung von Polyethylenterephthalaten |
| US4130552A (en) * | 1976-10-05 | 1978-12-19 | Stauffer Chemical Company | Polyester catalyst system and process |
| JPS5946258B2 (ja) * | 1976-10-05 | 1984-11-12 | 帝人株式会社 | ポリエステルの製造方法 |
| US4077944A (en) * | 1977-02-28 | 1978-03-07 | Union Carbide Corporation | Catalytic production of polyesters |
| US4116942A (en) * | 1977-02-28 | 1978-09-26 | Union Carbide Corporation | Process for catalytic production of polyesters |
| US4499226A (en) * | 1981-03-20 | 1985-02-12 | The Goodyear Tire & Rubber Company | High clarity colorless polyesters |
| JPS58101021A (ja) * | 1981-12-12 | 1983-06-16 | Toyobo Co Ltd | 2軸延伸ポリエステルフイルム |
| US4361694A (en) * | 1981-12-31 | 1982-11-30 | Union Carbide Corporation | Coordination complexes as polyesterification catalysts |
| US4356299A (en) * | 1982-02-04 | 1982-10-26 | Rohm And Haas Company | Catalyst system for a polyethylene terephthalate polycondensation |
| US4424140A (en) * | 1982-06-03 | 1984-01-03 | Union Carbide Corporation | Stabilization of polycondensation catalysts |
| US4468489A (en) * | 1982-06-03 | 1984-08-28 | Union Carbide Corporation | Stabilization of polycondensation catalysts |
| DE3300315A1 (de) * | 1983-01-07 | 1984-07-12 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur herstellung von hellfarbigen polyestern unter verwendung von titankatalysatoren |
| US4501878A (en) | 1984-01-30 | 1985-02-26 | Eastman Kodak Company | Process for the preparation of high molecular weight polyesters |
| US4590259A (en) * | 1984-11-30 | 1986-05-20 | General Electric Company | High molecular weight linear polyesters and method for their preparation |
| US5225115A (en) * | 1988-12-21 | 1993-07-06 | Aluminum Company Of America | Bromide intercalated hydrotalcite for use as a flame retardant, smoke suppressant additive |
| US5008230A (en) * | 1989-05-22 | 1991-04-16 | Hoechst Celanese Corporation | Catalyst for preparing high clarity, colorless polyethylene terephthalate |
| US5166311A (en) * | 1989-05-22 | 1992-11-24 | Hoechst Celanese Corporation | Catalyst system and process for preparing high clarity, colorless polyethylene terephthalate |
| US5019640A (en) * | 1989-10-23 | 1991-05-28 | Hoechst Celanese Corporation | Producing a polyethylene terephthalate based polymer from a lower dialkyl ester of a dicarboxylic acid and a glycol |
| US5066766A (en) * | 1990-04-13 | 1991-11-19 | Eastman Kodak Company | Process for the preparation of poly(ester-carbonates) |
| US5247103A (en) * | 1990-09-20 | 1993-09-21 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for the preparation of cyclic ethers |
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| EP0517511B1 (en) * | 1991-06-03 | 1997-11-05 | Polyplastics Co. Ltd. | Process for the preparation of polyester, and its composition |
| US5260495A (en) * | 1991-08-23 | 1993-11-09 | Union Carbide Chemicals & Plastics Technology Corporation | Monoalkylene glycol production using highly selective monoalkylene glycol catalysts |
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| DE69413710T2 (de) * | 1993-12-14 | 1999-02-18 | Unichema Chemie B.V., Gouda | Herstellung von polyglycerol |
| DE4400300A1 (de) * | 1994-01-07 | 1995-07-13 | Akzo Nobel Nv | Verfahren zur Herstellung von film- und faserbildenden Polyestern und Copolyestern |
| ATE165795T1 (de) * | 1994-02-03 | 1998-05-15 | Chemson Polymer Additive | Basische schichtgitterverbindungen |
| US5378796A (en) * | 1994-02-09 | 1995-01-03 | Eastman Chemical Company | Process for preparing copolyesters |
| US5478796A (en) * | 1994-03-04 | 1995-12-26 | Rhone-Poulenc Agrochimie | Plant growth regulatory mixture comprising mepiquat and cyclanilide or other cyclopropylmalonic acid anilides |
| US5776424A (en) * | 1994-04-29 | 1998-07-07 | Aluminum Company Of America | Two powder synthesis of hydrotalcite and hydrotalcite-like compounds with monovalen inorganic anions |
| DE4432839A1 (de) * | 1994-09-15 | 1996-03-21 | Zimmer Ag | Verfahren zur Einstellung des Trübungsgrades von Ethylenterephthalat-Polymeren |
| IT1271309B (it) * | 1994-12-21 | 1997-05-27 | Enichem Spa | Catalizzatori di policondensazione per la sintesi di polietilene tereftalato |
| TW354305B (en) * | 1994-12-22 | 1999-03-11 | Eastman Chem Co | Production of particular polyesters using a novel catalyst system |
| DE19503053B4 (de) * | 1995-02-01 | 2005-08-18 | Zimmer Ag | Verfahren zur direkten Herstellung von Polyester-Verpackungen |
| US5608032A (en) | 1995-03-28 | 1997-03-04 | Industrial Technology Research Institute | Catalytic compositions for the proparation of poly(ethylene terephthalate) with attenuated yellow color |
| US5623047A (en) | 1995-03-28 | 1997-04-22 | Industrial Technology Research Institute | Catalytic compositions for the preparation of poly(ethylene terephthalate) with improved color |
| DE19513056B4 (de) * | 1995-04-07 | 2005-12-15 | Zimmer Ag | Titanhaltige Katalysatoren und Verfahren zur Herstellung von Polyester |
| JPH08283394A (ja) * | 1995-04-10 | 1996-10-29 | Mitsui Petrochem Ind Ltd | ポリエチレンテレフタレートの製造方法 |
| EP0745630A3 (en) * | 1995-06-01 | 1997-08-27 | Enichem Spa | Highly active catalyst system for the production of polyethylene terephthalate |
| US5596069A (en) * | 1995-06-08 | 1997-01-21 | E. I. Du Pont De Nemours And Company | Catalyst and process for producing catalyst |
| EP0861279A1 (en) * | 1995-11-13 | 1998-09-02 | Eastman Chemical Company | Thermally stable polyesters formed utilizing antimony compounds as catalysts |
| US5789528A (en) * | 1995-12-08 | 1998-08-04 | Akzo Nobel Nv | Process for the preparation of polyesters and copolyesters |
| DE19638549A1 (de) | 1996-09-20 | 1998-03-26 | Zimmer Ag | Zeolith-Katalysator zur Polykondensation von Polyester |
| TW391975B (en) * | 1996-11-01 | 2000-06-01 | Mitsui Chemicals Inc | Process for producing polyester |
| EP0856535B1 (en) * | 1997-02-03 | 2003-10-08 | Teijin Limited | Polyethylene-2,6-naphthalene dicarboxylate resin and preform and bottle molded thereof |
| US5789333A (en) * | 1997-03-05 | 1998-08-04 | Iowa State University Research Foundation, Inc. | Catalyst system comprising a first catalyst system tethered to a supported catalyst |
| US5902873A (en) * | 1997-10-17 | 1999-05-11 | General Electric Company | Catalyst composition for the preparation of polyesters, and related processes |
| FR2772024B1 (fr) * | 1997-12-05 | 2000-01-21 | Atochem Elf Sa | Utilisation de composes de structure de type hydrotalcite pour la preparation de composes carbonyles-beta-hydroxy et/ou alpha-beta-insatures |
| US6066714A (en) * | 1998-04-17 | 2000-05-23 | E. I. Du Pont De Nemours And Company | Titanium-containing catalyst composition and processes therefor and therewith |
| US6346070B1 (en) * | 1998-12-25 | 2002-02-12 | Mitsui Chemicals Inc | Catalyst for polyester production, process for producing polyester using the catalyst, polyester obtained by the process, and uses of the polyester |
| AU780389B2 (en) * | 1999-11-11 | 2005-03-17 | Mitsubishi Chemical Corporation | Polyester resin and its production process |
| ATE293652T1 (de) * | 1999-12-10 | 2005-05-15 | Equipolymers Gmbh | Katalysatorsysteme für polykondensationsreaktionen |
| US6372879B1 (en) * | 2000-01-07 | 2002-04-16 | Atofina Chemicals, Inc. | Polyester polycondensation with catalyst and a catalyst enhancer |
| WO2003004547A2 (en) * | 2001-07-02 | 2003-01-16 | Dow Global Technologies Inc. | Procedure for the manufacture of polyalkylene terephthalates |
| US6953768B2 (en) * | 2002-11-26 | 2005-10-11 | Teck Cominco Metals Ltd. | Multi-component catalyst system for the polycondensation manufacture of polyesters |
-
2003
- 2003-04-28 AT AT03776175T patent/ATE344817T1/de not_active IP Right Cessation
- 2003-04-28 DE DE60309586T patent/DE60309586T2/de not_active Expired - Fee Related
- 2003-04-28 EP EP03776175A patent/EP1506248B1/en not_active Expired - Lifetime
- 2003-04-28 WO PCT/US2003/013132 patent/WO2004014982A2/en not_active Ceased
- 2003-04-28 MX MXPA04011110A patent/MXPA04011110A/es unknown
- 2003-04-28 CA CA002483897A patent/CA2483897A1/en not_active Abandoned
- 2003-04-28 AU AU2003282334A patent/AU2003282334A1/en not_active Abandoned
- 2003-04-28 KR KR10-2004-7017943A patent/KR20050012236A/ko not_active Withdrawn
- 2003-04-28 JP JP2004527544A patent/JP2005527697A/ja active Pending
- 2003-04-28 US US10/513,183 patent/US20060079395A1/en not_active Abandoned
-
2004
- 2004-02-18 TW TW093103969A patent/TW200528486A/zh unknown
- 2004-10-19 LT LT2004094A patent/LT5236B/lt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1506248A2 (en) | 2005-02-16 |
| LT5236B (lt) | 2005-06-27 |
| AU2003282334A8 (en) | 2004-02-25 |
| ATE344817T1 (de) | 2006-11-15 |
| DE60309586T2 (de) | 2007-02-15 |
| DE60309586D1 (de) | 2006-12-21 |
| WO2004014982A2 (en) | 2004-02-19 |
| AU2003282334A1 (en) | 2004-02-25 |
| US20060079395A1 (en) | 2006-04-13 |
| MXPA04011110A (es) | 2005-07-14 |
| TW200528486A (en) | 2005-09-01 |
| EP1506248B1 (en) | 2006-11-08 |
| JP2005527697A (ja) | 2005-09-15 |
| CA2483897A1 (en) | 2004-02-19 |
| WO2004014982A3 (en) | 2004-04-08 |
| KR20050012236A (ko) | 2005-01-31 |
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