LTIP621A - Strech-spinned artificial filaments based on polycaprolactam and manufacture thereof - Google Patents
Strech-spinned artificial filaments based on polycaprolactam and manufacture thereofInfo
- Publication number
- LTIP621A LTIP621A LTIP621A LTIP621A LTIP621A LT IP621 A LTIP621 A LT IP621A LT IP621 A LTIP621 A LT IP621A LT IP621 A LTIP621 A LT IP621A LT IP621 A LTIP621 A LT IP621A
- Authority
- LT
- Lithuania
- Prior art keywords
- polycaprolactam
- acids
- strech
- spinned
- manufacture
- Prior art date
Links
- 229920002292 Nylon 6 Polymers 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000002253 acid Substances 0.000 abstract 4
- 150000007513 acids Chemical class 0.000 abstract 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 229910018509 Al—N Inorganic materials 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 abstract 1
- GLUUGHFHXGJENI-UHFFFAOYSA-N diethylenediamine Natural products C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 229960005141 piperazine Drugs 0.000 abstract 1
- 238000009987 spinning Methods 0.000 abstract 1
- -1 sulpho groups Chemical group 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Polyamides (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Pluoštas iš polikaprolaktamo santykinio klampumo RV nuo 2,0 iki 3,0(klampumas matuojamas ištirpinus 1 g. pluošto 100 ml 96 svorio % sieros rūgštyje) gaunamas@(a) Ekstruduojant daugiausiai iš polikaprolaktamo sudarytą lydalą per filjerą, taip suformuojant polikaprolaktamo gijas;@(b) Atvėsinant taip pagamintas gijas ir@(c) Atvėsintus filamentus nuimant mažiausiai [3600+1250,(3,0-RV)] m/min greičiu,@kadanaudotas verpimui polikaprolaktamas sintetinamas dalyvaujant mažiausiai vienai dikarboninei rūgščiai, parinktai iš šių organinių rūgščių grupių:@-C4-C10-alkandikarboninių rūgščių;@-C5-C8-cikloalkandikarboninių rūgščių;@-Benzol- ir naftalindikarboninių rūgščių, galinčių turėti iki 2 sulfo grupių, kurių molėkulėse karboksilinės grupės nėra gretimos;@-N-C1-C6-alki-N,N-di(C4-C10-alkankarboninių rūgščių) aminų;@-1,4-piperazin-di(C1-C10-alkankarboninių rūgščių), o taip pat šių siūlų panaudojimas pluoštinių medžiagų ir tekstilinių gaminių gamyboje.Polycaprolactam relative viscosity RV from 2.0 to 3.0 (viscosity measured by dissolving 1 g of fiber in 100 ml of 96% sulfuric acid) is obtained by @ (a) Extraction of a polycaprolactam-based melt mainly through the filament to form polycaprolactam strands; (b) Cooling of the Threads Made in this way and @ (c) At least [3600 + 1250, (3.0-RV)] m / min of cooled filaments used for spinning, polycaprolactam is synthesized in the presence of at least one dicarbonic acid selected from these organic acids @ - C4-C10-alkanecarboxylic acids; @ - C5-C8-cycloalkanecarboxylic acids; @ - Benzene- and naphthalic-carbonic acids capable of containing up to 2 sulpho groups in which the carboxylic groups are not adjacent to the @ @ - N-C1-C6- Al-N, N-di (C4-C10-alkanoic acids) amines; @ - 1,4-piperazine di (C1-C10-alkanoic acids), as well as the use of these yarns in fibrous materials and textiles products.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4218719A DE4218719A1 (en) | 1992-06-06 | 1992-06-06 | Fast-spun threads based on polycaprolactam and process for their production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| LTIP621A true LTIP621A (en) | 1994-04-25 |
| LT3089B LT3089B (en) | 1994-11-25 |
Family
ID=6460537
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LTIP621A LT3089B (en) | 1992-06-06 | 1993-06-04 | Strech-spinned artificial filaments based on polycaprolactam and manufacture thereof |
Country Status (16)
| Country | Link |
|---|---|
| EP (1) | EP0644959B1 (en) |
| JP (1) | JP3179105B2 (en) |
| KR (1) | KR100264615B1 (en) |
| CN (1) | CN1046322C (en) |
| AU (1) | AU4317093A (en) |
| BR (1) | BR9306503A (en) |
| CA (1) | CA2137375C (en) |
| DE (2) | DE4218719A1 (en) |
| EE (1) | EE03196B1 (en) |
| ES (1) | ES2081217T3 (en) |
| LT (1) | LT3089B (en) |
| LV (1) | LV10794B (en) |
| RU (1) | RU2114939C1 (en) |
| SK (1) | SK283532B6 (en) |
| TW (1) | TW229237B (en) |
| WO (1) | WO1993025736A1 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8915736D0 (en) * | 1989-07-10 | 1989-08-31 | Du Pont | Improvements to multifilament apparel yarns of nylon |
| DE19537614C3 (en) * | 1995-10-09 | 2003-10-02 | Inventa Ag | Polycaprolactam with a new chain control |
| BE1010331A3 (en) * | 1996-06-06 | 1998-06-02 | Dsm Nv | ACID dyeable fiber. |
| DE19631421C2 (en) * | 1996-08-06 | 2002-07-18 | Beiersdorf Ag | Antimicrobial wound dressings |
| DE19858365A1 (en) * | 1998-12-17 | 2000-06-21 | Inventa Ag | Process for the preparation of polyamide-6 for spinning purposes |
| KR100364894B1 (en) * | 2000-08-07 | 2002-12-16 | 주식회사 효성 | Manufacturing a modified polyamide 6 fibre of excellent dyeing and spinning property |
| KR20040033962A (en) * | 2002-10-16 | 2004-04-28 | 주식회사 효성 | Manufacturing method of reformed polyamide 6 having high contents of amine terminal |
| FR2857984B1 (en) * | 2003-07-25 | 2008-02-08 | Rhodia Performance Fibres | THREADS, FIBERS, ABRASION RESISTANT FILAMENTS |
| FR2864094B1 (en) * | 2003-12-19 | 2006-02-10 | Rhodia Industrial Yarns Ag | COMPOSITE MATERIALS COMPRISING A REINFORCING MATERIAL AND A THERMOPLASTIC MATRIX, PRECURSOR COMPOUND ARTICLE OF THESE MATERIALS AND PRODUCTS OBTAINED FROM THESE MATERIALS |
| RU2270280C1 (en) * | 2004-07-26 | 2006-02-20 | Волгоградский государственный технический университет (ВолгГТУ) | Composition for manufacturing polycaproamide thread |
| JP5723155B2 (en) * | 2008-09-03 | 2015-05-27 | 株式会社Nbcメッシュテック | Antiviral agent |
| CN102675628A (en) * | 2012-04-25 | 2012-09-19 | 广东新会美达锦纶股份有限公司 | High-speed spinning bright nylon 6 slice and manufacturing method thereof |
| EP3394330B1 (en) * | 2015-12-23 | 2021-03-31 | AdvanSix Resins & Chemicals LLC | Dual-terminated polyamide for high speed spinning application |
| CN108754663B (en) * | 2018-06-06 | 2020-12-29 | 温州大学 | A kind of high-speed spinning nylon 6 slice and preparation method thereof |
| KR20230121751A (en) | 2020-12-17 | 2023-08-21 | 바스프 에스이 | Selective depolymerization of polyamide 6 to produce caprolactam from mixtures of caprolactam-containing polymers and polyurethane-containing polymers, particularly polyurethane block copolymers. |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3386976A (en) | 1964-09-17 | 1968-06-04 | Gen Aniline & Film Corp | Alkylation of polyacrylate esters |
| US3386967A (en) * | 1965-01-19 | 1968-06-04 | Allied Chem | Polycaproamide having excess number of carboxyl end groups over amino end groups |
| EP0201189B2 (en) | 1985-04-22 | 1995-02-15 | BASF Corporation | Improved high speed process of making polyamide filaments |
| DE4019780A1 (en) | 1990-06-21 | 1992-01-02 | Basf Ag | METHOD FOR THE CONTINUOUS PRODUCTION OF POLYCAPROLACTAM WITH REGULATED AMINO END GROUP CONTENT |
-
1992
- 1992-06-06 DE DE4218719A patent/DE4218719A1/en not_active Withdrawn
-
1993
- 1993-05-25 RU RU95105019A patent/RU2114939C1/en not_active IP Right Cessation
- 1993-05-25 WO PCT/EP1993/001304 patent/WO1993025736A1/en not_active Ceased
- 1993-05-25 AU AU43170/93A patent/AU4317093A/en not_active Abandoned
- 1993-05-25 DE DE59301269T patent/DE59301269D1/en not_active Ceased
- 1993-05-25 ES ES93912778T patent/ES2081217T3/en not_active Expired - Lifetime
- 1993-05-25 JP JP50105894A patent/JP3179105B2/en not_active Ceased
- 1993-05-25 CA CA002137375A patent/CA2137375C/en not_active Expired - Fee Related
- 1993-05-25 BR BR9306503A patent/BR9306503A/en not_active IP Right Cessation
- 1993-05-25 EP EP93912778A patent/EP0644959B1/en not_active Expired - Lifetime
- 1993-05-25 SK SK1509-94A patent/SK283532B6/en unknown
- 1993-05-25 KR KR1019940704487A patent/KR100264615B1/en not_active Expired - Fee Related
- 1993-06-04 LT LTIP621A patent/LT3089B/en not_active IP Right Cessation
- 1993-06-04 LV LVP-93-477A patent/LV10794B/en unknown
- 1993-06-05 CN CN93108287A patent/CN1046322C/en not_active Expired - Fee Related
- 1993-06-05 TW TW082104500A patent/TW229237B/zh active
-
1994
- 1994-11-23 EE EE9400245A patent/EE03196B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| LT3089B (en) | 1994-11-25 |
| CA2137375C (en) | 1999-09-21 |
| KR100264615B1 (en) | 2000-09-01 |
| RU2114939C1 (en) | 1998-07-10 |
| EP0644959A1 (en) | 1995-03-29 |
| DE59301269D1 (en) | 1996-02-08 |
| CN1089670A (en) | 1994-07-20 |
| SK150994A3 (en) | 1995-05-10 |
| EE03196B1 (en) | 1999-06-15 |
| ES2081217T3 (en) | 1996-02-16 |
| RU95105019A (en) | 1996-12-27 |
| AU4317093A (en) | 1994-01-04 |
| JPH07506639A (en) | 1995-07-20 |
| CN1046322C (en) | 1999-11-10 |
| SK283532B6 (en) | 2003-09-11 |
| BR9306503A (en) | 1998-09-15 |
| JP3179105B2 (en) | 2001-06-25 |
| CA2137375A1 (en) | 1993-12-23 |
| DE4218719A1 (en) | 1993-12-09 |
| WO1993025736A1 (en) | 1993-12-23 |
| LV10794A (en) | 1995-08-20 |
| TW229237B (en) | 1994-09-01 |
| LV10794B (en) | 1995-12-20 |
| EP0644959B1 (en) | 1995-12-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| LTIP621A (en) | Strech-spinned artificial filaments based on polycaprolactam and manufacture thereof | |
| KR910014439A (en) | Manufacturing method of porous resin molding, microfiber and microfiber nonwoven fabric | |
| DE3280442D1 (en) | METHOD FOR PRODUCING POLYMER FIBERS WITH HIGH TENSILE STRENGTH AND HIGH MODULE. | |
| DE60000468D1 (en) | Process for making a pure cashmere textile article | |
| IL43990A (en) | Method of spining fiber using a fusion-melt polymer composition | |
| GB917889A (en) | Preparation of shaped articles by spinning | |
| BR0112533A (en) | Melt Spinning Process, Filaments, Article and Polyester Yarn Production Method | |
| ES343530A1 (en) | PROCEDURE FOR OBTAINING POLYAMIDIC FIBERS. | |
| FR2643089B1 (en) | POLYAMIDE-IMIDE-BASED YARNS AND PROCESS FOR OBTAINING SAME | |
| US3846532A (en) | Continuous spinning and stretching process of the production of polyamide-6 filaments | |
| GB1141394A (en) | Slubbed filaments and process for the preparation thereof | |
| DE69126914D1 (en) | Process for spinning synthetic fibers with high strength, high modulus and low shrinkage | |
| ES473931A1 (en) | Process for producing self-crimping polyamide yarns | |
| EP0359692A3 (en) | Solution spinning process | |
| JPS5716918A (en) | Preparation of modified synthetic fiber | |
| JP2515368B2 (en) | Method for producing yarn by melt spinning polyethylene terephthalate | |
| GB719489A (en) | Improvements in the manufacture of articles from superpolyamides | |
| US3137655A (en) | Optical brightening | |
| ATE35003T1 (en) | HIGH-STRENGTH SUPPLY THREADS FOR SEWING THREADS AND PROCESS FOR THEIR MANUFACTURE. | |
| GB931678A (en) | Improvements in and relating to the production of artificial threads of poly-gamma-methyl glutamate | |
| GB1145677A (en) | Heat stabilization of polyamides | |
| JPS5545834A (en) | Production of polyvinylidene fluoride fiber | |
| DE2344676A1 (en) | DUE TO CATIONIC COLORS, SYNTHETIC, LINEAR POLYCARBONIC ACID AMIDE can be colored | |
| GB1097495A (en) | Polyamide yarns and filaments | |
| JPS5593818A (en) | Production of mixed yarn |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM9A | Lapsed patents |
Effective date: 20060604 |