LU86277A1 - Procede de traitement catalytique - Google Patents

Procede de traitement catalytique Download PDF

Info

Publication number: LU86277A1
Authority: LU; Luxembourg
Prior art keywords: halogenating agent; chosen; temperature; mixtures; silicalite
Prior art date: 1986-01-29

Application number

LU86277A

Other languages

English (en)

French (fr)

Inventor

Guy L G Debras

Raymond M Cahen

De Georges E M J Clippeleir

Original Assignee

Labofina Sa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-01-29

Filing date

1986-01-29

Publication date

1987-09-03

1986-01-29 Application filed by Labofina Sa filed Critical Labofina Sa

1986-01-29 Priority to LU86277A priority Critical patent/LU86277A1/fr

1987-01-23 Priority to AT87870009T priority patent/ATE52996T1/de

1987-01-23 Priority to DE8787870009T priority patent/DE3762843D1/de

1987-01-23 Priority to EP87870009A priority patent/EP0240480B1/de

1987-01-23 Priority to ES87870009T priority patent/ES2015324B3/es

1987-01-28 Priority to CA000528343A priority patent/CA1274549A/en

1987-01-29 Priority to JP62017400A priority patent/JPH0756030B2/ja

1987-01-29 Priority to US07/008,877 priority patent/US4748291A/en

1987-09-03 Publication of LU86277A1 publication Critical patent/LU86277A1/fr

Links

238000000034 method Methods 0.000 title claims abstract description 58
230000003197 catalytic effect Effects 0.000 title claims abstract description 18
239000003054 catalyst Substances 0.000 claims abstract description 36
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
229930195733 hydrocarbon Natural products 0.000 claims abstract description 14
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 14
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 7
230000026030 halogenation Effects 0.000 claims abstract description 6
238000005658 halogenation reaction Methods 0.000 claims abstract description 6
230000006641 stabilisation Effects 0.000 claims abstract description 3
238000011105 stabilization Methods 0.000 claims abstract description 3
239000003795 chemical substances by application Substances 0.000 claims description 23
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 22
230000002140 halogenating effect Effects 0.000 claims description 22
239000000203 mixture Substances 0.000 claims description 13
229910052736 halogen Inorganic materials 0.000 claims description 11
150000002367 halogens Chemical class 0.000 claims description 11
229910052757 nitrogen Inorganic materials 0.000 claims description 11
-1 saturated chlorinated aliphatic organic compounds Chemical class 0.000 claims description 9
150000001336 alkenes Chemical class 0.000 claims description 8
150000001875 compounds Chemical class 0.000 claims description 7
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 6
239000007789 gas Substances 0.000 claims description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 claims description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
DIKBFYAXUHHXCS-UHFFFAOYSA-N bromoform Chemical compound BrC(Br)Br DIKBFYAXUHHXCS-UHFFFAOYSA-N 0.000 claims description 4
229910052799 carbon Inorganic materials 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 4
239000001301 oxygen Substances 0.000 claims description 4
229910052760 oxygen Inorganic materials 0.000 claims description 4
229920006395 saturated elastomer Polymers 0.000 claims description 4
238000005899 aromatization reaction Methods 0.000 claims description 3
229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
238000006317 isomerization reaction Methods 0.000 claims description 3
SMYMDRJWEFCCCI-UHFFFAOYSA-N trichloro(trichloromethoxy)methane Chemical compound ClC(Cl)(Cl)OC(Cl)(Cl)Cl SMYMDRJWEFCCCI-UHFFFAOYSA-N 0.000 claims description 3
SWWWRTFPFVHGEQ-UHFFFAOYSA-N 1,1,1,2,2-pentachloro-2-(1,1,2,2,2-pentachloroethoxy)ethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)OC(Cl)(Cl)C(Cl)(Cl)Cl SWWWRTFPFVHGEQ-UHFFFAOYSA-N 0.000 claims description 2
229950005228 bromoform Drugs 0.000 claims description 2
239000001569 carbon dioxide Substances 0.000 claims description 2
150000002170 ethers Chemical class 0.000 claims description 2
TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims description 2
RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
WMIYKQLTONQJES-UHFFFAOYSA-N hexafluoroethane Chemical compound FC(F)(F)C(F)(F)F WMIYKQLTONQJES-UHFFFAOYSA-N 0.000 claims 1
239000001257 hydrogen Substances 0.000 claims 1
229910052739 hydrogen Inorganic materials 0.000 claims 1
238000006384 oligomerization reaction Methods 0.000 claims 1
150000004812 organic fluorine compounds Chemical class 0.000 claims 1
HJUGFYREWKUQJT-UHFFFAOYSA-N tetrabromomethane Chemical compound BrC(Br)(Br)Br HJUGFYREWKUQJT-UHFFFAOYSA-N 0.000 claims 1
150000004760 silicates Chemical class 0.000 abstract 1
238000006243 chemical reaction Methods 0.000 description 14
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical class CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
229910052782 aluminium Inorganic materials 0.000 description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
239000000945 filler Substances 0.000 description 6
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
229910052801 chlorine Inorganic materials 0.000 description 5
239000000460 chlorine Substances 0.000 description 5
230000000694 effects Effects 0.000 description 5
238000006471 dimerization reaction Methods 0.000 description 4
239000010457 zeolite Substances 0.000 description 4
239000012535 impurity Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
238000002407 reforming Methods 0.000 description 3
230000008929 regeneration Effects 0.000 description 3
238000011069 regeneration method Methods 0.000 description 3
239000007858 starting material Substances 0.000 description 3
CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
238000001354 calcination Methods 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
239000011324 bead Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
235000013844 butane Nutrition 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
229910002026 crystalline silica Inorganic materials 0.000 description 1
239000000686 essence Substances 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 description 1
229910000042 hydrogen bromide Inorganic materials 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
238000009434 installation Methods 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
125000000962 organic group Chemical group 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
239000002245 particle Substances 0.000 description 1
BNIXVQGCZULYKV-UHFFFAOYSA-N pentachloroethane Chemical compound ClC(Cl)C(Cl)(Cl)Cl BNIXVQGCZULYKV-UHFFFAOYSA-N 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000007670 refining Methods 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
- C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
- C07C5/41—Catalytic processes
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/03—Catalysts comprising molecular sieves not having base-exchange properties
- C07C2529/035—Crystalline silica polymorphs, e.g. silicalites

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)

LU86277A 1986-01-29 1986-01-29 Procede de traitement catalytique LU86277A1 (fr)

Priority Applications (8)

Application Number	Priority Date	Filing Date	Title
LU86277A LU86277A1 (fr)	1986-01-29	1986-01-29	Procede de traitement catalytique
AT87870009T ATE52996T1 (de)	1986-01-29	1987-01-23	Verfahren zur behandlung von kohlenwasserstoffen mit durch halogenisierung stabilisierten katalysatoren aus der silicalit-oder tea- silikatreihe.
DE8787870009T DE3762843D1 (de)	1986-01-29	1987-01-23	Verfahren zur behandlung von kohlenwasserstoffen mit durch halogenisierung stabilisierten katalysatoren aus der silicalit-oder tea-silikatreihe.
EP87870009A EP0240480B1 (de)	1986-01-29	1987-01-23	Verfahren zur Behandlung von Kohlenwasserstoffen mit durch Halogenisierung stabilisierten Katalysatoren aus der Silicalit-oder TEA-Silikatreihe
ES87870009T ES2015324B3 (es)	1986-01-29	1987-01-23	Procedimiento para el tratamiento de hidrocarburos con catalizadores del tipo de la silicalita o tea-silicato estabilizados.
CA000528343A CA1274549A (en)	1986-01-29	1987-01-28	Catalytic treatment process
JP62017400A JPH0756030B2 (ja)	1986-01-29	1987-01-29	接触的処理方法
US07/008,877 US4748291A (en)	1986-01-29	1987-01-29	Catalytic treatment process

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
LU86277A LU86277A1 (fr)	1986-01-29	1986-01-29	Procede de traitement catalytique
LU86277		1986-01-29

Publications (1)

Publication Number	Publication Date
LU86277A1 true LU86277A1 (fr)	1987-09-03

Family

ID=19730626

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
LU86277A LU86277A1 (fr)	1986-01-29	1986-01-29	Procede de traitement catalytique

Country Status (8)

Country	Link
US (1)	US4748291A (de)
EP (1)	EP0240480B1 (de)
JP (1)	JPH0756030B2 (de)
AT (1)	ATE52996T1 (de)
CA (1)	CA1274549A (de)
DE (1)	DE3762843D1 (de)
ES (1)	ES2015324B3 (de)
LU (1)	LU86277A1 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4795846A (en) *	1987-10-01	1989-01-03	Uop Inc.	Process for the dehydrocyclization of aliphatic hydrocarbons
EP0758635B1 (de) *	1995-08-11	1999-11-17	Fina Research S.A.	Verfahren zur Isomerisierung von Olefinen
US6207042B1 (en)	1998-01-08	2001-03-27	Chevron Chemical Company Llc	Reforming using a bound halided zeolite catalyst
JP5985139B2 (ja) *	2010-03-26	2016-09-06	Ｊｘエネルギー株式会社	パラキシレンを製造するための、ベンゼンのアルキル化反応、或いは、トルエンのアルキル化反応又はトルエンの不均化反応に用いる触媒及びその製造方法、並びにそれを用いたパラキシレンの製造方法
JP5871633B2 (ja) *	2012-01-24	2016-03-01	関東電化工業株式会社	ビス（１，１−ジクロロ−３，３，３−トリフルオロプロピル）エーテルおよびその製造方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3702886A (en) *	1969-10-10	1972-11-14	Mobil Oil Corp	Crystalline zeolite zsm-5 and method of preparing the same
US3941871A (en) *	1973-11-02	1976-03-02	Mobil Oil Corporation	Crystalline silicates and method of preparing the same
US4061724A (en) *	1975-09-22	1977-12-06	Union Carbide Corporation	Crystalline silica
US4104294A (en) *	1977-11-10	1978-08-01	Union Carbide Corporation	Crystalline silicates and method for preparing same
NL8001342A (nl) *	1980-03-06	1980-07-31	Shell Int Research	Werkwijze voor het uitvoeren van katalytische omzettingen.
US4414423A (en) *	1981-09-25	1983-11-08	Chevron Research Company	Multistep oligomerization process
GB2118570B (en) *	1982-04-16	1986-02-05	Ici Plc	Hydrocarbon conversion
US4490568A (en) *	1982-04-30	1984-12-25	Union Carbide Corporation	Conversion of certain hydrocarbons using calcined TEA-silicate catalyst
US4721825A (en) *	1983-06-17	1988-01-26	Idemitsu Kosan Company Limited	Process for the production of xylene
US4599473A (en) *	1983-12-19	1986-07-08	Cosden Technology, Inc.	Process for para selective alkylation of aromatic hydrocarbons
US4681865A (en) *	1985-05-07	1987-07-21	Research Association For Utilization Of Light Oil	Catalyst for the production of aromatic hydrocarbons
LU86279A1 (fr) *	1986-01-29	1987-09-03	Labofina Sa	Procede de stabilisation de catalyseurs de type tea-silicate
LU86278A1 (fr) *	1986-01-29	1987-09-03	Labofina Sa	Procede de stabilisation de catalyseurs de type silicalite

1986
- 1986-01-29 LU LU86277A patent/LU86277A1/fr unknown
1987
- 1987-01-23 EP EP87870009A patent/EP0240480B1/de not_active Expired - Lifetime
- 1987-01-23 ES ES87870009T patent/ES2015324B3/es not_active Expired - Lifetime
- 1987-01-23 DE DE8787870009T patent/DE3762843D1/de not_active Expired - Fee Related
- 1987-01-23 AT AT87870009T patent/ATE52996T1/de not_active IP Right Cessation
- 1987-01-28 CA CA000528343A patent/CA1274549A/en not_active Expired - Lifetime
- 1987-01-29 JP JP62017400A patent/JPH0756030B2/ja not_active Expired - Fee Related
- 1987-01-29 US US07/008,877 patent/US4748291A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
EP0240480A2 (de)	1987-10-07
JPS62230886A (ja)	1987-10-09
DE3762843D1 (de)	1990-06-28
EP0240480A3 (en)	1988-07-06
ATE52996T1 (de)	1990-06-15
US4748291A (en)	1988-05-31
JPH0756030B2 (ja)	1995-06-14
EP0240480B1 (de)	1990-05-23
ES2015324B3 (es)	1990-08-16
CA1274549A (en)	1990-09-25

Publication	Publication Date	Title
EP0175399B1 (de)	1988-11-30	Verfahren zur Herstellung von Äthylen aus Äthanol
FR2482953A1 (fr)	1981-11-27	Procede d'hydrogenation selective d'une di-olefine dans un melange d'hydrocarbures renfermant au moins 4 atomes de carbone et contenant une olefine -a
FR2593513A1 (fr)	1987-07-31	Procede de production d'essence
EP0753562B1 (de)	1999-12-15	Verfahren zur Umsetzung von Synthesegas in flüssiger Phase
CA2797748C (fr)	2018-05-08	Procede de deshydratation et d'isomerisation d'alcools en c4 utilisant un solide amorphe a porosite adaptee
FR2792550A1 (fr)	2000-10-27	Catalyseur comprenant un element des groupes 8,9 et 10 presentant une bonne accessibilite et son utilisation dans un procede de deshydrogenation des paraffines
CA2180283C (fr)	2007-01-09	Procede de fabrication du difluoromethane
EP0240480B1 (de)	1990-05-23	Verfahren zur Behandlung von Kohlenwasserstoffen mit durch Halogenisierung stabilisierten Katalysatoren aus der Silicalit-oder TEA-Silikatreihe
FR2528033A1 (fr)	1983-12-09	Procede de traitement d'une charge d'isobutylene
EP0643992B1 (de)	1997-03-12	Katalysator für die Alkylierung eines C4-C5 Isoparaffins mit mindestens einem C3-C6 Olefin
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