LU43887A1 - - Google Patents
Info
- Publication number
- LU43887A1 LU43887A1 LU43887DA LU43887A1 LU 43887 A1 LU43887 A1 LU 43887A1 LU 43887D A LU43887D A LU 43887DA LU 43887 A1 LU43887 A1 LU 43887A1
- Authority
- LU
- Luxembourg
- Prior art keywords
- methyl
- olefins
- metals
- butene
- catalyst
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 6
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 150000002739 metals Chemical class 0.000 abstract 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 abstract 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052770 Uranium Inorganic materials 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001299 aldehydes Chemical class 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- -1 butene-2 pentenes Chemical class 0.000 abstract 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 abstract 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000002825 nitriles Chemical class 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 abstract 1
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 abstract 1
- PVFYDPMTPBPRQA-UHFFFAOYSA-N 2-methylprop-2-enenitrile;prop-2-enenitrile Chemical compound C=CC#N.CC(=C)C#N PVFYDPMTPBPRQA-UHFFFAOYSA-N 0.000 abstract 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 abstract 1
- UZPWKTCMUADILM-UHFFFAOYSA-N 3-methylcyclohexene Chemical compound CC1CCCC=C1 UZPWKTCMUADILM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 150000004645 aluminates Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 229910000410 antimony oxide Inorganic materials 0.000 abstract 1
- 150000001642 boronic acid derivatives Chemical class 0.000 abstract 1
- 239000001273 butane Substances 0.000 abstract 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- ZXIJMRYMVAMXQP-UHFFFAOYSA-N cycloheptene Chemical compound C1CCC=CCC1 ZXIJMRYMVAMXQP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 abstract 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000001294 propane Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910010271 silicon carbide Inorganic materials 0.000 abstract 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of actinides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Olefins are oxidized to aldehydes or in the presence of ammonia to unsaturated nitriles using supported or unsupported antimony/uranium catalysts. If desired both nitriles and aldehydes may be produced simultaneously. The reactants used may comprise oxygen and an olefin having only 3 carbon atoms in a straight chain e.g. propylene, isobutylene or mixtures thereof. The olefins may be in admixture with paraffins e.g. ethane, propane, butane and pentane. A propylene-propane-oxygen mixture may constitute the feed gas. Examples are given which describe the preparation of achelein, acrylonitrile methacrylonitrile methachelein and methacrylic acid as main products and acetonitrile as by-product. Specifications 864,666, 867,438 and 876,446 are referred to.ALSO:The oxidative dehydrogenation of olefins to diolefins and aromatics is effected in the presence of supported or unsupported Sb/U catalysts. Specified olefins which may be dehydrogenated are butene-1, butene-2 pentenes 1 and 2, 2 methyl pentene-1, 3 methyl butene 1, 2 methyl butene 2, hexene-1, hexene-2, 4 methyl pentene 1, 3 : 4 dimethyl-pentene-1, 4-methyl pentene 2, heptene-1, octene-1, cyclopentene, cyclohexene, 3 methyl cyclohexene, and cycloheptene. The amount of oxygen used should be from 0.3-3.0 mols. per mol. of olefin. The gasous feed may additionally contain one or more paraffinic or naphthenic hydrocarbon or steam, carbon dioxide or nitrogen. Examples 17, 18 and 19 describe the conversion of butenes to butadiene. Specifications 864,666, 867,438 and 876,446 are referred to.ALSO:An oxidation catalyst comprises oxides of Sb and U such that the metals atomic ratio is within the range 1 : 50-99 : 1. The catalyst may be used per se or supported on silica, alumina, zirconia, "Alundum" (Registered Trade Mark), silicon carbide, alumina-silica or on stable phosphates, silicates, aluminates, borates and carbonates. The catalyst may be made by blending oxides of metals, dissolving metals in nitric acid or hydrolysing salts of metals. Regeneration may be effected by heating the catalyst in air. Examples are given. Specifications 864,666, 867,438 and 876,446 are referred to.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US20132962A | 1962-06-11 | 1962-06-11 | |
| US201279A US3251899A (en) | 1962-06-11 | 1962-06-11 | Process for the dehydrogenation of olefins |
| US247331A US3198750A (en) | 1962-12-26 | 1962-12-26 | Mixed antimony oxide-uranium oxide oxidation catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| LU43887A1 true LU43887A1 (en) | 1963-09-20 |
Family
ID=27394272
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LU43887D LU43887A1 (en) | 1962-06-11 | 1963-06-11 |
Country Status (13)
| Country | Link |
|---|---|
| BE (1) | BE633450A (en) |
| BR (1) | BR6349713D0 (en) |
| CA (1) | CA706421A (en) |
| CH (3) | CH455744A (en) |
| DE (1) | DE1205502B (en) |
| ES (1) | ES288881A1 (en) |
| FR (1) | FR1367589A (en) |
| GB (1) | GB971038A (en) |
| IT (1) | IT697511A (en) |
| LU (1) | LU43887A1 (en) |
| MX (1) | MX80662A (en) |
| NL (4) | NL6602740A (en) |
| SE (1) | SE306318B (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL135670C (en) | 1963-05-09 | |||
| DE59602040D1 (en) * | 1995-03-10 | 1999-07-08 | Basf Ag | Process of continuously operated heterogeneously catalyzed gas phase oxidation of propylene to acrolein, acrylic acid or a mixture thereof |
| DE19600955A1 (en) | 1996-01-12 | 1997-07-17 | Basf Ag | Process for the preparation of acrylic acid and its esters |
| DE19624674A1 (en) | 1996-06-20 | 1998-01-02 | Basf Ag | Process for the disposal of secondary components resulting from the production of acrylic acid or methacrylic acid |
| DE19902562A1 (en) | 1999-01-22 | 2000-07-27 | Basf Ag | Production of acrolein, useful as intermediate for glutardialdehyde, methionine, folic acid and acrylic acid, by catalytic oxidation of propene uses 2 consecutive reactors operating outside explosion range |
| DE19926082A1 (en) | 1999-06-08 | 2000-12-14 | Basf Ag | Process for the purification and production of acrylic acid or methacrylic acid |
| DE10220494A1 (en) | 2002-05-07 | 2003-11-20 | Basf Ag | Process for the preparation of an aqueous alkali acrylate solution |
| DE102008020688B3 (en) | 2008-04-24 | 2009-11-05 | Evonik Stockhausen Gmbh | Process for the preparation and purification of aqueous phases |
| CN120129670A (en) | 2022-10-28 | 2025-06-10 | 巴斯夫欧洲公司 | Process for producing propylene-derived chemicals of interest, particularly acrylates, from renewable sources of ethanol |
| EP4638400A1 (en) | 2022-12-20 | 2025-10-29 | Basf Se | Manufacture of an ethylene-derived chemical of interest, in particular acrylic acid, in combination with generation of heated steam |
| WO2025078362A1 (en) | 2023-10-09 | 2025-04-17 | Basf Se | Process for the manufacture of styrene acrylic copolymers having a renewably-sourced carbon content |
| WO2025224042A1 (en) | 2024-04-23 | 2025-10-30 | Basf Se | Process for the manufacture of renewably-sourced n-butanol or 2-ethylhexanol |
| WO2026002694A1 (en) | 2024-06-26 | 2026-01-02 | Basf Se | Manufacture of propylene-based chemical(s) from ethylene obtained from ethanol dehydration |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE415469C (en) * | 1923-05-06 | 1925-06-23 | Basf Ag | Process for the production of mixed catalysts |
| DE550933C (en) * | 1930-03-14 | 1932-05-23 | I G Farbenindustrie Akt Ges | Process for the production of catalysts by treating metals or metal compounds with phosphoric acid |
| DE693985C (en) * | 1934-01-12 | 1940-07-23 | I G Farbenindustrie Akt Ges | Process for carrying out catalytic reactions |
-
0
- CA CA706421D patent/CA706421A/en not_active Expired
- NL NL125238D patent/NL125238C/xx active
- NL NL293855D patent/NL293855A/xx unknown
- MX MX80662D patent/MX80662A/es unknown
- IT IT697511D patent/IT697511A/it unknown
- BE BE633450D patent/BE633450A/xx unknown
- NL NL123984D patent/NL123984C/xx active
-
1963
- 1963-05-23 GB GB2065063A patent/GB971038A/en not_active Expired
- 1963-06-07 DE DE1963ST020703 patent/DE1205502B/en active Pending
- 1963-06-07 BR BR14971363A patent/BR6349713D0/en unknown
- 1963-06-10 SE SE637963A patent/SE306318B/xx unknown
- 1963-06-10 ES ES288881D patent/ES288881A1/en not_active Expired
- 1963-06-10 FR FR937571A patent/FR1367589A/en not_active Expired
- 1963-06-11 CH CH502767A patent/CH455744A/en unknown
- 1963-06-11 LU LU43887D patent/LU43887A1/xx unknown
- 1963-06-11 CH CH726263A patent/CH440256A/en unknown
- 1963-06-11 CH CH502667A patent/CH462130A/en unknown
-
1966
- 1966-03-02 NL NL6602740A patent/NL6602740A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH440256A (en) | 1967-07-31 |
| FR1367589A (en) | 1964-07-24 |
| ES288881A1 (en) | 1963-11-16 |
| NL125238C (en) | |
| NL293855A (en) | |
| BR6349713D0 (en) | 1973-06-07 |
| CH455744A (en) | 1968-05-15 |
| SE306318B (en) | 1968-11-25 |
| MX80662A (en) | |
| DE1205502B (en) | 1965-11-25 |
| IT697511A (en) | |
| NL123984C (en) | |
| BE633450A (en) | |
| CH462130A (en) | 1968-09-15 |
| NL6602740A (en) | 1966-06-27 |
| GB971038A (en) | 1964-09-30 |
| CA706421A (en) | 1965-03-23 |
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